CN104058167A

CN104058167A - Anti-counterfeiting device for wine bottle

Info

Publication number: CN104058167A
Application number: CN201310095848.2A
Authority: CN
Inventors: 徐传毅
Original assignee: Nano New Energy Tangshan Co Ltd
Current assignee: Nano New Energy Tangshan Co Ltd
Priority date: 2013-03-22
Filing date: 2013-03-22
Publication date: 2014-09-24
Anticipated expiration: 2033-03-22
Also published as: CN104058167B; CN105966748A; CN105564806B; CN105966748B; CN105564806A

Abstract

The invention discloses an anti-counterfeiting device for a wine bottle. The anti-counterfeiting device comprises a display screen (1) and a nano friction power generator (2) electrically connected with the display screen (1), wherein the display screen (1) is used for displaying an anti-counterfeiting mark; and the nano friction power generator (2) generates electric energy after deformed and supplies power to the display screen (1). The anti-counterfeiting device for the wine bottle can check authenticity of wine in a simple pressing manner, the operation is simple and convenient, further, shapes, positions and the like of the device can be flexibly designed, and the anti-counterfeiting problem of the wine is effectively solved.

Description

A kind of false proof device for bottle

Technical field

The present invention relates to false proof demonstration field, particularly a kind of false proof device for bottle.

Background technology

A kind of culture of wine on entertaining guests at a banquet as China, becomes requisite beverage, and still, its true and false problem of high-grade wine on the market of appearing at present often becomes user's a scruple greatly.Therefore, how the true and false of actv. difference wine becomes the problem of needing solution badly.

In the disclosed patent application document 02214915.5 of China, it adopts the mode that bottle neck is cut off, user can only be opened once, although this kind of mode to a certain extent actv. prevents reusing of bottle, but, if the wine in bottle still has residue, wine can not be resealed, thereby cause the waste of wine.

As can be seen here, in prior art, lacking a kind of bottle that can either not destroy again can flexible design shape, and realize false proof object for the false proof device on bottle.

Summary of the invention

The problem to be solved in the present invention is to provide a kind of can neither destroy bottle flexible design shape again, and can realize false proof object for the false proof device on bottle.

For addressing the above problem, the invention provides a kind ofly for the false proof device on bottle, its concrete technical scheme is:

For a false proof device for bottle, the nano friction electrical generator that comprises read-out and be electrically connected to read-out, read-out is used for showing anti-counterfeiting mark, after nano friction electrical generator generation deformation, produces electric energy, is read-out power supply.

Further, read-out is electrically connected to nano friction electrical generator by wire, and after bottle is opened, read-out disconnects with the wire that is connected between nano friction electrical generator, and read-out cannot show anti-counterfeiting information again.

With respect to existing apparatus, the advantage of the false proof device for bottle of the present invention is:

(1) read-out that false proof device of the present invention adopts be flexibility, can carry out as required bending, and its shape can flexible design, can be applicable to the bottle of various profiles.And this false proof device shows anti-counterfeiting mark by read-out, can show false proof result in intuitive and convenient ground.

(2) false proof device of the present invention adopts nano friction generator powered, as long as make in use nano friction electrical generator produce deformation, can generate electricity, there will not be electric weight to use up situation about cannot use, therefore, false proof device of the present invention can not be subject to the restriction of power supply, all can use whenever and wherever possible.

(3) use of the nano friction electrical generator in the present invention, itself just can play false proof effect, if the read-out in the false proof device of installing on bottle still cannot be powered when nano friction electrical generator generation deformation, can determine that the false proof device of installing on this bottle palms off, therefore, this wine is also imitation.

Accompanying drawing explanation

Fig. 1 is the structural representation of false proof device provided by the invention;

Fig. 2 a is the block diagram of the first embodiment provided by the invention;

Fig. 2 b is that the assembling of the first embodiment provided by the invention completes figure;

Fig. 3 is the block diagram of the second embodiment provided by the invention;

Fig. 4 is the block diagram of the third embodiment provided by the invention;

Fig. 5 a is the block diagram of the 4th kind of embodiment provided by the invention;

Fig. 5 b is that the assembling of the 4th kind of embodiment provided by the invention completes figure;

Fig. 6 a is the block diagram of the 5th kind of embodiment provided by the invention;

Fig. 6 b is that the assembling of the 5th kind of embodiment provided by the invention completes figure;

Fig. 7 is the block diagram of the 6th kind of embodiment provided by the invention;

Fig. 8 is the block diagram of the 7th kind of embodiment provided by the invention;

Fig. 9 is the block diagram of the 8th kind of embodiment provided by the invention;

Figure 10 is the block diagram of the 9th kind of embodiment provided by the invention;

Figure 11 is the block diagram of the provided by the invention ten kind of embodiment;

Figure 12 is the block diagram of the 11 kind of embodiment provided by the invention;

Figure 13 is the first structural representation of the nano friction electrical generator in false proof device of the present invention;

Figure 14 is the cutaway view of the nano friction electrical generator in Figure 13;

Figure 15 is the second structural representation of the nano friction electrical generator in false proof device of the present invention;

Figure 16 is the cutaway view of the nano friction electrical generator in Figure 15;

Figure 17 is the third structural representation of the nano friction electrical generator in false proof device of the present invention;

Figure 18 is the cutaway view of the nano friction electrical generator in Figure 17.

The specific embodiment

In order better to understand object of the present invention, structure and function, below in conjunction with accompanying drawing, a kind of false proof device for bottle of the present invention is done to further detailed description.

Fig. 1 shows the structural representation of false proof device provided by the invention.This false proof device comprises read-out 1 and the nano friction electrical generator 2 being electrically connected to read-out 1.Wherein, read-out 1 is flexible display screen, can be the read-out of current existing LCD screen, electronic-paper display screen or other low-power consumption etc., read-out 1 can show the anti-counterfeiting mark (for example, false proof logo, security code, name of product or product related information etc.) pre-setting; There is deformation and can generate electricity in nano friction electrical generator 2, for electric energy being provided to read-out 1, makes read-out 1 show anti-counterfeiting mark.

Referring to Fig. 2 a to Figure 12, specifically describe the structure for the false proof device on bottle of the present invention:

Referring to Fig. 2 a and Fig. 2 b, it shows the first embodiment of the present invention, and in this embodiment, false proof device is arranged on the bottle cap of bottle.Wherein, referring to Fig. 2 a, the read-out 1 in false proof device is oblong, is arranged on the end face of bottle cap 3, is solidified as a whole, in order to show the anti-counterfeiting mark pre-setting with bottle cap; The nano friction electrical generator 2 being electrically connected to read-out 1, for circular, is also arranged on the end face of bottle cap 3, is positioned at a side of read-out 1.When needs carry out anti-counterfeit recognition, the nano friction electrical generator 2 that only need press on bottle cap 3 can be realized false proof demonstration.

