Summary of the invention
The technical problem that basic background technology exists, the present invention proposes a kind of high chromium lining sheet for ball mill, has higher wear resisting property, and hardness is moderate, and has higher elastic limit, yield-point and toughness, and impelling strength can reach 11-13J/cm
2, make liner plate can bear the impact of abrading-ball or mill section.
A kind of high chromium lining sheet for ball mill that the present invention proposes, its compositions in weight percentage comprises: C:1.8-2.2%, Si:0.5-0.7%, Mn:0.9-1.1%, Cr:17-19%, Mo:1.1-1.3%, Ca:0.4-0.7%, Al:0.7-1.2%, Ti:1.5-2.3%, S:0.01-0.04%, P:0.02-0.03%, surplus is Fe and inevitable impurity, wherein can form carbide (Fe, Cr)
7c
3, (Fe, Cr)
7c
3content meet following formula: (Fe, Cr)
7c
3=5 * C+Cr+ (1.7~2.3);
Its preparation process comprises melting, cast, four steps of normalizing and tempering:
S1, melting: take each raw material and carry out obtaining aluminium alloy after melting;
S2, cast: aluminium alloy is come out of the stove and obtained ball grinding machine lining board idiosome to pouring into a mould in mould;
S3, normalizing: the ball grinding machine lining board idiosome that S2 is obtained is heated to 900-1000 ℃, temperature-rise period meets T=(25~35)+arcsin (t+1)
2t is temperature, T unit is ℃, t is the time, and t unit is min, after insulation 10-20min, the average heating speed that continues to heat with 10-15 ℃/min rises to 1150-1200 ℃, after insulation 1.5-2h, take out and air-cooledly obtain ball grinding machine lining board after normalizing to room temperature, its average cooling rate is 20-30 ℃/min;
S4, tempering: ball grinding machine lining board after normalizing is placed in to electric furnace, and the average heating speed by temperature with 9-10 ℃/min rises to after 470-480 ℃, insulation 3.2-3.8h, takes out water-cooled and obtains high chromium lining sheet for ball mill.
Preferably, the weight ratio of Cr and C is 9:1.
Preferably, (Fe, Cr)
7c
3content be 29.5-30.5%.
When producing various iron or iron alloy by iron ore, due in iron ore often association have metal or the nonmetalliferous ores such as phosphorus, sulphur, cause the impurity that contains the elements such as phosphorus, sulphur and be difficult to avoid in final iron or iron alloy.
The present invention adopts the composition of Gao Ge, the eutectic carbides in liner plate is increased, and can improve the anti-corrosion wear of liner plate; By normalizing, make grain refining and distribution of carbides homogenizing again, remove internal stress, increase hardness, the main Types of carbide is wherein (Fe, Cr)
7c
3, and work as (Fe, Cr)
7c
3content meet following formula: (Fe, Cr)
7c
3=5 * C+Cr+ (1.7~2.3), has significantly improved the wear resisting property of liner plate, and the temperature-rise period of normalizing meets T=(25~35)+arcsin (t+1)
2, T is temperature, and T unit is ℃, and t is the time, and t unit is min, and liner plate can be rapidly heated to target temperature, then makes liner plate internal and external temperature remain consistent by insulation; Adopt afterwards the air-cooled too fast liner plate that causes of speed of cooling of avoiding broken; By average tempering, obtain tempering troostite again, the hardness of liner plate is slightly declined, reach 55-59HRC, but have higher elastic limit, yield-point and toughness, impelling strength can reach 11-13J/cm
2, make liner plate can bear the impact of abrading-ball or mill section, reduce the percentage of damage of abrading-ball, mill section or liner plate.
Embodiment
Below, by specific embodiment, technical scheme of the present invention is elaborated.
