CN104124442A - A preparing method of a nanometer Fe2O3/rGO composite material and applications of the composite material - Google Patents
A preparing method of a nanometer Fe2O3/rGO composite material and applications of the composite material Download PDFInfo
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- CN104124442A CN104124442A CN201410311647.6A CN201410311647A CN104124442A CN 104124442 A CN104124442 A CN 104124442A CN 201410311647 A CN201410311647 A CN 201410311647A CN 104124442 A CN104124442 A CN 104124442A
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- rgo composite
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- 239000002131 composite material Substances 0.000 title claims abstract description 40
- 238000000034 method Methods 0.000 title abstract description 10
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 title abstract 3
- 239000011259 mixed solution Substances 0.000 claims abstract description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- 238000002360 preparation method Methods 0.000 claims abstract description 22
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 21
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000000243 solution Substances 0.000 claims abstract description 16
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 10
- 239000010439 graphite Substances 0.000 claims abstract description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000003756 stirring Methods 0.000 claims abstract description 7
- 238000001132 ultrasonic dispersion Methods 0.000 claims abstract description 7
- 238000001291 vacuum drying Methods 0.000 claims abstract description 7
- 238000005406 washing Methods 0.000 claims abstract description 7
- 239000000463 material Substances 0.000 claims description 11
- 235000011187 glycerol Nutrition 0.000 claims description 9
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 6
- 229910052744 lithium Inorganic materials 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 239000010406 cathode material Substances 0.000 claims description 4
- 230000015572 biosynthetic process Effects 0.000 abstract description 2
- 239000002994 raw material Substances 0.000 abstract description 2
- 238000003786 synthesis reaction Methods 0.000 abstract description 2
- 239000000047 product Substances 0.000 abstract 3
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229910021389 graphene Inorganic materials 0.000 description 7
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 5
- 229910001416 lithium ion Inorganic materials 0.000 description 5
- 238000002389 environmental scanning electron microscopy Methods 0.000 description 4
- 238000000634 powder X-ray diffraction Methods 0.000 description 4
- 229910000859 α-Fe Inorganic materials 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 239000002135 nanosheet Substances 0.000 description 2
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 230000002500 effect on skin Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000009881 electrostatic interaction Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- -1 halide ion Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000002114 nanocomposite Substances 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/362—Composites
- H01M4/364—Composites as mixtures
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/021—Physical characteristics, e.g. porosity, surface area
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Nanotechnology (AREA)
- Composite Materials (AREA)
- General Chemical & Material Sciences (AREA)
- Electrochemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Inorganic Chemistry (AREA)
- Carbon And Carbon Compounds (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Compounds Of Iron (AREA)
Abstract
The invention relates to the field of preparation of nanometer composite materials, and particularly relates to a preparing method of a nanometer Fe2O3/rGO composite material and applications of the composite material. The preparing method includes steps of: dissolving Fe2SO4-7H2O into a liquid mixture comprising water and glycerol to form a mixed solution A; dispersing graphite oxide into water and performing ultrasonic dispersion to form a solution B; adding the solution B into the mixed solution A, and stirring uniformly to form a mixed solution C; adding the mixed solution C into a high-pressure reactor, putting the high-pressure reactor into a temperature environment having a temperature of 140-180 DEG C, and reacting 8-12 h to obtain a reaction product; and washing the product with aqueous ethanol and water separately for several times, adding the product into a vacuum drying oven having a temperature of 60-100 DEG C, and drying for several hours to obtain the nanometer Fe2O3/rGO composite material. The preparing method has characteristics of cheap and easily available raw materials, low cost, simple and feasible synthesis process, stable product quality and good process repeatability.
Description
Technical field
The present invention relates to the preparation field of nano composite material, be specifically related to a kind of nanometer Fe
2o
3the preparation method of/rGO composite material and application.
