CN104174660B - The zerolling method of flexibility - Google Patents
The zerolling method of flexibility Download PDFInfo
- Publication number
- CN104174660B CN104174660B CN201410342440.5A CN201410342440A CN104174660B CN 104174660 B CN104174660 B CN 104174660B CN 201410342440 A CN201410342440 A CN 201410342440A CN 104174660 B CN104174660 B CN 104174660B
- Authority
- CN
- China
- Prior art keywords
- temperature
- rolling
- steel
- heating furnace
- low
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Metal Rolling (AREA)
- Control Of Metal Rolling (AREA)
Abstract
本发明公开了一种柔性化的低温轧制方法,包括以下步骤:根据预设的不同级别钢种与临界温度的映射关系,确定当前待轧制的钢材在各轧制阶段所需的温度;根据确定出的各轧制阶段所需的温度,调整加热炉、粗轧机以及精轧机的参数;在根据所述钢材的屈服强度设定相应的轧制规程后,将所述钢材依次经所述加热炉、粗轧机以及精轧机中进行轧制。本柔性化的低温轧制方法一方面可降低轧制过程能耗,另一方面还可提高轧制效率,降低生产周期。
The invention discloses a flexible low-temperature rolling method, which comprises the following steps: according to the preset mapping relationship between different grades of steel and critical temperatures, determining the temperature required by the current steel to be rolled in each rolling stage; According to the determined temperature required for each rolling stage, adjust the parameters of the heating furnace, roughing mill and finishing mill; after setting the corresponding rolling schedule according to the yield strength of the steel, the steel is passed through the Rolling takes place in heating furnaces, roughing mills and finishing mills. On the one hand, the flexible low-temperature rolling method can reduce the energy consumption of the rolling process, on the other hand, it can also improve the rolling efficiency and reduce the production cycle.
Description
技术领域technical field
本发明涉及轧钢控制技术领域,尤其涉及一种柔性化的低温轧制方法。The invention relates to the technical field of steel rolling control, in particular to a flexible low-temperature rolling method.
背景技术Background technique
随着现代科学技术和经济建设的发展,大型化、连续化和集约化的钢铁生产很难满足用户对钢铁产品的多样化、个性化和优质化的要求。在热轧生产过程中,为了使轧制过程稳定,需要按照一定的轧制规程来安排生产。现有的热轧轧制规程需考虑钢种的加热温度、成分、强度等级以及尺寸等要求,按照加热温度从低温到高温、钢种强度从低等级到高等级的顺序,有序的安排轧制生产。因部分钢种加热温度及强度较高,需要安排大量的过渡材,缓慢地完成过渡,这样大大限制了生产的灵活性,延长了产品的轧制周期,不能有效的满足客户的需求,影响合同的完成。With the development of modern science and technology and economic construction, it is difficult for large-scale, continuous and intensive steel production to meet users' requirements for diversification, individualization and high-quality steel products. In the hot rolling production process, in order to make the rolling process stable, it is necessary to arrange production according to certain rolling procedures. The existing hot rolling procedures need to consider the heating temperature, composition, strength grade and size requirements of steel grades, and arrange the rolling in an orderly manner in the order of heating temperature from low temperature to high temperature and steel grade strength from low grade to high grade. production. Due to the high heating temperature and strength of some steel types, it is necessary to arrange a large number of transition materials to complete the transition slowly, which greatly limits the flexibility of production, prolongs the rolling cycle of the product, cannot effectively meet the needs of customers, and affects the contract the completion.
随着钢铁企业硬件设备的改善和轧制工艺的发展,柔性化的低温轧制技术能够解决上述矛盾。但是,现有的热轧生产技术,都是指在轧制过程中组织性能的柔性化。针对同一化学成分的钢种,通过轧后冷却方式的不同,来实现组织性能的不同。这种柔性化的生产只是从组织性能的方面进行柔性化考虑,并没有涉及到热轧整个轧制生产过程,同时现有的因为轧制温度较高,因此,需要安装大量的过渡材,使得生产周期长。With the improvement of hardware equipment in iron and steel enterprises and the development of rolling technology, flexible low-temperature rolling technology can solve the above contradictions. However, the existing hot rolling production technologies all refer to the flexibility of the structure and performance during the rolling process. For steel types with the same chemical composition, different cooling methods after rolling are used to achieve different microstructure and properties. This kind of flexible production is only considered from the perspective of organizational performance, and does not involve the entire rolling production process of hot rolling. At the same time, because the existing rolling temperature is high, it is necessary to install a large number of transition materials, so that The production cycle is long.
发明内容Contents of the invention
本发明的主要目的在于提供一种柔性化的低温轧制方法,旨在对热轧整个轧制生产过程进行柔性化的生产,同时提高轧制效率。The main purpose of the present invention is to provide a flexible low-temperature rolling method, aiming at flexible production of the entire rolling production process of hot rolling and improving rolling efficiency at the same time.
为实现上述目的,本发明提出一种柔性化的低温轧制方法,包括以下步骤:In order to achieve the above object, the present invention proposes a flexible low-temperature rolling method, comprising the following steps:
根据确定出的各轧制阶段所需的温度,调整加热炉、粗轧机以及精轧机的参数;Adjust the parameters of the heating furnace, roughing mill and finishing mill according to the determined temperature required for each rolling stage;
在根据所述钢材的屈服强度设定相应的轧制规程后,将所述钢材依次经所述加热炉、粗轧机以及精轧机中进行轧制。After the corresponding rolling schedule is set according to the yield strength of the steel, the steel is rolled sequentially through the heating furnace, the rough rolling mill and the finishing mill.
