CN104073687A - Superlattice Sm-Mg-Ni multiphase alloy, preparation method and application of superlattice Sm-Mg-Ni multiphase alloy as well as nickel-metal hydride battery - Google Patents
Superlattice Sm-Mg-Ni multiphase alloy, preparation method and application of superlattice Sm-Mg-Ni multiphase alloy as well as nickel-metal hydride battery Download PDFInfo
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- CN104073687A CN104073687A CN201410302046.9A CN201410302046A CN104073687A CN 104073687 A CN104073687 A CN 104073687A CN 201410302046 A CN201410302046 A CN 201410302046A CN 104073687 A CN104073687 A CN 104073687A
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- alloy
- superlattice
- hydrogen storage
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- 239000000956 alloy Substances 0.000 title claims abstract description 93
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 92
- 238000002360 preparation method Methods 0.000 title claims abstract description 26
- 229910052987 metal hydride Inorganic materials 0.000 title claims abstract description 16
- 229910019083 Mg-Ni Inorganic materials 0.000 title abstract 8
- 229910019403 Mg—Ni Inorganic materials 0.000 title abstract 8
- 239000001257 hydrogen Substances 0.000 claims abstract description 70
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 70
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 64
- 238000003860 storage Methods 0.000 claims abstract description 37
- 229910052772 Samarium Inorganic materials 0.000 claims abstract description 29
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 26
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 13
- 238000002844 melting Methods 0.000 claims abstract description 13
- 230000008018 melting Effects 0.000 claims abstract description 13
- 238000000227 grinding Methods 0.000 claims abstract description 11
- 230000006698 induction Effects 0.000 claims abstract description 10
- 239000002994 raw material Substances 0.000 claims abstract description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 66
- 238000000137 annealing Methods 0.000 claims description 23
- 239000000463 material Substances 0.000 claims description 15
- -1 nickel metal hydride Chemical class 0.000 claims description 14
- 239000010935 stainless steel Substances 0.000 claims description 8
- 229910001220 stainless steel Inorganic materials 0.000 claims description 8
- 239000007789 gas Substances 0.000 claims description 5
- 239000002131 composite material Substances 0.000 claims description 4
- 229910002058 ternary alloy Inorganic materials 0.000 claims description 4
- 238000000746 purification Methods 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 15
- 238000005245 sintering Methods 0.000 abstract description 10
- 239000011232 storage material Substances 0.000 abstract description 5
- 239000000843 powder Substances 0.000 abstract description 3
- 229910002335 LaNi5 Inorganic materials 0.000 abstract 1
- 238000010521 absorption reaction Methods 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- 230000002441 reversible effect Effects 0.000 abstract 1
- 230000004913 activation Effects 0.000 description 16
- 229910000990 Ni alloy Inorganic materials 0.000 description 9
- 238000002441 X-ray diffraction Methods 0.000 description 7
- 230000008569 process Effects 0.000 description 7
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 6
- 239000010931 gold Substances 0.000 description 6
- 229910052737 gold Inorganic materials 0.000 description 6
- 238000003991 Rietveld refinement Methods 0.000 description 5
- 229910000905 alloy phase Inorganic materials 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 230000014759 maintenance of location Effects 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 238000002425 crystallisation Methods 0.000 description 3
- 230000008025 crystallization Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 235000003283 Pachira macrocarpa Nutrition 0.000 description 2
- 238000003723 Smelting Methods 0.000 description 2
- 241001083492 Trapa Species 0.000 description 2
- 235000014364 Trapa natans Nutrition 0.000 description 2
- 238000000498 ball milling Methods 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 230000007420 reactivation Effects 0.000 description 2
- 235000009165 saligot Nutrition 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 229910000967 As alloy Inorganic materials 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000006253 efflorescence Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 206010037844 rash Diseases 0.000 description 1
- 238000003746 solid phase reaction Methods 0.000 description 1
- 238000010671 solid-state reaction Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000013077 target material Substances 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Powder Metallurgy (AREA)
- Manufacture Of Metal Powder And Suspensions Thereof (AREA)
Abstract
Description
