CN104086805A - Macromolecule composite fat powder surfactant as well as preparation method and application thereof - Google Patents
Macromolecule composite fat powder surfactant as well as preparation method and application thereof Download PDFInfo
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- CN104086805A CN104086805A CN201410372446.7A CN201410372446A CN104086805A CN 104086805 A CN104086805 A CN 104086805A CN 201410372446 A CN201410372446 A CN 201410372446A CN 104086805 A CN104086805 A CN 104086805A
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- powder
- surface treatment
- treatment agent
- polymer complex
- calcium carbonate
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- 239000000843 powder Substances 0.000 title claims abstract description 92
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 239000004094 surface-active agent Substances 0.000 title abstract 5
- 239000002131 composite material Substances 0.000 title abstract 3
- 229920002521 macromolecule Polymers 0.000 title abstract 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 104
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 52
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims abstract description 37
- 239000002994 raw material Substances 0.000 claims abstract description 31
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 claims abstract description 19
- -1 isopropoxy aluminate Chemical class 0.000 claims abstract description 19
- 238000006243 chemical reaction Methods 0.000 claims abstract description 10
- 229920000642 polymer Polymers 0.000 claims description 54
- 239000012756 surface treatment agent Substances 0.000 claims description 54
- 239000004594 Masterbatch (MB) Substances 0.000 claims description 24
- 239000003112 inhibitor Substances 0.000 claims description 23
- 230000003647 oxidation Effects 0.000 claims description 23
- 238000007254 oxidation reaction Methods 0.000 claims description 23
- 239000002253 acid Substances 0.000 claims description 19
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 19
- 239000000194 fatty acid Substances 0.000 claims description 19
- 229930195729 fatty acid Natural products 0.000 claims description 19
- 229940075507 glyceryl monostearate Drugs 0.000 claims description 18
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 claims description 18
- SMZOGRDCAXLAAR-UHFFFAOYSA-N aluminium isopropoxide Chemical compound [Al+3].CC(C)[O-].CC(C)[O-].CC(C)[O-] SMZOGRDCAXLAAR-UHFFFAOYSA-N 0.000 claims description 17
- 150000002148 esters Chemical class 0.000 claims description 17
- 229910052760 oxygen Inorganic materials 0.000 claims description 17
- 239000001301 oxygen Substances 0.000 claims description 17
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims description 7
- 238000001816 cooling Methods 0.000 claims description 7
- 238000010298 pulverizing process Methods 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- 150000004665 fatty acids Chemical class 0.000 claims description 5
- OURRXQUGYQRVML-AREMUKBSSA-N [4-[(2s)-3-amino-1-(isoquinolin-6-ylamino)-1-oxopropan-2-yl]phenyl]methyl 2,4-dimethylbenzoate Chemical compound CC1=CC(C)=CC=C1C(=O)OCC1=CC=C([C@@H](CN)C(=O)NC=2C=C3C=CN=CC3=CC=2)C=C1 OURRXQUGYQRVML-AREMUKBSSA-N 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 238000004381 surface treatment Methods 0.000 claims description 4
- 230000000694 effects Effects 0.000 abstract description 6
- 238000012545 processing Methods 0.000 abstract description 6
- 230000008878 coupling Effects 0.000 abstract description 2
- 238000010168 coupling process Methods 0.000 abstract description 2
- 238000005859 coupling reaction Methods 0.000 abstract description 2
- 239000006185 dispersion Substances 0.000 abstract description 2
- 231100000252 nontoxic Toxicity 0.000 abstract description 2
- 230000003000 nontoxic effect Effects 0.000 abstract description 2
- 235000010216 calcium carbonate Nutrition 0.000 abstract 2
- 239000003963 antioxidant agent Substances 0.000 abstract 1
- 230000003078 antioxidant effect Effects 0.000 abstract 1
- 238000005461 lubrication Methods 0.000 abstract 1
- 238000012856 packing Methods 0.000 abstract 1
- 239000004698 Polyethylene Substances 0.000 description 13
- 239000004033 plastic Substances 0.000 description 9
- 229920003023 plastic Polymers 0.000 description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 239000004743 Polypropylene Substances 0.000 description 4
- 239000007822 coupling agent Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 235000021355 Stearic acid Nutrition 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000007812 deficiency Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000011049 filling Methods 0.000 description 3
