CN104086804B - A kind of rubber antioxidant - Google Patents
A kind of rubber antioxidant Download PDFInfo
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- CN104086804B CN104086804B CN201410326680.6A CN201410326680A CN104086804B CN 104086804 B CN104086804 B CN 104086804B CN 201410326680 A CN201410326680 A CN 201410326680A CN 104086804 B CN104086804 B CN 104086804B
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Abstract
The invention discloses a kind of Novel rubber antioxidant, particularly as follows: be that 20%~60% metal salt of terephthalic acid is dried 30min in vacuum environment at 100 DEG C by mass ratio, it is cooled to room temperature under vacuum environment, add the silane coupler that mass ratio is 10%~40%, mix homogeneously, stop activation 10~20min, it is that 20%~60% antioxidant D is dissolved in acetone soln by mass ratio, add the mixture activated, reaction 1~5h, finally filtering, wash, be dried, acetone soln evaporimeter carries out concentrating recycling.Compared with prior art, the rubber anti-ageing agent toxicity of gained of the present invention reduces, and impurity content is low, and mobility is low, and preparation technology is simple.The present invention can effectively reduce age resistor and migrate the environmental pollution produced, good dispersion in elastomeric material, and practical function is high.
Description
Technical field
The present invention relates to a kind of rubber antioxidant.
Background technology
Rubber is during processing, storing and use, due to the combined influence by internal and external factor, it may appear that
Deliquescing, tacky, harden, chap, embrittlement, speckle, the catabiosis such as mouldy, loss of gloss, color change,
Rubber antioxidant is a kind of material that can prevent or delay ageing of rubber.Antioxidant D is the thirties in 20th century
Begin to an old brand amines antioxidants of production application.Owing to it can protective hot oxygen aging and subduing effectively
It is aging that fatigue causes, and cheap, and therefore in rubber industry, consumption is the biggest.But there is toxicity in it,
And bin stability is poor, exposes and in atmosphere and grey black will be become from white under daylight.At rubber product
During use, especially under the effect of light and heat, transparent rubber can become dark, simultaneously dirty by migrating
The material that dye is in contact with it.The chance phototropic of antioxidant D goes bad and oxidation deterioration, and tracing it to its cause is due to anti-
The chemical change that impurity in old agent causes.The most therefore, the U.S., Japan, West Europe before and after 1970 the most
Start significantly to compress the yield of D, D is modified simultaneously.
Present invention aim to provide a kind of modified rubber antioxidant D, to reduce its toxicity, mobility obtains
To effectively reducing, and impurity content therein effectively reduces.
Summary of the invention
Present invention aim to provide the modified rubber antioxidant D of a kind of low toxicity, low migration, low impurity
The technical scheme realizing the object of the invention is:
A kind of Novel rubber antioxidant, it is characterised in that: it is 20%~60% p-phthalic acid gold by mass ratio
Belonging to salt and be dried 30min in vacuum environment at 100 DEG C, be cooled to room temperature under vacuum environment, adding mass ratio is
The silane coupler of 10%~40%, mix homogeneously, stop activation 10~20min, by mass ratio be
20%~60% antioxidant D is dissolved in acetone soln, adds the mixture activated, and reacts 1~5h,
Finally filtering, wash, be dried, acetone soln evaporimeter carries out concentrating recycling.
As preferably, described metal salt of terephthalic acid is p-phthalic acid calcium, p-phthalic acid magnesium, right
In phthalic acid zinc, potassium terephthalate, para-phthalic sodium, p-phthalic acid barium, p-phthalic acid aluminum
One or more.
As preferably, described silane coupler is double-(the silica-based propyl group of γ-triethoxy) tetrasulfide
(Si69), double (the silica-based propyl group of triethoxy) disulphide (Si75), gamma-mercaptopropyltriethoxysilane
(KH-580), gamma-aminopropyl-triethoxy-silane (KH-550), γ-(2,3-epoxy the third oxygen) propyl group three
One or more in methoxy silane (KH-560).
The rubber anti-ageing agent of gained of the present invention is compared with traditional antioxidant D, and its toxicity reduces, and impurity contains
Measuring low, mobility is low.And its preparation technology is simple, low price, it is possible to decrease cost, improves product quality
And economic benefit.The present invention can effectively reduce age resistor and migrate the environmental pollution produced, and divides in elastomeric material
Dissipating property good, practical function is high.