优选地,所述预设的不同级别钢种与临界温度的映射关系为:Preferably, the preset mapping relationship between different grades of steel grades and critical temperature is:
RH=Max[T(热脆温度),T(C固溶温度),T(Mn固溶温度),T(Nb固溶温度),T(Ti固溶温度),T(除鳞温度)];RH=Max[T (hot embrittlement temperature), T (C solid solution temperature), T (Mn solid solution temperature), T (Nb solid solution temperature), T (Ti solid solution temperature), T (descaler temperature)] ;
RT=Max[T(粗轧机能力校核),T(粗轧机的咬入温度),T(FT0+ΔT运输过程温降+ΔT除鳞温降)];RT=Max[T (capability check of roughing mill), T (bite temperature of roughing mill), T(FT0+ΔT temperature drop during transportation+ΔT descaling temperature drop)];
FT0=Max[T(FT7+ΔT轧制过程温降),T(精轧机能力校核),T(钢材再结晶温度)];FT0=Max[T(FT7+ΔT temperature drop during rolling), T(finishing mill capacity check), T(steel recrystallization temperature)];
FT7=Min[T(Ar3),T(NbC析出温度),T(TiC析出温度),T(TiN析出温度)];FT7=Min[T(Ar3), T(NbC precipitation temperature), T(TiC precipitation temperature), T(TiN precipitation temperature)];
CT=T(相变温度);CT = T (phase transition temperature);
其中,RH为所述加热炉的出炉温度,RT为所述粗轧机的出口温度,FT0为精轧机的入口温度,FT7为所述精轧机的出口温度,CT为所述卷取机的卷取温度,T(Ar3)为钢冷却时奥氏体中开始析出铁素体的临界温度。Wherein, RH is the exit temperature of the heating furnace, RT is the outlet temperature of the rough rolling mill, FT0 is the inlet temperature of the finishing mill, FT7 is the outlet temperature of the finishing mill, and CT is the coiling temperature of the coiler. Temperature, T(Ar3) is the critical temperature at which ferrite begins to precipitate in austenite when the steel is cooled.
优选地,所述根据钢材的屈服强度设定相应的轧制规程的步骤具体包括:Preferably, the step of setting a corresponding rolling schedule according to the yield strength of the steel specifically includes:
当钢材为低强度级别钢种,轧制规程为6~8块烫辊材,其余为低强度级别钢种;当钢材为中等强度级别钢种,轧制规程为6~8块烫辊材、2~4块低强度级别钢种,其余为中等强度级别钢种;当钢材为高强度级别钢种,轧制规程为6~8块烫辊材、2~4块低强度级别钢种、4~6块中等强度级别钢种,其余为高强度级别钢种,其中,低强度级别钢种为屈服强度180~300Mpa级之间;中等强度级别钢种为屈服强度300~500MPa级之间;高等强度级别钢种为屈服强度500MPa级以上。When the steel is low-strength grade steel, the rolling schedule is 6-8 pieces of hot-rolled steel, and the rest are low-strength grade steel; when the steel is medium-strength grade steel, the rolling schedule is 6-8 hot-rolled pieces, 2-4 pieces of low-strength steel grades, and the rest are medium-strength grade steel grades; when the steel is high-strength grade steel grades, the rolling procedure is 6-8 pieces of hot-rolled steel grades, 2-4 pieces of low-strength grade steel grades, 4 ~6 medium-strength grade steel grades, and the rest are high-strength grade steel grades, among which, the low-strength grade steel grades are between 180-300Mpa in yield strength; the medium-strength grade steel grades are between 300-500MPa in yield strength; The strength level of steel is above the yield strength of 500MPa.
优选地,在轧制过程中,低强度级别钢种的轧制工艺参数如下:在加热过程的总在炉时间控制在130~155min,加热炉内保持微正压10~12Pa,加热炉的预热段空燃比控制在1.0~1.1,预热时间为60~70min,加热炉的加热段空燃比保持在0.9~1.0,加热时间为40~50min,加热炉的均热段温度空燃比保持在1.0~1.1,温度控制在1140~1160℃,均热时间为30~35min;在粗轧轧制过程中,除鳞道次大于等于4,粗轧出口温度控制为1010~1020℃;精轧机的轧制速度为5~12m/s,终轧温度为830~840℃;卷取机的卷取温度为610~640℃。Preferably, during the rolling process, the rolling process parameters of low-strength steel grades are as follows: the total time in the furnace during the heating process is controlled at 130-155 minutes, the heating furnace maintains a slight positive pressure of 10-12 Pa, the pre-heating furnace The air-fuel ratio of the hot section is controlled at 1.0-1.1, the preheating time is 60-70 minutes, the air-fuel ratio of the heating section of the heating furnace is kept at 0.9-1.0, the heating time is 40-50 minutes, and the temperature of the soaking section of the heating furnace is kept at 1.0 ~1.1, the temperature is controlled at 1140~1160℃, and the soaking time is 30~35min; during the rough rolling process, the descaling passes are greater than or equal to 4, and the rough rolling exit temperature is controlled at 1010~1020℃; The rolling speed is 5-12m/s, the final rolling temperature is 830-840°C; the coiling temperature of the coiler is 610-640°C.
优选地,在轧制过程中,中等强度级别钢种的轧制工艺参数如下:在加热过程的总在炉时间控制在135~170min,加热炉内保持微正压10~12Pa,加热炉的预热段空燃比保持在1.1~1.2,预热时间为60~70min,加热炉的加热段空燃比保持在0.9~1.0,加热时间为50~60min,加热炉的均热段温度空燃比保持在1.0~1.1,温度控制在1150~1180℃,均热时间为25~40min;在粗轧轧制过程,除鳞道次大于或等于4,粗轧机的出口温度为1020~1030℃;精轧机的轧制速度为5~10m/s,终轧温度为840~850℃;卷取机的卷取温度为610~640℃。Preferably, during the rolling process, the rolling process parameters of medium-strength grade steel grades are as follows: the total time in the furnace during the heating process is controlled at 135-170 minutes, the heating furnace maintains a slight positive pressure of 10-12 Pa, the pre-heating furnace The air-fuel ratio of the hot section is kept at 1.1-1.2, the preheating time is 60-70 minutes, the air-fuel ratio of the heating section of the heating furnace is kept at 0.9-1.0, the heating time is 50-60 minutes, and the temperature of the soaking section of the heating furnace is kept at 1.0 ~1.1, the temperature is controlled at 1150~1180℃, and the soaking time is 25~40min; in the rough rolling process, the descaling pass is greater than or equal to 4, and the exit temperature of the rough rolling mill is 1020~1030℃; The rolling speed is 5-10m/s, the final rolling temperature is 840-850°C; the coiling temperature of the coiler is 610-640°C.
