CN104130473B - A kind of fire retardant, anticorrosive high pressure rubber sebific duct filler special and preparation method thereof - Google Patents
A kind of fire retardant, anticorrosive high pressure rubber sebific duct filler special and preparation method thereof Download PDFInfo
- Publication number
- CN104130473B CN104130473B CN201410293417.1A CN201410293417A CN104130473B CN 104130473 B CN104130473 B CN 104130473B CN 201410293417 A CN201410293417 A CN 201410293417A CN 104130473 B CN104130473 B CN 104130473B
- Authority
- CN
- China
- Prior art keywords
- high pressure
- sebific duct
- pressure rubber
- add
- minute
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Abstract
A kind of fire retardant, anticorrosive high pressure rubber sebific duct filler special, is made up of the raw material of following weight part: calcium stearate 2-3, Zinic stearas 1-2, hypo-aluminum orthophosphate 6-8, magnesia powder 4-6, barium metaborate 10-14, Starso 5-8, citric acid 1.5-1.8, fatty alcohol-polyoxyethylene ether 0.2-0.3, benzotriazole 2-3, flyash 60-65,4-6% hydrochloric acid is appropriate, water appropriate, auxiliary agent 15-20; Filler of the present invention with the addition of barium metaborate, Starso, can increase the mildew-resistant of high pressure rubber sebific duct, fire resistance; By adding hypo-aluminum orthophosphate, improve the fire-retardant fireproof performance of high pressure rubber sebific duct; By adding benzotriazole, improve the Antimicrobial preservative performance of high pressure rubber sebific duct; By using flyash, reduce cost, reinforcing property is good; The application of the invention auxiliary agent, can improve the dispersiveness of filler, reinforcing property, not easily bubbling distortion.
Description
Technical field
The invention belongs to high pressure rubber sebific duct field, particularly a kind of fire retardant, anticorrosive high pressure rubber sebific duct filler special and preparation method thereof.
Background technology
High-pressure rubber pipe is used for carrying in mine hydraulic support, oil-field development, engineering construction, lifting transport, metallurgical forging and stamping, mining equiment, boats and ships, injection machine, agricultural machine, various lathe and each industrial sector mechanize, automatic liquid pressing system the pipeline of the petroleum base (as mineral oil, soluble oil, hydraulic efficiency oil, fuel oil, lubricating oil) with certain pressure and temperature and water fluid (as emulsion, oil-water emulsion, water) etc. and liquid transmission.
The inner glue layer of high-pressure rubber pipe has makes delivery medium bear pressure, the effect that protection steel wire does not weather, and outer glue-line protection steel wire is injury-free.The rubber of current high-pressure rubber pipe also exists some needs augmented performance, and as ageing-resistant, heat-resisting, low temperature resistant, acid and alkali-resistance, corrosion-resistant, intensity, UV resistant, fire-retardant, wear-resisting, toughness, the performance such as shock-resistant, also not fully up to expectations, production cost is also higher; Need to carry out modification to rubber hose performance, to improve reliability and stability, increase the service life, reduce the maintain and replace frequency, improve the production efficiency such as engineering machinery, coal mine machinery and safety in production.The performance of rubber can be improved by improving filler.
Summary of the invention
The object of the present invention is to provide a kind of fire retardant, anticorrosive high pressure rubber sebific duct filler special and preparation method thereof, this filler can increase mildew-resistant, the fire resistance of high pressure rubber sebific duct, improve the fire-retardant fireproof performance of high pressure rubber sebific duct, improve the Antimicrobial preservative performance of high pressure rubber sebific duct.
Technical scheme of the present invention is as follows:
A kind of fire retardant, anticorrosive high pressure rubber sebific duct filler special, is characterized in that being made up of the raw material of following weight part: calcium stearate 2-3, Zinic stearas 1-2, hypo-aluminum orthophosphate 6-8, magnesia powder 4-6, barium metaborate 10-14, Starso 5-8, citric acid 1.5-1.8, fatty alcohol-polyoxyethylene ether 0.2-0.3, benzotriazole 2-3, flyash 60-65,4-6% hydrochloric acid is appropriate, water appropriate, auxiliary agent 15-20;
Described auxiliary agent is made up of the raw material of following weight parts: potter's clay 6-8, 1-2% hydrochloric acid soln 10-15, 1-2 sodium hydroxide solution 10-15, neopentyl glycol 0.3-0.4, borax 0.3-0.5, sulfurized olefin cotton oil 0.2-0.3, methacrylic ester 1-2, boric acid 0.2-0.3, silane resin acceptor kh-550 0.1-0.2, ricinolic acid polyester 0.2-0.3, alkyl phenol ether sulfo-succinic acid ester sodium salt 0.1-0.2, pungent certain herbaceous plants with big flowers acid 0.1-0.2, aluminum nitride powder 2-2.5, jojoba oil 0.2-0.3, Potassium Persulphate 0.1-0.2, water is appropriate, preparation method is: mixed with 1-2% sodium hydroxide solution by potter's clay, be heated to 70-80 DEG C, stirring reaction 20-30 minute, filter, obtain filter residue, then mix with 1-2% hydrochloric acid soln, stirring reaction 20-30 minute, being washed to pH is 7-9, and ovendry power is broken into the particle of 2-40 μm, again alkyl phenol ether sulfo-succinic acid ester sodium salt is added in suitable quantity of water, add potter's clay particle again, add neopentyl glycol, methacrylic ester, jojoba oil, ricinolic acid polyester, silane resin acceptor kh-550 after stirring, after stirring, be warming up to 70-80 DEG C, add Potassium Persulphate, stirring reaction 20-30 minute, then add aluminum nitride powder, continue stirring reaction 30-40 minute, dry, mix with other remaining components, dispersion grinding becomes the particle of 2-50 μm, to obtain final product.
