CN104098322B - A kind of method of producing blue bricks watt - Google Patents

A kind of method of producing blue bricks watt Download PDF

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CN104098322B
CN104098322B CN201410311543.5A CN201410311543A CN104098322B CN 104098322 B CN104098322 B CN 104098322B CN 201410311543 A CN201410311543 A CN 201410311543A CN 104098322 B CN104098322 B CN 104098322B
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kiln car
discrete material
brick
tile base
roasting
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CN104098322A (en
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海龙
隋淑梅
赵庆彪
宋杨
游志忠
东巳宙
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Liaoning Technical University
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Liaoning Technical University
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Abstract

The invention belongs to building material field, be specifically related to a kind of method of producing blue bricks watt.First dried brick and tile base kiln car is loaded into tunnel furnace and carries out preheating and roasting by the present invention, then kiln car pull-out is entered discrete material and throw in district, being fallen by kiln car cover covers on kiln car, discrete material dispensing port is provided with on the top of kiln car cover, throwing in discrete material by discrete material dispensing port enters in kiln car cover, and be covered in around brick and tile base, nozzle of calming the anger is provided with on the downside of kiln car cover, non-oxidizing gas is sprayed in kiln car cover, discrete material is made to be filled in space between brick and tile base, after covering discrete material, kiln car is drawn in cooling zone, discrete material is separated with brick and tile base, obtaining outward appearance is caesious blue bricks watt product.The present invention adopts discrete material as heat-eliminating medium, cools without the need to spraying water in firing chamber, and the speed of cooling and the uniformity coefficient of cooling are easy to control, and avoids the infringement of water to brick and tile base and kiln, improves the quality of blue bricks watt product.