优选地,在轧制过程中,高强度级别钢种的轧制工艺参数如下:在加热过程的总在炉时间控制在160min~200min,加热炉内保持微正压10~12Pa,加热炉的预热段空燃比保持在1.0~1.1,预热时间为80~90min,加热炉的加热段空燃比保持在0.9~1.0,加热时间为50~60min,加热炉的均热段温度空燃比保持在1.1~1.2,温度控制在1170~1220℃,均热时间为30~50min;在粗轧轧制过程,除鳞道次大于或等于4,粗轧机的出口温度为1030~1060℃;精轧机的轧制速度为5~10m/s,终轧温度为850~860℃;卷取机的卷取温度为580~610℃。Preferably, during the rolling process, the rolling process parameters of high-strength grade steel grades are as follows: the total time in the furnace during the heating process is controlled at 160min-200min, the heating furnace maintains a slight positive pressure of 10-12Pa, the preheating furnace The air-fuel ratio of the hot section is kept at 1.0-1.1, the preheating time is 80-90 minutes, the air-fuel ratio of the heating section of the heating furnace is kept at 0.9-1.0, the heating time is 50-60 minutes, and the temperature of the soaking section of the heating furnace is kept at 1.1 ~1.2, the temperature is controlled at 1170~1220℃, and the soaking time is 30~50min; in the rough rolling process, the descaling pass is greater than or equal to 4, and the exit temperature of the rough rolling mill is 1030~1060℃; The rolling speed is 5-10m/s, the final rolling temperature is 850-860°C; the coiling temperature of the coiler is 580-610°C.
优选地,所述柔性化的低温轧制技术还包括以下步骤:Preferably, the flexible low-temperature rolling technology also includes the following steps:
在钢材的层流冷却过程中,采用边部遮挡技术以减少热轧带钢在冷却过程的边部温降。In the laminar flow cooling process of steel, the edge shielding technology is used to reduce the edge temperature drop of the hot-rolled strip during the cooling process.
优选地,所述柔性化的低温轧制技术还包括以下步骤:Preferably, the flexible low-temperature rolling technology also includes the following steps:
在粗轧过程采用保温罩以减少粗轧过程温降。The insulation cover is used in the rough rolling process to reduce the temperature drop in the rough rolling process.
本发明提出的柔性化的低温轧制方法,根据预设的不同级别钢种与临界温度的映射关系,确定当前待轧制的钢材在各轧制阶段所需的温度,从而保证在各轧制阶段所需的温度在临界温度之上,综合热轧各个钢种的生产特点,柔性化的组织生产,能够使轧制过程具有较大的灵活性与适应性,使之更加节能。另外,因为首先确定出钢材在各轧制阶段所需的临界温度,温度不需太高,因此,配套使用的过渡材的数量可大大减少,在一定程度上提高生产节奏,缩短了生产周期。The flexible low-temperature rolling method proposed by the present invention determines the temperature required by the steel to be rolled at each rolling stage according to the preset mapping relationship between different grades of steel and the critical temperature, thereby ensuring The temperature required in the stage is above the critical temperature, and the production characteristics of various steel types in hot rolling and the flexible organizational production can make the rolling process more flexible and adaptable, making it more energy-saving. In addition, because the critical temperature required for each rolling stage of the steel is determined first, the temperature does not need to be too high. Therefore, the number of supporting transition materials can be greatly reduced, which improves the production rhythm to a certain extent and shortens the production cycle.
附图说明Description of drawings
图1为本发明柔性化的低温轧制方法优选实施例的流程示意图。Fig. 1 is a flow diagram of a preferred embodiment of the flexible low-temperature rolling method of the present invention.
本发明目的的实现、功能特点及优点将结合实施例,参照附图做进一步说明。The realization of the purpose of the present invention, functional characteristics and advantages will be further described in conjunction with the embodiments and with reference to the accompanying drawings.
具体实施方式detailed description
应当理解,此处所描述的具体实施例仅仅用以解释本发明,并不用于限定本发明。It should be understood that the specific embodiments described here are only used to explain the present invention, not to limit the present invention.
参照图1,图1为本发明柔性化的低温轧制方法优选实施例的流程示意图。Referring to FIG. 1 , FIG. 1 is a schematic flowchart of a preferred embodiment of the flexible low-temperature rolling method of the present invention.
本发明提出的柔性化的低温轧制方法优选实施例。本实施例中,柔性化的低温轧制方法包括以下步骤:A preferred embodiment of the flexible low-temperature rolling method proposed by the present invention. In this embodiment, the flexible low-temperature rolling method includes the following steps:
步骤S10,根据预设的不同级别钢种与临界温度的映射关系,确定当前待轧制的钢材在各轧制阶段所需的温度,其中,轧制各阶段所需的温度均高于其所对应的临界温度;Step S10, according to the preset mapping relationship between different grades of steel and the critical temperature, determine the temperature required by the steel to be rolled in each rolling stage, wherein the temperature required by each rolling stage is higher than the required temperature. Corresponding critical temperature;
步骤S20,根据确定出的各轧制阶段所需的温度,调整加热炉、粗轧机以及精轧机的参数;Step S20, adjusting the parameters of the heating furnace, the rough rolling mill and the finishing mill according to the determined temperature required for each rolling stage;
步骤S30,在根据所述钢材的屈服强度设定相应的轧制规程后,将所述钢材依次经所述加热炉、粗轧机以及精轧机中进行轧制。Step S30, after setting the corresponding rolling schedule according to the yield strength of the steel, rolling the steel in the heating furnace, the rough rolling mill and the finish rolling mill in sequence.
具体地,对于FT7来说,其约束条件应大于Ar3,以确保精轧过程在奥氏体单相区轧制;对于FT0来说,其约束条件是一方面要确保FT7温度能够实现,另一方面也要确保精轧各道次温度在轧机负荷允许的范围之内。同样的,其它温度控制点,如RT2/RT4、CT以及RH等也都有相应的约束条件。Specifically, for FT7, the constraints should be greater than Ar3 to ensure that the finishing rolling process is rolled in the austenite single-phase region; for FT0, the constraints are to ensure that the temperature of FT7 can be achieved on the one hand, and the other On the one hand, it is also necessary to ensure that the temperature of each pass of the finish rolling is within the allowable range of the rolling mill load. Similarly, other temperature control points, such as RT2/RT4, CT, and RH, also have corresponding constraints.