The preparation method of described fire retardant, anticorrosive high pressure rubber sebific duct filler special, is characterized in that comprising the following steps:
(1) flyash is sent in calcining furnace, at 700-800 DEG C, calcine 2-3 hour, take out and pulverize, cross 100 mesh sieves, add 2-3 4-6% hydrochloric acid doubly again, be heated to 50-70 DEG C, stir 10-20 minute, filter, filter residue, pickling once, then is washed to neutrality more as stated above, filter, obtain particle;
(2) by calcium stearate, Zinic stearas, hypo-aluminum orthophosphate, magnesia powder, barium metaborate, Starso, citric acid, benzotriazole mixing, grinding 20-30 minute, obtains mixture;
(3) material that (1) step and (2) step obtain is mixed with fatty alcohol-polyoxyethylene ether, add suitable quantity of water and stir into pureed, grind to form the slurry of 2-50 μm, spraying dry, then mix with other remaining components, to obtain final product.
Beneficial effect of the present invention
Filler of the present invention with the addition of barium metaborate, Starso, can increase the mildew-resistant of high pressure rubber sebific duct, fire resistance; By adding hypo-aluminum orthophosphate, improve the fire-retardant fireproof performance of high pressure rubber sebific duct; By adding benzotriazole, improve the Antimicrobial preservative performance of high pressure rubber sebific duct; By using flyash, reduce cost, reinforcing property is good; The application of the invention auxiliary agent, can improve the dispersiveness of filler, reinforcing property, can improve intensity and the tough of high pressure rubber sebific duct, not easily bubbling distortion.
Embodiment
A kind of fire retardant, anticorrosive high pressure rubber sebific duct filler special, is made up of the raw material of following weight part (kilogram): calcium stearate 2.5, Zinic stearas 1.5, hypo-aluminum orthophosphate 7, magnesia powder 5, barium metaborate 12, Starso 7, citric acid 1.7, fatty alcohol-polyoxyethylene ether 0.3, benzotriazole 2.5, flyash 63,5% hydrochloric acid are appropriate, water appropriate, auxiliary agent 18;
Described auxiliary agent is made up of the raw material of following weight parts (kilogram): potter's clay 7,1.5% hydrochloric acid soln 13,1.5 sodium hydroxide solution 13, neopentyl glycol 0.3, borax 0.4, sulfurized olefin cotton oil 0.2, methacrylic ester 1.5, boric acid 0.3, silane resin acceptor kh-550 0.1, ricinolic acid polyester 0.2, alkyl phenol ether sulfo-succinic acid ester sodium salt 0.1, pungent certain herbaceous plants with big flowers acid 0.1, aluminum nitride powder 2.3, jojoba oil 0.2, Potassium Persulphate 0.1, water are appropriate; Preparation method is: mixed with 1.5% sodium hydroxide solution by potter's clay, is heated to 75 DEG C, stirring reaction 25 minutes, and filter, obtain filter residue, then mix with 1.5% hydrochloric acid soln, stirring reaction 25 minutes, being washed to pH is 8, and ovendry power is broken into the particle of 2-40 μm; Again alkyl phenol ether sulfo-succinic acid ester sodium salt is added in suitable quantity of water, add potter's clay particle again, add neopentyl glycol, methacrylic ester, jojoba oil, ricinolic acid polyester, silane resin acceptor kh-550 after stirring, after stirring, be warming up to 75 DEG C, add Potassium Persulphate, stirring reaction 25 minutes, then add aluminum nitride powder, continue stirring reaction 35 minutes, dry, mix with other remaining components, dispersion grinding becomes the particle of 2-50 μm, to obtain final product.
