Summary of the invention
For the problems referred to above, the object of this invention is to provide a kind of false proof grating with hyperchannel color changeable effect, there is the public and expert's double anti-forge function.
A false proof grating, it has hyperchannel color changeable effect, and described false proof grating comprises basalis, grating information layer and the dielectric layer of stratification successively, and described grating information layer is the sub-wave length grating of the sinusoidal relief type quasi-reflection of one dimension volume.
In the present invention's one better embodiment, described grating information layer is for to be formed by the hot pressing of nickel mother matrix, and described nickel mother matrix is made by the hyperfine photoetching of laser hologram or the accurate exposure technique of electron beam.
In the present invention's one better embodiment, described basalis is made by thermoplastic resin or glass; Described grating information layer is made by transparent resin, and its refractive index is 1.4~1.9; Described dielectric layer is made by high refractive index transparent material, and its refractive index is greater than 1.9, and thickness is 25~60nm; Described high refractive index transparent material is zinc sulphide or titania.
In the present invention's one better embodiment, described sub-wave length grating is monocycle grating, and its cycle is 320~420nm, and grating depth is 80~140nm.
In the present invention's one better embodiment, while observing described false proof grating with 25~miter angle, around the axle rotation perpendicular to the plane of delineation, observe, can reproduce the beautiful high-purity light of different colours; While observing described false proof grating with 60~80 degree angles, observing perpendicular to grating grid in-plane, can see first-order diffraction iridescence.
In the present invention's one better embodiment, described sub-wave length grating is binary cycle grating, it comprises minor cycle sinusoidal grating and large period sinusoidal grating, and the cycle of described minor cycle sinusoidal grating is 320~420nm, and the cycle of described large period sinusoidal grating is 600~900nm.
In the present invention's one better embodiment, while observing described false proof grating with 25~miter angle, around the axle rotation perpendicular to the plane of delineation, observe, can reproduce the beautiful high-purity light of different colours; While observing described false proof grating with 60~80 degree angles and with 5~30 degree angles, observing perpendicular to grating grid in-plane, all can see first-order diffraction iridescence.
The invention provides a kind of anti-false trademark, the main part of described anti-false trademark is false proof grating as mentioned above.
The invention provides a kind of gilding film, it comprises basalis, release layer, grating information layer, dielectric layer and the hot melt gum layer of stratification successively, and described grating information layer is the sub-wave length grating of the sinusoidal relief type quasi-reflection of one dimension volume.
The invention provides a kind of composite membrane, it comprises basalis, grating information layer, dielectric layer and the black pressure-sensitive adhesive layer of stratification successively, and described grating information layer is the sub-wave length grating of the sinusoidal relief type quasi-reflection of one dimension volume.
With respect to prior art, described false proof grating has hyperchannel color changeable effect, can combine well with expert identification the public is false proof, can effectively strengthen anti-counterfeit capability and the range of application of antifalsification label.
Above-mentioned explanation is only the general introduction of technical solution of the present invention, in order to better understand technological means of the present invention, and can be implemented according to the content of instructions, and for above and other objects of the present invention, feature and advantage can be become apparent, below especially exemplified by embodiment, and coordinate accompanying drawing, be described in detail as follows.
Embodiment
Below in conjunction with drawings and the specific embodiments, the present invention is further detailed explanation.
Refer to Fig. 1, the invention provides a kind of false proof grating 100, it has hyperchannel color changeable effect, and described false proof grating 100 comprises basalis 10, grating information layer 20 and the dielectric layer 30 of stratification successively, and described grating information layer 20 is the sub-wave length grating of the sinusoidal relief type quasi-reflection of one dimension volume.
Be understandable that, the characteristic dimension of sub-wave length grating has the identical order of magnitude with optical wavelength, light wave polarization has important impact to the diffracting effect of light wave, scalar diffraction theory can not practical requirement, must use the strict Vector Diffraction Theory based on Theory of Electromagnetic Field to analyze Grating Properties, such as rigorous coupled wave is theoretical.The parameter that affects sub-wave length grating diffraction characteristic is a lot, comprise that cycle T, refractive index n 1, groove depth h, the plating thickness d of deielectric-coating of incident light wavelength, incidence angle θ, incident orientation angle and grating are, the refractive index n of deielectric-coating 2 etc., as shown in Figure 2, when in these parameters, any one changes, diffraction efficiency all will change.When Grating Properties is analyzed, the present embodiment is theoretical based on rigorous coupled wave, utilize genetic algorithm iteration optimization to there is the false proof grating structural parameter of specific hyperchannel color changeable effect, comprise that cycle T, refractive index n 1, groove depth h, the plating thickness d of deielectric-coating of incidence angle θ, grating are, the refractive index n of deielectric-coating 2, these parameters mate mutually, make described false proof grating 100 have specific hyperchannel color changeable effect.
