CN104060164A - Hot rolled sheet steel for cold forming and making method thereof - Google Patents
Hot rolled sheet steel for cold forming and making method thereof Download PDFInfo
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Abstract
The invention discloses a hot rolled sheet steel for cold forming and a making method thereof, the making method of the hot rolled sheet steel for cold forming includes the steps of steelmaking, continuous casting, heating, hot continuous rolling and coiling, and the steelmaking molten steel is characterized by comprising the following components: 0.05 to 0.1 wt% of C, less than or equal to 0.1 wt% of Si, 1.7 to 1.95 wt% of Mn, 0.03 to 0.07 wt% of Nb, 0.09 to 0.14 wt% of Ti, 0.1 to 0.3 wt% of Mo, less than or equal to 0.025 wt% of P, less than or equal to 0.01 wt% of S, and the balance of Fe and unavoidable impurities; the precision rolling finish rolling temperature of the hot continuous rolling step is 850-900 DEG C; and the coiling temperature of the coiling step is 530 to 580 DEG C. According to the method, the high-strength hot rolled sheet steel for cold forming with yield strength of 750MPa is provided.
Description
Technical field
The present invention relates to a kind of hot rolled steel plate for cold formation and manufacture method thereof, particularly, relate to a kind of yield strength 750MPa level cold formability high tensile hot rolled steel sheet and preparation method thereof.
Background technology
Impact for fear of thermoforming process on hot-rolled steel sheet material softening problem, in actual applications, the hot-rolled steel sheet less to thickness of slab, adopting cooling formation technic to carry out the processing of clod wash part is a kind of economical and practical method, therefore, hot continuous rolling steel plate for cold forming has obtained very large development, and hot continuous rolling steel plate for cold forming is widely used in the fields such as automobile, engineering machinery, steel construction, building.
The hot-rolled steel sheet yield strength that cooling formation technic is used is at first within 400MPa, development along with all trades and professions, in order to reduce production costs and to improve member security, the steel grade of this intensity rank can not meet user's requirement, need to adopt the hot rolled steel plate for cold formation of higher height level, at automotive field, in order to alleviate vehicle weight, reduce oil consumption, improve automobile component intensity, to guarantee safety performance etc., more than automotive frame has been brought up to yield strength 650MPa with the intensity rank of hot-rolled steel sheet; Along with the increase of depth of building and the raising that safety performance is required, the rank of cold-formed hot continuous rolled steel plate for building is also brought up to even 460MPa of 420MPa from 345MPa.
The Domex 700MC hot-rolled steel sheet that Dong Feng Auto Corporation one full year of life Hua Dengdui Sweden SSAB company produces is analyzed, its chemical composition require as the Mn of the C of≤0.12 % by weight ,≤2.1 % by weight, the Ti of the Nb of≤0.07 % by weight ,≤0.1 % by weight, the Mo of≤0.5 % by weight, the mechanical property of typical case's finished steel plate is Rel=735MPa, Rm=820MPa, A=16%, Domex 700MC contains Mo noble element, and production cost is higher, and the unit elongation of Domex 700MC hot-rolled steel sheet is lower; The Zhang Fengquan of University of Science & Technology, Beijing etc. has discussed the TS780 hot-rolled steel sheet of Kawasaki, Japan company exploitation in the current situation and development article of Low Alloy Steel for Automobile, its chemical composition be the C of 0.08 % by weight, the Mn of the Si of 1.5 % by weight, 1.8 % by weight, the Ti of 0.1 % by weight, finished steel plate mechanical property is Rm >=800MPa, A >=20%, utilize titanium precipitation strength and ferrite+martensite polyphase structure of ferritic phase, reached good over-all properties, but finishing temperature and the coiling temperature of producing this kind of steel plate are low, and producting process difficulty is larger; Anshan iron and steel plant share technique center Chen Yan etc. are studied the NANO-HITEN steel of NKK exploitation at the research and development of products strategy article of Japanese JFE Iron And Steel Company, chemical composition is that the C of 0.2 % by weight is, the Mn of the Si of 1.46 % by weight, 1.45 % by weight, mechanical property is Rel=670MPa, Rm=830MPa, A=39%, the finishing temperature of NANO-HITEN steel plate is 800 ℃, coiling temperature is 380 ℃, low carbon levels and interpolation molybdenum have been avoided pearlitic generation, but finishing temperature and coiling temperature are low, and producting process difficulty is larger; A kind of method of producing high-strength steel with yield strength of 700 MPa of the inventions such as the burnt state of Hunan Hualing Lianyuan Iron And Steel Co., Ltd China, its chemical composition content is the C of 0.03-0.08 % by weight, the Si of 0.2-0.5 % by weight, 1.4-2 the Mn of % by weight, the Ti of 0.1-0.15 % by weight, the Nb of 0.02-0.08 % by weight, the V of 0-0.03 % by weight, adopt continuous casting and rolling technique of sheet bar, finishing temperature is 820-880 ℃, after laminar flow is cooling, coiling temperature is 550-620 ℃, the yield strength scope of product is 690-760MPa, and curling temperature is lower, and producting process difficulty is larger; A kind of 700MPa grade composite strengthening bainite steel of the new equality invention of Zhujiang Iron and Steel Co Ltd, Guangzhou's hair and preparation method thereof adopts continuous casting and rolling technique of sheet bar, its chemical composition content is the C of 0.03-0.07 % by weight, the Mn of 1.51-2.1 % by weight, the Cr of 0.5-0.8 % by weight, the Ti of 0.1-0.15 % by weight, the tissue of steel be take tiny bainite as main, more than product yield strength can reach 700MPa, in this steel plate, contain Cr, and Ti content is higher, production cost is higher, and coiling temperature is low, and producting process difficulty is larger.