Claims (8)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410302046.9A CN104073687B (en) | 2014-06-27 | 2014-06-27 | A kind of superlattice Sm – Mg – Ni polyphase alloy and its preparation method and application and nickel metal hydride battery |
Applications Claiming Priority (1)
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CN201410302046.9A CN104073687B (en) | 2014-06-27 | 2014-06-27 | A kind of superlattice Sm – Mg – Ni polyphase alloy and its preparation method and application and nickel metal hydride battery |
Publications (2)
Publication Number | Publication Date |
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CN104073687A true CN104073687A (en) | 2014-10-01 |
CN104073687B CN104073687B (en) | 2016-01-06 |
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CN201410302046.9A Active CN104073687B (en) | 2014-06-27 | 2014-06-27 | A kind of superlattice Sm – Mg – Ni polyphase alloy and its preparation method and application and nickel metal hydride battery |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108493436A (en) * | 2018-03-09 | 2018-09-04 | 燕山大学 | Ni-based quaternary hydrogen-storing alloy electrode material of a kind of super stacking provisions lanthanum-M-magnesium-of 2H types A5B19 and preparation method thereof |
CN114941058A (en) * | 2022-07-07 | 2022-08-26 | 上海大学 | High-purity Pr5Co19 type La-Y-Ni superlattice alloy and preparation method thereof |
CN116219228A (en) * | 2023-03-03 | 2023-06-06 | 包头中科轩达新能源科技有限公司 | A kind of (Gd, mg) 2 Ni 7 Preparation method of superlattice hydrogen storage alloy |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101323918A (en) * | 2008-06-19 | 2008-12-17 | 安徽工业大学 | Preparation of light hydrogen occluding alloy |
CN101501896A (en) * | 2006-08-09 | 2009-08-05 | 株式会社杰士汤浅 | Hydrogen storage alloy, hydrogen storage alloy electrode, secondary battery, and method for producing hydrogen storage alloy |
-
2014
- 2014-06-27 CN CN201410302046.9A patent/CN104073687B/en active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101501896A (en) * | 2006-08-09 | 2009-08-05 | 株式会社杰士汤浅 | Hydrogen storage alloy, hydrogen storage alloy electrode, secondary battery, and method for producing hydrogen storage alloy |
CN101323918A (en) * | 2008-06-19 | 2008-12-17 | 安徽工业大学 | Preparation of light hydrogen occluding alloy |
Non-Patent Citations (2)
Title |
---|
JINGJING LIU ET AL.: "Microstructure and Electrochemical Characteristics of Step-Wise Annealed La0.75Mg0.25Ni3.5 Alloy with A2B7- and A5B19- type Super-Stacking Structure", 《JOURNAL OF THE ELECTROCHEMICAL SOCIETY》, vol. 160, no. 8, 14 May 2013 (2013-05-14) * |
郭利召: "铸态及快淬态(Mg24Ni10)1-xSmx(x=0-0.2)合金气态吸放氢动力学性能研究", 《中国优秀硕士学位论文全文数据库 工程科技Ⅰ辑》, no. 5, 15 May 2013 (2013-05-15) * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108493436A (en) * | 2018-03-09 | 2018-09-04 | 燕山大学 | Ni-based quaternary hydrogen-storing alloy electrode material of a kind of super stacking provisions lanthanum-M-magnesium-of 2H types A5B19 and preparation method thereof |
CN114941058A (en) * | 2022-07-07 | 2022-08-26 | 上海大学 | High-purity Pr5Co19 type La-Y-Ni superlattice alloy and preparation method thereof |
CN114941058B (en) * | 2022-07-07 | 2023-05-23 | 上海大学 | High-purity Pr5Co19 type La-Y-Ni superlattice alloy and preparation method thereof |
CN116219228A (en) * | 2023-03-03 | 2023-06-06 | 包头中科轩达新能源科技有限公司 | A kind of (Gd, mg) 2 Ni 7 Preparation method of superlattice hydrogen storage alloy |
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Publication number | Publication date |
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CN104073687B (en) | 2016-01-06 |
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C41 | Transfer of patent application or patent right or utility model | ||
CB03 | Change of inventor or designer information |
Inventor after: Guo Aolin Inventor after: Ma Junjie Inventor before: Chen Ziliang Inventor before: Gong Xiumian |
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TR01 | Transfer of patent right |
Effective date of registration: 20160612 Address after: 419199, No. 92, umbrella alley, Zhi River Town, Zhi River Dong Autonomous County, Huaihua, Hunan Patentee after: Guo Aolin Address before: 243000 Anhui city of Ma'anshan province Xianglu mountain rain Ma Anhui University of Technology (East Campus) School of materials Patentee before: Chen Ziliang |
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C41 | Transfer of patent application or patent right or utility model | ||
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Inventor after: Zhang Shude Inventor before: Guo Aolin Inventor before: Ma Junjie |
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Effective date of registration: 20160721 Address after: 518100, Guangdong Province, Fuyong Town, Baoan District Ocean Development Zone, two district, 9, one or two, Shenzhen Patentee after: SHENZHEN DELIPOW BATTERY TECHNOLOGY CO., LTD. Address before: 419199, No. 92, umbrella alley, Zhi River Town, Zhi River Dong Autonomous County, Huaihua, Hunan Patentee before: Guo Aolin |