The hyperchannel color changeable effect of described false proof grating 100 specifically can be presented as:
Cycle T, refractive index n 1, groove depth h, the plating thickness d of deielectric-coating by designing the grating of mutual coupling are, the refractive index n of deielectric-coating 2.Perpendicular to grating grid in-plane, observing described false proof grating 100, when incident light is about 45 °, the color of the zero order light of reproduction is purple; When incident light is about 42 °, the color of the zero order light of reproduction is blue; When incident light is about 30 °, the color of the zero order light of reproduction is bright green; When incident light is about 70 °, reproduction be to dazzle beautiful first-order diffraction iridescence.Around the axle perpendicular to the plane of delineation, rotate approximately 45 ° and observe described false proof grating 100, when incident light is about 45 °, the color of the zero order light of reproduction is bright green; Around the axle rotation perpendicular to the plane of delineation, to 90 ° of described false proof gratings 100 of observation, when incident light is about 45 °, the color of the zero order light of reproduction is golden yellow; When incident light is about 30 °, the color of the zero order light of reproduction is peony.
While making described false proof grating 100, described grating information layer 20 and described dielectric layer 30 are formed at the surface, the same side of described basalis 10 successively, wherein, described dielectric layer 30 is for being formed at the surperficial coating of described grating information layer 20, and its shape, structure are determined by shape, the structure of described grating information layer 20.
In the present embodiment, described basalis 10 is made by thermoplastic resin or glass, particularly, can adopt and make as materials such as polycarbonate (PC), polyethylene terephthalate (PET), Polyvinylchloride (PVC), polymethylmethacrylate (PMMA), tygon (PE) or polypropylene (BOPP).
In the present embodiment, described grating information layer 20 is made by transparent resin, and its refractive index is 1.4~1.9, and described grating information layer 20 is formed by the hot pressing of nickel mother matrix, be understandable that, described nickel mother matrix can be made by the hyperfine photoetching of laser hologram or the accurate exposure technique of electron beam.
In the present embodiment, described dielectric layer 30 is made by high refractive index transparent material, and its refractive index is different from the refractive index of described grating information layer 20.Preferably, the refractive index of described dielectric layer 30 is greater than 1.9, and thickness is 25~60nm.
Be understandable that, described high refractive index transparent material can be the materials such as zinc sulphide or titania.
Embodiment 1
See also Fig. 1 and Fig. 2, described sub-wave length grating is monocycle grating, and the grating information layer 20 in described false proof grating 100 is monocycle optical grating construction, and its cycle T is 320~420nm, and grating depth is 80~140nm.
Described false proof grating 100 has hyperchannel colour change function, even under cloudy day or dim astigmatic environment, also can all reproduce different colours at a plurality of viewing planes.Particularly, while observing described false proof grating 100 with 25~miter angle, around the axle rotation perpendicular to the plane of delineation, observe, can reproduce the beautiful high-purity light of different colours, there is hyperchannel color changeable effect, without additionally observing by optical instrument; While observing described false proof grating 100 with 60~80 degree angles, observing perpendicular to grating grid in-plane, can obviously see first-order diffraction iridescence.
Embodiment 2
Refer to Fig. 3, described sub-wave length grating is binary cycle grating, be that grating information layer in described false proof grating 100 20 is binary cycle optical grating construction, it comprises minor cycle sinusoidal grating and large period sinusoidal grating, the cycle T 1 of described minor cycle sinusoidal grating is 320~420nm, and the cycle T 2 of described large period sinusoidal grating is 600~900nm.