Description

A kind of method of producing blue bricks watt
Technical field
The invention belongs to building material field, be specifically related to a kind of method of producing blue bricks watt.
Background technology
Blue bricks watt carries the unique and thick and heavy architectural aesthetic orientation of the Chinese nation, and giving plain, simple and unsophisticated and quiet aesthetic feeling, is that irreplaceable material of construction repaired by a lot of newly-built building in the style of the ancients and ancient building.Although blue bricks intensity, difference of hardness compared with common brick is few in addition, the performance in anti-oxidant, aquation, atmospheric corrosion etc. is better than common brick.
During firing brick-and tile, the ferro element in adobe material during roasting, makes product take on a red color under oxidizing atmosphere, and under reducing atmosphere roasting time, make product be cyan or grey.Produce traditional method many uses water chestnut kiln of blue bricks to fire, exist energy consumption high, pollute the shortcomings such as large and production efficiency is low.
The technology of blue bricks watt produced by the use tunnel furnace that occurs in recent years, the primary process of producing is: entrucking enters kiln-preheating-oxidizing roasting-reducing roasting-water-spraying control-naturally cooling-kiln discharge, and reducing roasting wherein and water-spraying control link are the key links making the finished product present cyan.For avoiding the brick and tile base through reducing roasting at high temperature again oxidized and making the finished product take on a red color, the method displacement air that usual employing is sprayed water in firing chamber and make brick and tile base be cooled to safety temperature about 400 DEG C under oxygen-free atmosphere, then be placed in general air ambient and be cooled to kiln discharge.The shortcoming of this method is that speed of cooling and uniformity coefficient are wayward, and water has infringement to brick and tile base and kiln.
For the shortcoming of water-spraying control, patent 93109410.0 proposes the method for another kind of cooling brick and tile base, the method arranges gas passage between tunnel furnace preheating zone malleation place and cooling zone afterbody, uses the gas of deoxidation to form circulation in preheating zone and cooling zone thus realizes the object of anoxic cooling brick and tile base.The shortcoming of the method is that the tightness of gas circulation requires higher, and the oxygen in recycle gas is not easily removed completely, and brick and tile base secondary oxidation may occur.
Patent 200710111254.0 proposes the Processes and apparatus that blue bricks watt produced by another kind tunnel furnace, and its technological process is: dress base enters tunnel furnace-preheating-oxidizing roasting-high temperature kiln discharge-cover upper inverted bell-reducing roasting-anaerobic cooling-naturally cooling-unload cover-kiln discharge.Its technical essential carries out reducing roasting by passing into the mixed gas that Sweet natural gas and the ratio of air are 2: 7 after the brick and tile base cover upper inverted bell of oxidizing roasting, in bell jar, then passes into the mixed gas that nitrogen and the ratio of Sweet natural gas are 9: 1 carry out anaerobic cooling.In bell jar, separately establish cooling line, cold wind can be passed in cooling line and bell jar environment is cooled indirectly.The shortcoming of the method in bell jar, passes into nitrogen when being cooling brick and tile base and sky hot gas adds production cost, production technique more complicated.
Summary of the invention
For prior art Problems existing, the invention provides a kind of method of producing blue bricks watt, object makes production process more simple and easy to do, reduces production cost simultaneously.
The technical scheme realizing the object of the invention is carried out according to following steps:
First preheating is carried out in the preheating zone that dried brick and tile base kiln car is loaded into tunnel furnace, the brick and tile base after preheating enters roasting band and carries out roasting;
Roasting band wicket is opened after roasting terminates, kiln car pull-out is entered discrete material and throws in district, being fallen by kiln car cover covers on kiln car, discrete material dispensing port is provided with on the top of kiln car cover, throw in discrete material by discrete material dispensing port to enter in kiln car cover, and be covered in around brick and tile base, on the downside of described kiln car cover, be provided with nozzle of calming the anger, in kiln car cover, spray non-oxidizing gas, make discrete material be filled in space between brick and tile base;
After covering discrete material, open cooling zone lifting wicket, kiln car is drawn in cooling zone, is separated by discrete material after cooling with brick and tile base, obtaining outward appearance is caesious blue bricks watt product.
In described roasting process, different according to product requirement, oxidizing roasting is first carried out to the brick and tile base after preheating and carries out reducing roasting, directly roasting or directly roasting in reducing environment in an oxidizing environment again.
When described covering material is covered in around brick and tile base, by vibration, waves kiln car or in kiln car cover, carry out mechanical agitation and lift and make discrete material be filled in space between brick and tile base.
The another kind of mode of described covering discrete material is, brick and tile base is unloaded from kiln car, be placed in cooling tank, one deck discrete material is spread in advance bottom cooling tank, then in cooling tank, throw in discrete material be covered on brick and tile base, then the cooling tank immigration cooling zone covering discrete material is cooled.
Described discrete material is flyash, mine tailing, haydite, bastard coal rock ballast, slag, sand or rubble, and described mine tailing comprises iron tailings, gold tailings, copper tailing;
Described discrete material is preheating to 200 DEG C ~ 800 DEG C and carries out thermal pretreatment before input.
Particulate or powdery combustiblematerials can be added in described discrete material.
Compared with prior art, feature of the present invention and beneficial effect are:
The present invention produces blue bricks watt, lower than traditional water chestnut kiln production energy consumption, pollute little, production efficiency is high, adopting discrete material as heat-eliminating medium, and to cool without the need to spraying water in firing chamber, the speed of cooling and the uniformity coefficient of cooling are easy to control, and avoid the infringement of water to brick and tile base and kiln;
The present invention forms gas circulation without the need to using depleted gas in preheating zone and cooling zone, tightness is less demanding, effectively can avoid the secondary oxidation of brick and tile base, the present invention without the need to carrying out reducing roasting and anaerobic cooling in airtight bell jar, also do not need to arrange cooling line to cool the environment closed, production technique is relatively simple.
The present invention is when discrete material selects flyash or bastard coal rock ballast, because discrete material itself is containing a certain proportion of carbon component, at high temperature consume the oxygen in discrete material gap and generate carbon monoxide and carbon dioxide, make to be in reducing atmosphere around brick and tile base, and control the speed of cooling of brick and tile base by exothermic heat of reaction.Additionally can also add the combustiblematerialss such as a certain amount of coal dust, bastard coal rock ballast, wood chip in addition, to regulate generation and the generation speed of carbon monoxide and carbonic acid gas, be controlled the speed of cooling of brick and tile base by exothermic heat of reaction simultaneously.For the discrete material not containing combustiblematerials composition, also the combustiblematerialss such as a certain amount of coal dust, bastard coal rock ballast, wood chip can additionally be added, to regulate generation and the speed of generation of carbon monoxide and carbonic acid gas, controlled the speed of cooling of brick and tile base by exothermic heat of reaction simultaneously.Also thermal pretreatment is carried out to discrete material in the present invention, the speed of cooling of brick and tile base can be avoided so too fast, thus make the contraction process of brick and tile base slack-off, improve the quality of blue bricks watt product.
