CN104087959A - Preparation method of aluminum alloy tube descaling operating fluid - Google Patents

Preparation method of aluminum alloy tube descaling operating fluid Download PDF

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Publication number
CN104087959A
CN104087959A CN201410268193.9A CN201410268193A CN104087959A CN 104087959 A CN104087959 A CN 104087959A CN 201410268193 A CN201410268193 A CN 201410268193A CN 104087959 A CN104087959 A CN 104087959A
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China
Prior art keywords
weight percent
stirring
throw
throwing
acid
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Pending
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CN201410268193.9A
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Chinese (zh)
Inventor
吴功益
朱剑文
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ZHANGJIAGANG SALEM FINE TUBING CO Ltd
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ZHANGJIAGANG SALEM FINE TUBING CO Ltd
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Application filed by ZHANGJIAGANG SALEM FINE TUBING CO Ltd filed Critical ZHANGJIAGANG SALEM FINE TUBING CO Ltd
Priority to CN201410268193.9A priority Critical patent/CN104087959A/en
Publication of CN104087959A publication Critical patent/CN104087959A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a preparation method of an aluminum alloy tube descaling operating fluid. The aluminum alloy tube descaling operating fluid is prepared by mixing raw materials comprising 65-72wt% of water, 0.3-0.8wt% of citric acid, 0.5-1.5wt% of anhydrous sodium carbonate, 2-7wt% of triethanolamine, 2-7wt% of fatty alcohol polyoxyethylene ether, 2-7wt% of alkylphenol polyoxyethylene, 0.2-0.9wt% of hexamethylenetetramine, 0.5-1.2wt% of nitric acid, 6-10wt% of tartaric acid, 1-3wt% of trisodium phosphate, 2-5wt% of ethanol, and the balance hydrofluoric acid at normal temperature. The aluminum alloy tube descaling operating fluid has the advantages of simple operation, no heating, good cleaning effect, no corrosion to the surface of an aluminum alloy tube, glossiness maintenance, repeated use, no damages to skins, low carbon, environmental protection and cost saving.