Further, during bottle cap 3 in turning on the present invention, the read-out 1 in false proof device and the connection line between nano friction electrical generator 2 can be destroyed, thereby make read-out 1 cannot show anti-counterfeiting information, reached further false proof function.The concrete structure of realizing above-mentioned functions in the present invention is described below:

Referring to Fig. 2 a, bottle cap 3 in the present embodiment comprises Moveable lid body 31 and fixing lid 32, and fixedly lid 32 is installed on bottle, and 31 of Moveable lid bodies can take off from bottle, to realize the unlatching of bottle, Moveable lid body 31 and fixedly lid 32 are connected into complete bottle cap 3 by 33 groups of lid joint portions.Wherein, the read-out 1 in the false proof device of the present embodiment and nano friction electrical generator 2 are arranged on Moveable lid body 31.

Further, the pig-tail wire on the read-out 1 in false proof device and the pig-tail wire on nano friction electrical generator 2 are arranged on Moveable lid body 31 and fixing 33 places, lid joint portion between lid 32, to realize the electrical connection of read-out 1 and nano friction electrical generator 2.And when opening wine bottle, need be from lid joint portion 33 by Moveable lid body 31 with fixedly lid 32 is separately, the connection that is arranged on thus the pig-tail wire at 33 places, lid joint portion just can disconnect, thereby cause the disconnection that is electrically connected between read-out 1 and nano friction electrical generator 2, therefore read-out 1 cannot normally show anti-counterfeiting information, reached further false proof function.

Referring to Fig. 2 b, a kind of optimal way as the present embodiment, the external packing box 4 of bottle is formed with opening in the position of the false proof device corresponding on bottle cap 3, the size of opening and shape are corresponding with the size and shape that is arranged on read-out 1 on bottle cap 3 and nano friction electrical generator 2, thereby can see the false proof device on bottle cap by the opening part from external packing box 4.When needs carry out anti-counterfeit recognition, can not open external packing box 4, directly the opening part from external packing box 4 is pressed nano friction electrical generator 2, to realize false proof demonstration.Certainly, also can be after opening external packing box 4, then the nano friction electrical generator 2 that pressing bottle covers is realized false proof demonstration.

Referring to Fig. 3, it shows the second embodiment of the present invention, and in this embodiment, false proof device is arranged on the bottle cap of bottle.Wherein, the read-out 1 in false proof device is circular, is arranged on the end face of bottle cap 3, is solidified as a whole, in order to show the anti-counterfeiting mark pre-setting with bottle cap 3; The nano friction electrical generator 2 being electrically connected to read-out 1 is crescent, is vertically set on the excircle of bottle cap 3, is preferably horizontally set.When needs carry out anti-counterfeit recognition, the meniscate nano friction electrical generator 2 that only need press on bottle cap 3 can be realized false proof demonstration.

Referring to Fig. 3, on the excircle of the bottle cap 3 in the present embodiment, the coated contraction glued membrane 5(that is provided with can be conventional transparent plastic film), further to realize the sealing of bottle.Pig-tail wire on read-out 1 in false proof device and the pig-tail wire on nano friction electrical generator 2 are arranged on shrinks glued membrane 5 places, to realize the electrical connection of read-out 1 and nano friction electrical generator 2.When opening wine bottle, need open and shrink glued membrane 5, the connection that is arranged on thus the pig-tail wire of shrinking glued membrane 5 places just can disconnect, thereby causes the disconnection that is electrically connected between read-out 1 and nano friction electrical generator 2, therefore read-out 1 cannot normally show anti-counterfeiting information, reached further false proof function.

It should be understood that, although what adopt in the present embodiment is by the disconnection that the contraction glued membrane 5 that can open is realized connection line between read-out 1 and nano friction electrical generator 2 is set on the excircle at bottle cap 3, but, what those of ordinary skill in the art can easily expect is, the pig-tail wire by the pig-tail wire on read-out 1 and nano friction electrical generator 2 adopting in the first embodiment be arranged on Moveable lid body 31 and fixedly the mode at 33 places, lid joint portion between lid 32 also can be used in the present embodiment, equally, what the mode in the present embodiment also can be equal to is applicable in other embodiment, do not repeat them here.

Referring to Fig. 4, it shows the third embodiment of the present invention, and in this embodiment, false proof device is arranged on the bottle cap of bottle.Wherein, the read-out 1 in false proof device is oblong, is arranged on the end face of bottle cap 3, is solidified as a whole, in order to show the anti-counterfeiting mark pre-setting with bottle cap 3; The nano friction electrical generator 2 being electrically connected to read-out 1, for circular, is arranged on the extension vertical with bottle cap 3 excircles, is preferably horizontally set.When needs carry out anti-counterfeit recognition, the nano friction electrical generator 2 that only need press on bottle cap 3 can be realized false proof demonstration.

Referring to Fig. 4, bottle cap 3 in the present embodiment comprises Moveable lid body 31 and fixing lid 32, and fixedly lid 32 is installed on bottle, and Moveable lid body 31 can take off from bottle, to realize the unlatching of bottle, Moveable lid body 31 and fixedly lid 32 are connected into complete bottle cap 3 by 33 groups of lid joint portions.Wherein, the read-out 1 in the false proof device of the present embodiment and nano friction electrical generator 2 are arranged on Moveable lid body 31.

Further, the pig-tail wire on the read-out 1 in false proof device and the pig-tail wire on nano friction electrical generator 2 are arranged on Moveable lid body 31 and fixing 33 places, lid joint portion between lid 32, to realize the electrical connection of read-out 1 and nano friction electrical generator 2.When opening wine bottle, need be from lid joint portion 33 by Moveable lid body 31 with fixedly lid 32 is separately, the connection that is arranged on thus the pig-tail wire at 33 places, lid joint portion just can disconnect, thereby cause the disconnection that is electrically connected between read-out 1 and nano friction electrical generator 2, therefore read-out 1 cannot normally show anti-counterfeiting information, reached further false proof function.

Referring to Fig. 5 a and Fig. 5 b, it shows the 4th kind of embodiment of the present invention, and in this embodiment, false proof device is arranged on the Anti-theft cap cover in the bottle cap outside that is sheathed on bottle.Wherein, the bottle cap of the present embodiment is existing bottle cap pattern, and the outer cover of bottle cap is provided with an Anti-theft cap cover 6, and this Anti-theft cap cover 6 is the hollow cylindrical of upper end sealing, lower ending opening.

Referring to Fig. 5 a, on the end face of Anti-theft cap cover 6, be provided with read-out 1, read-out 1 is oblong, is solidified as a whole, in order to show the anti-counterfeiting mark pre-setting with Anti-theft cap cover 6; The nano friction electrical generator (not shown) being electrically connected to read-out 1 is arranged on the below of read-out 1, and same and Anti-theft cap cover 6 is solidified as a whole.When needs carry out anti-counterfeit recognition, only need the Anti-theft cap cover 6 that pressing bottle covers can realize false proof demonstration.