The preparation method of described fire retardant, anticorrosive high pressure rubber sebific duct filler special, comprises the following steps:
(1) flyash is sent in calcining furnace, calcine 2.5 hours at 750 DEG C, take out and pulverize, cross 100 mesh sieves, then add 5% hydrochloric acid of 2.5 times, be heated to 60 DEG C, stir 15 minutes, filter, obtain filter residue, pickling once, then is washed to neutrality more as stated above, filters, obtains particle;
(2) by calcium stearate, Zinic stearas, hypo-aluminum orthophosphate, magnesia powder, barium metaborate, Starso, citric acid, benzotriazole mixing, grind 25 minutes, obtain mixture;
(3) material that (1) step and (2) step obtain is mixed with fatty alcohol-polyoxyethylene ether, add suitable quantity of water and stir into pureed, grind to form the slurry of 2-50 μm, spraying dry, then mix with other remaining components, to obtain final product.
Testing data:
This embodiment filler is used for paracril, and addition is 10-15%, and after tested, tensile strength at yield >=15MPa, 100% fixed stretching strength >=8MPa, sticking power >=170N, at 125 DEG C, flood in 3# oil the rubber obtained, more than 160 hours without be full of cracks.
Claims (2)
1. a fire retardant, anticorrosive high pressure rubber sebific duct filler special, is characterized in that being made up of the raw material of following weight part: calcium stearate 2-3, Zinic stearas 1-2, hypo-aluminum orthophosphate 6-8, magnesia powder 4-6, barium metaborate 10-14, Starso 5-8, citric acid 1.5-1.8, fatty alcohol-polyoxyethylene ether 0.2-0.3, benzotriazole 2-3, flyash 60-65,4-6% hydrochloric acid are appropriate, water appropriate, auxiliary agent 15-20;
Described auxiliary agent is made up of the raw material of following weight parts: potter's clay 6-8, 1-2% hydrochloric acid soln 10-15, 1-2% sodium hydroxide solution 10-15, neopentyl glycol 0.3-0.4, borax 0.3-0.5, sulfurized olefin cotton oil 0.2-0.3, methacrylic ester 1-2, boric acid 0.2-0.3, silane resin acceptor kh-550 0.1-0.2, ricinolic acid polyester 0.2-0.3, alkyl phenol ether sulfo-succinic acid ester sodium salt 0.1-0.2, pungent capric acid 0.1-0.2, aluminum nitride powder 2-2.5, jojoba oil 0.2-0.3, Potassium Persulphate 0.1-0.2, water is appropriate, preparation method is: mixed with 1-2% sodium hydroxide solution by potter's clay, be heated to 70-80 DEG C, stirring reaction 20-30 minute, filter, obtain filter residue, then mix with 1-2% hydrochloric acid soln, stirring reaction 20-30 minute, being washed to pH is 7-9, and ovendry power is broken into the particle of 2-40 μm, again alkyl phenol ether sulfo-succinic acid ester sodium salt is added in suitable quantity of water, add potter's clay particle again, add neopentyl glycol, methacrylic ester, jojoba oil, ricinolic acid polyester, silane resin acceptor kh-550 after stirring, after stirring, be warming up to 70-80 DEG C, add Potassium Persulphate, stirring reaction 20-30 minute, then add aluminum nitride powder, continue stirring reaction 30-40 minute, dry, mix with other remaining components, dispersion grinding becomes the particle of 2-50 μm, to obtain final product.
2. the preparation method of fire retardant, anticorrosive high pressure rubber sebific duct filler special according to claim 1, is characterized in that comprising the following steps:
(1) flyash is sent in calcining furnace, at 700-800 DEG C, calcine 2-3 hour, take out and pulverize, cross 100 mesh sieves, add 2-3 4-6% hydrochloric acid doubly again, be heated to 50-70 DEG C, stir 10-20 minute, filter, filter residue, pickling once, then is washed to neutrality more as stated above, filter, obtain particle;
(2) by calcium stearate, Zinic stearas, hypo-aluminum orthophosphate, magnesia powder, barium metaborate, Starso, citric acid, benzotriazole mixing, grinding 20-30 minute, obtains mixture;
(3) material that (1) step and (2) step obtain is mixed with fatty alcohol-polyoxyethylene ether, add suitable quantity of water and stir into pureed, grind to form the slurry of 2-50 μm, spraying dry, then mix with other remaining components, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410293417.1A CN104130473B (en) | 2014-06-26 | 2014-06-26 | A kind of fire retardant, anticorrosive high pressure rubber sebific duct filler special and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410293417.1A CN104130473B (en) | 2014-06-26 | 2014-06-26 | A kind of fire retardant, anticorrosive high pressure rubber sebific duct filler special and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104130473A CN104130473A (en) | 2014-11-05 |
| CN104130473B true CN104130473B (en) | 2016-03-30 |
Family
ID=51803342
