CN104129794A - Acidified pyrophillite - Google Patents

Acidified pyrophillite Download PDF

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Publication number
CN104129794A
CN104129794A CN201410358747.4A CN201410358747A CN104129794A CN 104129794 A CN104129794 A CN 104129794A CN 201410358747 A CN201410358747 A CN 201410358747A CN 104129794 A CN104129794 A CN 104129794A
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agalmatolite
batching
acidifying
pyrophillite
flap
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CN104129794B (en
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许庆华
邱茗
王跃皓
王鲁海
金白云
管永祥
蒋文兰
许盛英
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Zhejiang Chuangwei New Material Co., Ltd
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许盛英
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Abstract

The invention discloses acidified pyrophillite. The main point of a technical scheme provided by the invention is that acidified pyrophillite ingredients comprise pyrophillite, attapulgite clay, magnesium oxide, sulfuric acid, fast-dissolving sodium silicate, polyvinyl alcohol, hydroxypropyl methyl cellulose and sodium carbonate. The acidified pyrophillite ingredients are input into a mill for milling, and powder obtained after milling is the acidified pyrophillite. A production method for the acidified pyrophillite adopts a first step of acidification and a second step of compound batching and can prevent a chemical reaction of sulfuric acid with fast-dissolving sodium silicate, polyvinyl alcohol, hydroxypropyl methyl cellulose and sodium carbonate; after acidification of pyrophillite, the pH value of pyrophillite is controlled to be 5.5 to 7.0, and the utilization rate of pyrophillite can be increased. The acidified pyrophillite has the characteristics of good adsorptivity, thixotropy, heat stability, plasticity and caking performance and is applicable to production of environmental protection materials, building materials, foaming agents and fire-fighting products.