Visible, the production technology route of high tensile hot rolled steel sheet more than 700MPa level generally adopts the microalloying route of noble elements such as adding chromium, niobium, molybdenum and vanadium, and the molybdenum content of part steel grade even reaches 0.5 % by weight Mo, and chromium content reaches 0.5-0.8 % by weight Cr.In addition, portioned product adopts continuous casting and rolling technique of sheet bar, and low finishing temperature (as 800 ℃), low coiling temperature (as 380 ℃) and conventional process for cooling, make to introduce bainite or martensite strengthening in finished product tissue, and producting process difficulty is larger.Simultaneously, the Si content of all steel grades is all more than 0.1 % by weight, the hot rolled steel plate for cold formation of this composition is no problem as the delivery of hot rolling commodity, but silicone content more than 0.1 % by weight will reduce the sticking power of coating, affect the quality of coating, therefore the steel billet of this silicone content can not be as the raw material of cold rolling coating product, like this, hot-rolled product and cold-rolled products will adopt the raw material of different chemical composition, cause steel mill's steel grade trade mark many, bring very large difficulty to the organization of production arrangement in smelting and continuous casting, the utilization ratio and the hot delivery and hot charging rate that are unfavorable for slab storehouse, can not carry out Flexible Production.
Summary of the invention
The object of the invention is, in order to overcome in prior art the higher and larger defect of producting process difficulty of yield strength 750MPa level cold formability high tensile hot rolled steel sheet production cost, provides a kind of new yield strength 750MPa level cold formability high tensile hot rolled steel sheet and manufacture method thereof.
The present inventor surprisingly finds under study for action, adopt niobium, titanium, manganese, molybdenum microalloying mode, and each component is controlled in suitable content range, and adopt the high finish rolling finishing temperature of 850-900 ℃ and the high coiling temperature of 535-580 ℃, can make the cold formability high tensile hot rolled steel sheet of producing there is high-intensity high-tenacity, and do not need to add the noble elements such as Cr and V, and high finish rolling finishing temperature and high coiling temperature make controlling of production process simple, in addition, by adopting the silicon composition of low levels, thereby make steel billet both can be used as the raw material of hot continuous rolling steel plate for cold forming, can be used as again the raw material of cold-rolled steel sheet and cold rolling Coated Steel, the composition of hot-rolled product and cold-rolled products can be united, reduce mixed the watering between steel grade, be conducive to the utilization ratio in slab storehouse and the hot delivery and hot charging of steel billet, be conducive to realize Flexible Production, reduce the difficulty of steel mill's organization of production, improve the production efficiency of steel mill.
Therefore, to achieve these goals, on the one hand, the invention provides a kind of manufacture method of hot rolled steel plate for cold formation, the method comprises steel-making step, continuous casting step, heating steps, hot continuous rolling step and batches step, wherein, molten steel composition after described steel-making is: the C of 0.05-0.1 % by weight, the Si of≤0.1 % by weight, the Mn of 1.7-1.95 % by weight, the Nb of 0.03-0.07 % by weight, the Ti of 0.09-0.14 % by weight, the Mo of 0.1-0.3 % by weight, the P of≤0.025 % by weight, the S of≤0.01 % by weight, surplus is Fe and inevitable impurity; Finish rolling finishing temperature in described hot continuous rolling step is 850-900 ℃; The described coiling temperature batching in step is 535-580 ℃.
