CN104082288A - Ethephon powder composition as well as preparation method and use thereof - Google Patents

Ethephon powder composition as well as preparation method and use thereof Download PDF

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Publication number
CN104082288A
CN104082288A CN201410293646.3A CN201410293646A CN104082288A CN 104082288 A CN104082288 A CN 104082288A CN 201410293646 A CN201410293646 A CN 201410293646A CN 104082288 A CN104082288 A CN 104082288A
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China
Prior art keywords
ethrel
auxiliary agent
dust composition
ripening
inorganic base
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Pending
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CN201410293646.3A
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Chinese (zh)
Inventor
刘斌
陶阿建
施险峰
廖本仁
于鹏浩
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Shanghai Huayi Group Corp
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Shanghai Huayi Group Corp
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Priority to CN201410293646.3A priority Critical patent/CN104082288A/en
Publication of CN104082288A publication Critical patent/CN104082288A/en
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Abstract

The invention relates to an ethephon powder composition as well as a preparation method and use thereof and the ethephon powder composition can be used for mainly solving the problems of high cost, high dosage and poor forced ripening effect in the prior art. The problems are well solved by use of the technical scheme of the ethephon powder composition which comprises 3-50% of ethephon, 5-60% of inorganic base, 20-40% of auxiliary A and 1-10% of auxiliary B, as well as the preparation method and the use thereof; the ethephon powder composition can be applied to preparing the ethephon powder.