Description

Agalmatolite after acidifying
Technical field
The present invention relates to acidification, be specifically related to the agalmatolite after a kind of acidifying.
Background technology
Agalmatolite Ores In China aboundresources, exploitation aspect main products is ceramic grade, refractory materials level, glass level, engraving level, scale with abroad than less than normal, product specification is not high, deep processed product portion is few, thereby economic benefit is not good enough, the key overcoming the above problems is to strengthen the research and development of pyrophyllite deep processed product.
Agalmatolite is the one of clay mineral, and ore, taking bulk as main, also has earthy and fibrous, pyrophyllite normal with the mineral paragenesis such as quartz, kaolinite, montmorillonite, dickite, sericite and kyanite, andaluzite, corundum.
In order to improve the application quality of agalmatolite, need to carry out acidification to agalmatolite.
Summary of the invention
The object of the invention is to overcome weak point in prior art, the agalmatolite after a kind of acidifying is provided.
Agalmatolite batching after acidifying is made up of agalmatolite, attapulgite clay, magnesium oxide, sulfuric acid, quick dissolved sodium silicate, polyvinyl alcohol, Vltra tears and sodium carbonate.
The production method of the agalmatolite after acidifying: by abrasive dust in the agalmatolite batching input grinding machine after acidifying, the meal after abrasive dust is the agalmatolite after acidifying.
Agalmatolite slip fluidity is good, good penetrability, and agalmatolite has good thermostability and little hygral expansion, for this reason, can for the manufacture of size accurately, the product of Heat stability is good, body drying shrinks little, indeformable, burn till crack little, firing whiteness 90~96%, refractoriness >=1700 DEG C, insulation, heat insulating ability is good, and stable chemical performance, only has at high temperature and could be decomposed by sulfuric acid, the present invention selects the agalmatolite after pulverizing, particle fineness≤0.5 millimeter of agalmatolite.
Attapulgite clay has unique layer chain-like structure feature, and crystal is needle-like, fibrous or fiber collection shape.Attapulgite clay has unique dispersion, high temperature resistant, the anti-good colloidal property such as saline and alkaline and higher adsorptive power, and has certain plasticity-and cohesive force, and the present invention selects particle fineness≤5 millimeter of attapulgite clay.
Magnesium oxide has the general character of basic oxide, belongs to gelling material, can improve the colloidal property of agalmatolite.
It is 98% the vitriol oil that sulfuric acid is selected concentration.
Quick dissolved sodium silicate is white pulverulent material, can be dissolved in fast water, has that cohesive force is strong, intensity is higher, acid resistance, good heat resistance, the feature of alkali resistance and poor water resistance.
Polyethenol series white solid, that external form is divided is cotton-shaped, particulate state, Powdered three kinds; Nonpoisonous and tasteless, particulate state can be dissolved in 80--90 DEG C of water, pulverously after other powders pre-dispersed, can dissolve at normal temperatures.There is good viscosity, polymerizability, cohesiveness and water-retentivity.
Vltra tears has thickening capabilities, salt discharge, pH stability, water-retentivity, dimensional stability, good film-forming properties and the feature such as resistance to enzyme, dispersiveness and cohesiveness widely.
Sodium carbonate has the general character and the thermostability of salt, soluble in water, and its aqueous solution is alkalescence, in the present invention for adjusting the agalmatolite pH value after acidifying.
The present invention is achieved by following technical proposals:
1, the batching of the agalmatolite after acidifying is made up of following component by weight percentage: agalmatolite work in-process 90~98%, quick dissolved sodium silicate 0.1~5%, polyvinyl alcohol 0.1~5%, Vltra tears 0.01~3% and sodium carbonate 0~3% after acidifying.
2, the production method of the agalmatolite after acidifying: by abrasive dust in the agalmatolite batching input grinding machine after acidifying, particle fineness≤0.074 millimeter, the meal after abrasive dust is the agalmatolite finished product after acidifying.
3, the half-finished production method of the agalmatolite after acidifying: stir in the stirrer (1) input of the batching of agalmatolite mixture having been turned round, then dilute sulphuric acid is slowly added and carries out acidification in agalmatolite mixture; (2) by the agalmatolite mixture after acidification, push as agalmatolite flap thickness≤3 millimeter of agalmatolite flap by twin rollers; (3) agalmatolite flap is transported to roasting in rotary type stoving oven, roasting time is 1~3 hour, maturing temperature is controlled at 300~400 DEG C, agalmatolite flap water content≤2% after roasting, agalmatolite flap after roasting is the agalmatolite work in-process after acidifying, and PCm is weight percentage.
4, the batching of agalmatolite flap is made up of following component by weight percentage: agalmatolite mixture 75~95% and dilute sulphuric acid 5~25%.
5, the batching of agalmatolite mixture is made up of following component by weight percentage: agalmatolite 68~92%, attapulgite clay 5~30% and magnesium oxide 0.1~3%.
6, the batching of dilute sulphuric acid is made up of following component by weight percentage: the vitriol oil 1~25% that concentration is 98% and water 75~99%, the vitriol oil per-cent that concentration is 98% is weight percentage.
The production method of the agalmatolite after acidifying takes first acidifying to carry out compounding ingredient again, can avoid sulfuric acid and quick dissolved sodium silicate, polyvinyl alcohol, Vltra tears and sodium carbonate generation chemical reaction, give full play to raw-material characteristic separately in batching, and obtain complementation, guarantee the agalmatolite inner quality after acidifying.
According to the needs of quality product, adopt sodium carbonate to adjust the agalmatolite pH value after acidifying, method is simple.
After the acidified processing of agalmatolite, pH value is controlled at 5.5~7.0, can improve the utilization ratio of agalmatolite.
Agalmatolite after acidifying has good adsorptivity, thixotropy, thermostability, plasticity-and close-burning feature.
Agalmatolite after acidifying is applicable to produce environment-friendly materials, material of construction, whipping agent and fire product.
Embodiment
Below in conjunction with embodiment, the invention will be further described:
1, the batching of the agalmatolite after acidifying is made up of following component by weight percentage: agalmatolite work in-process 96.5%, quick dissolved sodium silicate 1.5%, polyvinyl alcohol 1.4%, Vltra tears 0.59% and sodium carbonate 0.01% after acidifying.
2, the production method of the agalmatolite after acidifying: by abrasive dust in the agalmatolite batching input grinding machine after acidifying, particle fineness≤0.074 millimeter, the meal after abrasive dust is the agalmatolite finished product after acidifying.
3, the half-finished production method of the agalmatolite after acidifying: stir in the stirrer (1) input of the batching of agalmatolite mixture having been turned round, then dilute sulphuric acid is slowly added and carries out acidification in agalmatolite mixture; (2) by the agalmatolite mixture after acidification, push as agalmatolite flap thickness≤3 millimeter of agalmatolite flap by twin rollers; (3) agalmatolite flap is transported to roasting in rotary type stoving oven, roasting time is 2 hours, and maturing temperature is controlled at 300~350 DEG C, agalmatolite flap water content≤2% after roasting, and the agalmatolite flap after roasting is the agalmatolite work in-process after acidifying.
4, the batching of agalmatolite flap is made up of following component by weight percentage: agalmatolite mixture 82% and dilute sulphuric acid 18%.
5, the batching of agalmatolite mixture is made up of following component by weight percentage: agalmatolite 80%, attapulgite clay 18% and magnesium oxide 2%.
6, the batching of dilute sulphuric acid is made up of following component by weight percentage: the vitriol oil 4% that concentration is 98% and water 96%.

