CN104070575B - The long-acting modification agent for timber of a kind of timber floor - Google Patents

Abstract

The present invention relates to timber floor Wooden modifying process field, be specifically related to long-acting modification agent for a kind of timber floor timber, this modifier is made by the raw material of following weight portion: propane diols 10-12, methyl acrylate 12-15, alkyl polyglucoside 6-8, gallic acid 10-12, zinc chloride 1-3, Grape Skin 2-3, white wine 15-18, neopelex 3-4, urea 35-40, water 380-400, auxiliary agent 6-8; Modifier raw material environmental protection prepared by the present invention is easy to get, and preparation method is simple, and growth cost is low, and there is good penetration, and what energy was uniform and stable infiltrates through timber inside, and chemical stability is good, resistance to storage, the timber color and luster after modification is naturally bright, good stability of the dimension, mildew resistant moistureproof, fire-retardant complete, mechanical property also obtains necessarily improving, modified effect is lasting, the timber floor that timber after modification is made is more durable in use with the floor of material, and range of application is wider, and the market competitiveness is strong.

Description

The long-acting modification agent for timber of a kind of timber floor

Technical field

The present invention relates to timber floor Wooden modifying process field, be specifically related to a kind of long-acting modification agent and preparation method thereof for timber floor timber.

Background technology

Timber floor is common fitment material for family, mainly comprise the kinds such as solid wooden floor board, laminated flooring, solid wooden compound floor, due to the core material-timber of timber floor, it is biological material, itself there is inflammable, perishable, yielding, the shortcoming such as wet-heat resisting not, seriously limited its scope of application, necessary timber is carried out to some pretreatment, to improve the timber defensive ability/resistance ability of environment to external world, improve environment tolerance level.

Existing method for modifying wood mainly utilizes some physical means, chemical modification agent solution is infiltrated through to timber inside, reach and improve physics, chemical property, the final object that improves its serviceability, but more existing chemical modification methods timber after treatment, in follow-up use procedure, may have a large amount of volatile organic matter discharges, can produce harm to surrounding environment, also there is inorganic agent high expensive, performance is not lasting, affect the shortcomings such as decorate properties, in the urgent need to developing the Wood modifier of the novel environment-friendly high-efficiency of a class, fundamentally improve the serviceability of timber floor, improve the shortcoming on Traditional Wood floor.

Summary of the invention

The object of the invention is to provide long-acting modification agent for a kind of timber floor timber, with the lasting timber mechanics performance that effectively improves, widens the scope of application, and to achieve these goals, the technical solution used in the present invention is as follows:

The long-acting modification agent for timber of a kind of timber floor, it is characterized in that, this modifier is made up of the raw material of following weight portion: propane diols 10-12, methyl acrylate 12-15, alkyl polyglucoside 6-8, gallic acid 10-12, zinc chloride 1-3, Grape Skin 2-3, white wine 15-18, neopelex 3-4, urea 35-40, water 380-400, auxiliary agent 6-8;

Auxiliary agent is made up of the raw material of following weight portion: the aqueous polyurethane emulsion 10-12 that solid content is 50%, sodium phosphate trimer 1-3, sodium humate 4-5, Ludox 2-3, secondary alcohol APEO 1-2, Eugenol 0.1-0.2, water 30, its preparation method is: first by sodium phosphate trimer, sodium humate mixes with water, being stirred to mixed material dissolves completely, add subsequently secondary alcohol APEO, Eugenol, aqueous polyurethane emulsion, dispersed with stirring 20-30min, add again Ludox, stir after 10min, mixed solution ball milling 1-2h, make stabilizing solution, obtain auxiliary agent.

Described long-acting modification agent for a kind of timber floor timber, its preparation method is:

(1) first by Grape Skin and white spirit mixed, airtight immersion 5-6 days, soaks and finishes rear material filtering, and filtrate is for subsequent use;

(2) by evenly for subsequent use to methyl acrylate and mixed with propylene glycol;

(3) alkyl polyglucoside, zinc chloride, neopelex, urea are mixed with water, be stirred to after dissolving completely, add step (1), (2) gained material and other leftover materials, stir 1-2h with the rotating speed of 1500-1800 rev/min, to obtain final product.

Wood modifier advantage of the present invention is: the raw material adopting is environmental protection composition, not containing volatile toxicant, can not work the mischief to environment and human body, production process is simple, and cost is low, in preparation method, utilize soaking in Chinese liquor Grape Skin, simply extract efficiently active ingredient wherein, reach effect of anti-oxidation and antisepsis, Grape Skin after immersion can also recycle, and avoids the wasting of resources; In addition, the raw materials such as methyl acrylate in raw material, alkyl polyglucoside, zinc chloride, urea, infiltrate through behind timber inside, can be good at adsorbing mutually with lumber fibre, reach and improve dimensional stability, moisture retardant texts, the timber mechanics performance after modification agent modification of the present invention obtains and promotes, modifier is difficult for running off, modified effect is lasting, and the timber after modification is more durable in use with the floor of material, and the market competitiveness is strong.