本实施例中,预设的不同级别钢种与临界温度的映射关系为:In this embodiment, the preset mapping relationship between different grades of steel and critical temperature is:
加热炉的出炉温度RH通过以下公式计算:The furnace temperature RH is calculated by the following formula:
RH=Max[T(热脆温度),T(C固溶温度),T(Mn固溶温度),T(Nb固溶温度),T(Ti固溶温度),T(除鳞温度)];RH=Max[T (hot embrittlement temperature), T (C solid solution temperature), T (Mn solid solution temperature), T (Nb solid solution temperature), T (Ti solid solution temperature), T (descaler temperature)] ;
T(热脆温度)为某一钢种对应的热脆温度,T(C固溶温度)为某一钢种中C的固溶温度,T(Mn固溶温度)为某一钢种中Mn的固溶温度,T(Nb固溶温度)为某一钢种中Nb的固溶温度,T(Ti固溶温度)为某一钢种中Ti的固溶温度,T(除鳞温度)为某一钢种的钢材对应的除鳞温度;T (hot embrittlement temperature) is the hot embrittlement temperature corresponding to a certain steel grade, T (C solid solution temperature) is the solid solution temperature of C in a certain steel grade, T (Mn solid solution temperature) is the Mn solid solution temperature in a certain steel grade T (Nb solid solution temperature) is the solid solution temperature of Nb in a certain steel grade, T (Ti solid solution temperature) is the solid solution temperature of Ti in a certain steel grade, T (descaler temperature) is Descaling temperature corresponding to a certain steel grade;
粗轧机的出口温度RT通过以下公式计算:The exit temperature RT of the roughing mill is calculated by the following formula:
RT=Max[T(粗轧机能力校核),T(粗轧机的咬入温度),T(FT0+ΔT运输过程温降+ΔT除鳞温降)];RT=Max[T (capability check of roughing mill), T (bite temperature of roughing mill), T(FT0+ΔT temperature drop during transportation+ΔT descaling temperature drop)];
T(粗轧机能力校核)为粗轧机所能轧制的最低温度(因钢材温度过低,粗轧机会无法轧制钢材),ΔT除鳞温降为除鳞过程中钢材的温降值;T (capability check of roughing mill) is the lowest temperature that the roughing mill can roll (because the steel temperature is too low, the roughing machine cannot roll the steel), and ΔT descaling temperature drop is the temperature drop value of the steel during the descaling process;
精轧机的入口温度FT0通过以下公式计算:The inlet temperature FT0 of the finishing mill is calculated by the following formula:
FT0=Max[T(FT7+ΔT轧制过程温降),T(精轧机能力校核),T(钢材再结晶温度)];FT0=Max[T(FT7+ΔT temperature drop during rolling), T(finishing mill capacity check), T(steel recrystallization temperature)];
T(精轧机能力校核)为精轧机所能轧制的最低温度(因钢材温度过低,精轧机会无法轧制钢材),T(钢材再结晶温度)为某一钢种的钢材对应的再结晶温度;T (finishing mill capacity check) is the lowest temperature that the finishing mill can roll (because the steel temperature is too low, the finishing mill will not be able to roll the steel), T (steel recrystallization temperature) is the corresponding temperature of a certain steel type recrystallization temperature;
精轧机的出口温度通过以下公式计算:The exit temperature of the finishing mill is calculated by the following formula:
FT7=Min[T(Ar3),T(NbC析出温度),T(TiC析出温度),T(TiN析出温度)];FT7=Min[T(Ar3), T(NbC precipitation temperature), T(TiC precipitation temperature), T(TiN precipitation temperature)];
T(Ar3)为钢冷却时奥氏体中开始析出铁素体的临界温度,T(NbC析出温度)为某一钢种的钢材中NbC的析出温度,T(TiC析出温度)为某一钢种的钢材中TiC的析出温度,T(TiN析出温度)为某一钢种的钢材中TiN的析出温度;T(Ar3) is the critical temperature at which ferrite begins to precipitate in austenite when the steel is cooled, T(NbC precipitation temperature) is the precipitation temperature of NbC in a certain steel, and T(TiC precipitation temperature) is the temperature of a certain steel The precipitation temperature of TiC in the steel of a certain type of steel, T (TiN precipitation temperature) is the precipitation temperature of TiN in the steel of a certain steel type;
卷取机的卷取温度CT通过以下公式计算:The coiling temperature CT of the coiler is calculated by the following formula:
CT=T(相变温度);CT = T (phase transition temperature);
T(相变温度)某一钢种的钢材的相变温度。T (phase transition temperature) is the phase transition temperature of a certain type of steel.
粗轧机的出口温度确定后,可根据出口温度再相应设置粗轧机的入口温度。确定出某一种钢种在轧制各个阶段的临界温度后,只要保证轧制温度略高于临界温度即可,一般取20~30℃。此时,既有利于节能(因温度越低,各设备的功率越低),同时还保证了钢种的力学性能和各设备的轧制条件(因温度过低会不利于设备轧制)。After the outlet temperature of the roughing mill is determined, the inlet temperature of the roughing mill can be set accordingly according to the outlet temperature. After determining the critical temperature of a certain steel grade at each stage of rolling, it is sufficient to ensure that the rolling temperature is slightly higher than the critical temperature, generally 20-30°C. At this time, it is not only beneficial to energy saving (because the lower the temperature, the lower the power of each equipment), but also ensures the mechanical properties of the steel and the rolling conditions of each equipment (because the temperature is too low, it will not be conducive to equipment rolling).