Description

Ethrel dust composition and its production and use
Technical field
The present invention relates to a kind of ethrel dust composition and its production and use.
Background technology
Ethrel, chemical name: 2 chloroethyl phosphoric acid, molecular formula is C 2h 6clO 3p, molecular weight is: 144.49, sterling is white, needle-shaped crystals, fusing point: 74~75 ℃.Ethrel powder product is generally white powder, and immersion slowly releases ethene, by the ethylene gas corresponding fruit product that accelerates the ripening.Plant growth regulator ethrel, have promote organ come off and old and feeble, regulate sex to transform, the effect such as suppress cell elongation and accelerate the ripening of fruit.
Now the conventional fruit method of accelerating the ripening is that ethephon solution soaks fruit, calcium carbide is stifling or small aluminium bottle output ethylene gas accelerates the ripening etc.Therein ethylene profit solution soaks the germ that may exist in highly acid, ethrel liquid contact fruit surface and the liquid of the mode of accelerating the ripening of fruit due to ethrel itself, the perishable and color and luster of fruit is difficult for even, and workload is larger; The fruit peculiar smell of the fruit that the mode of accelerating the ripening that calcium carbide accelerates the ripening is accelerated the ripening is large, and consumption is many, and cost is high; The small aluminium bottle output ethylene gas of CN1306748 report accelerates the ripening in method, in fruit accelerates the ripening, need in special accelerate the ripening room or case, carry out, and need to grasp the safe handling operation of small-sized steel cylinder, and in the process of accelerating the ripening the strict output quantity of controlling small aluminium bottle ethene etc., require high and complex operation, be difficult for promoting.
Ethrel decomposes gradually when pH value 4 is above, and will discharge ethene, by the ethylene gas corresponding fruit product that accelerates the ripening, have easy and simple to handle, the advantage of safety and environmental protection.But in the solid fruit-vegetable ripener of CN10175810 report, ethrel to formula host requires high, be required to be 99.9% solid vinyl profit, at present in the domestic ethrel Yuan Yao of Ministry of Agriculture's registration manufacturing enterprise, there is no the former medicine registration of 99.9% ethrel, domestic enterprise fails to supply raw material, and makes cost of material increase simultaneously.
The present invention has solved this problem targetedly.
Summary of the invention
One of technical problem to be solved by this invention is higher, the large usage quantity of cost, the poor problem of the effect of accelerating the ripening in prior art, and a kind of new ethrel dust composition is provided.Said composition, for the preparation of ethrel pulvis, has advantages of that cost is lower, consumption is less.Two of technical problem to be solved by this invention is to provide a kind of preparation method of the ethrel dust composition corresponding with one of technical solution problem.Three of technical problem to be solved by this invention is to provide a kind of purposes of the ethrel dust composition corresponding with one of technical solution problem.
For one of addressing the above problem, the technical solution used in the present invention is as follows: a kind of ethrel dust composition, in mass fraction, comprise the ethrel of 3-50%, the auxiliary agent A of the inorganic base of 5-60%, 20-40%, the auxiliary agent B of 1-10%.
In technique scheme, preferably, described ethrel is that commercially available purity is the former medicine of ethrel of 70-91%.
In technique scheme, preferably, described inorganic base is at least one in slaked lime, calcium oxide, magnesium hydroxide, magnesia, sodium acetate.
In technique scheme, more preferably, described inorganic base is at least one in slaked lime, magnesium hydroxide, sodium acetate.
In technique scheme, preferably, described auxiliary agent A is calcium carbonate, magnesium carbonate, aluminium oxide, barium sulfate, calcium sulphate magnesium sulfate, at least one in sodium sulphate.
In technique scheme, more preferably, described auxiliary agent A is at least one in calcium carbonate, aluminium oxide, barium sulfate, sodium sulphate.
In technique scheme, preferably, described auxiliary agent B is at least one in sodium chloride, magnesium chloride, potassium chloride, calcium chloride.
In technique scheme, more preferably, described auxiliary agent B is at least one in sodium chloride, potassium chloride, calcium chloride.
In technique scheme, preferably, in mass fraction, comprise the ethrel of 15-40%, the auxiliary agent A of the inorganic base of 15-50%, 25-35%, the auxiliary agent B of 3-8%.
For address the above problem two, the technical solution used in the present invention is as follows: a kind of preparation method of ethrel dust composition, the raw material that comprises described ethrel, inorganic base, auxiliary agent A, auxiliary agent B is mixed in reactor, obtain described ethrel powder product.
In technique scheme, preferably, described reactor is stirred autoclave, and reaction condition is: reaction temperature is 20-60 ℃, and reaction pressure is counted normal pressure with gauge pressure.
For address the above problem three, the technical solution used in the present invention is as follows: described ethrel dust composition accelerates the ripening for fruit.
In ethrel dust composition of the present invention and preparation process thereof, can adopt commercially available purity is the former medicine of ethrel of 70-91%, reduced production cost, and this ethrel dust composition is met the effect that glassware for drinking water slowly discharges for ethene, make product long effective time of accelerating the ripening, reduced the consumption of ethrel pulvis.Meanwhile, this ethrel dust composition is when for the accelerating the ripening of fruit, and little with fruit Exposure, the fruit color and luster accelerating the ripening is even, not perishable, and mouthfeel is good, accelerates the ripening effective, and fruit quality is high, has obtained good technique effect.
Below by embodiment, the invention will be further elaborated, but be not limited only to the present embodiment.
Embodiment
[embodiment 1]
