CN104129899A - Sludge modifying agent - Google Patents

Sludge modifying agent Download PDF

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Publication number
CN104129899A
CN104129899A CN201310160500.7A CN201310160500A CN104129899A CN 104129899 A CN104129899 A CN 104129899A CN 201310160500 A CN201310160500 A CN 201310160500A CN 104129899 A CN104129899 A CN 104129899A
Authority
CN
China
Prior art keywords
sludge
weight
modification agent
hydrogen peroxide
ferrous sulfate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201310160500.7A
Other languages
Chinese (zh)
Inventor
黄党军
吕奇波
俞雨军
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
XINCHANG ZHONGFA ENVIRONMENTAL PROTECTION MATERIAL Co Ltd
Original Assignee
XINCHANG ZHONGFA ENVIRONMENTAL PROTECTION MATERIAL Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by XINCHANG ZHONGFA ENVIRONMENTAL PROTECTION MATERIAL Co Ltd filed Critical XINCHANG ZHONGFA ENVIRONMENTAL PROTECTION MATERIAL Co Ltd
Priority to CN201310160500.7A priority Critical patent/CN104129899A/en
Publication of CN104129899A publication Critical patent/CN104129899A/en
Pending legal-status Critical Current

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  • Treatment Of Sludge (AREA)

Abstract

The invention relates to a sludge modifying agent which mainly includes following components, by weight, 400-800 of an acid solution with a pH value being 3-4, 300-600 parts of ferrous sulfate and 100-300 parts of hydrogen peroxide. By means of a technical scheme in the invention, dehydration of the sludge can be carried out conveniently and high-efficiently. A dehydration effect that a dehydration ratio can be less than 50% can be achieved. Meanwhile, a cost is low.

Description

Sludge modification agent
Technical field
The present invention relates to a kind of sludge modification agent.
Technical background
Along with China's economy develops the quickening with urbanization rapidly, the scale of municipal sewage treatment constantly expands, and sludge yield is also in quick increase.China's dewatered sludge generation in 2011 approaches 2,200 ten thousand tons, according to < < China sludge treatment, dispose Market Report > > and predicted for 2015 end of the years, China's dewatered sludge annual production will be over 2,600 ten thousand tons.Moisture percentage in sewage sludge is high, can cause mud to stack that floor space is large, transportation cost is high, percolate is difficult, easily produces stench and multiplies mosquitos and flies, produces serious environmental problem.Therefore, improve the dewatering of mud, making reducing sludge volume minimizing is the key of sludge disposal.Current, the water ratio of the mud of municipal sewage plant's discharge is generally up to 80%, in the < < urban wastewater treatment firm mud shale national standard > > implementing at present, also stipulate, moisture percentage in sewage sludge is less than 80%.
But the mud of 80% water ratio is not eliminated the harm of environment, country is decided to be moisture percentage in sewage sludge by standard, and to be less than 80% be to consider China's national conditions in developmental stage at present, and further dehydration will expend a large amount of human and material resources and financial resources.
Summary of the invention
For addressing the above problem, the object of the invention be to provide a kind of convenience, effectively, inexpensively by sludge dewatering, the sludge modification agent that makes the water ratio of dehydrated sludge be less than 50%.
For reaching above-mentioned purpose, provide following technical scheme:
A sludge modification agent, mainly comprises the component of following parts by weight:
PH value is 3~4 acid solution 400~800;
Ferrous sulfate 300~600;
Hydrogen peroxide 100~300.
As a preferred scheme, in formula, also comprise that ratio of weight and number is 1~10 aluminum chloride.
Under the acidic conditions that is 3~4 in pH value, ferrous sulfate reacts with hydrogen peroxide and generates trivalent iron salt, destroys cellularstructure, carries out mud-water separation.As preferred scheme, add aluminum chloride, utilize its throwing out, reduce the requirement of processed to dehydration equipment.
Compared with prior art, adopt technical scheme of the present invention can facilitate, effectively mud be dewatered, can reach dehydration rate is to be less than 50% dehydrating effect; Adopt also very economical of technical scheme of the present invention, cost is lower simultaneously.
Embodiment
For making technique means of the present invention, reach object and effect is easy to understand, below in conjunction with embodiment, further set forth the present invention.
One embodiment of the present of invention are: a kind of sludge modification agent: the component that mainly comprises following parts by weight:
PH value is 3 sulphuric acid soln 400;
Ferrous sulfate 600;
Hydrogen peroxide 100;
Aluminum chloride 1.
An alternative embodiment of the invention is: a kind of sludge modification agent: the component that mainly comprises following parts by weight:
PH value is 4 hydrochloric acid soln 800
Ferrous sulfate 300;
Hydrogen peroxide 300;
Aluminum chloride 10.
An alternative embodiment of the invention is: a kind of sludge modification agent: the component that mainly comprises following parts by weight:
PH value is 3.5 salpeter solution 600;
Ferrous sulfate 450;
Hydrogen peroxide 150;
Aluminum chloride 2.5.
An alternative embodiment of the invention is: a kind of sludge modification agent: the component that mainly comprises following parts by weight:
PH value is 3.5 salpeter solution 500;
Ferrous sulfate 400;
Hydrogen peroxide 200;
Aluminum chloride 5.
An alternative embodiment of the invention is: a kind of sludge modification agent: the component that mainly comprises following parts by weight:
PH value is 4 salpeter solution 700;
Ferrous sulfate 500;
Hydrogen peroxide 180;
Aluminum chloride 5.
An alternative embodiment of the invention is: a kind of sludge modification agent: the component that mainly comprises following parts by weight:
PH value is 4 salpeter solution 550;
Ferrous sulfate 450;
Hydrogen peroxide 180;
Aluminum chloride 1.
Compared with prior art, adopt technical scheme of the present invention, adopt technical scheme of the present invention can facilitate, effectively mud be dewatered, can reach the dehydrating effect that dehydration rate is less than 50%; Adopt also very economical of technical scheme of the present invention, cost is lower simultaneously.
More than show and described ultimate principle of the present invention, principal character and advantage of the present invention.The technician of the industry should understand, the present invention is not restricted to the described embodiments, in above-described embodiment and specification sheets only for principle of the present invention is described, the present invention also has various changes and modifications without departing from the spirit and scope of the present invention, and these changes and improvements all belong to the scope of the invention.Invent claimed scope by claims and equivalent circle thereof of appendix.