Embodiment 1
A kind of high chromium lining sheet for ball mill that the present invention proposes, its compositions in weight percentage comprises: C:1.8%, Si:0.7%, Mn:0.9%, Cr:19%, Mo:1.1%, Ca:0.7%, Al:0.7%, Ti:2.3%, S:0.01%, P:0.03%, surplus is Fe and inevitable impurity, wherein can form carbide (Fe, Cr)
7c
3, (Fe, Cr)
7c
3content meet following formula: (Fe, Cr)
7c
3=5 * C+Cr+1.7;
Its preparation process comprises melting, cast, four steps of normalizing and tempering:
S1, melting: take each raw material and carry out obtaining aluminium alloy after melting;
S2, cast: aluminium alloy is come out of the stove and obtained ball grinding machine lining board idiosome to pouring into a mould in mould;
S3, normalizing: the ball grinding machine lining board idiosome that S2 is obtained is heated to 1000 ℃, temperature-rise period meets T=25+arcsin (t+1)
2, T is temperature, T unit is ℃ that t is the time, t unit is min, and after insulation 10min, the average heating speed that continues to heat with 15 ℃/min rises to 1150 ℃, after insulation 2h, take out and air-cooledly obtain ball grinding machine lining board after normalizing to room temperature, its average cooling rate is 20 ℃/min;
S4, tempering: ball grinding machine lining board after normalizing is placed in to electric furnace, and the average heating speed by temperature with 10 ℃/min rises to after 470 ℃, insulation 3.8h, takes out water-cooled and obtains high chromium lining sheet for ball mill.
Embodiment 2
A kind of high chromium lining sheet for ball mill that the present invention proposes, its compositions in weight percentage comprises: C:2.2%, Si:0.5%, Mn:1.1%, Cr:17%, Mo:1.3%, Ca:0.4%, Al:1.2%, Ti:1.5%, S:0.04%, P:0.02%, surplus is Fe and inevitable impurity, wherein can form carbide (Fe, Cr)
7c
3, (Fe, Cr)
7c
3content meet following formula: (Fe, Cr)
7c
3=5 * C+Cr+2.3;
Its preparation process comprises melting, cast, four steps of normalizing and tempering:
S1, melting: take each raw material and carry out obtaining aluminium alloy after melting;
S2, cast: aluminium alloy is come out of the stove and obtained ball grinding machine lining board idiosome to pouring into a mould in mould;
S3, normalizing: the ball grinding machine lining board idiosome that S2 is obtained is heated to 950 ℃, temperature-rise period meets T=20+arcsin (t+1)
2, T is temperature, T unit is ℃ that t is the time, t unit is min, and after insulation 13min, the average heating speed that continues to heat with 14 ℃/min rises to 1180 ℃, after insulation 1.8h, take out and air-cooledly obtain ball grinding machine lining board after normalizing to room temperature, its average cooling rate is 25 ℃/min;
S4, tempering: ball grinding machine lining board after normalizing is placed in to electric furnace, and the average heating speed by temperature with 9.7 ℃/min rises to after 476 ℃, insulation 3.5h, takes out water-cooled and obtains high chromium lining sheet for ball mill.
Embodiment 3
A kind of high chromium lining sheet for ball mill that the present invention proposes, its compositions in weight percentage comprises: C:2%, Si:0.6%, Mn:1%, Cr:18%, Mo:1.2%, Ca:0.6%, Al:1%, Ti:2%, S:0.02%, P:0.025%, surplus is Fe and inevitable impurity, wherein can form carbide (Fe, Cr)
7c
3, (Fe, Cr)
7c
3content meet following formula: (Fe, Cr)
7c
3=5 * C+Cr+2;
Its preparation process comprises melting, cast, four steps of normalizing and tempering:
S1, melting: take each raw material and carry out obtaining aluminium alloy after melting;
S2, cast: aluminium alloy is come out of the stove and obtained ball grinding machine lining board idiosome to pouring into a mould in mould;
S3, normalizing: the ball grinding machine lining board idiosome that S2 is obtained is heated to 900 ℃, temperature-rise period meets T=35+arcsin (t+1)
2, T is temperature, T unit is ℃ that t is the time, t unit is min, and after insulation 10min, the average heating speed that continues to heat with 15 ℃/min rises to 1150 ℃, after insulation 2h, take out and air-cooledly obtain ball grinding machine lining board after normalizing to room temperature, its average cooling rate is 20 ℃/min;
S4, tempering: ball grinding machine lining board after normalizing is placed in to electric furnace, and the average heating speed by temperature with 10 ℃/min rises to after 470 ℃, insulation 3.8h, takes out water-cooled and obtains high chromium lining sheet for ball mill.
The above; it is only preferably embodiment of the present invention; but protection scope of the present invention is not limited to this; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; according to technical scheme of the present invention and inventive concept thereof, be equal to replacement or changed, within all should being encompassed in protection scope of the present invention.