- 239000000314 lubricant Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000008117 stearic acid Substances 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000008602 contraction Effects 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 238000004453 electron probe microanalysis Methods 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 229920001903 high density polyethylene Polymers 0.000 description 2
- 239000004700 high-density polyethylene Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 229910021502 aluminium hydroxide Inorganic materials 0.000 description 1
- 201000009310 astigmatism Diseases 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- NKWPZUCBCARRDP-UHFFFAOYSA-L calcium bicarbonate Chemical compound [Ca+2].OC([O-])=O.OC([O-])=O NKWPZUCBCARRDP-UHFFFAOYSA-L 0.000 description 1
- 229910000020 calcium bicarbonate Inorganic materials 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 125000005456 glyceride group Chemical group 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 229920000092 linear low density polyethylene Polymers 0.000 description 1
- 239000004707 linear low-density polyethylene Substances 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000012764 mineral filler Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000001603 reducing effect Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 125000003011 styrenyl group Chemical class [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 238000012795 verification Methods 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
Abstract
The invention relates to the technical field of surfactants, and in particular relates to a macromolecule composite fat powder surfactant as well as a preparation method and an application thereof. The macromolecule composite fat powder surfactant comprises the following raw materials in percentage by weight: 5-15% of distearoyl isopropoxy aluminate, 8-15% of butyl stearate, 10-25% of glycerin monostearate, 50-70% of aliphatic ester and 2-6% of antioxidant. The surfactant is a multifunctional product with integrated functions of coupling, dispersion and lubrication, is large in reaction activity with surface of CaCO3 powder, light in color, non-toxic and small in odor and has the effect of improving the processing fluidity and the physical and mechanical properties of a CaCO3 packing system.
Description
Technical field
The present invention relates to surface treatment agent technical field, be specifically related to polymer complex liped surface treatment agent for powder and preparation method thereof and application.
Background technology
The processing technology of China's calcium carbonate powder and utilisation technology in development at a quick pace, are all widely applied in high molecular products industries such as plastics, rubber, coating.Calcium carbonate powder adds as weighting agent, can reduce the cost of product.In plastics, add calcium carbonate can play following effect: 1, increment, reduces costs; 2, improve the thermotolerance of plastics, in polypropylene, add 40% CaCO
3, its heat-drawn wire can improve 20oC left and right; 3, the astigmatism of improving plastics, plays shading or photoextinction; 4, improve plating performance or the printing performance of plastics; 5, reduce plastics dimensional contraction rate, improve dimensional stability.
Along with customizations and the nanometer of calcium carbonate particles, the defect of itself has greatly limited its application: the one, CaCO
3particle diameter is less, and lip-deep atomicity is more, and surface can be higher, and adsorption is stronger, between each particle, mutually reunites; The 2nd, CaCO
3as a kind of mineral filler, the hydrophilic oleophobic of particle surface, poor with the affinity of organic polymer, easily form aggregate, cause superpolymer subsurface defect, mechanical property variation.In order to improve the filling properties of calcium carbonate, must adopt effective technique and surface modifying method to carry out surface modification to calcium carbonate.
Summary of the invention
The object of the invention is to overcome the deficiency that prior art exists, a kind of raising CaCO is provided
3the polymer complex liped surface treatment agent for powder of the filling properties of powder.
Another object of the present invention is to overcome the deficiency that prior art exists, and a kind of raising CaCO is provided
3the preparation method of the polymer complex liped surface treatment agent for powder of the filling properties of powder.
Another object of the present invention is to overcome the deficiency that prior art exists, and a kind of calcium carbonate master batch prepared by polymer complex liped surface treatment agent for powder of applying is provided.
Object of the present invention is achieved through the following technical solutions.