Accompanying drawing explanation
Fig. 1 is that the present invention produces one of process schematic representation of blue bricks watt;
Wherein: 1: brick and tile base; 2: kiln car; 3: tunnel furnace; 4: roasting band wicket; 5: cooling zone lifting wicket; 6: discrete material throws in district's kiln car; A: preheating zone; B: roasting band; C: discrete material throws in district; D: cooling zone; B ': oxidizing roasting band; B ": reducing roasting band;
Fig. 2 is the structural representation of the discrete material input district kiln car in Fig. 1;
Wherein: 7: discrete material; 8: kiln car cover; 9: nozzle of calming the anger; 10: discrete material dispensing port;
Fig. 3 is the another kind of mode schematic diagram that the present invention produces that blue bricks watt carries out discrete material covering;
Wherein: 11: cooling tank.
Embodiment
As shown in Figure of description, first the dried brick and tile base 1 preheating zone A that kiln car 2 is loaded into tunnel furnace is carried out preheating, the brick and tile base after preheating enters roasting band B and carries out roasting;
Roasting band wicket 4 is opened after roasting terminates, kiln car 2 pull-out is entered discrete material and throws in district C, being fallen by kiln car cover 8 covers on kiln car 2, discrete material dispensing port is provided with on the top of kiln car cover 8, throw in discrete material 1 by discrete material dispensing port 10 to enter in kiln car cover 8, and be covered in around brick and tile base 1, on the downside of described kiln car cover 8, be provided with nozzle 9 of calming the anger, in kiln car cover, spray non-oxidizing gas, make discrete material 7 be filled in space between brick and tile base 1;
After covering discrete material 7, open cooling zone lifting wicket 5, kiln car 2 is drawn in cooling zone D, is separated by discrete material 7 after cooling with brick and tile base 1, obtaining outward appearance is caesious blue bricks watt product.
Embodiment 1
In the present embodiment, brick and tile base raw material adopts and accounts for the clay of raw material total mass 40% and the coal gangue of 60%, and discrete material adopts self-igniting coal gangue slag.
Coal gangue is broken through twice Hubei Province formula, and the largest particle particle diameter after fragmentation is 5mm; Break up starting material, mix, the amount of water of compound in whipping process is 11%; Compound digestion time is 10 days, and the compound after ageing adds water to 12% while stirring; Blank forming adopts compression moulding, and forming pressure is 20MPa; Adobe natural air drying after shaping 20 days.
The dried brick and tile base 1 preheating zone A that kiln car 2 is loaded into tunnel furnace is carried out preheating, and the brick and tile base after preheating enters roasting band B and carries out reducing roasting, and the temperature rise rate of roasting is 60 DEG C/h, and sintering temperature is 1000 DEG C, and soaking time is 180min;
Roasting band wicket 4 is opened after roasting terminates, kiln car 2 pull-out is entered discrete material and throws in district C, being fallen by kiln car cover 8 covers on kiln car 2, discrete material dispensing port is provided with on the top of kiln car cover 8, throw in discrete material 1 by discrete material dispensing port 10 to enter in kiln car cover 8, and be covered in around brick and tile base 1, on the downside of described kiln car cover 8, be provided with nozzle 9 of calming the anger, in kiln car cover, spray non-oxidizing gas, make discrete material 7 be filled in space between brick and tile base 1;
After covering discrete material 7, open cooling zone lifting wicket 5, kiln car 2 is drawn in cooling zone D, is separated by discrete material 7 after cooling with brick and tile base 1, obtaining outward appearance is caesious blue bricks watt product.
Embodiment 2
In the present embodiment, brick and tile base raw material adopts and accounts for the clay of raw material total mass 40% and the coal gangue of 60%, and discrete material adopts iron tailings.
Coal gangue is broken through twice Hubei Province formula, and the largest particle particle diameter after fragmentation is 5mm; Break up starting material, mix, the amount of water of compound in whipping process is 11%; Compound digestion time is 10 days, and the compound after ageing adds water to 12% while stirring; Blank forming adopts compression moulding, and forming pressure is 20MPa; Adobe natural air drying after shaping 20 days.
The dried brick and tile base 1 preheating zone A that kiln car 2 is loaded into tunnel furnace is carried out preheating, and the brick and tile base after preheating enters roasting band B and carries out roasting, and roasting band B is divided into oxidizing roasting band with reducing roasting band , first carry out oxidizing roasting to brick and tile base 1, then carry out reducing roasting, the temperature rise rate of roasting is 60 DEG C/h, and sintering temperature is 1000 DEG C, and soaking time is 180min;
Roasting band wicket 4 is opened after roasting terminates, kiln car 2 pull-out is entered discrete material and throws in district C, being fallen by kiln car cover 8 covers on kiln car 2, discrete material dispensing port is provided with on the top of kiln car cover 8, throw in discrete material 1 by discrete material dispensing port 10 to enter in kiln car cover 8, and be covered in around brick and tile base 1, on the downside of described kiln car cover 8, be provided with nozzle 9 of calming the anger, in kiln car cover, spray non-oxidizing gas, make discrete material 7 be filled in space between brick and tile base 1;
After covering discrete material 7, open cooling zone lifting wicket 5, kiln car 2 is drawn in cooling zone D, is separated by discrete material 7 after cooling with brick and tile base 1, obtaining outward appearance is caesious blue bricks watt product.
Embodiment 3
In the present embodiment, brick and tile base raw material adopts and accounts for the clay of raw material total mass 80% and the coal gangue of 20%, and discrete material adopts haydite, and in discrete material, extra interpolation accounts for the particulate coal dust of discrete material quality 6%.
Coal gangue is broken through twice Hubei Province formula, and the largest particle particle diameter after fragmentation is 5mm; Break up starting material, mix, the amount of water of compound in whipping process is 13%; Compound digestion time is 10 days, and the compound after ageing adds water to 14% while stirring; Blank forming adopts compression moulding, and forming pressure is 20MPa; Adobe natural air drying after shaping 20 days.
The dried brick and tile base 1 preheating zone A that kiln car 2 is loaded into tunnel furnace is carried out preheating, and the brick and tile base after preheating enters roasting band B and carries out oxidizing roasting, and the temperature rise rate of roasting is 60 DEG C/h, and sintering temperature is 950 DEG C, and soaking time is 240min;
Roasting band wicket 4 is opened after roasting terminates, kiln car 2 pull-out is entered discrete material and throws in district C, being fallen by kiln car cover 8 covers on kiln car 2, discrete material dispensing port is provided with on the top of kiln car cover 8, throw in discrete material 1 by discrete material dispensing port 10 to enter in kiln car cover 8, and be covered in around brick and tile base 1, on the downside of described kiln car cover 8, be provided with nozzle 9 of calming the anger, in kiln car cover, spray non-oxidizing gas, make discrete material 7 be filled in space between brick and tile base 1;