Background technology
Nanometer Fe
2o
3as a kind of important nano material, because it has unique physicochemical properties, as small-size effect, skin effect, interfacial effect etc., it is all widely used in each technical field.At present, nanometer Fe
2o
3also the negative material that can be used as lithium ion battery is applied in the middle of secondary cell, but the nanometer Fe of existing preparation method's gained
2o
3when discharging and recharging, because it conducts electricity rate variance, the coefficient of cubical expansion is poor, and the lithium ion battery obtaining is poor effect often.
And Graphene is as a kind of good material and nanometer Fe
2o
3compound can addressing the deficiencies of the prior art, and there is the nanometer Fe of specific morphology
2o
3be embedded in Graphene so far there are no report.
Summary of the invention
Technical problem to be solved by this invention is to provide kind of a nanometer Fe
2o
3the preparation method of/rGO composite material.
Another object of the present invention is to provide the Fe of above-mentioned preparation method's gained
2o
3/ rGO composite material is as the application of lithium cell cathode material.
Technical problem to be solved by this invention is achieved by the following technical programs:
A kind of nanometer Fe
2o
3the preparation method of/rGO composite material, comprises following steps:
A) by FeSO
47H
2o is dissolved in the mixing material of water and glycerine and forms mixed solution A;
B) graphite oxide is scattered in water and ultrasonic dispersion, forms solution B;
C) solution B is added in mixed solution A, after stirring, forms mixed solution C;
D) described mixed solution C is put into autoclave, described autoclave is placed under the temperature environment of 140 ~ 180 ℃ and reacts after 8 ~ 12 hours and obtain product;
E) product is used respectively absolute ethyl alcohol and water washing for several times, put into 60～100 ℃ of vacuum drying chambers and be dried a few hours, obtain described nanometer Fe
2o
3/ rGO composite material.
Further, the volume ratio of the water in described step a) and glycerine is 3.5 ~ 4:1.
Further, the concentration of described mixed solution A is 0.035 ~ 0.045 mol/L.
Further, in described step b), ultrasonic time is 1.5 ~ 3h.
Further, the concentration of described solution B is 1 ~ 1.5g/L.
The nanometer Fe of described preparation method's gained
2o
3/ rGO composite material is as the application of lithium cell cathode material.
The present invention has following beneficial effect:
(1) preparation method's provided by the invention raw material is cheap and easy to get, and cost is low, and synthesis technique is simple and easy to realize, and constant product quality and process repeatability can be good.
(2) nanometer Fe that prepared by the present invention
2o
3/ rGO composite material size, pattern homogeneous, and Fe
2o
3nanometer sheet is embedded in Graphene uniformly.
(3) this preparation method need not use any surfactant, halide ion etc., nanometer Fe that can be to gained of the present invention
2o
3/ rGO composite material is introduced any impurity.
(4) nanometer Fe of this preparation method gained
2o
3when/rGO composite material is used as lithium cell cathode material, charge-discharge performance is good, even capacity is still up to 429 mAh/g after 10C discharges and recharges 1000 weeks.
Accompanying drawing explanation
Fig. 1 is the prepared nanometer Fe of embodiments of the invention 1
2o
3the XRD collection of illustrative plates of/rGO composite material.
Fig. 2 is the prepared nanometer Fe of embodiments of the invention 1
2o
3the SEM figure of/rGO composite material.
Fig. 3 is the prepared nanometer Fe of embodiments of the invention 1
2o
3the TEM figure of/rGO composite material.
Fig. 4 is the prepared nanometer Fe of embodiments of the invention 2
2o
3the SEM figure of/rGO composite material.
Fig. 5 is that embodiments of the invention 5 are with nanometer Fe
2o
3under the lithium battery different multiplying that/rGO composite material is prepared as negative pole, charge and discharge electrograph.
Fig. 6 is that embodiments of the invention 5 are with nanometer Fe
2o
3the cycle graph of the lithium battery that/rGO composite material is prepared as negative pole under 10C discharges and recharges.
Embodiment
Below in conjunction with drawings and Examples, the present invention will be described in detail.
Graphite oxide used is all synthetic with prior art in the present invention, for example Hummers method.