具体地,步骤S30中根据钢材的屈服强度设定相应的轧制规程具体采用如下方法:当钢材为低强度级别钢种,轧制规程为6~8块烫辊材,其余为低强度级别钢种;当钢材为中等强度级别钢种,轧制规程为6~8块烫辊材、2~4块低强度级别钢种,其余为中等强度级别钢种;当钢材为高强度级别钢种,轧制规程为6~8块烫辊材、2~4块低强度级别钢种、4~6块中等强度级别钢种,其余为高强度级别钢种,其中,低强度级别钢种为屈服强度180~300Mpa级之间;中等强度级别钢种为屈服强度300~500MPa级之间;高等强度级别钢种为屈服强度500MPa级以上。Specifically, in step S30, the corresponding rolling schedule is set according to the yield strength of the steel. Specifically, the following method is used: when the steel is a low-strength grade steel, the rolling schedule is 6 to 8 pieces of hot-rolled steel, and the rest are low-strength grade steel. When the steel is a medium-strength grade steel, the rolling procedure is 6-8 pieces of hot-rolled steel, 2-4 low-strength grade steel, and the rest are medium-strength grade steel; when the steel is a high-strength grade steel, The rolling procedure is 6-8 pieces of hot roll materials, 2-4 pieces of low-strength steel grades, 4-6 pieces of medium-strength grade steel grades, and the rest are high-strength grade steel grades. Among them, the low-strength grade steel grades are yield strength Between 180 and 300Mpa; medium-strength steel grades have a yield strength of 300-500MPa; high-strength grade steels have a yield strength of 500MPa and above.
具体地,本实施例中给出三种钢材分别为低强度级别钢种、中等强度级别钢种和高强度级别钢种的三种轧制工艺参数。Specifically, in this embodiment, three kinds of rolling process parameters for the three kinds of steel materials, namely low-strength grade steel, medium-strength grade steel and high-strength grade steel, are given.
在轧制过程中,低强度级别钢种的轧制工艺参数如下:在加热过程的总在炉时间控制在130~155min,加热炉内保持微正压10~12Pa,加热炉的预热段空燃比控制在1.0~1.1,预热时间为60~70min,加热炉的加热段空燃比保持在0.9~1.0,加热时间为40~50min,加热炉的均热段温度空燃比保持在1.0~1.1,温度控制在1140~1160℃,均热时间为30~35min;在粗轧轧制过程中,除鳞道次大于等于4,粗轧出口温度控制为1010~1020℃;精轧机的轧制速度为5~12m/s,终轧温度为830~840℃;卷取机的卷取温度为610~640℃。During the rolling process, the rolling process parameters of low-strength steel grades are as follows: the total time in the furnace during the heating process is controlled at 130-155 minutes, the heating furnace maintains a slight positive pressure of 10-12 Pa, and the preheating section of the heating furnace is empty. The fuel ratio is controlled at 1.0-1.1, the preheating time is 60-70 minutes, the air-fuel ratio in the heating section of the heating furnace is kept at 0.9-1.0, the heating time is 40-50 minutes, the temperature and air-fuel ratio of the soaking section of the heating furnace is kept at 1.0-1.1, The temperature is controlled at 1140-1160°C, and the soaking time is 30-35 minutes; during the rough rolling process, the descaling passes are greater than or equal to 4, and the exit temperature of the rough rolling is controlled at 1010-1020°C; the rolling speed of the finishing mill is 5~12m/s, the final rolling temperature is 830~840℃; the coiling temperature of the coiler is 610~640℃.
而现有的同等低强度级别钢种,因轧制各阶段温度较高,现有技术中常规的轧制需要8~10块烫辊。However, for existing steels of the same low-strength grade, the conventional rolling in the prior art requires 8 to 10 ironing rollers because the temperatures in each rolling stage are high.
在轧制过程中,中等强度级别钢种的轧制工艺参数如下:在加热过程的总在炉时间控制在135~170min,加热炉内保持微正压10~12Pa,加热炉的预热段空燃比保持在1.1~1.2,预热时间为60~70min,加热炉的加热段空燃比保持在0.9~1.0,加热时间为50~60min,加热炉的均热段温度空燃比保持在1.0~1.1,温度控制在1150~1180℃,均热时间为25~40min;在粗轧轧制过程,除鳞道次大于或等于4,粗轧机的出口温度为1020~1030℃;精轧机的轧制速度为5~10m/s,终轧温度为840~850℃;卷取机的卷取温度为610~640℃。During the rolling process, the rolling process parameters of medium-strength steel grades are as follows: the total time in the furnace during the heating process is controlled at 135-170 minutes, the heating furnace maintains a slight positive pressure of 10-12 Pa, and the preheating section of the heating furnace is empty. The fuel ratio is kept at 1.1-1.2, the preheating time is 60-70 minutes, the air-fuel ratio of the heating section of the heating furnace is kept at 0.9-1.0, the heating time is 50-60 minutes, the temperature and air-fuel ratio of the soaking section of the heating furnace is kept at 1.0-1.1, The temperature is controlled at 1150-1180°C, and the soaking time is 25-40 minutes; during the rough rolling process, the descaling pass is greater than or equal to 4, and the exit temperature of the rough rolling mill is 1020-1030°C; the rolling speed of the finishing mill is 5~10m/s, the final rolling temperature is 840~850℃; the coiling temperature of the coiler is 610~640℃.
同样条件下,因轧制各阶段温度较高,现有技术中采用常规轧制需要8~10块烫辊加4~8块低强度级别钢种Under the same conditions, due to the high temperature in each rolling stage, the conventional rolling in the prior art requires 8-10 ironing rolls plus 4-8 low-strength steel grades
在轧制过程中,高强度级别钢种的轧制工艺参数如下:在加热过程的总在炉时间控制在160min~200min,加热炉内保持微正压10~12Pa,加热炉的预热段空燃比保持在1.0~1.1,预热时间为80~90min,加热炉的加热段空燃比保持在0.9~1.0,加热时间为50~60min,加热炉的均热段温度空燃比保持在1.1~1.2,温度控制在1170~1220℃,均热时间为30~50min;在粗轧轧制过程,除鳞道次大于或等于4,粗轧机的出口温度为1030~1060℃;精轧机的轧制速度为5~10m/s,终轧温度为850~860℃;卷取机的卷取温度为580~610℃。During the rolling process, the rolling process parameters of high-strength steel grades are as follows: the total time in the furnace during the heating process is controlled at 160min to 200min, the heating furnace maintains a slight positive pressure of 10 to 12Pa, and the preheating section of the heating furnace is empty. The fuel ratio is kept at 1.0-1.1, the preheating time is 80-90 minutes, the air-fuel ratio of the heating section of the heating furnace is kept at 0.9-1.0, the heating time is 50-60 minutes, the temperature of the soaking section of the heating furnace is kept at 1.1-1.2, The temperature is controlled at 1170-1220°C, and the soaking time is 30-50 minutes; during the rough rolling process, the descaling passes are greater than or equal to 4, and the exit temperature of the rough rolling mill is 1030-1060°C; the rolling speed of the finishing mill is 5~10m/s, the final rolling temperature is 850~860℃; the coiling temperature of the coiler is 580~610℃.
