CN104086955B - A kind of low cost oil resistant heatproof PET cable jacket material - Google Patents

A kind of low cost oil resistant heatproof PET cable jacket material Download PDF

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Publication number
CN104086955B
CN104086955B CN201410295174.5A CN201410295174A CN104086955B CN 104086955 B CN104086955 B CN 104086955B CN 201410295174 A CN201410295174 A CN 201410295174A CN 104086955 B CN104086955 B CN 104086955B
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pet
oil resistant
low cost
cable jacket
pvdf
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CN104086955A (en
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谢华
谢罡
张静
束维武
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Zhejiang xinyuanhong polymer materials Co., Ltd
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Lvbao Cable Group Co Ltd
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Abstract

The present invention relates to a kind of CABLE MATERIALS, be specifically related to a kind of low cost oil resistant heatproof PET cable jacket material, this material comprises the raw material of following weight part: waste PET bottle sheet particle 30-34, polyvinylidene difluoride (PVDF) 23-25, EVA12-15, calcium-zinc composite stabilizing agent 2-3, ammonium molybdate 1-3, cupric oxide 4-5, ferric oxide 3-4, Sodium hexametaphosphate 99 2-3,10-HAD 1-2, acetyl tributyl citrate 16-18, octyl epoxy stearate 12-13, calcium sulfate 3-6, N330 carbon black 30-40, antimonous oxide 5-6, auxiliary agent 14-16; This insulating material combines the advantage of the raw materials such as PET, polyvinylidene difluoride (PVDF), EVA, the strength of materials of preparation is high, satisfactory mechanical property, oil resistant and chemical corrosion, high temperature resistant low temperature aging, resistance to oxidation, resistance to x radiation x, long service life, and in formula, PET is refuse reclamation, effectively reduce production cost, there is great marketing using value.

Description

A kind of low cost oil resistant heatproof PET cable jacket material
Technical field
The present invention relates to a kind of CABLE MATERIALS, be specifically related to a kind of low cost oil resistant heatproof PET cable jacket material and preparation method thereof.
Background technology
Along with expanding economy, need to use the place of cable to become variation, stricter and various requirement has been had to the performance index of cable jacket material, such as insulativity, tensile strength, use temperature, the indexs such as flame retardant properties all have strict requirement, the performance of continuous raising sheath material, it is the active demand of economy and social development, there is poor fire more in traditional sheath material, poor chemical stability, high temperature is yielding, poor mechanical property, the problems such as work-ing life is short, bring a lot of inconvenience to actual use, even threaten the security of the lives and property of people, therefore, be badly in need of changing original sheath material formula, improve material property, with the demand that appropriate cable market is various.
Summary of the invention
The object of the invention is to, a kind of low cost oil resistant heatproof PET cable jacket material is provided, improve the performance of conventional P ET plastics, it is made to possess good mechanical property and processing characteristics, reclaim waste PET material and effectively reduce material cost, the material of preparation can adapt to specific environment for use condition, and the technical solution used in the present invention is as follows:
A kind of low cost oil resistant heatproof PET cable jacket material; it is characterized in that; material of the present invention comprises the component of following weight part: waste PET bottle sheet particle 30-34; polyvinylidene difluoride (PVDF) 23-25; EVA12-15, calcium-zinc composite stabilizing agent 2-3, ammonium molybdate 1-3; cupric oxide 4-5; ferric oxide 3-4, Sodium hexametaphosphate 99 2-3,10-HAD 1-2; acetyl tributyl citrate 16-18; octyl epoxy stearate 12-13, calcium sulfate 3-6, N330 carbon black 30-40; antimonous oxide 5-6, auxiliary agent 14-16.
Described auxiliary agent comprises the raw material of following weight part: lazurite 20-24, hexamethylene diisocyanate 3-4, tri (propylene glycol) diacrylate 2-3, altax 3-4, Z 250 1-2, tetrafluoroethylene 3-4, Iron-ore Slag powder 6-8, aluminium hydroxide 8-10, jade 2-3, calcium stearate 1-2, vinyltriethoxysilane 2-3, Fructus Zanthoxyli oil 1-2; Preparation method is by lazurite, jade is put into calcining furnace and calcine 3-4 hour at 550-570 DEG C, and cooling, puts into 12-15% hydrochloric acid soln and soak 2-3 hour after being ground into 50-100 order, filter out lazurite, jade powder, clear water is cleaned, and dries, be ground into 200-300 order powder, mix with other remaining component, grinding distribution 1-2 hour, to obtain final product.
Described a kind of low cost oil resistant heatproof PET cable jacket material, its preparation method is: cleaned by waste PET bottle sheet particle and drain, with polyvinylidene difluoride (PVDF), EVA blended evenly after, add other remaining components, send in high-speed kneading machine, at 120-180 DEG C, mediate 6-15min, after the cooling of kneading material, send into twin screw extruder granulation, obtain insulating material of the present invention.
Present invention incorporates the advantage of the raw materials such as PET, polyvinylidene difluoride (PVDF), EVA, improve the performance of conventional P ET plastics, make it have good processing characteristics and mechanical property, the strength of materials of preparation is high, satisfactory mechanical property, oil resistant and chemical corrosion, high temperature resistant low temperature aging, resistance to oxidation, resistance to x radiation x, long service life, and in formula, PET is refuse reclamation, effectively reduce production cost, there is great marketing using value.
Embodiment
Embodiment
The present embodiment comprises the raw material of following weight part: waste PET bottle sheet particle 34, polyvinylidene difluoride (PVDF) 25, EVA15; calcium-zinc composite stabilizing agent 3, ammonium molybdate 2, cupric oxide 5; ferric oxide 4, Sodium hexametaphosphate 99 3,10-HAD 2; acetyl tributyl citrate 18; octyl epoxy stearate 13, calcium sulfate 6, N330 carbon black 40; antimonous oxide 6, auxiliary agent 15.
Described auxiliary agent comprises the raw material of following weight part: lazurite 24, hexamethylene diisocyanate 4, tri (propylene glycol) diacrylate 3, altax 4, Z 250 2, tetrafluoroethylene 4, Iron-ore Slag powder 8, aluminium hydroxide 10, jade 3, calcium stearate 2, vinyltriethoxysilane 3, Fructus Zanthoxyli oil 2; Preparation method is by lazurite, jade is put into calcining furnace and is calcined 4 hours at 570 DEG C, cooling, puts into 15% hydrochloric acid soln and soak 3 hours after being ground into 100 orders, filter out lazurite, jade powder, clear water is cleaned, and dries, be ground into 300 order powder, mix with other remaining component, grinding distribution 2 hours, to obtain final product.
Described a kind of low cost oil resistant heatproof PET cable jacket material, its preparation method is: cleaned by waste PET bottle sheet particle and drain, with polyvinylidene difluoride (PVDF), EVA blended evenly after, add other remaining components, send in high-speed kneading machine, at 180 DEG C, mediate 12min, after the cooling of kneading material, send into twin screw extruder granulation, obtain insulating material of the present invention.
The performance test results of material of the present invention is: tensile strength is 18.1Mpa, elongation at break is 409%, after IRM902 oil 90 DEG C × 70h process, tensile strength and elongation at break are respectively 17.4Mpa, 381%, after 136 DEG C × 168h hot air aging, stretching strength retentivity 96.5%, elongation at break conservation rate is 97.4%, 20 DEG C of volume specific resistances is 1.37 × 10 14Ω m, through 60 DEG C 15% NaCl solution soak 7 days after, the pick up of material is 0.0031%, after soaking, volume specific resistance velocity of variation is 0.0028%, after 80 DEG C of toluene solvants soak 7 days, nothing obviously swelling and cracking phenomena, can maintain a long-term stability under 120 DEG C of conditions, minimum use temperature is-40 DEG C, for a long time outdoor be exposed to the sun under do not ftracture, indeformable.