Detailed description of the invention

Embodiment

The modifier of the present embodiment by following weight portion (kilogram) raw material make: propane diols 12, methyl acrylate 13, alkyl polyglucoside 8, gallic acid 12, zinc chloride 2, Grape Skin 2, white wine 15, neopelex 4, urea 40, water 400, auxiliary agent 8; Auxiliary agent is made up of the raw material of following weight portion: aqueous polyurethane emulsion 12, sodium phosphate trimer 3, sodium humate 5, Ludox 2, secondary alcohol APEO 2, Eugenol 0.1, water 30 that solid content is 50%, its preparation method is: first sodium phosphate trimer, sodium humate are mixed with water, being stirred to mixed material dissolves completely, add subsequently secondary alcohol APEO, Eugenol, aqueous polyurethane emulsion, dispersed with stirring 30min, add again Ludox, stir after 10min, mixed solution ball milling 2h, make stabilizing solution, obtain auxiliary agent.

The preparation method for modifier of the present embodiment is:

(1) first by Grape Skin and white spirit mixed, airtight immersion 6 days, soaks and finishes rear material filtering, and filtrate is for subsequent use;

(2) by evenly for subsequent use to methyl acrylate and mixed with propylene glycol;

(3) alkyl polyglucoside, zinc chloride, neopelex, urea are mixed with water, be stirred to after dissolving completely, add step (1), (2) gained material and other leftover materials, stir 2h with the rotating speeds of 1800 revs/min, to obtain final product.

The present embodiment impregnates and processes China fir veneer as example taking modifier, the China fir veneer of same specification is dried after 10h under 50-60 DEG C of condition, be divided into two groups, experimental group is soaked in synthermal modifier, in vacuum is-0.1MPa, pressure is to impregnate 2h under 0.5MPa condition, take out, after the washing of surface, in natural environment, be dried 7 days, finally under 50-60 DEG C of condition, cure, keep moisture content at 5-6%; Control group is left intact. Two groups of veneers enter subsequent processes, make laminated flooring.

Experimental group China fir veneer after modification and undressed control group China fir veneer carry out respectively performance test, result shows, experimental group China fir compression strength improves 15.4% compared with control group timber, at wood surface inoculation wood after mould and black mould, experimental group China fir veneer surface clean is without mycelia, otherwise control group China fir surface from mildewing is serious; The anti-lixiviate value of experimental group China fir veneer reaches 90.6%, show that the timber after modifier treatment has the resistance leachability having resisted, and the moisture absorption ratio of experimental group China fir is lower, reduces by 6.4% than control group; Results of combustion tests shows, experimental group China fir HRR reduces by 68.4% compared with control group, and total heat liberation rate, heat release rate reduces by 67.8%, illustrates that the China fir after modifier treatment of the present invention has fire resistance, and security is higher.

Claims (2)

1. a long-acting modification agent for timber floor timber, it is characterized in that, this inorganic agent is made up of the raw material of following weight portion: propane diols 10-12, methyl acrylate 12-15, alkyl polyglucoside 6-8, gallic acid 10-12, zinc chloride 1-3, Grape Skin 2-3, white wine 15-18, neopelex 3-4, urea 35-40, water 380-400, auxiliary agent 6-8;

Auxiliary agent is made up of the raw material of following weight portion: aqueous polyurethane emulsion 10-12, sodium phosphate trimer 1-3, sodium humate 4-5, Ludox 2-3, secondary alcohol APEO 1-2, Eugenol 0.1-0.2, water 30 that solid content is 50%,

Its preparation method is: first sodium phosphate trimer, sodium humate are mixed with water, being stirred to mixed material dissolves completely, add subsequently the aqueous polyurethane emulsion that secondary alcohol APEO, Eugenol, solid content are 50%, dispersed with stirring 20-30min, add again Ludox, stir after 10min mixed solution ball milling 1-2h, make stabilizing solution, obtain auxiliary agent.

2. long-acting modification agent for a kind of timber floor timber as claimed in claim 1, its preparation method is:

(1) first by Grape Skin and white spirit mixed, airtight immersion 5-6 days, soaks and finishes rear material filtering, and filtrate is for subsequent use;

(2) by evenly for subsequent use to methyl acrylate and mixed with propylene glycol;

(3) alkyl polyglucoside, zinc chloride, neopelex, urea are mixed with water, be stirred to after dissolving completely, add step (1), (2) gained material and other leftover materials, stir 1-2h with the rotating speed of 1500-1800 rev/min, to obtain final product.