After covering discrete material 7, open cooling zone lifting wicket 5, kiln car 2 is drawn in cooling zone D, is separated by discrete material 7 after cooling with brick and tile base 1, obtaining outward appearance is caesious blue bricks watt product.
Embodiment 4
In the present embodiment, brick and tile base raw material adopts and accounts for the clay of raw material total mass 20% and the coal gangue of 80%, and discrete material adopts slag.
Coal gangue is broken through twice Hubei Province formula, and the largest particle particle diameter after fragmentation is 5mm; Break up starting material, mix, the amount of water of compound in whipping process is 11%; Compound digestion time is 10 days, and the compound after ageing adds water to 12% while stirring; Blank forming adopts compression moulding, and forming pressure is 20MPa; Adobe natural air drying after shaping 20 days.
The dried brick and tile base 1 preheating zone A that kiln car 2 is loaded into tunnel furnace is carried out preheating, and the brick and tile base after preheating enters roasting band B and carries out reducing roasting, and the temperature rise rate of roasting is 80 DEG C/h, and sintering temperature is 1050 DEG C, and soaking time is 180min;
Roasting band wicket 4 is opened after roasting terminates, kiln car 2 pull-out is entered discrete material and throws in district C, being fallen by kiln car cover 8 covers on kiln car 2, discrete material dispensing port is provided with on the top of kiln car cover 8, throwing in discrete material 1 by discrete material dispensing port 10 enters in kiln car cover 8, and be covered in around brick and tile base 1, simultaneously also by vibration, the mode of waving kiln car 2 makes discrete material 4 be filled in space between brick and tile base 1, nozzle 9 of calming the anger is provided with on the downside of described kiln car cover 8, non-oxidizing gas is sprayed in kiln car cover, discrete material 7 is made to be filled in space between brick and tile base 1,
After covering discrete material 7, open cooling zone lifting wicket 5, kiln car 2 is drawn in cooling zone D, is separated by discrete material 7 after cooling with brick and tile base 1, obtaining outward appearance is caesious blue bricks watt product.
Embodiment 5
In the present embodiment, brick and tile base raw material adopts the shale of 100%, and discrete material adopts sand, and in discrete material, extra interpolation accounts for the particulate coal dust of discrete material quality 5%.
Shale is broken through twice Hubei Province formula, and the largest particle particle diameter after fragmentation is 5mm; Stir starting material, the amount of water in whipping process is 12%; Compound digestion time is 10 days, and the compound after ageing adds water to 13% while stirring; Blank forming adopts compression moulding, and forming pressure is 20MPa; Adobe natural air drying after shaping 20 days.
The dried brick and tile base 1 preheating zone A that kiln car 2 is loaded into tunnel furnace is carried out preheating, and the brick and tile base after preheating enters roasting band B and carries out reducing roasting, and the temperature rise rate of roasting is 60 DEG C/h, and sintering temperature is 1050 DEG C, and soaking time is 240min;
Roasting band wicket 4 is opened after roasting terminates, kiln car 2 pull-out is entered discrete material and throws in district C, being fallen by kiln car cover 8 covers on kiln car 2, discrete material dispensing port is provided with on the top of kiln car cover 8, throwing in discrete material 1 by discrete material dispensing port 10 enters in kiln car cover 8, and be covered in around brick and tile base 1, mode simultaneously also by carrying out machinery lift in kiln car cover 6 makes discrete material 4 be filled in space between brick and tile base 1, nozzle 9 of calming the anger is provided with on the downside of described kiln car cover 8, non-oxidizing gas is sprayed in kiln car cover, discrete material 7 is made to be filled in space between brick and tile base 1,
After covering discrete material 7, open cooling zone lifting wicket 5, kiln car 2 is drawn in cooling zone D, is separated by discrete material 7 after cooling with brick and tile base 1, obtaining outward appearance is caesious blue bricks watt product.
Embodiment 6
In the present embodiment, brick and tile base raw material adopts and accounts for the clay of raw material total mass 40% and the coal gangue of 60%, and discrete material adopts copper tailing.
Coal gangue is broken through twice Hubei Province formula, and the largest particle particle diameter after fragmentation is 5mm; Break up starting material, mix, the amount of water of compound in whipping process is 11%; Compound digestion time is 10 days, and the compound after ageing adds water to 12% while stirring; Blank forming adopts compression moulding, and forming pressure is 20MPa; Adobe natural air drying after shaping 20 days.
The dried brick and tile base 1 preheating zone A that kiln car 2 is loaded into tunnel furnace is carried out preheating, and the brick and tile base after preheating enters roasting band B and carries out reducing roasting, and the temperature rise rate of roasting is 60 DEG C/h, and sintering temperature is 1000 DEG C, and soaking time is 180min;
Roasting band wicket 4 is opened after roasting terminates, brick and tile base 1 is unloaded from kiln car 2, be placed in cooling tank 11, one deck discrete material 7 is spread in advance bottom cooling tank 11, then in cooling tank 11, throw in discrete material 7 is covered on brick and tile base 1, again the cooling tank 11 covering discrete material 7 is moved into cooling zone D to cool, be separated by discrete material 7 after cooling with brick and tile base 1, obtaining outward appearance is caesious blue bricks watt product.
Embodiment 7
In the present embodiment, brick and tile base raw material adopts and accounts for the clay of raw material total mass 40% and the coal gangue of 60%, and discrete material adopts rubble.
Coal gangue is broken through twice Hubei Province formula, and the largest particle particle diameter after fragmentation is 5mm; Break up starting material, mix, the amount of water of compound in whipping process is 11%; Compound digestion time is 10 days, and the compound after ageing adds water to 12% while stirring; Blank forming adopts compression moulding, and forming pressure is 20MPa; Adobe natural air drying after shaping 20 days.
The dried brick and tile base 1 preheating zone A that kiln car 2 is loaded into tunnel furnace is carried out preheating, and the brick and tile base after preheating enters roasting band B and carries out reducing roasting, and the temperature rise rate of roasting is 60 DEG C/h, and sintering temperature is 1000 DEG C, and soaking time is 180min;
Roasting band wicket 4 is opened after roasting terminates, kiln car 2 pull-out is entered discrete material and throws in district C, being fallen by kiln car cover 8 covers on kiln car 2, discrete material dispensing port is provided with on the top of kiln car cover 8, throw in discrete material 1 by discrete material dispensing port 10 to enter in kiln car cover 8, and be covered in around brick and tile base 1, on the downside of described kiln car cover 8, be provided with nozzle 9 of calming the anger, in kiln car cover, spray non-oxidizing gas, make discrete material 7 be filled in space between brick and tile base 1; Described discrete material is preheating to 200 DEG C ~ 800 DEG C and carries out thermal pretreatment before input;
After covering discrete material 7, open cooling zone lifting wicket 5, kiln car 2 is drawn in cooling zone D, is separated by discrete material 7 after cooling with brick and tile base 1, obtaining outward appearance is caesious blue bricks watt product.