同样条件下,因轧制各阶段温度较高,现有技术中采用常规轧制8~10块烫辊、4~8块烫辊以及6~10块中等强度级别钢种。Under the same conditions, due to the high temperature in each rolling stage, conventional rolling of 8-10 hot rolls, 4-8 hot rolls and 6-10 medium-strength steel grades is adopted in the prior art.
进一步地,本发明提出的柔性化的低温轧制方法还包括以下步骤:Further, the flexible low-temperature rolling method proposed by the present invention also includes the following steps:
在钢材的层流冷却过程中,采用边部遮挡技术以减少热轧带钢在冷却过程的边部温降。In the laminar flow cooling process of steel, the edge shielding technology is used to reduce the edge temperature drop of the hot-rolled strip during the cooling process.
进一步地,本发明提出的柔性化的低温轧制方法还包括以下步骤:Further, the flexible low-temperature rolling method proposed by the present invention also includes the following steps:
在粗轧过程采用保温罩以减少粗轧过程温降。The insulation cover is used in the rough rolling process to reduce the temperature drop in the rough rolling process.
此时,可使本柔性化的低温轧制方法可进一步降低轧制生产能耗。At this time, the low-temperature rolling method that can make this flexible can further reduce the energy consumption of rolling production.
具体地,本实施例中,采用三种板坯进行轧制以更好说明本柔性化的低温轧制方法。Specifically, in this embodiment, three types of slabs are used for rolling to better illustrate the flexible low-temperature rolling method.
三种板坯的具体成分见下表所示:The specific composition of the three slabs is shown in the table below:
表1三种板坯的冶炼成分Table 1 Smelting composition of three kinds of slabs
表2轧制过程温度Table 2 Rolling process temperature
板坯1为低强度级别钢种,轧制规程为:加热炉中先安排8块烫辊材,即可安排其轧制生产。相应的轧制工艺参数调整如下:板坯1在加热过程的总在炉时间控制在130min。炉内保持微正压12Pa,防止吸入冷风,预热段空燃比保持在1.0,预热时间60min,加热段空燃比保持在0.95,加热时间40min,均热段温度空燃比保持在1.0,温度控制在1160℃,均热时间30min。在粗轧轧制过程优化轧制制度与除鳞道次,保证除鳞道次≥4,并采用保温罩减少粗轧过程温降,粗轧出口温度为1020℃。精轧入口在原有的温度制度上基本上保持不变或略有降低,提升精轧轧制速度,保证终轧温度和卷取温度在原有常规热轧工艺上不变,轧制速度12m/s,终轧温度835℃,卷取温度640℃,在层流冷却过程采用边部遮挡技术,减少热轧带钢在冷却过程的边部温降。The slab 1 is a low-strength steel grade, and the rolling procedure is as follows: 8 pieces of hot-rolled rolls are first arranged in the heating furnace, and then the rolling production can be arranged. The corresponding rolling process parameters are adjusted as follows: the total furnace time of the slab 1 during the heating process is controlled at 130 minutes. Keep a slight positive pressure of 12Pa in the furnace to prevent the inhalation of cold wind. The air-fuel ratio in the preheating section is kept at 1.0, the preheating time is 60 minutes, the air-fuel ratio in the heating section is kept at 0.95, and the heating time is 40 minutes. At 1160°C, the soaking time is 30min. In the rough rolling process, the rolling system and the descaling passes are optimized to ensure that the descaling passes are ≥ 4, and the heat preservation cover is used to reduce the temperature drop during the rough rolling process, and the exit temperature of the rough rolling is 1020°C. The entrance of finishing rolling basically remains unchanged or slightly lowered in the original temperature system, and the rolling speed of finishing rolling is increased to ensure that the finishing rolling temperature and coiling temperature remain unchanged in the original conventional hot rolling process, and the rolling speed is 12m/s , The final rolling temperature is 835°C, and the coiling temperature is 640°C. The edge shielding technology is used in the laminar cooling process to reduce the edge temperature drop of the hot-rolled strip during the cooling process.
板坯2为中等强度级别钢种,轧制规程为:加热炉中先安排8块烫辊材,再安排2块过低强度级别钢种后,即可安排其轧制生产。相应的轧制工艺参数调整如下:在加热过程的总在炉时间控制在150min。炉内保持微正压12Pa,防止吸入冷风,预热段空燃比保持在1.1,预热时间60min,加热段空燃比保持在1.0,加热时间50min,均热段温度空燃比保持在1.1,温度控制在1180℃,均热时间40min。在粗轧轧制过程优化轧制制度与除鳞道次,保证除鳞道次≥4,并采用保温罩减少粗轧过程温降,粗轧出口温度为1030℃。精轧入口在原有的温度制度上基本上保持不变或略有降低,提升精轧轧制速度,保证终轧温度和卷取温度在原有常规热轧工艺上不变,轧制速度10m/s,终轧温度840℃,卷取温度613℃,在层流冷却过程采用边部遮挡技术,减少热轧带钢在冷却过程的边部温降。The slab 2 is a medium-strength steel grade, and the rolling procedure is as follows: first arrange 8 pieces of hot-rolled roll materials in the heating furnace, and then arrange 2 pieces of low-strength grade steel grades, and then arrange its rolling production. The corresponding rolling process parameters are adjusted as follows: the total time in the furnace during the heating process is controlled at 150min. Keep a slight positive pressure of 12Pa in the furnace to prevent the inhalation of cold wind. The air-fuel ratio in the preheating section is kept at 1.1. The preheating time is 60 minutes. The air-fuel ratio in the heating section is kept at 1.0. The heating time is 50 minutes. At 1180°C, the soaking time is 40min. In the rough rolling process, the rolling system and the descaling passes are optimized to ensure that the descaling passes are ≥ 4, and the heat preservation cover is used to reduce the temperature drop during the rough rolling process, and the rough rolling exit temperature is 1030°C. The entrance of finishing rolling basically remains unchanged or slightly lowered in the original temperature system, and the rolling speed of finishing rolling is increased to ensure that the finishing rolling temperature and coiling temperature remain unchanged in the original conventional hot rolling process, and the rolling speed is 10m/s , The final rolling temperature is 840°C, and the coiling temperature is 613°C. The edge shielding technology is used in the laminar cooling process to reduce the edge temperature drop of the hot-rolled strip during the cooling process.