Polymer complex liped surface treatment agent for powder, it is comprised of the raw material of following weight percent:
Distearyl acyl-oxygen aluminum isopropoxide acid esters 5% ~ 15%
Butyl stearate 8% ~ 15%
Glyceryl monostearate 10% ~ 25%
Fatty acid ester 50% ~ 70%
Oxidation inhibitor 2% ~ 6%.
Further, it is comprised of the raw material of following weight percent:
Distearyl acyl-oxygen aluminum isopropoxide acid esters 5% ~ 8%
Butyl stearate 8% ~ 11%
Glyceryl monostearate 10% ~ 16%
Fatty acid ester 60% ~ 70%
Oxidation inhibitor 4% ~ 6%.
Further, it is comprised of the raw material of following weight percent:
Distearyl acyl-oxygen aluminum isopropoxide acid esters 9% ~ 15%
Butyl stearate 12% ~ 15%
Glyceryl monostearate 18% ~ 25%
Fatty acid ester 50% ~ 59%
Oxidation inhibitor 2% ~ 3%.
Further, it is comprised of the raw material of following weight percent:
Distearyl acyl-oxygen aluminum isopropoxide acid esters 9% ~ 13%
Butyl stearate 10% ~ 12%
Glyceryl monostearate 12% ~ 21%
Fatty acid ester 55% ~ 65%
Oxidation inhibitor 3% ~ 5%.
Preferably, it is comprised of the raw material of following weight percent:
Distearyl acyl-oxygen aluminum isopropoxide acid esters 6%
Butyl stearate 10%
Glyceryl monostearate 20%
Fatty acid ester 60%
Oxidation inhibitor 4%.
The compound that distearyl acyl-oxygen aluminum isopropoxide acid esters is coupling agent, white or faint yellow waxy solid, applicable resin: PP, PE, PVC, PS etc., suitable fillers: light/calcium bicarbonate, talcum powder, White Carbon black, aluminium hydroxide, titanium dioxide, red iron oxide etc.
The Chinese of butyl stearate: butyl stearate, has another name called: the positive butyl ester of stearic acid; For various kinds of resin adds lubricant and the releasing agent in man-hour, extrusion molding, injection moulding and calendered goods and the modified styrene polymer of and hard soft for polyvinyl chloride transparent.Also can be used for lubricant, water-resisting agent and lubricating oil, the shoe polish of metal and fabric, the additive of makeup.
Glyceryl monostearate, for the wax-like thin slice of white or bead solid, water insoluble, mix and dispersible in water through strong vibration with hot water, be water-in-oil type emulsifier.Glyceryl monostearate is to contain C16-C18 longer chain fatty acid and glycerol is carried out esterification and makes.It is a kind of tensio-active agent of non-ionic type.It existing hydrophilic have again oleophilic group because of, there is the several functions such as wetting, emulsification, foaming.
Fatty acid ester, glycerin fatty acid ester, claims again mixed fatty glycerides, its chemical formula is: C
3h
5o
3(COR)
3.All fatty acid esters all can be used for the present invention.
Wherein, described oxidation inhibitor is that antioxidant 1010 mixes with the ratio of 2:1 ~ 3:1 with irgasfos 168.
The preparation method of polymer complex liped surface treatment agent for powder, by weight percentage, described raw material is dropped into reactor, reactor is heated to 80 ℃ ~ 90 ℃, rotating speed with 40 ~ 60r/min stirs 30 ~ 40 minutes simultaneously, after reaction, flow into tabletting machine, carry out compressing tablet cooling forming, through pulverizing, make polymer complex liped surface treatment agent for powder.
The application of polymer complex liped surface treatment agent for powder, described polymer complex liped surface treatment agent for powder is applied to the surface treatment of calcium carbonate powder.
Apply a calcium carbonate master batch prepared by polymer complex liped surface treatment agent for powder, described calcium carbonate master batch is made by calcium carbonate powder and 2% ~ 10% the polymer complex liped surface treatment agent for powder that accounts for calcium carbonate powder weight percent.
Particularly, described calcium carbonate master batch is made by calcium carbonate powder and 2%, 3%, 4%, 5%, 6%, 7%, 8%, 9%, 10% the polymer complex liped surface treatment agent for powder that accounts for calcium carbonate powder weight percent.