Claims (6)

1. produce a method for blue bricks watt, it is characterized in that carrying out according to following steps:
First preheating is carried out in the preheating zone that dried brick and tile base kiln car is loaded into tunnel furnace, the brick and tile base after preheating enters roasting band and carries out roasting;
Roasting band wicket is opened after roasting terminates, kiln car pull-out is entered discrete material and throws in district, being fallen by kiln car cover covers on kiln car, discrete material dispensing port is provided with on the top of kiln car cover, throw in discrete material by discrete material dispensing port to enter in kiln car cover, and be covered in around brick and tile base, on the downside of described kiln car cover, be provided with nozzle of calming the anger, in kiln car cover, spray non-oxidizing gas, make discrete material be filled in space between brick and tile base;
After covering discrete material, open cooling zone lifting wicket, kiln car is drawn in cooling zone, is separated by discrete material after cooling with brick and tile base, obtaining outward appearance is caesious blue bricks watt product.
2. a kind of method of producing blue bricks watt according to claim 1, it is characterized in that in described roasting process, different according to product requirement, oxidizing roasting is first carried out to the brick and tile base after preheating and carries out reducing roasting, directly roasting or directly roasting in reducing environment in an oxidizing environment again.
3. a kind of method of producing blue bricks watt according to claim 1, when it is characterized in that described discrete material is covered in around brick and tile base, by vibration, wave kiln car or in kiln car cover, carry out mechanical agitation and lift and make discrete material be filled in space between brick and tile base.
4. a kind of method of producing blue bricks watt according to claim 1, it is characterized in that described discrete material is flyash, mine tailing, haydite, bastard coal rock ballast, slag, sand or rubble, described mine tailing is iron tailings, gold tailings, copper tailing.
5. a kind of method of producing blue bricks watt according to claim 1, is characterized in that described discrete material is preheating to 200 DEG C ~ 800 DEG C and carries out thermal pretreatment before input.
6. a kind of method of producing blue bricks watt according to claim 1, is characterized in that adding particulate or powdery combustiblematerials in described discrete material.
CN201410311543.5A 2014-07-02 2014-07-02 A kind of method of producing blue bricks watt Active CN104098322B (en)