Claims (7)

1. the agalmatolite after an acidifying, it is characterized in that, the agalmatolite batching after acidifying is made up of following component by weight percentage: agalmatolite work in-process 90~98%, quick dissolved sodium silicate 0.1~5%, polyvinyl alcohol 0.1~5%, Vltra tears 0.01~3% and sodium carbonate 0~3% after acidifying.
2. the production method of the agalmatolite after acidifying according to claim 1, is characterized in that, by abrasive dust in the agalmatolite batching input grinding machine after acidifying, and particle fineness≤0.074 millimeter, the meal after abrasive dust is the agalmatolite finished product after acidifying.
3. the half-finished production method of agalmatolite after acidifying according to claim 1, is characterized in that, stirs, then dilute sulphuric acid is slowly added and in agalmatolite mixture, carries out acidification in the stirrer (1) input of the batching of agalmatolite mixture having been turned round; (2) by the agalmatolite mixture after acidification, push as agalmatolite flap thickness≤3 millimeter of agalmatolite flap by twin rollers; (3) agalmatolite flap is transported to roasting in rotary type stoving oven, roasting time is 1~3 hour, maturing temperature is controlled at 300~400 DEG C, agalmatolite flap water content≤2% after roasting, and the agalmatolite flap after roasting is the agalmatolite work in-process after acidifying.
4. the batching of agalmatolite flap according to claim 3, is characterized in that, the batching of agalmatolite flap is made up of following component by weight percentage: agalmatolite mixture 75~95% and dilute sulphuric acid 5~25%.
5. the batching of agalmatolite mixture according to claim 4, is characterized in that, the batching of agalmatolite mixture is made up of following component by weight percentage: agalmatolite 68~92%, attapulgite clay 5~30% and magnesium oxide 0.1~3%.
6. the batching of dilute sulphuric acid according to claim 4, is characterized in that, the batching of dilute sulphuric acid is made up of following component by weight percentage: the vitriol oil 1~25% that concentration is 98% and water 75~99%.
7. the batching of agalmatolite mixture according to claim 5, is characterized in that, selects particle fineness≤0.5 millimeter of agalmatolite, particle fineness≤5 millimeter of attapulgite clay.
CN201410358747.4A 2014-07-27 2014-07-27 Pyrophillite after acidifying Active CN104129794B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106883458A (en) * 2017-03-09 2017-06-23 浙江皓翔矿业有限公司 A kind of preparation method of modified pyrophyllite powder
CN111410203A (en) * 2020-03-27 2020-07-14 中国地质大学(北京) Method for synthesizing pyrophyllite by utilizing leucite

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101559349A (en) * 2009-05-08 2009-10-21 济南大学 Calcination-free zeolite filter material activated by hydrochloric acid and preparation method thereof
CN101940909A (en) * 2010-05-04 2011-01-12 中国矿业大学(北京) Efficient ecotype inorganic formaldehyde adsorbing material and preparation method thereof
CN102489245A (en) * 2011-12-08 2012-06-13 环境保护部华南环境科学研究所 Modified pumice absorbing material and preparation method as well as application thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101559349A (en) * 2009-05-08 2009-10-21 济南大学 Calcination-free zeolite filter material activated by hydrochloric acid and preparation method thereof
CN101940909A (en) * 2010-05-04 2011-01-12 中国矿业大学(北京) Efficient ecotype inorganic formaldehyde adsorbing material and preparation method thereof
CN102489245A (en) * 2011-12-08 2012-06-13 环境保护部华南环境科学研究所 Modified pumice absorbing material and preparation method as well as application thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106883458A (en) * 2017-03-09 2017-06-23 浙江皓翔矿业有限公司 A kind of preparation method of modified pyrophyllite powder
CN111410203A (en) * 2020-03-27 2020-07-14 中国地质大学(北京) Method for synthesizing pyrophyllite by utilizing leucite
CN111410203B (en) * 2020-03-27 2023-07-21 中山市清融嘉创能源科技有限责任公司 Method for synthesizing pyrophyllite by utilizing leucite

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