CN104119760B - A kind of carbon nano-tube coating for packer and preparation method thereof - Google Patents
A kind of carbon nano-tube coating for packer and preparation method thereof Download PDFInfo
- Publication number
- CN104119760B CN104119760B CN201410292922.4A CN201410292922A CN104119760B CN 104119760 B CN104119760 B CN 104119760B CN 201410292922 A CN201410292922 A CN 201410292922A CN 104119760 B CN104119760 B CN 104119760B
- Authority
- CN
- China
- Prior art keywords
- carbon nano
- parts
- tube coating
- packer
- cnt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Abstract
The invention discloses a kind of carbon nano-tube coating for packer and preparation method thereof.This carbon nano-tube coating is made up of the component comprising following weight portion: poly hydroxy ethyl acrylate 50 65 parts, brium carbonate 15 25 parts, 10 15 parts of kieselguhr, CNT 28 parts, sodium hydroxymethane sulfonate 10 12 parts, glass microballoon 58 parts, calcium stearate 12 18 parts and titanium dioxide 58 parts.Present invention also offers the preparation method of a kind of carbon nano-tube coating for packer, the carbon nano-tube coating prepared by the method has good dispersibility, either spraying or coating, material surface all can be made to have good homogeneity, its preparation method is simple simultaneously, low cost, can be applicable to all kinds of high speed printing and all kinds of packaging machine surface, can be effectively improved the decay resistance of steel surface.
Description
Technical field
The invention belongs to field of functional materials, particularly relate to a kind of carbon nano-tube coating for packer and preparation side thereof
Method.
Background technology
Existing packaging is mainly produced by device of full automatic packaging, winding the packaging material supplied form continuous print pipe
Cylinder, is packed coil of band material product by packer.
In recent years, along with the continuous progress of all types of industries, building industry and production industry, steel product quality is required the highest
Meanwhile, also harsher to the coating performance of steel surface, the requirement to steel often focuses on its high intensity, low temperature
The aspect such as toughness and processing characteristics.For manufacturing machine context, owing to there is certain frictional force in running,
And heat can be released in continuous operation process, the performance of machine can be affected, in order to enable the machine to good operation, thus
Need the steel meeting stable friction factor under high-speed and high-temperature, noise is low.
Summary of the invention
For above-mentioned demand, a kind of carbon nano-tube coating for packer and system thereof are it is an object of the invention to provide
Preparation Method, the carbon nano-tube coating that the present invention prepares has good dispersibility, and either spraying or coating, all can make material
Surface has good homogeneity, and its preparation method is simple simultaneously, and low cost can be applicable to all kinds of high speed printing and all kinds of packaging
Machine surface, can be effectively improved the decay resistance of steel surface.
The purpose of the present invention can be achieved through the following technical solutions:
A kind of carbon nano-tube coating for packer, is made up of the component comprising following weight portion:
Poly hydroxy ethyl acrylate 50-65 part,
Brium carbonate 15-25 part,
Kieselguhr 10-15 part,
CNT 2-8 part,
Sodium hydroxymethane sulfonate 10-12 part,
Glass microballoon 5-8 part,
Calcium stearate 12-18 part,
Titanium dioxide 5-8 part.
Described CNT is to process through sulphuric acid and phosphoric acid.
The volume of described sulphuric acid and phosphoric acid is 2:3.
The preparation method of a kind of carbon nano-tube coating for packer, comprises the following steps:
(1) just poly hydroxy ethyl acrylate, kieselguhr, brium carbonate, calcium stearate and titanium dioxide add ball mill,
Grind 2-3 hour, standby；
(2) by the mixed liquor adding sulphuric acid and phosphoric acid volume ratio 2:3 in CNT, being placed at 65 DEG C, heating 3 is little
Time, then regulating pH value with sodium carbonate saturated aqueous solution is 7, filters, and adds water ultrasonic cleaning, dries at being placed in 50-65 DEG C, standby
With；
(3) poly hydroxy ethyl acrylate 50-65 part, brium carbonate 15-25 part, kieselguhr 10-15 part, CNT are weighed
2-8 part, sodium hydroxymethane sulfonate 10-12 part, glass microballoon 5-8 part, fat acid calcium 12-18 part and titanium dioxide 5-8 part, add homogenizing
In machine, mixing, obtain carbon nano-tube coating.
The time of described ultrasonic cleaning is 10-15 minute, and temperature is 30-35 DEG C.
Mixing temperature in described step 3 is 80-110 DEG C.
Compared with prior art, beneficial effects of the present invention:
(1) carbon nano-tube coating for packer of the present invention has good dispersibility, either spraying or painting
Cover, material surface all can be made to have good homogeneity.
(2) carbon nano-tube coating for packer of the present invention is compared with traditional coating, has more preferable associativity,
Can use at a higher temperature, and coating surface has stable coefficient of friction.
(3) present invention is for the carbon nano-tube coating of packer, and its preparation method is simple, and low cost can be applicable to all kinds of
High speed printing and all kinds of packaging machine surface, can be effectively improved the decay resistance of steel surface.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is further illustrated.