In stirred autoclave, in mass fraction, add ethrel (commercially available, purity is 89%) 8%, inorganic base (slaked lime 40%, sodium acetate 20%), (wherein calcium carbonate 15% for auxiliary agent A, calcium sulphate 15%), auxiliary agent B (magnesium chloride 2%), reaction temperature is 58 ℃, normal pressure, stir 0.5h, discharging, gained powder is ethrel pulvis.
By the ethrel pulvis obtaining, for the accelerating the ripening of banana, this ethrel pulvis is met the effect that glassware for drinking water slowly discharges for ethene, makes product long effective time of accelerating the ripening, the consumption of the ethrel pulvis that per kilogram banana is required is only 0.050g, the banana color and luster accelerating the ripening is even, not perishable, and mouthfeel is good.
[embodiment 2]
In stirred autoclave, in mass fraction, add ethrel (commercially available, purity is 88%) 15%, inorganic base (slaked lime 45%, magnesia 5%), (wherein barium sulfate 15% for auxiliary agent A, aluminium oxide 15%), auxiliary agent B (sodium chloride 5%), reaction temperature is 50 ℃, normal pressure, stir 0.5h, discharging, gained powder is ethrel pulvis.
By the ethrel pulvis obtaining, for the accelerating the ripening of banana, this ethrel pulvis is met the effect that glassware for drinking water slowly discharges for ethene, makes product long effective time of accelerating the ripening, the consumption of the ethrel pulvis that per kilogram banana is required is only 0.039g, the banana color and luster accelerating the ripening is even, not perishable, and mouthfeel is good.
[embodiment 3]
In stirred autoclave, in mass fraction, add ethrel (commercially available, purity is 85%) 25%, inorganic base (calcium oxide 30%, magnesia 15%), auxiliary agent A (sodium sulphate 15%, magnesium sulfate 12%), auxiliary agent B (calcium chloride 3%), reaction temperature is 55 ℃, normal pressure, stir 0.5h, discharging, gained powder is ethrel pulvis.
By ethrel pulvis the accelerating the ripening for kiwi fruit obtaining, this ethrel pulvis is met the effect that glassware for drinking water slowly discharges for ethene, make product long effective time of accelerating the ripening, the consumption of the ethrel pulvis that per kilogram kiwi fruit is required is only 0.020g, the kiwi fruit color and luster accelerating the ripening is even, not perishable, and mouthfeel is good.
[embodiment 4]
In stirred autoclave, in mass fraction, add ethrel (commercially available, purity is 84%) 27%, inorganic base calcium oxide 55%, auxiliary agent A (aluminium oxide 10%), auxiliary agent B (potassium chloride 8%), reaction temperature is 45 ℃, normal pressure, stir 0.5h, discharging, gained powder is ethrel pulvis.
By ethrel pulvis the accelerating the ripening for kiwi fruit obtaining, this ethrel pulvis is met the effect that glassware for drinking water slowly discharges for ethene, make product long effective time of accelerating the ripening, the consumption of the ethrel pulvis that per kilogram kiwi fruit is required is only 0.025g, the kiwi fruit color and luster accelerating the ripening is even, not perishable, and mouthfeel is good.
[embodiment 5]
In stirred autoclave, in mass fraction, add ethrel (commercially available, purity is 80%) 30%, inorganic base magnesium hydroxide 40%, (wherein calcium sulphate 15% for auxiliary agent A, sodium sulphate 10%), auxiliary agent B (sodium chloride 2%, potassium chloride 3%), reaction temperature is 50 ℃, normal pressure, stir 0.5h, discharging, gained powder is ethrel pulvis.
By the ethrel pulvis obtaining, for the accelerating the ripening of apple, this ethrel pulvis is met the effect that glassware for drinking water slowly discharges for ethene, makes product long effective time of accelerating the ripening, the consumption of the ethrel pulvis that per kilogram apple is required is only 0.026g, the apple color and luster accelerating the ripening is even, not perishable, and mouthfeel is good.
[embodiment 6]
In stirred autoclave, in mass fraction, add ethrel (commercially available, purity is 78%) 35%, inorganic base (magnesia 32%, sodium acetate 3%), auxiliary agent A (wherein calcium carbonate 28%), auxiliary agent B (magnesium chloride 2%), reaction temperature is 40 ℃, and normal pressure stirs 0.5h, discharging, gained powder is ethrel pulvis.
By the ethrel pulvis obtaining, for the accelerating the ripening of apple, this ethrel pulvis is met the effect that glassware for drinking water slowly discharges for ethene, makes product long effective time of accelerating the ripening, the consumption of the ethrel pulvis that per kilogram apple is required is only 0.028kg, the apple color and luster accelerating the ripening is even, not perishable, and mouthfeel is good.
[embodiment 7]
In reactor, in mass fraction, add ethrel (commercially available, purity is 75%) 40%, inorganic base (slaked lime 30%, sodium acetate 10%), auxiliary agent A (wherein sodium sulphate 10%), auxiliary agent B (calcium chloride 5%, sodium chloride 5%), reaction temperature is 40 ℃, normal pressure, stir 0.5h, discharging, gained powder is ethrel pulvis.
By the ethrel pulvis obtaining, for the accelerating the ripening of mango, this ethrel pulvis is met the effect that glassware for drinking water slowly discharges for ethene, makes product long effective time of accelerating the ripening, the consumption of the ethrel pulvis that per kilogram mango is required is only 0.12g, the mango color and luster accelerating the ripening is even, not perishable, and mouthfeel is good.
[embodiment 8]
In stirred autoclave, in mass fraction, add ethrel (commercially available, purity is 72%) 45%, inorganic base magnesia 15%, auxiliary agent A (wherein calcium carbonate 30%, aluminium oxide 9%), auxiliary agent B (magnesium chloride 1%), reaction temperature is 35 ℃, and normal pressure stirs 0.5h, discharging, gained powder is ethrel pulvis.
By the ethrel pulvis obtaining, for the accelerating the ripening of mango, this ethrel pulvis is met the effect that glassware for drinking water slowly discharges for ethene, makes product long effective time of accelerating the ripening, the consumption of the ethrel pulvis that per kilogram mango is required is only 0.11g, the mango color and luster accelerating the ripening is even, not perishable, and mouthfeel is good.
[comparative example]
According to the condition described in embodiment 7, just adopt the commercially available fruit-vegetable ripener mango that accelerates the ripening, the required ripener consumption of per kilogram mango is 0.30g, required time of the mango that accelerates the ripening is longer, perishable, and mouthfeel is poor.