Detailed description of the invention
Embodiment 1
It is that 20% p-phthalic acid calcium is dried 30min, vacuum environment in vacuum environment at 100 DEG C by mass ratio
Under be cooled to room temperature, add the silane coupler Si69 that mass ratio is 20%, mix homogeneously, stop activation
20min, is that 60% antioxidant D is dissolved in acetone soln by mass ratio, adds the mixture activated,
Reaction 5h, finally filters, washs, is dried, obtain No. 1 age resistor.
Embodiment 2
It is that 60% p-phthalic acid magnesium is dried 30min, vacuum environment in vacuum environment at 100 DEG C by mass ratio
Under be cooled to room temperature, add the silane coupler Si75 that mass ratio is 20%, mix homogeneously, stop activation
10min, is that 20% antioxidant D is dissolved in acetone soln by mass ratio, adds the mixture activated,
Reaction 1h, finally filters, washs, is dried, obtain No. 2 age resistor.
Embodiment 3
It is that 30% p-phthalic acid zinc is dried 30min, vacuum environment in vacuum environment at 100 DEG C by mass ratio
Under be cooled to room temperature, add the silane coupler KH-580 that mass ratio is 10%, mix homogeneously, stop activation
20min, is that 60% antioxidant D is dissolved in acetone soln by mass ratio, adds the mixture activated,
Reaction 3h, finally filters, washs, is dried, obtain No. 3 age resistor.
Embodiment 4
It is that 20% potassium terephthalate, 20% para-phthalic sodium are in vacuum environment at 100 DEG C by mass ratio
Be dried 30min, under vacuum environment, be cooled to room temperature, add silane resin acceptor kh-550 that mass ratio is 15%,
The KH-560 of 15%, mix homogeneously, stop activation 10min, be that 30% antioxidant D is dissolved in by mass ratio
In acetone soln, add the mixture activated, react 4h, finally filter, wash, be dried, to obtain final product
No. 4 age resistor.
Embodiment 5
It is that 15% p-phthalic acid barium, 15% p-phthalic acid aluminum, 15% p-phthalic acid calcium exist by mass ratio
Being dried 30min in vacuum environment at 100 DEG C, be cooled to room temperature under vacuum environment, adding mass ratio is 15%
Silane coupler Si69, mix homogeneously, stop activation 15min, be that 40% antioxidant D dissolves by mass ratio
In acetone soln, add the mixture activated, react 2h, finally filter, wash, be dried, i.e.
Obtain No. 5 age resistor.
Embodiment 6
Being 20% p-phthalic acid calcium and the silane coupler Si69 that mass ratio is 20% by mass ratio, mixing is all
Even, stop activation 20min, be that 60% antioxidant D is dissolved in acetone soln by mass ratio, add the most alive
The mixture changed, reacts 5h, finally filters, washs, is dried, obtains No. 6 age resistor.
Embodiment 7
Being 20% p-phthalic acid calcium and the silane coupler Si69 that mass ratio is 20% by mass ratio, mixing is all
Even, stop activation 20min, adding mass ratio is 60% antioxidant D reaction 5h, finally filter, wash,
It is dried, obtains No. 7 age resistor.
Embodiment 8
The said goods and antioxidant D being put under sunlight and directly shine, observation period color changes.
NR50 part, NBR50 part, white carbon black N33040 part, zinc oxide 3 parts, stearic acid 2 parts, age resistor
2.5 parts, 4 parts of paraffin, accelerant CZ 0.7 part, sulfur 2 parts.
NR Yu NBR is blended uniformly in two-roll mill, roller temperature 100 DEG C, mixing time 15min, adds
Entering remaining compounding ingredient of carbon removal infrablack, add white carbon black after mix homogeneously, the elastomeric compound obtained is vulcanizer 155 DEG C
Lower sheeting, snip, test performance.