板坯3为高强度级别钢种,轧制规程为:加热炉中先安排8块烫辊材,安排2块低强度级别钢种,再安排4块中等强度级别钢种,即可安排其轧制生产。相应的轧制工艺参数调整如下:板坯3在加热过程的总在炉时间180min。炉内保持微正压12Pa,预热段空燃比保持在1.1,预热时间80min,加热段空燃比保持在1.05,加热时间70min,均热段温度空燃比保持在1.15,均热温度控制在1210℃,加热时间30min。在粗轧轧制采取3/4连续式轧机轧制,R1除鳞1道,R2轧制5道次,除鳞2道,R3除鳞1道,R4不除鳞,总除鳞道次为4道次,采用保温罩减少粗轧过程温降,RT4粗轧出口温度为1040℃,轧制速度为7.6m/s,终轧温度856℃,卷取温度580℃,在层流冷却过程采用边部遮挡技术,减少热轧带钢在冷却过程的边部温降。The slab 3 is a high-strength steel grade, and the rolling procedure is as follows: first arrange 8 pieces of hot-rolled roll materials in the heating furnace, arrange 2 pieces of low-strength grade steel grades, and then arrange 4 pieces of medium-strength grade steel grades, and then arrange the rolling. production. The corresponding rolling process parameters are adjusted as follows: the total furnace time of the slab 3 during the heating process is 180 minutes. The furnace maintains a slight positive pressure of 12Pa, the air-fuel ratio of the preheating section is kept at 1.1, the preheating time is 80min, the air-fuel ratio of the heating section is kept at 1.05, and the heating time is 70min. ℃, heating time 30min. In the rough rolling, 3/4 continuous rolling mill is adopted, R1 descaling 1 pass, R2 rolling 5 passes, descaling 2 passes, R3 descaling 1 pass, R4 no descaling, the total descaling pass is 4 passes, heat preservation cover is used to reduce the temperature drop in the rough rolling process, the exit temperature of RT4 rough rolling is 1040°C, the rolling speed is 7.6m/s, the final rolling temperature is 856°C, and the coiling temperature is 580°C. The edge shielding technology reduces the edge temperature drop of the hot-rolled strip during the cooling process.
轧制完成后,3块板坯轧制出的热轧板卷力学性能对比见表3。After the rolling is completed, see Table 3 for the comparison of the mechanical properties of the hot-rolled coils rolled from the three slabs.
表3组织、力学性能对比Table 3 Comparison of organization and mechanical properties
由表3可以看出,只要保证各阶段的轧制温度在相应的临界温度以上,3块板坯轧制出的钢卷组织和力学性能均满足标准要求。It can be seen from Table 3 that as long as the rolling temperature at each stage is above the corresponding critical temperature, the microstructure and mechanical properties of the steel coils rolled from the three slabs all meet the standard requirements.
本发明提出的柔性化的低温轧制方法,根据预设的不同级别钢种与临界温度的映射关系,确定当前待轧制的钢材在各轧制阶段所需的温度,从而保证在各轧制阶段所需的温度在临界温度之上,本柔性化的低温轧制方法一方面可降低轧制过程能耗,另一方面还可提高轧制效率。本柔性化的低温轧制方法综合热轧各个钢种的生产特点,柔性化的组织生产,能够使轧制过程具有较大的灵活性与适应性,降低了轧制生产能耗。另外,因为首先确定出钢材在各轧制阶段所需的临界温度,温度不需太高,因此,配套使用的过渡材的数量可大大减少,在一定程度上提高生产节奏,缩短了生产周期,从而提高了轧制效率。The flexible low-temperature rolling method proposed by the present invention determines the temperature required by the steel to be rolled at each rolling stage according to the preset mapping relationship between different grades of steel and the critical temperature, thereby ensuring The temperature required for the stage is above the critical temperature. On the one hand, the flexible low-temperature rolling method can reduce the energy consumption of the rolling process, and on the other hand, it can also improve the rolling efficiency. The flexible low-temperature rolling method integrates the production characteristics of various hot-rolled steel types, and the flexible tissue production can make the rolling process have greater flexibility and adaptability, and reduce the energy consumption of rolling production. In addition, because the critical temperature required for each rolling stage of the steel is determined first, the temperature does not need to be too high, so the number of supporting transition materials can be greatly reduced, the production rhythm is improved to a certain extent, and the production cycle is shortened. Thereby improving rolling efficiency.
以上仅为本发明的优选实施例,并非因此限制本发明的专利范围,凡是利用本发明说明书及附图内容所作的等效结构变换,或直接或间接运用在其他相关的技术领域,均同理包括在本发明的专利保护范围内。The above are only preferred embodiments of the present invention, and are not intended to limit the patent scope of the present invention. All equivalent structural transformations made by using the description of the present invention and the contents of the accompanying drawings, or directly or indirectly used in other related technical fields, are all the same. included in the scope of patent protection of the present invention.