Claims (9)

1. an ethrel dust composition, in mass fraction, comprise the ethrel of 3-50%, the auxiliary agent A of the inorganic base of 5-60%, 20-40%, the auxiliary agent B of 1-10%.
2. ethrel dust composition according to claim 1, is characterized in that described ethrel is that commercially available purity is the former medicine of ethrel of 70-91%; Described inorganic base is at least one in slaked lime, calcium oxide, magnesium hydroxide, magnesia, sodium acetate; Described auxiliary agent A is calcium carbonate, magnesium carbonate, aluminium oxide, barium sulfate, calcium sulphate magnesium sulfate, at least one in sodium sulphate; Described auxiliary agent B is at least one in sodium chloride, magnesium chloride, potassium chloride, calcium chloride.
3. ethrel dust composition according to claim 1, is characterized in that in mass fraction, comprise the ethrel of 15-40%, the auxiliary agent A of the inorganic base of 15-50%, 25-35%, the auxiliary agent B of 3-8%.
4. ethrel dust composition according to claim 2, is characterized in that described inorganic base is at least one in slaked lime, magnesium hydroxide, sodium acetate.
5. ethrel dust composition according to claim 2, is characterized in that described auxiliary agent A is at least one in calcium carbonate, aluminium oxide, barium sulfate, sodium sulphate
6. ethrel dust composition according to claim 2, is characterized in that described auxiliary agent B is at least one in sodium chloride, potassium chloride, calcium chloride.
7. the preparation method of ethrel dust composition described in claim 1 mixes the raw material that comprises described ethrel, inorganic base, auxiliary agent A, auxiliary agent B in reactor, obtains described ethrel powder product.
8. ethrel dust composition according to claim 7, is characterized in that described reactor is stirred autoclave, and reaction condition is: reaction temperature is 20-60 ℃, and reaction pressure is counted normal pressure with gauge pressure.
9. ethrel dust composition described in claim 1, accelerates the ripening for fruit.
CN201410293646.3A 2014-06-25 2014-06-25 Ethephon powder composition as well as preparation method and use thereof Pending CN104082288A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104604933A (en) * 2015-02-11 2015-05-13 四川国光农化股份有限公司 Plant ethylene regulation composite, preparation and applications thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104604933A (en) * 2015-02-11 2015-05-13 四川国光农化股份有限公司 Plant ethylene regulation composite, preparation and applications thereof

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Application publication date: 20141008