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410293417.1A Active CN104130473B (en) | 2014-06-26 | 2014-06-26 | A kind of fire retardant, anticorrosive high pressure rubber sebific duct filler special and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104130473B (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4734305A (en) * | 1985-03-08 | 1988-03-29 | Toyoda Gosei Co., Ltd. | High-pressure rubber hose |
| CN103539989A (en) * | 2013-09-29 | 2014-01-29 | 青岛博玉特橡塑制品有限公司 | Environment-friendly, antibacterial and mouldproof rubber |
-
2014
- 2014-06-26 CN CN201410293417.1A patent/CN104130473B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4734305A (en) * | 1985-03-08 | 1988-03-29 | Toyoda Gosei Co., Ltd. | High-pressure rubber hose |
| CN103539989A (en) * | 2013-09-29 | 2014-01-29 | 青岛博玉特橡塑制品有限公司 | Environment-friendly, antibacterial and mouldproof rubber |
Non-Patent Citations (2)
| Title |
|---|
| 《新型填料FZ－1和SAC－1在胶管中的应用研究》;曾柏林;《橡胶工业》;19951231;第42卷(第9期);第536-538页 * |
| 《粉煤灰在胶管生产中的应用》;刘林书;《化工之友》;19941231(第1期);第23-25页 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104130473A (en) | 2014-11-05 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106609132A (en) | Multiple composite gel leak-stopping agent used for well drilling | |
| CN103910531A (en) | Refractory concrete | |
| CN104130472B (en) | A kind of anti tear low temperature resistant high pressure rubber sebific duct filler special and preparation method thereof | |
| CN104130473B (en) | A kind of fire retardant, anticorrosive high pressure rubber sebific duct filler special and preparation method thereof | |
| CN104119568A (en) | Special filler for antibacterial anti-ageing cable sheath material and preparation method thereof | |
| CN104130471A (en) | Filler specialized for high temperature-resistant high-pressure rubber hose, and preparation method thereof | |
| CN104151725A (en) | Special packing for high-pressure rubber tube for petroleum transportation, and preparation method of packing | |
| CN104119572A (en) | Special packing for wear-resistant and corrosion-resistant high-pressure rubber pipe and preparation method of special packing | |
| CN104130470B (en) | A kind of water-fast high pressure rubber sebific duct filler special and preparation method thereof | |
| CN104130449A (en) | Filler specialized for high-strength and durable high-pressure rubber hose, and preparation method thereof | |
| CN104130474A (en) | Filler specialized for fire-resistant high-pressure rubber hose, and preparation method thereof | |
| CN104119582A (en) | Special packing material for high-toughness water-resistant high-pressure rubber tube and preparation method thereof | |
| CN102190886B (en) | Material special for high-temperature gas leakage repair | |
| CN104130454A (en) | High-pressure rubber hose and preparation method thereof | |
| CN104130447A (en) | Filler specialized for high-strength and insulated high-pressure rubber hose, and preparation method thereof | |
| CN104130451A (en) | Filler specialized for flame-retardant and fire-resistant high-pressure rubber hose, and preparation method thereof | |
| CN104151713A (en) | Special packing for oxidation-resistant high-pressure rubber hoses and preparation method thereof | |
| CN104151728A (en) | Filler specially used for mouldproof and high-pressure rubber tube and preparation method thereof | |
| CN104119581A (en) | Special filler for cold-resistant ultraviolet-resistant high-pressure rubber tubes and preparation method thereof | |
| CN104130450A (en) | Filler specialized for cold-resistant and anti-bacterial high-pressure rubber hose, and preparation method thereof | |
| CN104109366A (en) | Cable material filler and preparation method thereof | |
| CN104151609A (en) | Special packing for antibacterial high-strength high-pressure rubber tube and preparation method of packing | |
| CN104119571A (en) | Special reinforcing filler for high-pressure rubber tubes and preparation method thereof | |
| CN102993705A (en) | Oil-proof nylon polyamide 12 (PA12) material for inner layer of automobile oil pipe, and preparation method of 0il-proof nylon PA12 material | |
| CN104119580A (en) | Light-resistant weather-resistant filler for high-pressure rubber tube and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Filler specialized for flame-retardant and corrosion-resistant high-pressure rubber hose, and preparation method thereof Effective date of registration: 20170616 Granted publication date: 20160330 Pledgee: China Co. truction Bank Corp Hefei Luyang branch Pledgor: HEFEI HEAN MACHINERY MANUFACTURING Co.,Ltd. Registration number: 2017340000093 |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20221125 Granted publication date: 20160330 Pledgee: China Co. truction Bank Corp Hefei Luyang branch Pledgor: HEFEI HEAN MACHINERY MANUFACTURING Co.,Ltd. Registration number: 2017340000093 |