Under preferable case, molten steel composition after described steel-making is: the C of 0.05-0.08 % by weight, the Si of≤0.05 % by weight, the Mn of 1.8-1.95 % by weight, the Nb of 0.045-0.06 % by weight, the Ti of 0.1-0.125 % by weight, the Mo of 0.15-0.25 % by weight, the P of≤0.025 % by weight, the S of≤0.01 % by weight, surplus is Fe and inevitable impurity.
Preferably, the finish rolling finishing temperature in described hot continuous rolling step is 870-895 ℃; The described coiling temperature batching in step is 540-575 ℃.
Preferably, after finish rolling, the cooling rate with 10-30 ℃/s is cooled to coiling temperature.
On the other hand, the invention provides a kind of hot rolled steel plate for cold formation being made by aforesaid method.
The present invention adopts niobium, titanium, manganese, molybdenum microalloying mode, the molten steel composition of controlling after steel-making is: the C of 0.05-0.1 % by weight, the Si of≤0.1 % by weight, the Mn of 1.7-1.95 % by weight, the Nb of 0.03-0.07 % by weight, the Ti of 0.09-0.14 % by weight, the Mo of 0.1-0.3 % by weight, the P of≤0.025 % by weight, the S of≤0.01 % by weight, surplus is Fe and inevitable impurity.Avoid adding the noble elements such as Cr and V, reduced production cost; Adopt high-temperature final rolling, high temperature coiling and process for cooling system fast simultaneously, successfully produce that to take acicular ferrite be main yield strength 750MPa level cold formability high tensile hot rolled steel sheet, rolling technology is controlled simple, strong adaptability; And the cold formability high tensile hot rolled steel sheet mechanical property of the inventive method manufacture meets the requirement of cold formability high tensile hot rolled steel sheet.
Other features and advantages of the present invention partly in detail are described the embodiment subsequently.
Embodiment
Below the specific embodiment of the present invention is elaborated.Should be understood that, embodiment described herein only, for description and interpretation the present invention, is not limited to the present invention.
The invention provides a kind of manufacture method of hot rolled steel plate for cold formation, the method comprises makes steel step, continuous casting step, heating steps, hot continuous rolling step and batches step, and wherein, the molten steel composition after described steel-making is: the C of 0.05-0.1 % by weight, the Si of≤0.1 % by weight, the Mn of 1.7-1.95 % by weight, the Nb of 0.03-0.07 % by weight, the Ti of 0.09-0.14 % by weight, the Mo of 0.1-0.3 % by weight, the P of≤0.025 % by weight, the S of≤0.01 % by weight, surplus is Fe and inevitable impurity; Finish rolling finishing temperature in described hot continuous rolling step is 850-900 ℃; The described coiling temperature batching in step is 535-580 ℃.
According to the present invention, as long as make the molten steel composition after steel-making be: the C of 0.05-0.1 % by weight, the Si of≤0.1 % by weight, the Mn of 1.7-1.95 % by weight, the Nb of 0.03-0.07 % by weight, the Ti of 0.09-0.14 % by weight, the Mo of 0.1-0.3 % by weight, the P of≤0.025 % by weight, the S of≤0.01 % by weight, surplus is Fe and inevitable impurity; Finish rolling finishing temperature in described hot continuous rolling step is 850-900 ℃; The described coiling temperature batching in step is 535-580 ℃, can realize object of the present invention, reduces production costs, and rolling technology is controlled simple, and the hot rolled steel plate for cold formation producing meets the requirement of cold formability high tensile hot rolled steel sheet.But under preferable case, molten steel composition after steel-making is: the C of 0.0.05-0.08 % by weight, the Si of≤0.05 % by weight, the Mn of 1.8-1.95 % by weight, the Nb of 0.045-0.06 % by weight, the Ti of 0.1-0.125 % by weight, the Mo of 0.15-0.25 % by weight, the P of≤0.025 % by weight, the S of≤0.01 % by weight, surplus is Fe and inevitable impurity, can further improve intensity and the toughness of the cold formability high tensile hot rolled steel sheet of producing.
In addition,, in order further to improve intensity and the toughness of the cold formability high tensile hot rolled steel sheet of producing, the finish rolling finishing temperature in preferred described hot continuous rolling step is 870-895 ℃, more preferably 875-895 ℃; The coiling temperature batching in step is preferably 540-575 ℃; 545-570 ℃ more preferably.