Embodiment 1
(1) just poly hydroxy ethyl acrylate, kieselguhr, brium carbonate, calcium stearate and titanium dioxide add ball mill,
Grind 2 hours, standby；
(2) by the mixed liquor adding sulphuric acid and phosphoric acid volume ratio 2:3 in CNT, being placed at 65 DEG C, heating 3 is little
Time, then regulating pH value with sodium carbonate saturated aqueous solution is 7, filters, and adds water, and at 30 DEG C, ultrasonic cleaning 10 minutes, are placed in 55
Dry at DEG C, standby；
(3) poly hydroxy ethyl acrylate 50kg, brium carbonate 20kg, kieselguhr 15kg, CNT 6kg, hydroxyl first are weighed
Base sodium sulfonate 12kg, glass microballoon 5kg, fat acid calcium 12kg and titanium dioxide 8kg, add in homogenizer, mix, obtain at 80 DEG C
Carbon nano-tube coating.
Embodiment 2
(1) just poly hydroxy ethyl acrylate, kieselguhr, brium carbonate, calcium stearate and titanium dioxide add ball mill,
Grind 2 hours, standby；
(2) by the mixed liquor adding sulphuric acid and phosphoric acid volume ratio 2:3 in CNT, being placed at 65 DEG C, heating 3 is little
Time, then regulating pH value with sodium carbonate saturated aqueous solution is 7, filters, and adds ultrasonic cleaning 15 minutes at 35 DEG C of water, is placed in 50 DEG C
Lower drying, standby；
(3) poly hydroxy ethyl acrylate 65kg, brium carbonate 25kg, kieselguhr 10kg, CNT 8kg, hydroxyl first are weighed
Base sodium sulfonate 10kg, glass microballoon 8kg, fat acid calcium 18kg and titanium dioxide 6kg, add in homogenizer, mix at 100 DEG C,
To carbon nano-tube coating.
Embodiment 3
(1) just poly hydroxy ethyl acrylate, kieselguhr, brium carbonate, calcium stearate and titanium dioxide add ball mill,
Grind 3 hours, standby；
(2) by the mixed liquor adding sulphuric acid and phosphoric acid volume ratio 2:3 in CNT, being placed at 65 DEG C, heating 3 is little
Time, then regulating pH value with sodium carbonate saturated aqueous solution is 7, filters, and adds ultrasonic cleaning 15 minutes at 35 DEG C of water, is placed in 65 DEG C
Lower drying, standby；
(3) poly hydroxy ethyl acrylate 60kg, brium carbonate 15kg, kieselguhr 13kg, CNT 2kg, hydroxyl first are weighed
Base sodium sulfonate 10kg, glass microballoon 5kg, fat acid calcium 16kg and titanium dioxide 5kg, add in homogenizer, mix at 110 DEG C,
To carbon nano-tube coating.
Table 1
The invention is not restricted to embodiment here, those skilled in the art are according to the announcement of the present invention, without departing from the present invention
Improvement and amendment that category is made all should be within protection scope of the present invention.
Claims (1)
1. the carbon nano-tube coating for packer, it is characterised in that be made up of the component comprising following weight portion:
Poly hydroxy ethyl acrylate 50-65 part,
Brium carbonate 15-25 part,
Kieselguhr 10-15 part,
CNT 2-8 part,
Sodium hydroxymethane sulfonate 10-12 part,
Glass microballoon 5-8 part,
Calcium stearate 12-18 part,
Titanium dioxide 5-8 part；
Described CNT is to process through sulphuric acid and phosphoric acid；
The volume of described sulphuric acid and phosphoric acid is 2: 3；
Described a kind of carbon nano-tube coating for packer is prepared by following preparation method:
(1) poly hydroxy ethyl acrylate, kieselguhr, brium carbonate, calcium stearate and titanium dioxide are separately added into ball mill,
Grind 2-3 hour, standby；
(2) by adding sulphuric acid and the mixed liquor of phosphoric acid of volume ratio 2: 3 in CNT, being placed at 65 DEG C, heating 3 is little
Time, then regulating pH value with sodium carbonate saturated aqueous solution is 7, filters, and adds water ultrasonic cleaning, dries at being placed in 50-65 DEG C,
Standby；
(3) poly hydroxy ethyl acrylate 50-65 part, brium carbonate 15-25 part, kieselguhr 10-15 part, CNT are weighed
2-8
Part, sodium hydroxymethane sulfonate 10-12 part, glass microballoon 5-8 part, calcium stearate 12-18 part and titanium dioxide 5-8 part,
Add in homogenizer, mixing, obtain carbon nano-tube coating；
The time of described ultrasonic cleaning is 10-15 minute, and temperature is 30-35 DEG C；
Mixing temperature in described step (3) is 80-110 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410292922.4A CN104119760B (en) | 2014-06-27 | 2014-06-27 | A kind of carbon nano-tube coating for packer and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410292922.4A CN104119760B (en) | 2014-06-27 | 2014-06-27 | A kind of carbon nano-tube coating for packer and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104119760A CN104119760A (en) | 2014-10-29 |
| CN104119760B true CN104119760B (en) | 2016-07-13 |
Family
ID=51765406
