CN104098142A - Preparation method of hexagram-shaped epsilon-MnO2 and ORR application of epsilon-MnO2 - Google Patents
Preparation method of hexagram-shaped epsilon-MnO2 and ORR application of epsilon-MnO2 Download PDFInfo
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- CN104098142A CN104098142A CN201410328623.1A CN201410328623A CN104098142A CN 104098142 A CN104098142 A CN 104098142A CN 201410328623 A CN201410328623 A CN 201410328623A CN 104098142 A CN104098142 A CN 104098142A
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- preparation
- mno2
- epsilon
- mno
- solution
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- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- 229910006343 ε-MnO2 Inorganic materials 0.000 title abstract 6
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims abstract description 39
- 239000012153 distilled water Substances 0.000 claims abstract description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 238000003756 stirring Methods 0.000 claims abstract description 13
- BZSXEZOLBIJVQK-UHFFFAOYSA-N 2-methylsulfonylbenzoic acid Chemical compound CS(=O)(=O)C1=CC=CC=C1C(O)=O BZSXEZOLBIJVQK-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229940071125 manganese acetate Drugs 0.000 claims abstract description 10
- UOGMEBQRZBEZQT-UHFFFAOYSA-L manganese(2+);diacetate Chemical compound [Mn+2].CC([O-])=O.CC([O-])=O UOGMEBQRZBEZQT-UHFFFAOYSA-L 0.000 claims abstract description 10
- 238000001027 hydrothermal synthesis Methods 0.000 claims abstract description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 238000006722 reduction reaction Methods 0.000 claims description 3
- 239000000463 material Substances 0.000 abstract description 8
- 230000015572 biosynthetic process Effects 0.000 abstract description 5
- 239000002994 raw material Substances 0.000 abstract description 2
- 238000003786 synthesis reaction Methods 0.000 abstract description 2
- 238000004090 dissolution Methods 0.000 abstract 1
- 238000009776 industrial production Methods 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 13
- 239000007788 liquid Substances 0.000 description 6
- 230000003197 catalytic effect Effects 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 238000000634 powder X-ray diffraction Methods 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 238000005755 formation reaction Methods 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 239000007772 electrode material Substances 0.000 description 2
- VASIZKWUTCETSD-UHFFFAOYSA-N oxomanganese Chemical compound [Mn]=O VASIZKWUTCETSD-UHFFFAOYSA-N 0.000 description 2
- 238000012797 qualification Methods 0.000 description 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000003637 basic solution Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 229910000314 transition metal oxide Inorganic materials 0.000 description 1
Abstract
Description
Claims (6)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201410328623.1A CN104098142B (en) | 2014-07-11 | 2014-07-11 | A kind of ε-MnO of hexagonal star-shape2Preparation method and ORR application thereof |
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CN201410328623.1A CN104098142B (en) | 2014-07-11 | 2014-07-11 | A kind of ε-MnO of hexagonal star-shape2Preparation method and ORR application thereof |
Publications (2)
Publication Number | Publication Date |
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CN104098142A true CN104098142A (en) | 2014-10-15 |
CN104098142B CN104098142B (en) | 2016-05-04 |
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CN201410328623.1A Expired - Fee Related CN104098142B (en) | 2014-07-11 | 2014-07-11 | A kind of ε-MnO of hexagonal star-shape2Preparation method and ORR application thereof |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111389391A (en) * | 2020-04-11 | 2020-07-10 | 广东中投环保股份有限公司 | Ce doped-MnO2Preparation method and application of nanoparticles |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103193273A (en) * | 2013-05-03 | 2013-07-10 | 广东工业大学 | Preparation method of extra-long manganese dioxide nanowires |
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2014
- 2014-07-11 CN CN201410328623.1A patent/CN104098142B/en not_active Expired - Fee Related
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103193273A (en) * | 2013-05-03 | 2013-07-10 | 广东工业大学 | Preparation method of extra-long manganese dioxide nanowires |
Non-Patent Citations (1)
Title |
---|
YUN-SHUANG DING, ET AL.: "Hydrothermal growth of manganese dioxide into three-dimensional hierarchical nanoarchitectures", 《ADVANCED FUNCTIONAL MATERIALS》 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111389391A (en) * | 2020-04-11 | 2020-07-10 | 广东中投环保股份有限公司 | Ce doped-MnO2Preparation method and application of nanoparticles |
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CN104098142B (en) | 2016-05-04 |
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C41 | Transfer of patent application or patent right or utility model | ||
CB03 | Change of inventor or designer information |
Inventor after: Lan Bang Inventor before: Chen Xiuqiong Inventor before: Lan Qingfeng |
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COR | Change of bibliographic data | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20151027 Address after: 514021, Guangdong, Meizhou Province, No. 135, South Road, bin Fang Avenue building Applicant after: Lan Bang Address before: 516000 Guangdong County of Longmen city in Huizhou Province Road in Xishi Village Applicant before: Chen Xiuqiong |
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C41 | Transfer of patent application or patent right or utility model | ||
CB03 | Change of inventor or designer information |
Inventor after: Liu Rongcong Inventor after: Liu Sicheng Inventor after: Hong Ling Inventor after: Fang Dan Inventor after: Lei Weiqiang Inventor before: Lan Bang |
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TA01 | Transfer of patent application right |
Effective date of registration: 20160325 Address after: 362300, Gong 3, Gong Village, wharf Town, Nanan City, Fujian, Quanzhou Applicant after: Lei Weiqiang Address before: 514021, Guangdong, Meizhou Province, No. 135, South Road, bin Fang Avenue building Applicant before: Lan Bang |
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Granted publication date: 20160504 Termination date: 20200711 |
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CF01 | Termination of patent right due to non-payment of annual fee |