Claims (5)

1. a sludge modification agent, is characterized in that: the component that mainly comprises following parts by weight:
PH value is 3~4 acid solution 400~800;
Ferrous sulfate 300~600;
Hydrogen peroxide 100~300.
2. sludge modification agent according to claim 1, is characterized in that: the component that mainly comprises following parts by weight:
PH value is 3~4 acid solution 500~700;
Ferrous sulfate 400~500;
Hydrogen peroxide 150~200.
3. sludge modification agent according to claim 2, is characterized in that: the component that mainly comprises following parts by weight:
PH value is 3~4 acid solution 550~600;
Ferrous sulfate 450~500;
Hydrogen peroxide 180~200.
4. according to the sludge modification agent described in any claim in claims 1 to 3, it is characterized in that: also comprise that parts by weight are 1~10 aluminum chloride.
5. according to the sludge modification agent described in claim 4, it is characterized in that: the parts by weight of described aluminum chloride are 2.5.
CN201310160500.7A 2013-05-03 2013-05-03 Sludge modifying agent Pending CN104129899A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310160500.7A CN104129899A (en) 2013-05-03 2013-05-03 Sludge modifying agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201310160500.7A CN104129899A (en) 2013-05-03 2013-05-03 Sludge modifying agent

Publications (1)

Publication Number Publication Date
CN104129899A true CN104129899A (en) 2014-11-05

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201310160500.7A Pending CN104129899A (en) 2013-05-03 2013-05-03 Sludge modifying agent

Country Status (1)

Country Link
CN (1) CN104129899A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105478450A (en) * 2016-01-07 2016-04-13 浙江荣晟环保纸业股份有限公司 Comprehensive treatment method of papermaking biochemical sludge
CN106746483A (en) * 2017-02-10 2017-05-31 周毅 The agent of compound type sludge decrement, preparation method and applications

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101759337A (en) * 2010-01-07 2010-06-30 北京林业大学 Method for improving dewatering performance of excess sludge by combining biological acidification and Fenton-like oxidation
EP1461292B1 (en) * 2001-11-29 2010-11-17 Corporation Biolix Method for stabilizing and conditioning urban and industrial wastewater sludge
CN102180583A (en) * 2011-04-08 2011-09-14 北京师范大学 Technique for conditioning sludge by using synergic action of Fenton reagent and polyacrylamide

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1461292B1 (en) * 2001-11-29 2010-11-17 Corporation Biolix Method for stabilizing and conditioning urban and industrial wastewater sludge
CN101759337A (en) * 2010-01-07 2010-06-30 北京林业大学 Method for improving dewatering performance of excess sludge by combining biological acidification and Fenton-like oxidation
CN102180583A (en) * 2011-04-08 2011-09-14 北京师范大学 Technique for conditioning sludge by using synergic action of Fenton reagent and polyacrylamide

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
李娟: "Fenton氧化破解城市污泥及生物淋滤处理河道底泥", 《中国优秀硕士学位论文全文数据库 工程科技Ⅰ辑》 *
李娟: "Fenton氧化破解城市污泥及生物淋滤处理河道底泥", 《中国优秀硕士学位论文全文数据库 工程科技Ⅰ辑》, no. 08, 15 August 2009 (2009-08-15), pages 027 - 316 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105478450A (en) * 2016-01-07 2016-04-13 浙江荣晟环保纸业股份有限公司 Comprehensive treatment method of papermaking biochemical sludge
CN106746483A (en) * 2017-02-10 2017-05-31 周毅 The agent of compound type sludge decrement, preparation method and applications

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Application publication date: 20141105