Claims (2)

1. a low cost oil resistant heatproof PET cable jacket material, it is characterized in that, this Insulation Material is made up of the raw material of following weight part: waste PET bottle sheet particle 30-34, polyvinylidene difluoride (PVDF) 23-25, EVA12-15, calcium-zinc composite stabilizing agent 2-3, ammonium molybdate 1-3, cupric oxide 4-5, ferric oxide 3-4, Sodium hexametaphosphate 99 2-3,10-HAD 1-2, acetyl tributyl citrate 16-18, octyl epoxy stearate 12-13, calcium sulfate 3-6, N330 carbon black 30-40, antimonous oxide 5-6, auxiliary agent 14-16;
Described auxiliary agent comprises the raw material of following weight part: lazurite 20-24, hexamethylene diisocyanate 3-4, tri (propylene glycol) diacrylate 2-3, altax 3-4, Z 250 1-2, tetrafluoroethylene 3-4, Iron-ore Slag powder 6-8, aluminium hydroxide 8-10, jade 2-3, calcium stearate 1-2, vinyltriethoxysilane 2-3, Fructus Zanthoxyli oil 1-2; Preparation method is by lazurite, jade is put into calcining furnace and calcine 3-4 hour at 550-570 DEG C, and cooling, puts into 12-15% hydrochloric acid soln and soak 2-3 hour after being ground into 50-100 order, filter out lazurite, jade powder, clear water is cleaned, and dries, be ground into 200-300 order powder, mix with other remaining component, grinding distribution 1-2 hour, to obtain final product.
2. a kind of low cost oil resistant heatproof PET cable jacket material as claimed in claim 1, its manufacture craft is: cleaned by waste PET bottle sheet particle and drain, with polyvinylidene difluoride (PVDF), EVA blended evenly after, add other remaining components, send in high-speed kneading machine, at 120-180 DEG C, mediate 6-15min, after the cooling of kneading material, send into twin screw extruder granulation, obtain insulating material of the present invention.
CN201410295174.5A 2014-06-27 2014-06-27 A kind of low cost oil resistant heatproof PET cable jacket material Active CN104086955B (en)

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CN106189002A (en) * 2016-08-08 2016-12-07 安徽埃克森科技集团有限公司 A kind of petrochemical industry fluoroplastics oil resistant cable sheath
CN106810834A (en) * 2017-02-09 2017-06-09 安徽万安塑料制品有限公司 Special PET/ Nano composite material of montmorillonite of a kind of engineering plastics and preparation method thereof

Citations (1)

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Publication number Priority date Publication date Assignee Title
CN101412591B (en) * 2008-11-18 2012-03-28 广州鹿山新材料股份有限公司 Preparation of PET and PVC composite film for decorating glass

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CN101681946B (en) * 2007-06-15 2012-10-24 阿科玛股份有限公司 Photovoltaic modules having a polyvinylidene fluoride backsheet

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101412591B (en) * 2008-11-18 2012-03-28 广州鹿山新材料股份有限公司 Preparation of PET and PVC composite film for decorating glass

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* Cited by examiner, † Cited by third party
Title
"Delamination behaviour of multi-layer films for PV encapsulation";G. Oreski et al;《Solar Energy Materials and Solar Cells》;20051115;第89卷(第2-3期);第139-151页 *

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Inventor after: Zhang Jingmin

Inventor before: Xie Hua

Inventor before: Xie Gang

Inventor before: Zhang Jing

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