Further, during Anti-theft cap cover 6 in turning on the present invention, the read-out 1 in false proof device and the connection line between nano friction electrical generator 2 can be destroyed, thereby make read-out 1 cannot show anti-counterfeiting information, reached further false proof function.The concrete structure of realizing above-mentioned functions in the present invention is described below:

Referring to Fig. 5 a, Anti-theft cap cover 6 in the present embodiment comprises movable body 61 and fixing body 62, fixedly body 62 is installed on the bottle cap of bottle, movable body 61 can take off from the bottle cap of bottle, to realize the unlatching of bottle, movable body 61 and fixedly body 62 are connected into complete Anti-theft cap cover 6 by 63 groups of body joint portions.Wherein, the read-out 1 on the Anti-theft cap cover of the present embodiment and nano friction electrical generator 2 are arranged on movable body 61.

Further, the pig-tail wire on the read-out 1 on Anti-theft cap cover and the pig-tail wire on nano friction electrical generator 2 are arranged on movable body 61 and fixing 63 places, body joint portion between body 62, to realize the electrical connection of read-out 1 and nano friction electrical generator 2.And when opening wine bottle, need first from body joint portion 63 movable body 61 and fixedly body 62 is separately, the connection that is arranged on thus the pig-tail wire at 63 places, body joint portion just can disconnect, thereby cause the disconnection that is electrically connected between read-out 1 and nano friction electrical generator 2, therefore read-out 1 cannot normally show anti-counterfeiting information, reached further false proof function.

Referring to Fig. 5 b, a kind of optimal way as the present embodiment, the external packing box 4 of bottle is formed with opening in the position of the read-out 1 corresponding on Anti-theft cap cover 6, the size of opening and shape are corresponding with the read-out 1 being arranged on Anti-theft cap cover 6, thereby can see the read-out 1 on Anti-theft cap cover 6 by the opening part from external packing box 4.When needs carry out anti-counterfeit recognition, can not open external packing box 4, directly the opening part from external packing box 4 is pressed Anti-theft cap cover 6, to realize false proof demonstration.Certainly, also can be after opening external packing box 4, then press Anti-theft cap cover 6 and realize false proof demonstration.

Referring to Fig. 6 a and Fig. 6 b, it shows the 5th kind of embodiment of the present invention, and in this embodiment, false proof device is arranged on the false proof accessory on the bottle cap of bottle.Wherein, the bottle cap of the present embodiment is existing bottle cap pattern, and a false proof accessory 7 is additionally set on bottle cap, and this false proof accessory 7 has the banded label 71 that surreptitiously opens, and surreptitiously opens label 71 false proof accessory 7 is fixed on bottle cap.

Referring to Fig. 6 a, the read-out 1 in false proof accessory is oblong, is arranged on the end face of bottle cap, in order to show the anti-counterfeiting mark pre-setting; The nano friction electrical generator 2 being electrically connected to read-out 1, for circular, is arranged on the extension in read-out 1 outside, is preferably horizontally set.When needs carry out anti-counterfeit recognition, the nano friction electrical generator 2 that only need press on false proof accessory 7 can be realized false proof demonstration.

Further, when taking off the false proof accessory 7 in the present invention from bottle cap, the read-out 1 in false proof device and the connection line between nano friction electrical generator 2 can be destroyed, thereby make read-out 1 cannot show anti-counterfeiting information, reached further false proof function.The concrete structure of realizing above-mentioned functions in the present invention is described below:

In the present embodiment, the banded label 71 that surreptitiously opens on false proof accessory 7 is fixedly installed on bottle cap open place, as want opening wine bottle, must first demolish and surreptitiously open label 71, and read-out 1 in false proof accessory and the electrical connecting wire between nano friction electrical generator 2 are arranged on and surreptitiously open on label 71.When bottle cap takes off false proof accessory, must cut off or tear to pieces and surreptitiously open label 71, being arranged on thus the electrical connecting wire surreptitiously opening on label 71 just can disconnect, thereby cause the disconnection that is electrically connected between read-out 1 and nano friction electrical generator 2, therefore read-out 1 cannot normally show anti-counterfeiting information, reached further false proof function.

Referring to Fig. 6 b, a kind of optimal way as the present embodiment, the external packing box 4 of bottle is formed with opening in the position of the read-out 1 corresponding on false proof accessory 7, the size of opening and shape are corresponding with the read-out 1 being arranged on false proof accessory 7, thereby can see the read-out 1 on false proof accessory 7 by the opening part from external packing box 4.In addition, the nano friction electrical generator 2 on false proof accessory 7 also can be extended out external packing box 4, is directly placed on the outer surface of external packing box 4.So, when needs carry out anti-counterfeit recognition, can not open external packing box 4, directly press the nano friction electrical generator 2 being arranged on external packing box 4 outer surfaces, to realize false proof demonstration.Certainly, also can be after opening external packing box 4, then the nano friction electrical generator 2 of pressing on false proof accessory 7 is realized false proof demonstration.

Referring to Fig. 7, it shows the 6th kind of embodiment of the present invention, and in this embodiment, false proof device is arranged on the Anti-theft cap cover in the bottle cap outside that is sheathed on bottle.Wherein, the bottle cap of the present embodiment is existing bottle cap pattern, and the outer cover of bottle cap is provided with an Anti-theft cap cover 6, and this Anti-theft cap cover 6 is cylinder barrel shaped.

Further, the read-out 1 in Anti-theft cap cover is oblong, is arranged in the vertical rectangle framework being connected of excircle with Anti-theft cap cover 6, is preferably longitudinal setting, in order to show the anti-counterfeiting mark pre-setting; The nano friction electrical generator 2 being electrically connected to read-out 1 is also oblong, is arranged on the outer circle wall of Anti-theft cap cover 6.When needs carry out anti-counterfeit recognition, the nano friction electrical generator 2 that only need press on Anti-theft cap cover 6 can be realized false proof demonstration.

Further, when when bottle cap takes off the Anti-theft cap cover 6 in the present invention, the read-out 1 in Anti-theft cap cover and the connection line between nano friction electrical generator 2 can be destroyed, thereby make read-out 1 cannot show anti-counterfeiting information, reached further false proof function.The concrete structure of realizing above-mentioned functions in the present invention is described below:

In the present embodiment, the read-out 1 in Anti-theft cap cover and the electrical connecting wire between nano friction electrical generator 2 are arranged on read-out separation unit 64 places on Anti-theft cap cover 6, and read-out separation unit 64 is positioned at the junction of read-out 1 and Anti-theft cap cover 6 outer circle walls.When bottle cap takes off Anti-theft cap cover, need pull read-out 1 until read-out 1 departs from Anti-theft cap cover 6, thereby cause the electrical connecting wire between read-out 1 and nano friction electrical generator 2 to disconnect, therefore read-out 1 cannot normally show anti-counterfeiting information, reached further false proof function.