Preferably, described calcium carbonate master batch is made by calcium carbonate powder and 5% ~ 8% the polymer complex liped surface treatment agent for powder that accounts for calcium carbonate powder weight percent.
compared with prior art, tool has the following advantages and beneficial effect in the present invention:
Distearyl acyl-oxygen aluminum isopropoxide acid esters of the present invention is as coupling agent, and butyl stearate, glyceryl monostearate, lipid acid are as inside and outside lubricant agent, to CaCO
3powder is coated, and changes CaCO
3the polarity of powder surface; Oxidation inhibitor is used as auxiliary material.The present invention strengthens CaCO
3the consistency at powder and organic resin interface, infiltrates and wetting CaCO
3the surface of powder, make its be dispersed into trickle, stable, be distributed in master batch uniformly.The present invention is for the coupling of holding concurrently, dispersion, lubricated Trinitarian multifunctional product, with CaCO
3powder surface reactive behavior is large, of light color, nontoxic, and taste is little, has raising CaCO
3the effect of filler systems processing fluidity and physical and mechanical property.
There is chemical reaction in the present invention and Paris white surface, generates unimolecular layer, and through experimental verification, effect is as follows:
1) the present invention is added in calcium carbonate powder, homogenizer carries out surface treatment at 100 ℃, and surface-treated calcium carbonate powder surface part of hydroxyl disappears;
2) calcium carbonate powder of crossing through surface treatment of the present invention, coating reaction has hydrophobicity, bubbles through the water column completely, still can be suspended in the surface of dilute acid soln in 1mol/L dilute hydrochloric acid;
3) by the CaCO processing through the present invention
3with HDPE product, natural section is done electron probe microanalysis (EPMA) scanning, finds that the present invention is that Chemical bond is at CaCO
3on surface, even after the melting and shearing process of filled HDPE, do not come off yet;
4) the present invention has obvious viscosity reduction effect to calcium carbonate powder medium system viscosity, has good viscosity reducing effect;
5) surface-treated CaCO of the present invention
3powder, is more prone to plasticizing with PE material, and processing fluidity is good, and stable contraction rate improves output;
6) the different shapes CaCO processing through the present invention
3powder, after PE material mixing, surface luster and the shock resistance of PE material are all significantly increased;
7), when the present invention produces together with the plastics such as PP, PE, only need the present invention and CaCO
3powder, PP, PE mix by a certain percentage and can produce, and use simply, avoid needing to add multiple auxiliary agent in prior art and the error that causes the stability of favourable subsequent production and persistence, the constant product quality of production.
Accompanying drawing explanation
Fig. 1 is the demonstration figure of the calcium carbonate master batch prepared of application polymer complex liped surface treatment agent for powder of the present invention under electron microscope.
embodiment:
For the ease of those skilled in the art's understanding, below in conjunction with embodiment and accompanying drawing, the present invention is described in further detail, but protection scope of the present invention is not limited to following embodiment.
embodiment 1.
Polymer complex liped surface treatment agent for powder, it is comprised of the raw material of following weight percent: distearyl acyl-oxygen aluminum isopropoxide acid esters 5%, butyl stearate 15%, glyceryl monostearate 10%, fatty acid ester 66%, oxidation inhibitor 4%; Wherein, oxidation inhibitor is mixed and forms with 1% irgasfos 168 by 3% antioxidant 1010.
The preparation method of the polymer complex liped surface treatment agent for powder of the present embodiment, by weight percentage, described raw material is dropped into reactor, reactor is heated to 80 ℃, rotating speed with 40r/min stirs 30 minutes simultaneously, after reaction, flow into tabletting machine, carry out compressing tablet cooling forming, through pulverizing, make polymer complex liped surface treatment agent for powder.
embodiment 2.
Polymer complex liped surface treatment agent for powder, it is comprised of the raw material of following weight percent: distearyl acyl-oxygen aluminum isopropoxide acid esters 8%, butyl stearate 11%, glyceryl monostearate 14%, fatty acid ester 61%, oxidation inhibitor 6%.Wherein, oxidation inhibitor is mixed and forms with 2% irgasfos 168 by 4% antioxidant 1010.