Embodiment 1
A) by 1.1gFeSO
47H
2o is dissolved in the mixing material of 80ml water and 20ml glycerine and forms mixed solution A;
B) 0.04 graphite oxide is scattered in 40ml water and ultrasonic dispersion 2h, forms solution B;
C) solution B is added in mixed solution A, after stirring, forms mixed solution C;
D) described mixed solution C is put into autoclave, described autoclave is placed under the temperature environment of 180 ℃ and reacts after 10 hours and obtain product;
E) product is used respectively absolute ethyl alcohol and water washing for several times, put into 70 ℃ of vacuum drying chambers and be dried a few hours, obtain described nanometer Fe
2o
3/ rGO composite material.
Product is accredited as α-Fe through X-ray powder diffraction
2o
3, powder X-ray x ray diffraction result as shown in Figure 1; Material pattern by ESEM, transmission electron microscope as Fig. 2, shown in 3, the α-Fe of nano-sheet as we know from the figure
2o
3evenly be embedded in Graphene.
In the middle of this preparation method, because the graphite oxide surface adding has abundant functional group, can be by electrostatic interaction by Fe
2+absorption forms α-Fe from the teeth outwards
2o
3.And the glycerine adding its not only can induce α-Fe
2o
3form the structure of nanometer sheet, and it contains a large amount of hydroxyls and have reproducibility, graphite oxide can be reduced into Graphene.
Embodiment 2
A) by 1.1gFeSO
47H
2o is dissolved in the mixing material of 70ml water and 20ml glycerine and forms mixed solution A;
B) 0.04 graphite oxide is scattered in 40ml water and ultrasonic dispersion 2h, forms solution B;
C) solution B is added in mixed solution A, after stirring, forms mixed solution C;
D) described mixed solution C is put into autoclave, described autoclave is placed under the temperature environment of 140 ℃ and reacts after 10 hours and obtain product;
E) product is used respectively absolute ethyl alcohol and water washing for several times, put into 70 ℃ of vacuum drying chambers and be dried a few hours, obtain described nanometer Fe
2o
3/ rGO composite material.
Products therefrom is as similar in Fig. 1 through X ray powder diffraction, and material pattern passes through ESEM as shown in Figure 4, as we know from the figure α-the Fe of nano-sheet
2o
3evenly be embedded in Graphene.
Embodiment 3
A) by 1.1gFeSO
47H
2o is dissolved in the mixing material of 80ml water and 20ml glycerine and forms mixed solution A;
B) 0.04 graphite oxide is scattered in 40ml water and ultrasonic dispersion 2.5h, forms solution B;
C) solution B is added in mixed solution A, after stirring, forms mixed solution C;
D) described mixed solution C is put into autoclave, described autoclave is placed under the temperature environment of 150 ℃ and reacts after 12 hours and obtain product;
E) product is used respectively absolute ethyl alcohol and water washing for several times, put into 60 ℃ of vacuum drying chambers and be dried a few hours, obtain described nanometer Fe
2o
3/ rGO composite material.
Products therefrom is identified (with the nanometer Fe of embodiment 1 preparation through X ray powder diffraction, ESEM
2o
3/ rGO composite material is similar) known its be nanometer Fe
2o
3/ rGO composite material.
Embodiment 4
A) by 1.1gFeSO
47H
2o is dissolved in the mixing material of 80ml water and 20ml glycerine and forms mixed solution A;
B) 0.04 graphite oxide is scattered in 40ml water and ultrasonic dispersion 2h, forms solution B;
C) solution B is added in mixed solution A, after stirring, forms mixed solution C;
D) described mixed solution C is put into autoclave, described autoclave is placed under the temperature environment of 160 ℃ and reacts after 9 hours and obtain product;
E) product is used respectively absolute ethyl alcohol and water washing for several times, put into 60 ℃ of vacuum drying chambers and be dried a few hours, obtain described nanometer Fe
2o
3/ rGO composite material.