Referring to Fig. 8, it shows the 7th kind of embodiment of the present invention, and in this embodiment, false proof device is arranged on the false proof accessory on the bottle cap of bottle.Wherein, the bottle cap 3 of the present embodiment is existing bottle cap pattern, and a false proof accessory 7 is additionally set on bottle cap 3, and this false proof accessory 7 has the banded label 71 that surreptitiously opens, and surreptitiously opens label 71 and is fixed on bottle cap 3.

Further, the read-out 1 in false proof accessory is circular, with the separated setting of bottle cap 3, in order to show the anti-counterfeiting mark pre-setting; The nano friction electrical generator 2 being electrically connected to read-out 1 is oblong, is arranged on and is fixed on surreptitiously opening on label 71 on bottle cap 3.When needs carry out anti-counterfeit recognition, the nano friction electrical generator 2 that only need press on false proof accessory 7 can be realized false proof demonstration.

In the present embodiment, the banded label 71 that surreptitiously opens on false proof accessory 7 is fixed on bottle cap open place, as want opening wine bottle, must first demolish and surreptitiously open label 71, and read-out 1 in false proof accessory and the electrical connecting wire between nano friction electrical generator 2 are arranged on and surreptitiously open on label 71.When opening wine bottle, must cut off or tear to pieces and surreptitiously open label 71, being arranged on thus the electrical connecting wire surreptitiously opening on label 71 just can disconnect, thereby cause the disconnection that is electrically connected between read-out 1 and nano friction electrical generator 2, therefore read-out 1 cannot normally show anti-counterfeiting information, reached further false proof function.

Referring to Fig. 9, it shows the 8th kind of embodiment of the present invention, and in this embodiment, false proof device is arranged on the false proof accessory on the bottle cap of bottle.Wherein, the bottle cap of the present embodiment is existing bottle cap pattern, and a false proof accessory 7 is additionally set on bottle cap, and this false proof accessory 7 has the banded label 71 that surreptitiously opens, and surreptitiously opens label 71 false proof accessory 7 is fixed on bottle cap.

Further, the read-out 1 in false proof accessory is circular, is arranged on the end face of bottle cap, in order to show the anti-counterfeiting mark pre-setting; The nano friction electrical generator 2 being electrically connected to read-out 1 is oblong, is arranged on and is positioned at surreptitiously opening on label 71 on bottle cap.When needs carry out anti-counterfeit recognition, the nano friction electrical generator 2 that only need press on false proof accessory 7 can be realized false proof demonstration.

In the present embodiment, the banded label 71 that surreptitiously opens on false proof accessory 7 is fixed on bottle cap open place, as want opening wine bottle, must first demolish and surreptitiously open label 71, and read-out 1 in false proof accessory and the electrical connecting wire between nano friction electrical generator 2 are arranged on and surreptitiously open on label 71.When opening wine bottle, must cut off or tear to pieces and surreptitiously open label 71, being arranged on thus the electrical connecting wire surreptitiously opening on label 71 just can disconnect, thereby cause the disconnection that is electrically connected between read-out 1 and nano friction electrical generator 2, therefore read-out 1 cannot normally show anti-counterfeiting information, reached further false proof function.In addition, in the present embodiment, the end that surreptitiously opens label 71 also can be provided with draw ring 73, when opening wine bottle, can disconnect or tear to pieces by pulling draw ring 73 to make surreptitiously to open label 71, realizes further antiforge function.

Referring to Figure 10, it shows the 9th kind of embodiment of the present invention, and in this embodiment, false proof device is arranged on the bottle cap of bottle on false proof accessory.Wherein, the bottle cap 3 of the present embodiment is existing bottle cap pattern, and a false proof accessory 7 is additionally set on bottle cap 3, and this false proof accessory 7 has the banded label 71 that surreptitiously opens, and surreptitiously opens label 71 false proof accessory 7 is fixed on bottle cap 3.

Further, the read-out 1 in false proof accessory is oblong, with vertical setting of end face of bottle cap 3, in order to show the anti-counterfeiting mark pre-setting; The nano friction electrical generator 2 being electrically connected to read-out 1 is oblong, is arranged on and is positioned at surreptitiously opening on label 71 on bottle cap 3.When needs carry out anti-counterfeit recognition, the nano friction electrical generator 2 that only need press on false proof accessory 7 can be realized false proof demonstration.

In the present embodiment, the read-out 1 in false proof accessory and the electrical connecting wire between nano friction electrical generator 2 are arranged on read-out separation unit 72 places on false proof accessory 7, and read-out separation unit 72 is positioned at the junction of read-out 1 and bottle cap 3 end faces.When bottle cap takes off false proof accessory, need pull read-out 1 until read-out 1 departs from the end face of bottle cap 3, thereby cause the electrical connecting wire between read-out 1 and nano friction electrical generator 2 to disconnect, therefore read-out 1 cannot normally show anti-counterfeiting information, reached further false proof function.

Referring to Figure 11, it shows the of the present invention ten kind of embodiment, and in this embodiment, false proof device is arranged on the Anti-theft cap cover in the bottle cap outside that is sheathed on bottle.Wherein, the bottle cap of the present embodiment is existing bottle cap pattern, and the outer cover of bottle cap is provided with an Anti-theft cap cover 6, and this Anti-theft cap cover 6 is cylinder barrel shaped.

Further, the read-out 1 in Anti-theft cap cover is oblong, is arranged on the outer circle wall of this Anti-theft cap cover 6, in order to show the anti-counterfeiting mark pre-setting; The nano friction electrical generator 2 being electrically connected to read-out 1, for circular, is also located on the outer circle wall of Anti-theft cap cover 6, is preferably arranged on the below of read-out 1.When needs carry out anti-counterfeit recognition, the nano friction electrical generator 2 that only need press on Anti-theft cap cover 6 can be realized false proof demonstration.

Further, during Anti-theft cap cover 6 in turning on the present invention, the read-out 1 on Anti-theft cap cover and the connection line between nano friction electrical generator 2 can be destroyed, thereby make read-out 1 cannot show anti-counterfeiting information, reached further false proof function.The concrete structure of realizing above-mentioned functions in the present invention is described below:

Referring to Figure 11, Anti-theft cap cover 6 in the present embodiment comprises movable body 61 and fixing body 62, fixedly body 62 is installed on the bottle cap of bottle, movable body 61 can take off from the bottle cap of bottle, to realize the unlatching of bottle, movable body 61 and fixedly body 62 are connected into complete Anti-theft cap cover 6 by 63 groups of body joint portions.Wherein, the read-out 1 on the Anti-theft cap cover of the present embodiment and nano friction electrical generator 2 can be arranged on movable body 61 or fixedly on body 62 simultaneously, also or be separately positioned on movable body 61 and fixedly on body 62.