In the present invention, for steel-making step, without particular requirement, can adopt the conventional process for making in this area, for example, through desulfurizing iron, converter smelting, LF stove Ca, process, by molten steel composition control, be: the C of 0.05-0.1 % by weight, the Si of≤0.1 % by weight, the Mn of 1.7-1.95 % by weight, the Nb of 0.03-0.07 % by weight, the Ti of 0.09-0.14 % by weight, the Mo of 0.1-0.3 % by weight, the P of≤0.025 % by weight, the S of≤0.01 % by weight, surplus is Fe and inevitable impurity.
For continuous casting step, also can adopt the conventional continuous casting process in this area, for example, adopt whole argon gas-sealed casting, molten steel injects tundish by the slide gate nozzle of ladle bottom, tundish temperature is without particular requirement, for the conventional temperature adopting in this area, be for example 1530-1560 ℃, adopt funnel-type crystallizer, Casting speed is without particular requirement, for the conventional Casting speed adopting in this area, be for example 0.7-0.9m/min, the continuous casting steel billet thickness that continuous casting step obtains is preferably 200-250mm.
In the present invention, heating steps is preferably strand is heated (heating comprises preheating section, soaking zone etc.) at 1230-1265 ℃ of (being preferably 1240-1260 ℃) temperature, described strand heating can be carried out on the device for strand heating of various routines, and the device heating for strand can be for example walking beam furnace.
In the present invention, hot continuous rolling step is to make strand after heating after high-pressure water descaling is removed the upper iron scale forming in surface, enter reversible roughing unit, through the rolling of 5-7 passage, every time deflection is not less than 20%(and is preferably 21-36%), after roughing, the thickness of intermediate blank is 40-60mm, enter subsequently Coil Box, make to be with steel toe, tail transposing, then carry out finish rolling, after finish rolling, the thickness of steel plate is preferably 5-10mm.The temperature out of roughing, without particular requirement, can adopt the conventional temperature in this area, and for example roughing temperature out is 1030-1080 ℃, is preferably 1050-1070 ℃.Finish rolling start rolling temperature is preferably 950-1000 ℃, is preferably 975-1000 ℃; In addition, as mentioned above, finish rolling finishing temperature is 850-900 ℃; Be preferably 870-895 ℃; 875-895 ℃ more preferably.
In the present invention, batching step is that coiled sheet batches the step of rolling by reeling machine through overcooling.For cooling mode, be preferably the cooling mode of laminar flow, the cooling speed of cooling being preferably with 10-30 ℃/s of laminar flow is cooled to coiling temperature from finish rolling finishing temperature, and more preferably the speed of cooling with 15-26 ℃/s is cooled to coiling temperature from finish rolling finishing temperature.Coiling temperature is 535-580 ℃, is preferably 540-575 ℃; More preferably 545-570 ℃.
The present invention also provides a kind of cold formability high tensile hot rolled steel sheet being made by aforesaid method.The tissue of this cold formability high tensile hot rolled steel sheet is mainly acicular ferrite.The yield strength of this cold formability high tensile hot rolled steel sheet is more than 750MPa, to be preferably 755-780MPa, and tensile strength is more than 800MPa, to be preferably 820-860MPa, and unit elongation more than 17%, is preferably 17-21%.
More than describe the preferred embodiment of the present invention in detail; but the present invention is not limited to the detail in above-mentioned embodiment, within the scope of technical conceive of the present invention; can carry out multiple simple variant to technical scheme of the present invention, these simple variant all belong to protection scope of the present invention.
Embodiment
The present invention is further illustrated for following embodiment, but therefore do not limit the present invention.
Embodiment 1-5
Molten steel is after steel-making step (molten steel composition after steel-making is referring to table 1), adopt whole argon gas-sealed casting, molten steel injects tundish by the slide gate nozzle of ladle bottom, tundish temperature is 1538 ℃, adopt funnel-type crystallizer, Casting speed is 0.7m/min, and continuous casting steel billet thickness is 200mm～230mm; Continuous casting steel billet is heated in process furnace, strand after heating is after dephosphorize by high pressure water is removed the upper iron scale forming in surface, enter reversible roughing unit, intermediate blank after roughing enters Coil Box, make to be with steel toe, tail transposing, then carry out finish rolling, after finish rolling, carry out laminar flow cooling and batch, thereby make hot-rolled steel sheet, wherein, the temperature of heating of plate blank, roughing temperature out, the thickness of speed of cooling, coiling temperature and steel plate that the workpiece thickness after roughing, finish rolling temperature in, finish rolling finishing temperature, laminar flow are cooling is as shown in table 2 respectively.