Vulcanizate is soaked in water performance test after 72h
Gained age resistor color under light illumination of the present invention change is inconspicuous, and traditional antiaging agent color becomes soon
Brown, illustrates that the impurity in gained age resistor of the present invention effectively is shone.In ageing resistace this
Bright and traditional antioxidant D compares favourably, after water soaking, add the present invention the hot air aging of age resistor
Performance is substantially excellent than former age resistor, and gained age resistor color under light illumination of the present invention change is inconspicuous, and passes
The antiaging agent color browning color soon of system, illustrates that the impurity in gained age resistor of the present invention obtains effectively
Shine.In ageing resistace, the present invention compares favourably with tradition antioxidant D, after water soaking, adds this
The thermal aging property of bright age resistor is substantially excellent than former age resistor, and gained age resistor of the present invention is described
Can effectively reduce mobility, later stage anti ageing property is good.
With the above-mentioned desirable embodiment according to the present invention for enlightenment, by above-mentioned description, phase
Close staff and can carry out various in the range of without departing from this invention technological thought completely
Change and amendment.The content that the technical scope of this invention is not limited in description, must
Its technical scope need be determined according to right.
Claims (3)
1. a rubber antioxidant, it is characterised in that be 20%~60% terephthalic acid metal by mass ratio
Salt is dried 30min in vacuum environment at 100 DEG C, be cooled to room temperature under vacuum environment, adds mass ratio and is
The silane coupler of 10%~40%, mix homogeneously, stop activation 10~20min, by mass ratio be
20%~60% antioxidant D is dissolved in acetone soln, adds the mixture that activated, reaction 1~
5h, finally filters, washs, is dried, and acetone soln evaporimeter carries out concentrating recycling.
A kind of rubber antioxidant the most according to claim 1, it is characterised in that: described terephthaldehyde
Acid metal salt is p-phthalic acid calcium, p-phthalic acid magnesium, p-phthalic acid zinc, potassium terephthalate, right
One or more in phthalic acid sodium, p-phthalic acid barium, p-phthalic acid aluminum.
A kind of rubber antioxidant the most according to claim 1, it is characterised in that:, described silane is even
Connection agent is double-(the silica-based propyl group of γ-triethoxy) tetrasulfide (Si69), double (the silica-based propyl group of triethoxy)
Disulphide (Si75), gamma-mercaptopropyltriethoxysilane (KH-580), gamma-aminopropyl-triethoxy silicon
One or several in alkane (KH-550), γ-(2,3-epoxy the third oxygen) propyl trimethoxy silicane (KH-560)
Kind.
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CN201410326680.6A CN104086804B (en) | 2014-07-09 | 2014-07-09 | A kind of rubber antioxidant |
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CN201410326680.6A CN104086804B (en) | 2014-07-09 | 2014-07-09 | A kind of rubber antioxidant |
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CN104086804B true CN104086804B (en) | 2016-09-21 |
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CN106674887A (en) * | 2015-11-05 | 2017-05-17 | 南通市永顺化工有限公司 | Novel rubber anti-aging agent |
CN106674888A (en) * | 2015-11-05 | 2017-05-17 | 南通市永顺化工有限公司 | Novel rubber anti-aging agent |
CN105778155B (en) * | 2016-05-12 | 2019-04-19 | 上海橡瑞新材料科技有限公司 | A kind of antioxidant NBC and preparation method thereof coating nano material |
CN111816356B (en) * | 2020-08-07 | 2022-02-11 | 居盛文 | Flat flexible cable of insulating sheath based on butyronitrile polyvinyl chloride |
Citations (2)
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CN102061023A (en) * | 2010-12-07 | 2011-05-18 | 江苏爱特恩高分子材料有限公司 | Novel rubber antioxidant and preparation method thereof |
CN102153806A (en) * | 2011-04-20 | 2011-08-17 | 江苏爱特恩高分子材料有限公司 | Plastic filling master batch and preparation method thereof |
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US20050058822A1 (en) * | 2003-08-04 | 2005-03-17 | Ittel Steven Dale | Fiber-reinforced thermoplastic matrices |
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CN102061023A (en) * | 2010-12-07 | 2011-05-18 | 江苏爱特恩高分子材料有限公司 | Novel rubber antioxidant and preparation method thereof |
CN102153806A (en) * | 2011-04-20 | 2011-08-17 | 江苏爱特恩高分子材料有限公司 | Plastic filling master batch and preparation method thereof |
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