Referring to Figure 12, it shows the 11 kind of embodiment of the present invention, and in this embodiment, false proof device is arranged on the false proof accessory on the external packing box of bottle.Wherein, the pattern that the external packing box for wine bottle 4 of the present embodiment is existing external packing box, additionally arranges a false proof accessory 7 on external packing box 4, and this false proof accessory 7 has the banded label 71 that surreptitiously opens, and surreptitiously opens label 71 false proof accessory 7 is fixed on external packing box 4.

Further, read-out 1 is oblong, is arranged on the end face of external packing box 4, in order to show the anti-counterfeiting mark pre-setting; The nano friction electrical generator 2 being electrically connected to read-out 1, for circular, is arranged on and surreptitiously opens on label 71, is positioned on the side of external packing box 4.When needs carry out anti-counterfeit recognition, the nano friction electrical generator 2 that only need press on false proof accessory 7 can be realized false proof demonstration.

Further, when taking off the false proof accessory 7 in the present invention from external packing box, read-out 1 on false proof accessory and the connection line between nano friction electrical generator 2 can be destroyed, thereby make read-out 1 cannot show anti-counterfeiting information, reached further false proof function.The concrete structure of realizing above-mentioned functions in the present invention is described below:

In the present embodiment, the banded label 71 that surreptitiously opens on false proof accessory 7 is fixed on external packing box 4 open places, as wish, open external packing box 4, must first demolish and surreptitiously open label 71, and read-out 1 in false proof accessory and the electrical connecting wire between nano friction electrical generator 2 are arranged on and surreptitiously open on label 71.When external packing box takes off false proof accessory, must cut off or tear to pieces and surreptitiously open label 71, being arranged on thus the electrical connecting wire surreptitiously opening on label 71 just can disconnect, thereby cause the disconnection that is electrically connected between read-out 1 and nano friction electrical generator 2, therefore read-out 1 cannot normally show anti-counterfeiting information, reached further false proof function.

Of the present inventionly for the false proof device on bottle, by simply pressing mode, can check the true and false of wine, simple to operation, and this device design shape, position etc. flexibly, actv. has solved the anti-pseudo problem of wine.

Referring to Figure 13 to Figure 18, the version for the present invention's nano friction electrical generator is described:

Referring to Figure 13 and Figure 14, it shows the first structure of the nano friction electrical generator in the present invention.As shown in figure 14, nano friction electrical generator 2 in the present embodiment comprises: the first electrode 21, the first high molecular polymer insulating barriers 22 that are cascading, and the second electrode 23, wherein, the first electrode 21 and the second electrode 23 are the voltage and current output electrode of nano friction electrical generator.

Further, the first electrode 21 in the present embodiment is arranged on the first side surface of the first high molecular polymer insulating barrier 22; The Surface Contact friction of the second side surface of the first high molecular polymer insulating barrier 22 and the second electrode 23 also induces electric charge at the first electrode 21 and the second electrode 23 places.Wherein, at least one surface in two surfaces that the first high molecular polymer insulating barrier 22 and the second electrode 23 are oppositely arranged, be provided with micro-nano concaveconvex structure 24.

Further, the first high molecular polymer insulating barrier 22 in the present embodiment is for being selected from Kapton, aniline formaldehyde resin film, polyformaldehyde film, ethyl cellulose film, polyamide film, melamino-formaldehyde film, carbowax succinate film, cellophane, cellulose acetate film, polyethylene glycol adipate film, polydiallyl phthalate film, fiber (regeneration) sponge film, elastic polyurethane body thin film, styrene-acrylonitrile copolymer copolymer film, styrene-butadiene-copolymer film, regenerated fiber film, poly-methyl film, methyl acrylic acid ester film, polyvinyl alcohol film, polyvinyl alcohol film, mylar, polyisobutene film, polyurethane flexible sponge film, pet film, polyvinyl butyral film, formaldehyde phenol film, poly-chloroprene rubber film, butadiene-propylene copolymer film, natural rubber film, polyacrylinitrile film, a kind of in acrylonitrile vinyl chloride film and polyethylene the third diphenol carbonate thin film.

Further, the first electrode 21 material therefors in the present embodiment are indium tin oxide, Graphene, nano silver wire film, metal or alloy; Wherein, metal is Au Ag Pt Pd, aluminium, nickel, copper, titanium, chromium, selenium, iron, manganese, molybdenum, tungsten or vanadium; Alloy is aluminum alloy, titanium alloy, magnesium alloy, beryllium alloy, copper alloy, zinc alloy, manganese alloy, nickel alloy, lead alloy, tin alloy, cadmium alloy, bismuth alloy, indium alloy, gallium alloy, tungsten alloy, molybdenum alloy, niobium alloy or tantalum alloy; The second electrode 23 material therefors are metal or alloy; Wherein, metal is Au Ag Pt Pd, aluminium, nickel, copper, titanium, chromium, selenium, iron, manganese, molybdenum, tungsten or vanadium; Alloy is aluminum alloy, titanium alloy, magnesium alloy, beryllium alloy, copper alloy, zinc alloy, manganese alloy, nickel alloy, lead alloy, tin alloy, cadmium alloy, bismuth alloy, indium alloy, gallium alloy, tungsten alloy, molybdenum alloy, niobium alloy or tantalum alloy.

During based on metal and high molecular polymer friction, the more volatile de-electromation of metal, therefore adopt metal electrode and high molecular polymer friction energy effectively to improve energy output in the present invention.Therefore, above-mentioned nano friction electrical generator mainly produces electric signal by the friction between metal (the second electrode 23) and poly-mer (the first high molecular polymer insulating barrier 22), be to have utilized metal easily to lose the characteristic of electronics, make to form induction field between the second electrode 23 and the first high molecular polymer insulating barrier 22, thereby produce voltage or electric current.

Lower mask body is introduced the principle of work of the nano friction electrical generator in the present embodiment:

When each layer of this nano friction electrical generator is bent downwardly, the second electrode 23 in nano friction electrical generator produces static charge with the surperficial phase mutual friction of the first high molecular polymer insulating barrier 22, the generation of static charge can make the electric capacity between the first electrode 21 and the second electrode 23 change, thereby causes occurring electric potential difference between the first electrode 21 and the second electrode 23.

Due to the existence of electric potential difference between the first electrode 21 and the second electrode 23, free electron by by external circuit by the low effluent of electromotive force to the high side of electromotive force, thereby in external circuit, form electric current.And when each layer of this nano friction electrical generator returns to original state, at this moment the built-in potential being formed between the first electrode 21 and the second electrode 23 disappears, now between Balanced the first electrode 21 and the second electrode 23, will again produce reverse electric potential difference, free electron forms counter-current by external circuit.By repeatedly rubbing and recovering, just can in external circuit, form periodic ac signal thus.