Described false proof grating 100 has hyperchannel colour change function, even under cloudy day or dim astigmatic environment, also can all reproduce different colours at a plurality of viewing planes.Particularly, while observing described false proof grating with 25~miter angle, around the axle rotation perpendicular to the plane of delineation, observe, can reproduce the beautiful high-purity light of different colours, there is hyperchannel color changeable effect, and without additionally observing by optical instrument; While observing described false proof grating with 60~80 degree angles and with 5~30 degree angles, observing perpendicular to grating grid in-plane, all can see first-order diffraction iridescence.
For verifying the characteristic of described false proof grating 100, the present embodiment utilizes ultraviolet-visible pectrophotometer in the situation that of different viewing planes and Different Light incident angle, zero order reflection rate to described false proof grating 100 is tested, as shown in Fig. 4 a to 4d, known, described false proof grating 100 has the reflectivity higher than 80% at royal purple light, green glow, golden yellow light and red spectral band, and has the half-wave bandwidth higher than 50nm, and the high-purity luminance brightness that therefore described false proof grating 100 reproduces is high.
Be understandable that, utilize described false proof grating 100, can form the printing figure message that Clairvoyant type hologram marking film covers, be printed on confidential documents, above encrypted document, neither affect the observation of laser hologram image, also do not affect reading of document content.In the angle of normal reading file, because the reflection wavelength angle of incident angle and false proof figure does not overlap, its false proof figure can stash because cannot see, and does not affect the normal reading to document content; And by the document certain angle that tilts, the false proof figure of hiding will be shown.
Described false proof grating 100, under diffuse illumination condition, can obviously be observed hyperchannel color changeable effect by naked eyes, and change color is specific, describable; The zero order light of reproducing is polarized light, can utilize coherent detection instrument to identify.Therefore, described false proof grating 100 can combine with expert identification well by the public is false proof, can effectively strengthen anti-counterfeit capability and the range of application of antifalsification label.
Described false proof grating 100 also can combine with gilding film, composite membrane, transfer membrane etc., forms novel, diversified anti-fake product, is applied in the various products such as card card, tobacco and wine, clothes, cosmetics, medicine, computer hardware.
Second embodiment of the invention provides a kind of anti-false trademark, and its main part is described false proof grating 100.Described anti-false trademark combines relief type grating and reflective volume type grating well, therefore can be used in moulding replication, mass industrialized production, and cost is low.
Refer to Fig. 5, third embodiment of the invention provides a kind of gilding film 200, and it comprises basalis 10, grating information layer 20, dielectric layer 30, release layer 40 and hot melt gum layer 50.Described basalis 10, described release layer 40, described grating information layer 20, described dielectric layer 30 and described hot melt gum layer 50 be stratification successively, and described grating information layer 20 is the sub-wave length grating of the sinusoidal relief type quasi-reflection of one dimension volume.
Described release layer 40 plays dissociation in the use of described gilding film 200, and the raw material using is all the wax that fusing point is 80-90 ℃ conventionally.Described hot melt gum layer 50 is the superficial layer of described gilding film 200, and it is covered in described dielectric layer 30, when the use of described gilding film 200, plays the effect adhering to mutually with printed material surface.
Be understandable that, described gilding film 200 is the application of described false proof grating 100.
Refer to Fig. 6, fourth embodiment of the invention provides a kind of composite membrane 300, and it comprises basalis 10, grating information layer 20, dielectric layer 30 and black pressure-sensitive adhesive layer 60.Described basalis 10, described grating information layer 20, described dielectric layer 30 and described black pressure-sensitive adhesive layer 60 be stratification successively, and described grating information layer 20 is the sub-wave length grating of the sinusoidal relief type quasi-reflection of one dimension volume.
Described black pressure-sensitive adhesive 60 is covered in described dielectric layer 30, and it can absorb parasitic light, increases color contrast, strengthen hyperchannel color change effect.
Be understandable that, described composite membrane 300 is the application of described false proof grating 100.
The above, only embodiments of the invention, not the present invention is done to any pro forma restriction, although the present invention discloses as above with embodiment, yet not in order to limit the present invention, any those skilled in the art, do not departing within the scope of technical solution of the present invention, when can utilizing the technology contents of above-mentioned announcement to make a little change or being modified to the equivalent embodiment of equivalent variations, in every case be not depart from technical solution of the present invention content, any simple modification of above embodiment being done according to technical spirit of the present invention, equivalent variations and modification, all still belong in the scope of technical solution of the present invention.