Description

A kind of preparation method of aluminium-alloy pipe scale removal working fluid
Technical field
The present invention relates to chemical cleaning technique field, especially a kind of preparation method who is applicable to aluminium-alloy pipe scale removal working fluid.
Background technology
At present, in order to remove the dirt of aluminium-alloy pipe, traditional cleaning agent formula is for heating to 90 ℃-95 ℃ after the 5:4:3:8 mixing by mass percentage of nitric acid, hydrofluoric acid, hydrochloric acid and water, aluminium alloy to be cleaned soak 4-4.5 hour ability process clean, 8 hours can only cleaning aluminum alloy pipe 40-45 ton, efficiency is not high, and because nitric acid, hydrofluoric acid and hydrochloric acid are through heating generation acid mist, human body is had to great harm, severe contamination air, the discharge of waste acid water is severe contamination water resources also.
Summary of the invention
The technical problem to be solved in the present invention is: overcome the deficiencies in the prior art, provide a kind of without heating, can cleaning aluminum alloy pipe erode metallic surfaces not again, the preparation method of aluminium-alloy pipe scale removal working fluid harmless and free from environmental pollution.
The technical solution adopted for the present invention to solve the technical problems is: a kind of preparation method of aluminium-alloy pipe scale removal working fluid, has following steps:
(1), under normal temperature, in stirrer, adding weight percent is the water of 65%-72%;
(2), throw in while stirring the citric acid that weight percent is 0.3%-0.8%;
(3), throw in while stirring the anhydrous sodium carbonate that weight percent is 0.5%-1.5%;
(4), throw in while stirring the trolamine that weight percent is 2%-7%;
(5), throw in while stirring the fatty alcohol-polyoxyethylene ether that weight percent is 2%-7%;
(6), throw in while stirring the alkylphenol polyoxyethylene that weight percent is 2%-7%;
(7), throw in while stirring the vulkacit H that weight percent is 0.2%-0.9%;
(8), throw in while stirring the pin acid that weight percent is 0.5%-1.2%;
(9), throw in while stirring the tartrate that weight percent is 6%-10%;
(10), throw in while stirring the tertiary sodium phosphate that weight percent is 1%-3%;
(11), throw in while stirring the ethanol that weight percent is 2%-5%;
(12), throw in while stirring the hydrofluoric acid that weight percent is surplus;
(13), after whole feeding in raw material, stir again and within 20-30 minute, be finished product;
The weight percent of wherein said nitric acid is 25%.
Further, the preparation method of described aluminium-alloy pipe scale removal working fluid, has following steps:
(1), under normal temperature, in stirrer, adding weight percent is 68.9% water;
(2), throwing in while stirring weight percent is 0.5% citric acid;
(3), throwing in while stirring weight percent is 1% anhydrous sodium carbonate;
(4), throwing in while stirring weight percent is 5% trolamine;
(5), throwing in while stirring weight percent is 5% fatty alcohol-polyoxyethylene ether;
(6), throwing in while stirring weight percent is 3% alkylphenol polyoxyethylene;
(7), throw in while stirring the vulkacit H that weight percent is 0.6%-1.2%;
(8), throwing in while stirring weight percent is the acid of 1% pin;
(9), throwing in while stirring weight percent is 8% tartrate;
(10), throwing in while stirring weight percent is 2% tertiary sodium phosphate;
(11), throwing in while stirring weight percent is 3% ethanol;
(12), throwing in while stirring weight percent is 2% hydrofluoric acid;
(13), after whole feeding in raw material, stir again and within 20-30 minute, be finished product;
The weight percent of wherein said nitric acid is 25%.
The invention has the beneficial effects as follows: the present invention is simple to operate, without heating, cleaning performance is good, the surface of not corroding aluminium-alloy pipe, the glossiness of maintenance aluminium-alloy pipe simultaneously; And aluminium-alloy pipe scale removal working fluid can reuse, to skin contact without injury, low-carbon environment-friendly, cost-saving.
Embodiment
The present invention is further illustrated now.In embodiment, fatty alcohol-polyoxyethylene ether is JFC permeate agent, and alkylphenol polyoxyethylene is emulsifier op-10, and vulkacit H is urotropine.
A preparation method for aluminium-alloy pipe scale removal working fluid, has following steps: under (1), normal temperature, in stirrer, adding weight percent is the water of 689 kilograms; (2), throw in while stirring 5 kilograms of content 99.3% citric acids; (3), throw in while stirring 10 kilograms of anhydrous sodium carbonates; (4), throw in while stirring 50 kilograms of content 85% trolamines; (5), throw in while stirring 50 kilograms of JFC permeate agents; (6), throw in while stirring the emulsifier op-10 of 30 kilograms; (7), throwing in while stirring content is 6 kilograms of 99% urotropines; (8), throw in while stirring 10 kilograms of content 25% pin acid; (9), throw in while stirring 80 kilograms, tartrate; (10), throw in while stirring 20 kilograms of tertiary sodium phosphates; (11), throw in while stirring 30 kilograms of ethanol; (12), throw in while stirring 20 kilograms, content 90% hydrofluoric acid; (13), after whole feeding in raw material, stir again and within 20-30 minute, be finished product.
The above-mentioned foundation desirable embodiment of the present invention of take is enlightenment, and by above-mentioned description, relevant staff can, within not departing from the scope of this invention technological thought, carry out various change and modification completely.The technical scope of this invention is not limited to the content on specification sheets, must determine its technical scope according to claim scope.