The preparation method of the polymer complex liped surface treatment agent for powder of the present embodiment, by weight percentage, described raw material is dropped into reactor, reactor is heated to 82 ℃, rotating speed with 55r/min stirs 38 minutes simultaneously, after reaction, flow into tabletting machine, carry out compressing tablet cooling forming, through pulverizing, make polymer complex liped surface treatment agent for powder.
embodiment 3.
Polymer complex liped surface treatment agent for powder, it is comprised of the raw material of following weight percent: distearyl acyl-oxygen aluminum isopropoxide acid esters 15%, butyl stearate 13%, glyceryl monostearate 18%, fatty acid ester 50%, oxidation inhibitor 4%.Wherein, oxidation inhibitor is mixed and forms with 1% irgasfos 168 by 3% antioxidant 1010.
The preparation method of the polymer complex liped surface treatment agent for powder of the present embodiment, by weight percentage, described raw material is dropped into reactor, reactor is heated to 85 ℃, rotating speed with 45r/min stirs 40 minutes simultaneously, after reaction, flow into tabletting machine, carry out compressing tablet cooling forming, through pulverizing, make polymer complex liped surface treatment agent for powder.
embodiment 4.
Polymer complex liped surface treatment agent for powder, it is comprised of the raw material of following weight percent: distearyl acyl-oxygen aluminum isopropoxide acid esters 12%, butyl stearate 10%, glyceryl monostearate 21%, fatty acid ester 54%, oxidation inhibitor 3%.Wherein, oxidation inhibitor is mixed and forms with 1% irgasfos 168 by 2% antioxidant 1010.
The preparation method of the polymer complex liped surface treatment agent for powder of the present embodiment, by weight percentage, described raw material is dropped into reactor, reactor is heated to 88 ℃, rotating speed with 50r/min stirs 35 minutes simultaneously, after reaction, flow into tabletting machine, carry out compressing tablet cooling forming, through pulverizing, make polymer complex liped surface treatment agent for powder.
embodiment 5.
Polymer complex liped surface treatment agent for powder, it is comprised of the raw material of following weight percent: distearyl acyl-oxygen aluminum isopropoxide acid esters 10%, butyl stearate 8%, glyceryl monostearate 10%, fatty acid ester 70%, oxidation inhibitor 2%.Wherein, oxidation inhibitor is mixed and forms with 0.5% irgasfos 168 by 1.5% antioxidant 1010.
The preparation method of the polymer complex liped surface treatment agent for powder of the present embodiment, by weight percentage, described raw material is dropped into reactor, reactor is heated to 90 ℃, rotating speed with 60r/min stirs 40 minutes simultaneously, after reaction, flow into tabletting machine, carry out compressing tablet cooling forming, through pulverizing, make polymer complex liped surface treatment agent for powder.
embodiment 6.
A calcium carbonate master batch prepared by the polymer complex liped surface treatment agent for powder of Application Example 1 ~ 5 arbitrary embodiment, described calcium carbonate master batch is made by calcium carbonate powder and 2% the polymer complex liped surface treatment agent for powder that accounts for calcium carbonate powder weight percent.
embodiment 7.
A calcium carbonate master batch prepared by the polymer complex liped surface treatment agent for powder of Application Example 1 ~ 5 arbitrary embodiment, described calcium carbonate master batch is made by calcium carbonate powder and 6% the polymer complex liped surface treatment agent for powder that accounts for calcium carbonate powder weight percent.
embodiment 8.
A calcium carbonate master batch prepared by the polymer complex liped surface treatment agent for powder of Application Example 1 ~ 5 arbitrary embodiment, described calcium carbonate master batch is made by calcium carbonate powder and 10% the polymer complex liped surface treatment agent for powder that accounts for calcium carbonate powder weight percent.
As shown in Figure 1, under electron microscope, show, the calcium carbonate master batch of embodiments of the invention 6 ~ 8 preparations presents fabulous dispersing property.