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410292922.4A Expired - Fee Related CN104119760B (en) | 2014-06-27 | 2014-06-27 | A kind of carbon nano-tube coating for packer and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104119760B (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102286234A (en) * | 2011-05-09 | 2011-12-21 | 陕西科技大学 | Preparation method of modified acrylic resin leather coating material of carbon nano tubes (CNTs) in situ |
| CN103013256A (en) * | 2012-12-24 | 2013-04-03 | 青岛宣威涂层材料有限公司 | Invisible coating material and preparation method thereof |
| CN103232781A (en) * | 2013-05-03 | 2013-08-07 | 昆明理工大学 | Preparation method of carbon-nanotube-reinforced polyaniline metal anticorrosive paint |
| CN103484009A (en) * | 2013-09-23 | 2014-01-01 | 句容市睿远科技有限公司 | Waterproof paint for high-speed rail and preparation method thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5735430B2 (en) * | 2008-11-27 | 2015-06-17 | コリア インスティテュート オブ インダストリアル テクノロジー | Coating composition having excellent conductivity and corrosion resistance, method for producing the same, and article coated using the same |
-
2014
- 2014-06-27 CN CN201410292922.4A patent/CN104119760B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102286234A (en) * | 2011-05-09 | 2011-12-21 | 陕西科技大学 | Preparation method of modified acrylic resin leather coating material of carbon nano tubes (CNTs) in situ |
| CN103013256A (en) * | 2012-12-24 | 2013-04-03 | 青岛宣威涂层材料有限公司 | Invisible coating material and preparation method thereof |
| CN103232781A (en) * | 2013-05-03 | 2013-08-07 | 昆明理工大学 | Preparation method of carbon-nanotube-reinforced polyaniline metal anticorrosive paint |
| CN103484009A (en) * | 2013-09-23 | 2014-01-01 | 句容市睿远科技有限公司 | Waterproof paint for high-speed rail and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104119760A (en) | 2014-10-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP2531564B1 (en) | A process for the preparation of carbon black pellets | |
| CN102690403B (en) | Modified phenol formaldehyde resin and preparation method thereof | |
| CN106995303A (en) | A kind of bamboo and woods fiber plate and preparation method thereof | |
| CN102796428A (en) | Plant paint and preparation method thereof | |
| CN104119760B (en) | A kind of carbon nano-tube coating for packer and preparation method thereof | |
| CN103866616A (en) | Softening agent and preparation method thereof | |
| CN100497816C (en) | Ultramicro stearic amide aqueous emulsifying dispersion solution and process for producing the same | |
| CN103772862B (en) | A kind of partial alcoholysis type pva powder being easily dispersed in water and preparation method thereof | |
| CN103866629A (en) | Papermaking processing aid and preparation method thereof | |
| CN105064118A (en) | High-performance packing paper | |
| CN103709353A (en) | High-hydroxyl methylated melamine resin and preparation method thereof | |
| CN104805691B (en) | A kind of weaving smooth agent and preparation method thereof | |
| CN103556532B (en) | A kind of retention aid for paper making and preparation method thereof | |
| CN103540271B (en) | A kind of Phenolic resin wood adhesive properties-correcting agent and application thereof | |
| CN105903889A (en) | Anti-adhesion precoated sand | |
| CN104325529A (en) | Paraffin emulsion | |
| CN103866627B (en) | A kind of polyurethane sizing agent and preparation method thereof | |
| CN103866636B (en) | A kind of urea resin wet strength agent and preparation method thereof | |
| CN103981759B (en) | Emulsion-type wet strength agent and preparation method thereof | |
| CN103170804A (en) | Manufacturing technique of medical fastening screw | |
| CN107825550A (en) | A kind of Wood modifier and preparation method thereof | |
| CN103866626B (en) | A kind of arabic gum sizing agent and preparation method thereof | |
| CN106747897A (en) | A kind of water supports the preparation method of ball | |
| CN104436985A (en) | Formaldehyde absorbing material and preparation method thereof | |
| CN103866622A (en) | Bismaleimide resin sizing agent and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| CB03 | Change of inventor or designer information |
Inventor after: Gao Zhuqing Inventor before: Zhang Taiyuan |
|
| COR | Change of bibliographic data | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20160617 Address after: 030024 Shanxi province Taiyuan city Berlin District Wan wa flow Road No. 66 Applicant after: Taiyuan Univ. of Science & Technology Address before: High tech Industrial Development Zone, Suzhou City, Jiangsu province 215000 Xuguan Industrial Park Hu Yang Road No. 26 Applicant before: Suzhou Shengbaiwei Package Equipment Co., Ltd. |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160713 Termination date: 20170627 |