The afterbody sampling of the coil of strip of the hot rolled steel plate for cold formation making in above embodiment 1-5, and detect yield strength (ReL), tensile strength (Rm) and unit elongation (A%) according to the method for GB/T228.1-2010 regulation; Method according to GB/T232-2010 regulation detects cold-bending property (B=35mm, α=180 °, d=2a; D represents that Bend diameter, a represent that sample thickness, α represent that crooked angle, B represent the width of sample), its detected result is shown in Table 3.
Table 1
Table 2
Table 3
| Embodiment | Yield strength (MPa) | Tensile strength (MPa) | Unit elongation (%) | Cold-bending property |
| 1 | 765 | 832 | 19.5 | Qualified |
| 2 | 772 | 849 | 18.0 | Qualified |
| 3 | 756 | 823 | 20.5 | Qualified |
| 4 | 768 | 844 | 19.0 | Qualified |
| 5 | 775 | 857 | 17.5 | Qualified |
Note: do not occur in cold-bending property test that cracking is for qualified, occur that cracking is for defective.
From above-mentioned table 1-3, can find out, the hot rolled steel plate for cold formation of the inventive method manufacture not only has high strength but also have high tenacity, and its mechanical property meets the requirement of cold formability high tensile hot rolled steel sheet completely.
Claims (10)
1. the manufacture method of a hot rolled steel plate for cold formation, the method comprises makes steel step, continuous casting step, heating steps, hot continuous rolling step and batches step, it is characterized in that, the molten steel composition after described steel-making is: the C of 0.05-0.1 % by weight, the Si of≤0.1 % by weight, the Mn of 1.7-1.95 % by weight, the Nb of 0.03-0.07 % by weight, the Ti of 0.09-0.14 % by weight, the Mo of 0.1-0.3 % by weight, the P of≤0.025 % by weight, the S of≤0.01 % by weight, surplus is Fe and inevitable impurity; Finish rolling finishing temperature in described hot continuous rolling step is 850-900 ℃; The described coiling temperature batching in step is 535-580 ℃.
2. method according to claim 1, wherein, molten steel composition after described steel-making is: the C of 0.05-0.08 % by weight, the Si of≤0.05 % by weight, the Mn of 1.8-1.95 % by weight, the Nb of 0.045-0.06 % by weight, the Ti of 0.1-0.125 % by weight, the Mo of 0.15-0.25 % by weight, the P of≤0.025 % by weight, the S of≤0.01 % by weight, surplus is Fe and inevitable impurity.
3. method according to claim 1 and 2, wherein, the finish rolling finishing temperature in described hot continuous rolling step is 870-895 ℃; The described coiling temperature batching in step is 540-575 ℃.
4. method according to claim 1 and 2, wherein, the speed of cooling with 10-30 ℃/s after finish rolling is cooled to coiling temperature.
5. according to the method described in any one in claim 1-4, wherein, the finish rolling start rolling temperature in described hot continuous rolling step is 950-1000 ℃.
6. according to the method described in any one in claim 1-5, wherein, in described hot continuous rolling step, after roughing, the thickness of intermediate blank is 40-60mm.
7. according to the method described in any one in claim 1-6, wherein, the thickness of the steel plate after described finish rolling is 5-10mm.
8. according to the method described in any one in claim 1-7, wherein, described heating steps for heating strand at 1230-1265 ℃ of temperature.
9. a hot rolled steel plate for cold formation, is characterized in that, described hot rolled steel plate for cold formation method described in any one in claim 1-8 makes.
10. hot rolled steel plate for cold formation according to claim 9, wherein, the yield strength of this hot rolled steel plate for cold formation is 755-780MPa, and tensile strength is 820-860MPa, and unit elongation is 17-21%.
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| CN106734246A (en) * | 2016-11-21 | 2017-05-31 | 首钢京唐钢铁联合有限责任公司 | A kind of method for reducing cold-rolled biphase steel aberration |
| CN116694989A (en) * | 2023-05-24 | 2023-09-05 | 邯郸钢铁集团有限责任公司 | 700 Mpa-level thin-specification easy-to-weld suspension arm steel and production method thereof |
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| CN116694989A (en) * | 2023-05-24 | 2023-09-05 | 邯郸钢铁集团有限责任公司 | 700 Mpa-level thin-specification easy-to-weld suspension arm steel and production method thereof |
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