Calcium carbonate master batch (the CaCO of embodiments of the invention 6 ~ 8 preparations
3master batch) fill the mechanics average behaviour test chart of PE.
。
(7042) 4 parts+LDPE(2426H of remarks: PE=LLDPE) 1 part.
As seen from the above table, the calcium carbonate master batch (CaCO that prepared by the present invention
3master batch) fill after PE, tensile strength, yield strength Young's modulus and shock resistance are all significantly increased.
application example one.
Get polymer complex liped surface treatment agent for powder 4kg prepared by any embodiment of embodiments of the invention 1 ~ 5, with the calcium carbonate powder of 75kg, the PE7042 high-speed mixing of 9kg, then enter twin screw extruder and extrude.
Polymer complex liped surface treatment agent for powder prepared by the present invention, together with PE plastics during extrusion, only needing to add three kinds of raw materials can enter twin screw extruder and extrude, with prior art at least need add titanium ester coupling agent, PE wax, stearic acid, EBS, Zinic stearas, diffusion wet goods plurality of raw materials and compare, reduced widely because the error that plurality of raw materials causes is added in manual operation, further reduced the situation of the unstable product quality causing due to manual operation interpolation plurality of raw materials.
application example two.
Get calcium carbonate master batch 25kg prepared by any embodiment of embodiments of the invention 6 ~ 8, mix with the PE7042 of 75kg, can enter inflation film manufacturing machine and carry out blown film.Calcium carbonate master batch prepared by polymer complex liped surface treatment agent for powder prepared by the present invention, when blown film is produced together with PE plastics, only needing to add two kinds of raw materials can enter inflation film manufacturing machine and carry out blown film, with prior art at least need add titanium ester coupling agent, PE wax, stearic acid, EBS, Zinic stearas, diffusion wet goods plurality of raw materials and compare, reduced widely because the error that plurality of raw materials causes is added in manual operation, further reduced the situation of the unstable product quality causing due to manual operation interpolation plurality of raw materials.
Above-described embodiment is preferably embodiment of the present invention, but embodiments of the present invention are not restricted to the described embodiments, and the equivalent variations of therefore doing according to the present patent application the scope of the claims, within being included in protection scope of the present invention.
Claims (10)
1. polymer complex liped surface treatment agent for powder, is characterized in that: it is comprised of the raw material of following weight percent:
Distearyl acyl-oxygen aluminum isopropoxide acid esters 5% ~ 15%
Butyl stearate 8% ~ 15%
Glyceryl monostearate 10% ~ 25%
Fatty acid ester 50% ~ 70%
Oxidation inhibitor 2% ~ 6%.
2. polymer complex liped surface treatment agent for powder according to claim 1, is characterized in that: it is comprised of the raw material of following weight percent:
Distearyl acyl-oxygen aluminum isopropoxide acid esters 5% ~ 8%
Butyl stearate 8% ~ 11%
Glyceryl monostearate 10% ~ 16%
Fatty acid ester 60% ~ 70%
Oxidation inhibitor 4% ~ 6%.
3. polymer complex liped surface treatment agent for powder according to claim 1, is characterized in that: it is comprised of the raw material of following weight percent:
Distearyl acyl-oxygen aluminum isopropoxide acid esters 9% ~ 15%
Butyl stearate 12% ~ 15%
Glyceryl monostearate 18% ~ 25%
Fatty acid ester 50% ~ 59%
Oxidation inhibitor 2% ~ 3%.
4. polymer complex liped surface treatment agent for powder according to claim 1, is characterized in that: it is comprised of the raw material of following weight percent:
Distearyl acyl-oxygen aluminum isopropoxide acid esters 9% ~ 13%
Butyl stearate 10% ~ 12%
Glyceryl monostearate 12% ~ 21%
Fatty acid ester 55% ~ 65%
Oxidation inhibitor 3% ~ 5%.
5. polymer complex liped surface treatment agent for powder according to claim 1, is characterized in that: it is comprised of the raw material of following weight percent:
Distearyl acyl-oxygen aluminum isopropoxide acid esters 6%
Butyl stearate 10%
Glyceryl monostearate 20%
Fatty acid ester 60%
Oxidation inhibitor 4%.