Referring to Figure 15 and Figure 16, it shows the second structure of the nano friction electrical generator in the present invention.As shown in figure 16, the nano friction electrical generator 2 in the present embodiment further comprises: be arranged on the second high molecular polymer insulating barrier 25 between the second electrode 23 and the first high molecular polymer insulating barrier 22; Wherein, the first electrode 21 and the second electrode 23 are the voltage and current output electrode of nano friction electrical generator.

Further, the second electrode 23 is arranged on the first side surface of the second high molecular polymer insulating barrier 25; The second side surface contact friction of the second side surface of the first high molecular polymer insulating barrier 22 and the second high molecular polymer insulating barrier 25 also induces electric charge at the first electrode 21 and the second electrode 23 places.Wherein, at least one surface in two surfaces that the first high molecular polymer insulating barrier 22 and the second high molecular polymer insulating barrier 25 are oppositely arranged, be provided with micro-nano concaveconvex structure 24.

Further, the first high molecular polymer insulating barrier 22 in the present embodiment and the second high molecular polymer insulating barrier 25 are respectively and are selected from Kapton, aniline formaldehyde resin film, polyformaldehyde film, ethyl cellulose film, polyamide film, melamino-formaldehyde film, carbowax succinate film, cellophane, cellulose acetate film, polyethylene glycol adipate film, polydiallyl phthalate film, fiber (regeneration) sponge film, elastic polyurethane body thin film, styrene-acrylonitrile copolymer copolymer film, styrene-butadiene-copolymer film, regenerated fiber film, poly-methyl film, methyl acrylic acid ester film, polyvinyl alcohol film, polyvinyl alcohol film, mylar, polyisobutene film, polyurethane flexible sponge film, pet film, polyvinyl butyral film, formaldehyde phenol film, poly-chloroprene rubber film, butadiene-propylene copolymer film, natural rubber film, polyacrylinitrile film, a kind of in acrylonitrile vinyl chloride film and polyethylene the third diphenol carbonate thin film.

Further, the first electrode 21 in the present embodiment and the second electrode 23 material therefors are indium tin oxide, Graphene, nano silver wire film, metal or alloy; Wherein, metal is Au Ag Pt Pd, aluminium, nickel, copper, titanium, chromium, selenium, iron, manganese, molybdenum, tungsten or vanadium; Alloy is aluminum alloy, titanium alloy, magnesium alloy, beryllium alloy, copper alloy, zinc alloy, manganese alloy, nickel alloy, lead alloy, tin alloy, cadmium alloy, bismuth alloy, indium alloy, gallium alloy, tungsten alloy, molybdenum alloy, niobium alloy or tantalum alloy.

It should be noted, the first high molecular polymer insulating barrier 22 in the present embodiment and the material of the second high molecular polymer insulating barrier 25 can be identical, also can be different.But if the material of two-layer high molecular polymer insulating barrier is all identical, will cause the quantity of electric charge of triboelectrification very little.Therefore, preferably, the first high molecular polymer insulating barrier 22 in the present embodiment is different from the material of the second high molecular polymer insulating barrier 25.

When each layer of this nano friction electrical generator is bent downwardly, the first high molecular polymer insulating barrier 22 in nano friction electrical generator produces static charge with the surperficial phase mutual friction of the second high molecular polymer insulating barrier 25, the generation of static charge can make the electric capacity between the first electrode 21 and the second electrode 23 change, thereby causes occurring electric potential difference between the first electrode 21 and the second electrode 23.

Due to the existence of electric potential difference between the first electrode 21 and the second electrode 23, free electron by by external circuit by the low effluent of electromotive force to the high side of electromotive force, thereby in external circuit, form electric current.When each layer of this nano friction electrical generator returns to original state, at this moment the built-in potential being formed between the first electrode 21 and the second electrode 23 disappears, now between Balanced the first electrode 21 and the second electrode 23, will again produce reverse electric potential difference, free electron forms counter-current by external circuit.By repeatedly rubbing and recovering, just can in external circuit, form periodic ac signal thus.

Referring to Figure 17 and Figure 18, it shows the third structure of the nano friction electrical generator in the present invention.As shown in figure 18, the nano friction electrical generator of the present embodiment further comprises: be arranged on the thin layer between two parties 26 between the first high molecular polymer insulating barrier 22 and the second high molecular polymer insulating barrier 25, wherein, the first electrode 21 and the second electrode 23 are the voltage and current output electrode of nano friction electrical generator.

Further, thin layer between two parties 26 in the present embodiment is also high molecular polymer insulating barrier, and at least one face in two faces that described thin layer between two parties 26 and the first high molecular polymer insulating barrier 22 are oppositely arranged is provided with micro-nano concaveconvex structure 24, and/or at least one face in two faces being oppositely arranged of described thin layer between two parties 26 and the second high molecular polymer insulating barrier 25 is provided with micro-nano concaveconvex structure 24.Wherein, between two parties thin layer 26 respectively with the second side surface contact friction of the first high molecular polymer insulating barrier 22 second side surfaces and the second high molecular polymer insulating barrier 25 and induce electric charge on the first electrode 21 and the second electrode 23.

Further, the first high molecular polymer insulating barrier 22 in the present embodiment, the second high molecular polymer insulating barrier 25 and between two parties thin layer 26 are respectively and are selected from Kapton, aniline formaldehyde resin film, polyformaldehyde film, ethyl cellulose film, polyamide film, melamino-formaldehyde film, carbowax succinate film, cellophane, cellulose acetate film, polyethylene glycol adipate film, polydiallyl phthalate film, fiber (regeneration) sponge film, elastic polyurethane body thin film, styrene-acrylonitrile copolymer copolymer film, styrene-butadiene-copolymer film, regenerated fiber film, poly-methyl film, methyl acrylic acid ester film, polyvinyl alcohol film, polyvinyl alcohol film, mylar, polyisobutene film, polyurethane flexible sponge film, pet film, polyvinyl butyral film, formaldehyde phenol film, poly-chloroprene rubber film, butadiene-propylene copolymer film, natural rubber film, polyacrylinitrile film, a kind of in acrylonitrile vinyl chloride film and polyethylene the third diphenol carbonate thin film.

It should be noted, the first high molecular polymer insulating barrier 22, the second high molecular polymer insulating barrier 25 in the present embodiment and the material of thin layer 26 can be identical between two parties, also can be different.If but the material of three floor height Molecularly Imprinted Polymer insulating barriers is all identical, can cause the quantity of electric charge of triboelectrification very little.Therefore, preferably, the first high molecular polymer insulating barrier 22 in the present embodiment is different from the material of thin layer 26 between two parties, the second high molecular polymer insulating barrier 25 is different from the material of thin layer 26 between two parties, and the first high molecular polymer insulating barrier 22 is identical with the material of the second high molecular polymer insulating barrier 25, so that minimizing material category, makes making of the present invention convenient.