Claims (7)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410342440.5A CN104174660B (en) | 2014-07-18 | 2014-07-18 | The zerolling method of flexibility |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410342440.5A CN104174660B (en) | 2014-07-18 | 2014-07-18 | The zerolling method of flexibility |
Publications (2)
Publication Number | Publication Date |
---|---|
CN104174660A CN104174660A (en) | 2014-12-03 |
CN104174660B true CN104174660B (en) | 2016-02-03 |
Family
ID=51956165
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201410342440.5A Expired - Fee Related CN104174660B (en) | 2014-07-18 | 2014-07-18 | The zerolling method of flexibility |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN104174660B (en) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107138660B (en) * | 2017-06-28 | 2018-08-07 | 武汉理工大学 | A kind of high-carbon-chromium bearing steel warm-rolling loop forming method for realizing tissue nodularization |
CN109590339B (en) * | 2018-12-06 | 2020-09-01 | 武汉钢铁有限公司 | Hot-rolled edge quality control method of low-temperature high-magnetic-induction oriented silicon steel |
CN113649421B (en) * | 2021-07-07 | 2023-04-18 | 阳春新钢铁有限责任公司 | Control system and method for temperature drop compensation of finish rolling inlet |
CN114369753B (en) * | 2022-01-07 | 2023-03-03 | 鞍钢股份有限公司 | Method for producing multi-strength-level alloy structural steel based on flexible rolling technology |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5651281A (en) * | 1993-03-29 | 1997-07-29 | Sms Schloemann-Siemaq | Method and apparatus for rolling rolled strips |
CN1927485A (en) * | 2006-09-29 | 2007-03-14 | 邯郸钢铁股份有限公司 | Technique for CSP sheet billet production line cold rolling feeding |
CN101603150A (en) * | 2009-07-15 | 2009-12-16 | 北京科技大学 | A kind of flexible rolling production method of high-strength hot-rolled dual-phase steel |
CN102671940A (en) * | 2012-05-23 | 2012-09-19 | 山西太钢不锈钢股份有限公司 | Rolling method for producing phase changes in finish rolling process of low-grade non-oriented silicon steel |
CN103276172A (en) * | 2013-05-14 | 2013-09-04 | 武汉钢铁(集团)公司 | Energy-saving rolling method of low alloy steel based on critical temperature |
CN103331308A (en) * | 2013-05-22 | 2013-10-02 | 武汉钢铁(集团)公司 | Energy-saving carbon manganese steel rolling method based on critical temperature |
EP2733226A1 (en) * | 2012-11-14 | 2014-05-21 | Muhr und Bender KG | Method for producing a product from a flexible rolled strip material |
-
2014
- 2014-07-18 CN CN201410342440.5A patent/CN104174660B/en not_active Expired - Fee Related
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5651281A (en) * | 1993-03-29 | 1997-07-29 | Sms Schloemann-Siemaq | Method and apparatus for rolling rolled strips |
CN1927485A (en) * | 2006-09-29 | 2007-03-14 | 邯郸钢铁股份有限公司 | Technique for CSP sheet billet production line cold rolling feeding |
CN101603150A (en) * | 2009-07-15 | 2009-12-16 | 北京科技大学 | A kind of flexible rolling production method of high-strength hot-rolled dual-phase steel |
CN102671940A (en) * | 2012-05-23 | 2012-09-19 | 山西太钢不锈钢股份有限公司 | Rolling method for producing phase changes in finish rolling process of low-grade non-oriented silicon steel |
EP2733226A1 (en) * | 2012-11-14 | 2014-05-21 | Muhr und Bender KG | Method for producing a product from a flexible rolled strip material |
CN103276172A (en) * | 2013-05-14 | 2013-09-04 | 武汉钢铁(集团)公司 | Energy-saving rolling method of low alloy steel based on critical temperature |
CN103331308A (en) * | 2013-05-22 | 2013-10-02 | 武汉钢铁(集团)公司 | Energy-saving carbon manganese steel rolling method based on critical temperature |
Non-Patent Citations (1)
Title |
---|
"柔性经验启发模型在轧制计划中的应用";王路兵;《轧钢》;20040830(第4期);正文第前言部分第2段和正文第2页 * |
Also Published As
Publication number | Publication date |
---|---|
CN104174660A (en) | 2014-12-03 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN102080192B (en) | Low-yield ratio, high-plasticity, ultrafine-grain and high-strength steel and manufacturing method thereof | |
CN101209456B (en) | A kind of production method of high-strength medium-thick steel plate | |
CN102581008A (en) | Processing method for producing low-cost high-formability IF (interstitial-free) steel | |
CN102277539A (en) | High-strength steel with low yield ratio, high plasticity and ultrafine grain and preparation method thereof | |
CN107858586A (en) | A kind of preparation method of high strength and ductility without yield point elongation cold rolling medium managese steel plate | |
CN105483549A (en) | High-strength cold-rolled steel plate for wide and thin automobile and production method thereof | |
CN105177422B (en) | Ultra-long thin EH36 steel and production method of ultra-long thin EH36 steel on steckle mill | |
CN103589948B (en) | Low-carbon aluminum-killed steel hot-dip galvanized sheet and production method thereof | |
CN104174660B (en) | The zerolling method of flexibility | |
CN104032109B (en) | A kind of high-strength steel passes through hot rolling and the preparation method of burning optimization on line | |
CN101532119A (en) | Production device and technique used both for hot galvanizing and continuous annealing | |
CN103774039A (en) | Manufacturing process for steel hot-rolled plate coil for welded gas bottle | |
CN107723602A (en) | 750MPa levels hot-rolled ferrite-bainite dual-phase steel and its production method | |
CN104307911B (en) | Improve the method for high surface grade IF steel percentage elongation | |
CN109482646B (en) | Dynamic variable-schedule ferrite rolling method based on endless rolling | |
CN105950972A (en) | Thick-specification X80 pipeline steel plate with process time being shortened and manufacturing method thereof | |
CN112813347B (en) | Ferrite rolling production method of high-r-value low-carbon aluminum killed steel | |
CN109097700A (en) | A kind of easy pickling mild steel steel plate of CSP process and its manufacturing method | |
CN106435364A (en) | Low-carbon micro-alloy superfine grained steel and manufacturing method thereof | |
CN102534364B (en) | Production method for improving magnetic property of common oriented silicon steel | |
CN100419108C (en) | A kind of production method of 250MPa grade cold-rolled magnetic pole steel | |
CN109338229B (en) | Low-carbon Si-Mn series hot-rolled multiphase steel based on the concept of quenching-carbon distribution and its manufacturing method | |
CN115254954B (en) | Copper plate and strip hot rolling method | |
CN103276172B (en) | Energy-saving rolling method of low alloy steel based on critical temperature | |
CN111842483A (en) | A multi-mode energy-saving hot-rolled strip steel production line and using method thereof |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right |
Effective date of registration: 20170717 Address after: 430083, Gate No. 2, Qingshan District, Hubei, Wuhan Patentee after: WUHAN IRON AND STEEL Co.,Ltd. Address before: 430080 Wuhan, Hubei Friendship Road, No. 999, Wuchang Patentee before: WUHAN IRON AND STEEL (GROUP) Corp. |
|
TR01 | Transfer of patent right | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160203 |