Claims (2)

1. a preparation method for aluminium-alloy pipe scale removal working fluid, is characterized in that: have following steps:
(1), under normal temperature, in stirrer, adding weight percent is the water of 65%-72%;
(2), throw in while stirring the citric acid that weight percent is 0.3%-0.8%;
(3), throw in while stirring the anhydrous sodium carbonate that weight percent is 0.5%-1.5%;
(4), throw in while stirring the trolamine that weight percent is 2%-7%;
(5), throw in while stirring the fatty alcohol-polyoxyethylene ether that weight percent is 2%-7%;
(6), throw in while stirring the alkylphenol polyoxyethylene that weight percent is 2%-7%;
(7), throw in while stirring the vulkacit H that weight percent is 0.2%-0.9%;
(8), throw in while stirring the pin acid that weight percent is 0.5%-1.2%;
(9), throw in while stirring the tartrate that weight percent is 6%-10%;
(10), throw in while stirring the tertiary sodium phosphate that weight percent is 1%-3%;
(11), throw in while stirring the ethanol that weight percent is 2%-5%;
(12), throw in while stirring the hydrofluoric acid that weight percent is surplus;
(13), after whole feeding in raw material, stir again and within 20-30 minute, be finished product;
The weight percent of wherein said nitric acid is 25%.
2. the preparation method of aluminium-alloy pipe scale removal working fluid according to claim 1, is characterized in that: have following steps:
(1), under normal temperature, in stirrer, adding weight percent is 68.9% water;
(2), throwing in while stirring weight percent is 0.5% citric acid;
(3), throwing in while stirring weight percent is 1% anhydrous sodium carbonate;
(4), throwing in while stirring weight percent is 5% trolamine;
(5), throwing in while stirring weight percent is 5% fatty alcohol-polyoxyethylene ether;
(6), throwing in while stirring weight percent is 3% alkylphenol polyoxyethylene;
(7), throw in while stirring the vulkacit H that weight percent is 0.6%-1.2%;
(8), throwing in while stirring weight percent is the acid of 1% pin;
(9), throwing in while stirring weight percent is 8% tartrate;
(10), throwing in while stirring weight percent is 2% tertiary sodium phosphate;
(11), throwing in while stirring weight percent is 3% ethanol;
(12), throwing in while stirring weight percent is 2% hydrofluoric acid;
(13), after whole feeding in raw material, stir again and within 20-30 minute, be finished product;
The weight percent of wherein said nitric acid is 25%.
CN201410268193.9A 2014-06-16 2014-06-16 Preparation method of aluminum alloy tube descaling operating fluid Pending CN104087959A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410268193.9A CN104087959A (en) 2014-06-16 2014-06-16 Preparation method of aluminum alloy tube descaling operating fluid

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410268193.9A CN104087959A (en) 2014-06-16 2014-06-16 Preparation method of aluminum alloy tube descaling operating fluid

Publications (1)

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CN104087959A true CN104087959A (en) 2014-10-08

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CN201410268193.9A Pending CN104087959A (en) 2014-06-16 2014-06-16 Preparation method of aluminum alloy tube descaling operating fluid

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107022766A (en) * 2016-01-29 2017-08-08 比亚迪股份有限公司 The method of metal surface cleaning agent, preparation method and cleaning metal surface
CN107675227A (en) * 2017-09-29 2018-02-09 徐州轩辕铝业有限公司 A kind of process of surface treatment of aluminium alloy extrusions

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101135056A (en) * 2007-09-29 2008-03-05 吴铭鑫 Stainless steel cleaning agent
CN102400165A (en) * 2011-11-28 2012-04-04 常州市凯纳环保科技有限公司 Cleaning agent for stainless steel seamless stay tubes and preparation method for cleaning agent
CN102953076A (en) * 2011-08-31 2013-03-06 杨细龙 Preparation method of descaling treating fluid for stainless steel weld joints

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101135056A (en) * 2007-09-29 2008-03-05 吴铭鑫 Stainless steel cleaning agent
CN102953076A (en) * 2011-08-31 2013-03-06 杨细龙 Preparation method of descaling treating fluid for stainless steel weld joints
CN102400165A (en) * 2011-11-28 2012-04-04 常州市凯纳环保科技有限公司 Cleaning agent for stainless steel seamless stay tubes and preparation method for cleaning agent

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107022766A (en) * 2016-01-29 2017-08-08 比亚迪股份有限公司 The method of metal surface cleaning agent, preparation method and cleaning metal surface
CN107675227A (en) * 2017-09-29 2018-02-09 徐州轩辕铝业有限公司 A kind of process of surface treatment of aluminium alloy extrusions

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Application publication date: 20141008