When each layer of this nano friction electrical generator is bent downwardly, the first high molecular polymer insulating barrier 22 in nano friction electrical generator produces static charge with thin layer 26 phase mutual friction between two parties, the generation of static charge can make the electric capacity between the first electrode 21 and the second electrode 23 change, thereby causes occurring electric potential difference between the first electrode 21 and the second electrode 23.

In addition, preferably micron order or nano level concaveconvex structure of the micro-nano concaveconvex structure 24 in the nano friction electrical generator of above-mentioned three kinds of structures.

Thus, when nano friction electrical generator of the present invention adopts above-mentioned several forms to realize, the false proof device of this bottle can be realized self-energizing, as long as be subject to friction, can produce electric energy, the situation that there will not be battery electric quantity to exhaust and cannot use, greatly facilitates user's use.

Due to the characteristic of nano friction electrical generator triboelectricity, this false proof device can not arrange source switch, while needing read-out to carry out false proof demonstration, and only need be by triboelectricity.Or, also can utilize energy-storage travelling wave tube, the electric energy that for example reservoir capacitance produces nano friction electrical generator stores, and meanwhile, a source switch is set on false proof device of the present invention, for controlling nano friction electrical generator, when to read-out, powers.

In addition, above-mentioned nano friction electrical generator also can adopt slimline battery to substitute.Wherein, slimline battery comprises: flexible package lithium cell, all solid-state thin-film lithium battery and paper battery etc.Use slimline battery the false proof device for bottle of the present invention can be made to obtain to small volume and less weight more.While adopting slimline battery to realize, also a source switch can be set on false proof device, for controlling slimline battery, when to read-out, power.

By specific embodiment, the present invention is further described above; but it should be understood that; here concrete description; should not be construed as the restriction to the spirit and scope of the invention; one of ordinary skilled in the art, reading the various modifications of after this specification sheets, above-described embodiment being made, belongs to the scope that the present invention protects.

Claims

1. the false proof device for bottle, it is characterized in that, comprise read-out (1) and the nano friction electrical generator (2) being electrically connected to read-out (1), read-out (1) is for showing anti-counterfeiting mark, nano friction electrical generator (2) occurs to produce electric energy after deformation, is read-out (1) power supply.

2. the false proof device for bottle according to claim 1, it is characterized in that, read-out (1) is electrically connected to nano friction electrical generator (2) by wire, after bottle is opened, read-out (1) disconnects with the wire that is connected between nano friction electrical generator (2), and read-out (1) cannot show anti-counterfeiting information again.

3. the false proof device for bottle according to claim 1, it is characterized in that, the bottle cap of false proof device and bottle (3) is wholely set, read-out (1) and nano friction electrical generator (2) are set directly on bottle cap (3), by pressing the nano friction electrical generator (2) on bottle cap (3), can make read-out (1) realize false proof demonstration.

4. the false proof device for bottle according to claim 3, is characterized in that, read-out (1) and nano friction electrical generator (2) are arranged on the end face of bottle cap (3).

5. the false proof device for bottle according to claim 3, is characterized in that, read-out (1) is arranged on the end face of bottle cap (3), and nano friction electrical generator (2) is vertically set on the excircle of bottle cap (3).

6. the false proof device for bottle according to claim 3, is characterized in that, read-out (1) is arranged on the end face of bottle cap (3), and nano friction electrical generator (2) is arranged on the extension vertical with bottle cap (3) excircle.

7. according to arbitrary described false proof device for bottle in claim 4 to 6, it is characterized in that, bottle cap (3) comprises the Moveable lid body (31) that can take off from bottle and is installed in the fixedly lid (32) on bottle, Moveable lid body (31) is connected by lid joint portion (33) with fixing lid (32), pig-tail wire on pig-tail wire on read-out (1) and nano friction electrical generator (2) is arranged on lid joint portion (33) and locates, after Moveable lid body (31) and fixedly lid (32) separate, the pig-tail wire of read-out (1) and nano friction electrical generator (2) be connected disconnection.

8. the false proof device for bottle according to claim 5, it is characterized in that, on the excircle of bottle cap (3), coated being provided with shunk glued membrane (5), pig-tail wire on pig-tail wire on read-out (1) and nano friction electrical generator (2) is arranged on contraction glued membrane (5) and locates, open and shrink after glued membrane (5), the pig-tail wire of read-out (1) and nano friction electrical generator (2) be connected disconnection.

9. the false proof device for bottle according to claim 4, it is characterized in that, the external packing box of bottle (4) is formed with opening in the position of the false proof device corresponding on bottle cap (3), and the false proof device that can directly press bottle cap (3) from opening part is realized false proof demonstration.

10. the false proof device for bottle according to claim 1, it is characterized in that, the bottle cap of bottle (3) outside is arranged with Anti-theft cap cover (6), false proof device and Anti-theft cap cover (6) are wholely set, read-out (1) and nano friction electrical generator (2) are set directly on Anti-theft cap cover (6), by pressing the nano friction electrical generator (2) on Anti-theft cap cover (6), can make read-out (1) realize false proof demonstration.

11. false proof devices for bottle according to claim 10, is characterized in that, read-out (1) is arranged on the end face of Anti-theft cap cover (6), and nano friction electrical generator (2) is arranged on the below of read-out (1).

12. false proof devices for bottle according to claim 10, is characterized in that, read-out (1) and nano friction electrical generator (2) are arranged on the outer circle wall of Anti-theft cap cover (6).

13. according to the false proof device for bottle described in claim 11 or 12, it is characterized in that, Anti-theft cap cover (6) comprises the movable body (61) that can take off from bottle cap and is installed in the fixedly body (62) on bottle cap, movable body (61) is connected by body joint portion (63) with fixing body (62), pig-tail wire on pig-tail wire on read-out (1) and nano friction electrical generator (2) is arranged on body joint portion (63) and locates, after activity body (61) and fixedly body (62) separate, the pig-tail wire of read-out (1) and nano friction electrical generator (2) be connected disconnection.

14. false proof devices for bottle according to claim 10, it is characterized in that, read-out (1) is arranged in the vertical rectangle framework being connected of excircle with Anti-theft cap cover (6), and nano friction electrical generator (2) is arranged on the outer circle wall of Anti-theft cap cover (6).

15. false proof devices for bottle according to claim 14, it is characterized in that, the read-out separation unit (64) that electrical connecting wire between read-out (1) and nano friction electrical generator (2) is arranged on Anti-theft cap cover (6) is located, read-out separation unit (64) is positioned at the junction of read-out (1) and Anti-theft cap cover (6) outer circle wall, after pulling read-out (1) and Anti-theft cap cover (6) to depart from, read-out (1) disconnects with the electrical connecting wire of nano friction electrical generator (2).

16. false proof devices for bottle according to claim 11, it is characterized in that, the external packing box of bottle (4) is formed with opening in the position of the false proof device corresponding on Anti-theft cap cover (6), can directly from opening part, press Anti-theft cap cover (6) and realize false proof demonstration.