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CN109053141B (en) * 2018-09-06 2021-11-16 涞水国兴兆烨建筑材料制造有限公司 Method for making ancient building black bricks by using household garbage
CN112010643A (en) * 2020-08-11 2020-12-01 安徽龙钰徽派古建工艺制品有限公司 Preparation method of high-strength grey brick for ancient building restoration
CN114907099A (en) * 2022-03-18 2022-08-16 冯文锦 Method for producing mud blank sintered product by using solid powder to separate oxygen and reduce
CN115784713A (en) * 2022-11-11 2023-03-14 李扬 Method for preparing black brick or green tile from iron-selecting tailings

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CN101328056A (en) * 2007-06-20 2008-12-24 北京市西六建材有限责任公司 Processes and apparatus for producing grey brick
CN102826833A (en) * 2012-08-20 2012-12-19 河南省偃师市古典园林有限公司 Porcelain grey tile without carburization and sintering method thereof
CN103351152A (en) * 2013-08-05 2013-10-16 敬治民 Production method of environment-friendly antiqued black bricks

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CN1101026A (en) * 1993-07-31 1995-04-05 杨兆安 Method for production of blue brick and tile by using tunnel kiln
CN101328056A (en) * 2007-06-20 2008-12-24 北京市西六建材有限责任公司 Processes and apparatus for producing grey brick
CN102826833A (en) * 2012-08-20 2012-12-19 河南省偃师市古典园林有限公司 Porcelain grey tile without carburization and sintering method thereof
CN103351152A (en) * 2013-08-05 2013-10-16 敬治民 Production method of environment-friendly antiqued black bricks

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