Products therefrom is identified (with the nanometer Fe of embodiment 1 preparation through X ray powder diffraction, ESEM
2o
3/ rGO composite material is similar) known its be nanometer Fe
2o
3/ rGO composite material.
Embodiment 5
By the nanometer Fe of embodiment 1 ~ 4 gained
2o
3/ rGO composite material is prepared into lithium ion battery (routine techniques that preparation method is this technical field, is not described in detail in the present invention) as negative pole
As can be seen from Figure 5, due to nanometer Fe
2o
3for being embedded in the middle of Graphene, so nanometer Fe of the present invention
2o
3/ rGO composite material has good high rate performance as the negative pole of lithium ion battery; And as can be seen from Figure 6, rice Fe of the present invention
2o
3/ rGO composite material discharges and recharges 1000 weeks rear capacity still up to 429 mAh/g as the negative pole of lithium ion battery under the condition of 10C.
The above embodiment has only expressed embodiments of the present invention; it describes comparatively concrete and detailed; but can not therefore be interpreted as the restriction to the scope of the claims of the present invention; as long as employing is equal to the technical scheme that the form of replacement or equivalent transformation obtains, within all should dropping on protection scope of the present invention.
Claims (6)
1. a nanometer Fe
2o
3the preparation method of/rGO composite material, is characterized in that comprising following steps:
A) by FeSO
47H
2o is dissolved in the mixing material of water and glycerine and forms mixed solution A;
B) graphite oxide is scattered in water and ultrasonic dispersion, forms solution B;
C) solution B is added in mixed solution A, after stirring, forms mixed solution C;
D) described mixed solution C is put into autoclave, described autoclave is placed under the temperature environment of 140 ~ 180 ℃ and reacts after 8 ~ 12 hours and obtain product;
E) product is used respectively absolute ethyl alcohol and water washing for several times, put into 60～100 ℃ of vacuum drying chambers and be dried a few hours, obtain described nanometer Fe
2o
3/ rGO composite material.
2. a kind of nanometer Fe according to claim 1
2o
3the preparation method of/rGO composite material, is characterized in that, the water in described step a) and the volume ratio of glycerine are 3.5 ~ 4:1.
3. a kind of nanometer Fe according to claim 2
2o
3the preparation method of/rGO composite material, is characterized in that, the concentration of described mixed solution A is 0.035 ~ 0.045 mol/L.
4. according to a kind of nanometer Fe according to claim 3
2o
3the preparation method of/rGO composite material, is characterized in that, in described step b), ultrasonic time is 1.5 ~ 3h.
5. according to a kind of nanometer Fe according to claim 4
2o
3the preparation method of/rGO composite material, is characterized in that, the concentration of described solution B is 1 ~ 1.5g/L.
6. the nanometer Fe of preparation method's gained claimed in claim 1
2o
3/ rGO composite material is as the application of lithium cell cathode material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410311647.6A CN104124442B (en) | 2014-07-02 | 2014-07-02 | A kind of nanometer Fe2O3The preparation method of/rGO composite and application |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410311647.6A CN104124442B (en) | 2014-07-02 | 2014-07-02 | A kind of nanometer Fe2O3The preparation method of/rGO composite and application |
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| Publication Number | Publication Date |
|---|---|
| CN104124442A true CN104124442A (en) | 2014-10-29 |
| CN104124442B CN104124442B (en) | 2016-07-13 |
Family
ID=51769780
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104528836A (en) * | 2015-01-23 | 2015-04-22 | 哈尔滨工业大学 | Method for regulating and controlling shape of alpha-Fe2O3/graphene composite material |