17. false proof devices for bottle according to claim 1, it is characterized in that, on the bottle cap of bottle (3), be provided with false proof accessory (7), false proof device and false proof accessory (7) are wholely set, read-out (1) and nano friction electrical generator (2) are set directly on false proof accessory (7), by pressing the nano friction electrical generator (2) on false proof accessory (7), can make read-out (1) realize false proof demonstration.

18. false proof devices for bottle according to claim 17, it is characterized in that, on false proof accessory (7), have and surreptitiously open label (71), surreptitiously opening label (71) is fixed on false proof accessory (7) on bottle cap (3), read-out (1) on false proof accessory (7) is arranged on the end face of bottle cap (3), and nano friction electrical generator (2) is arranged on the extension in read-out (1) outside.

19. false proof devices for bottle according to claim 17, it is characterized in that, on false proof accessory (7), have and surreptitiously open label (71), surreptitiously opening label (71) is fixed on bottle cap (3), read-out (1) on false proof accessory (7) and the separated setting of bottle cap (3), nano friction electrical generator (2) is arranged on and is fixed on surreptitiously opening on label (71) on bottle cap (3).

20. false proof devices for bottle according to claim 17, it is characterized in that, on false proof accessory (7), have and surreptitiously open label (71), surreptitiously opening label (71) is fixed on false proof accessory (7) on bottle cap (3), read-out (1) on false proof accessory (7) is arranged on the end face of bottle cap (3), nano friction electrical generator (2) is arranged on and surreptitiously opens label (71) above, and the end that surreptitiously opens label (71) is provided with draw ring (73).

21. according to claim 18 to arbitrary described false proof device for bottle in 20, it is characterized in that, electrical connecting wire between read-out (1) and nano friction electrical generator (2) is arranged on and surreptitiously opens on label (71), demolition is surreptitiously opened after label (71), and read-out (1) disconnects with the electrical connecting wire of nano friction electrical generator (2).

22. false proof devices for bottle according to claim 17, it is characterized in that, on false proof accessory (7), have and surreptitiously open label (71), surreptitiously opening label (71) is fixed on false proof accessory (7) on bottle cap (3), read-out (1) on false proof accessory (7) is arranged on and surreptitiously opens on label (71) with vertical setting of end face of bottle cap (3), nano friction electrical generator (2).

23. false proof devices for bottle according to claim 22, it is characterized in that, the read-out separation unit (72) that electrical connecting wire between read-out (1) and nano friction electrical generator (2) is arranged on false proof accessory (7) is located, read-out separation unit (72) is positioned at the junction of read-out (1) and bottle cap (3) end face, after pulling read-out (1) and bottle cap (3) to depart from, read-out (1) disconnects with the electrical connecting wire of nano friction electrical generator (2).

24. false proof devices for bottle according to claim 18, it is characterized in that, the external packing box of bottle (4) is formed with opening in the position of the false proof device corresponding on false proof accessory (7), nano friction electrical generator (2) extends external packing box (4), be arranged on the outer surface of external packing box (4), can directly press the nano friction electrical generator (2) in external packing box (4) outside and realize false proof demonstration.

25. false proof devices for bottle according to claim 1, it is characterized in that, on the external packing box of bottle (4), be provided with false proof accessory (7), false proof device and false proof accessory (7) are wholely set, read-out (1) and nano friction electrical generator (2) are set directly on false proof accessory (7), by pressing the nano friction electrical generator (2) on false proof accessory (7), can make read-out (1) realize false proof demonstration.

26. false proof devices for bottle according to claim 25, it is characterized in that, on false proof accessory (7), have and surreptitiously open label (71), surreptitiously opening label (71) is fixed on false proof accessory (7) on external packing box (4), read-out (1) on false proof accessory (7) is arranged on the end face of external packing box (4), nano friction electrical generator (2) is arranged on and surreptitiously opens label (71) above, is positioned at the side of external packing box (4).

27. false proof devices for bottle according to claim 26, it is characterized in that, electrical connecting wire between read-out (1) and nano friction electrical generator (2) is arranged on and surreptitiously opens on label (71), demolition is surreptitiously opened after label (71), and read-out (1) disconnects with the electrical connecting wire of nano friction electrical generator (2).

28. false proof devices for bottle according to claim 1, is characterized in that, nano friction electrical generator (2) comprising:

The first high molecular polymer insulating barrier (22);

The first electrode (21), is arranged on the first side surface of the first high molecular polymer insulating barrier (22);

The second electrode (23), the surface of the second electrode (23) contacts with the second side surface of the first high molecular polymer insulating barrier (22);

On at least one surface in two surfaces that the first high molecular polymer insulating barrier (22) and the second electrode (23) are oppositely arranged, be provided with micro-nano concaveconvex structure (24);

The first electrode (21) and the second electrode (23) are the voltage and current output electrode of nano friction electrical generator.

29. false proof devices for bottle according to claim 28, is characterized in that, nano friction electrical generator (2) further comprises:

Be arranged on the second high molecular polymer insulating barrier (25) between the second electrode (23) and the first high molecular polymer insulating barrier (22);

The second electrode (23) is arranged on the first side surface of the second high molecular polymer insulating barrier (25), and the second side surface of the first high molecular polymer insulating barrier (22) contacts with the second side surface of the second high molecular polymer insulating barrier (25);

On at least one surface in two surfaces that the first high molecular polymer insulating barrier (22) and the second high molecular polymer insulating barrier (25) are oppositely arranged, be provided with micro-nano concaveconvex structure (24);

30. false proof devices for bottle according to claim 29, is characterized in that, the first high molecular polymer insulating barrier (22) is different from the material of the second high molecular polymer insulating barrier (25).

31. false proof devices for bottle according to claim 29, is characterized in that, nano friction electrical generator (2) further comprises:

Be arranged on the thin layer between two parties (26) between the first high molecular polymer insulating barrier (22) and the second high molecular polymer insulating barrier (25), thin layer (26) is high molecular polymer insulating barrier between two parties, and at least one face in two faces that thin layer (26) and the first high molecular polymer insulating barrier (22) are oppositely arranged is between two parties provided with micro-nano concaveconvex structure (24), and/or at least one face in two faces that thin layer (26) and the second high molecular polymer insulating barrier (25) are oppositely arranged is between two parties provided with micro-nano concaveconvex structure (24);

Thin layer (26) is respectively with the second side surface contact friction of the first high molecular polymer insulating barrier (22) second side surfaces and the second high molecular polymer insulating barrier (25) and induce electric charge on the first electrode (21) and the second electrode (23) between two parties;

32. false proof devices for bottle according to claim 31, it is characterized in that, the first high molecular polymer insulating barrier (22) is different from the material of thin layer (26) between two parties, and the first high molecular polymer insulating barrier (22) is identical with the material of the second high molecular polymer insulating barrier (25).