6. polymer complex liped surface treatment agent for powder according to claim 1, is characterized in that: described oxidation inhibitor is the mixture that antioxidant 1010 mixes with the ratio of 2:1 ~ 3:1 with irgasfos 168.
7. the preparation method of the polymer complex liped surface treatment agent for powder described in claim 1 ~ 6 any one, it is characterized in that: by weight percentage, described raw material is dropped into reactor, reactor is heated to 80 ℃ ~ 90 ℃, rotating speed with 40 ~ 60r/min stirs 30 ~ 40 minutes simultaneously, after reaction, flow into tabletting machine, carry out compressing tablet cooling forming, through pulverizing, make polymer complex liped surface treatment agent for powder.
8. the application of the polymer complex liped surface treatment agent for powder described in claim 1 ~ 6 any one, is characterized in that: described polymer complex liped surface treatment agent for powder is applied to the surface treatment of calcium carbonate powder.
9. application rights requires a calcium carbonate master batch prepared by the polymer complex liped surface treatment agent for powder described in 8, it is characterized in that: described calcium carbonate master batch is made by calcium carbonate powder and 2% ~ 10% the polymer complex liped surface treatment agent for powder that accounts for calcium carbonate powder weight percent.
10. the calcium carbonate master batch that prepared by polymer complex liped surface treatment agent for powder according to claim 9, is characterized in that: described calcium carbonate master batch is made by calcium carbonate powder and 5% ~ 8% the polymer complex liped surface treatment agent for powder that accounts for calcium carbonate powder weight percent.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105254921A (en) * | 2015-10-13 | 2016-01-20 | 广东盛朗白石工业有限公司 | Water-soluble polymer complex lipid powder surface treating agent |
| CN114230911A (en) * | 2021-12-15 | 2022-03-25 | 东莞市柏林高分子材料有限公司 | Stone ceramic-like resin and preparation method thereof |
| CN114806016A (en) * | 2022-05-18 | 2022-07-29 | 东莞市柏林高分子材料有限公司 | Thin-wall tableware resin for high-speed injection molding and preparation method thereof |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1181128C (en) * | 2002-09-27 | 2004-12-22 | 南风化工集团股份有限公司 | Polyolefin packing material and its production method |
| CN1793213A (en) * | 2005-12-30 | 2006-06-28 | 上海心尔塑胶材料有限公司 | Process for preparing foamed filling mother material of EVA (ethylene-acetate ethylene copolymer) |
| CN103555032B (en) * | 2013-09-26 | 2016-05-25 | 安徽盛佳彩印包装有限公司 | The preparation method of nanometer grade calcium carbonate for a kind of anti-corrosive paints |
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2014
- 2014-07-31 CN CN201410372446.7A patent/CN104086805B/en active Active
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105254921A (en) * | 2015-10-13 | 2016-01-20 | 广东盛朗白石工业有限公司 | Water-soluble polymer complex lipid powder surface treating agent |
| CN114230911A (en) * | 2021-12-15 | 2022-03-25 | 东莞市柏林高分子材料有限公司 | Stone ceramic-like resin and preparation method thereof |
| CN114230911B (en) * | 2021-12-15 | 2024-05-14 | 东莞市柏林高分子材料有限公司 | Stone imitation porcelain resin and preparation method thereof |
| CN114806016A (en) * | 2022-05-18 | 2022-07-29 | 东莞市柏林高分子材料有限公司 | Thin-wall tableware resin for high-speed injection molding and preparation method thereof |
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| CN104086805B (en) | 2017-07-14 |
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Effective date of registration: 20211129 Address after: 523000 No. 65, haocui street, Weizhen community, Zhangmutou town, Dongguan City, Guangdong Province Patentee after: Dongguan Berlin polymer material Co., Ltd Address before: 523620 Room B, 23rd floor, Huadu Pavilion, AIDU garden, Zhangmutou town, Dongguan City, Guangdong Province Patentee before: Xu Meizhen |