| CN106854389A (en) * | 2017-01-11 | 2017-06-16 | 山东欧铂新材料有限公司 | A kind of micaceous iron oxide/graphene oxide composite material and preparation method thereof |
| CN107452943A (en) * | 2017-07-13 | 2017-12-08 | 陕西科技大学 | A kind of preparation method of graphene-supported ferriferous oxide self assembly class mulberries structure lithium ion battery negative material |
| CN109295552A (en) * | 2018-09-05 | 2019-02-01 | 山东理工大学 | A kind of preparation method of di-iron trioxide composite graphite alkene cladding cotton carbon fibre material |
| CN112481652A (en) * | 2020-11-20 | 2021-03-12 | 河南大学 | Graphene modified CoOOH/Fe2O3Composite electrode material and preparation method thereof |
| CN114275822A (en) * | 2021-12-31 | 2022-04-05 | 吕梁学院 | Preparation method and application of iron-containing compound modified graphene nano-composite with different morphologies and crystalline phases |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103367720A (en) * | 2013-07-09 | 2013-10-23 | 上海交通大学 | Preparation method of graphene and porous ferric oxide composite |
| CN103464740A (en) * | 2013-08-16 | 2013-12-25 | 安徽师范大学 | Micro and nano alpha-Fe2O3 material and preparation method thereof |
| CN103560228A (en) * | 2013-10-29 | 2014-02-05 | 中国石油大学(华东) | Method for compositing iron oxide and graphene by virtue of hydrothermal process |
-
2014
- 2014-07-02 CN CN201410311647.6A patent/CN104124442B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103367720A (en) * | 2013-07-09 | 2013-10-23 | 上海交通大学 | Preparation method of graphene and porous ferric oxide composite |
| CN103464740A (en) * | 2013-08-16 | 2013-12-25 | 安徽师范大学 | Micro and nano alpha-Fe2O3 material and preparation method thereof |
| CN103560228A (en) * | 2013-10-29 | 2014-02-05 | 中国石油大学(华东) | Method for compositing iron oxide and graphene by virtue of hydrothermal process |
Non-Patent Citations (1)
| Title |
|---|
| BING ZHAO 等: ""Nanorod-like Fe2O3/graphene composite as a high-performance anode material for lithium ion batteries"", 《J APPL ELECTROCHEM》 * |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104528836A (en) * | 2015-01-23 | 2015-04-22 | 哈尔滨工业大学 | Method for regulating and controlling shape of alpha-Fe2O3/graphene composite material |
| CN106854389A (en) * | 2017-01-11 | 2017-06-16 | 山东欧铂新材料有限公司 | A kind of micaceous iron oxide/graphene oxide composite material and preparation method thereof |
| CN106854389B (en) * | 2017-01-11 | 2020-06-26 | 山东欧铂新材料有限公司 | Mica iron oxide/graphene oxide composite material and preparation method thereof |
| CN107452943A (en) * | 2017-07-13 | 2017-12-08 | 陕西科技大学 | A kind of preparation method of graphene-supported ferriferous oxide self assembly class mulberries structure lithium ion battery negative material |
| CN107452943B (en) * | 2017-07-13 | 2020-12-22 | 陕西科技大学 | Preparation method of graphene-loaded iron oxide self-assembled mulberry-like structure lithium ion battery negative electrode material |
| CN109295552A (en) * | 2018-09-05 | 2019-02-01 | 山东理工大学 | A kind of preparation method of di-iron trioxide composite graphite alkene cladding cotton carbon fibre material |
| CN112481652A (en) * | 2020-11-20 | 2021-03-12 | 河南大学 | Graphene modified CoOOH/Fe2O3Composite electrode material and preparation method thereof |
| CN112481652B (en) * | 2020-11-20 | 2022-01-21 | 河南大学 | Graphene modified CoOOH/Fe2O3Composite electrode material and preparation method thereof |
| CN114275822A (en) * | 2021-12-31 | 2022-04-05 | 吕梁学院 | Preparation method and application of iron-containing compound modified graphene nano-composite with different morphologies and crystalline phases |
| CN114275822B (en) * | 2021-12-31 | 2023-12-22 | 吕梁学院 | Preparation method and application of iron-containing compound modified graphene nanocomposite with different morphologies and crystalline phases |
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| Publication number | Publication date |
|---|---|
| CN104124442B (en) | 2016-07-13 |
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