CN104057678A - High wear-resistant waterproof moisture-proof composite board and preparation method and application thereof - Google Patents
High wear-resistant waterproof moisture-proof composite board and preparation method and application thereof Download PDFInfo
- Publication number
- CN104057678A CN104057678A CN201310090162.4A CN201310090162A CN104057678A CN 104057678 A CN104057678 A CN 104057678A CN 201310090162 A CN201310090162 A CN 201310090162A CN 104057678 A CN104057678 A CN 104057678A
- Authority
- CN
- China
- Prior art keywords
- layer
- continuous fiber
- thickness
- composite
- composite plate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Laminated Bodies (AREA)
- Floor Finish (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
Abstract
The invention belongs to the field of composite materials, and relates to a composite board and a preparation method and application thereof. The composite board comprises, from top to bottom, an upper surface layer, a core layer and a lower surface, wherein the upper surface layer and/or the lower surface layer are/is a wear resistant composite material. Compared with the prior art, the composite board is more scientific and rational in structure, not only has the traditional floor decorative effect, but also has the advantages of being friction resistant, waterproof, moisture-proof, free of deformation and the like, can be widely used in decoration-used floors, and floors or inner wall plates of refrigerators and refrigeration houses and the like.
Description
Technical field
The invention belongs to field of compound material, relate to a kind of waterproof damp-proof compound plate and its production and use.
Background technology
Often can use the wood based panel taking solid wood, real bamboo, bamboo wood-base fibre and particle panel material as raw material in the industry such as building decoration, furniture; wood based panel not anti-fighting has a large amount of harmful substances; serious harm user's is healthy; because forest is prohibited, to cut down raw material day tight; and use silicon cement, this class inorganic matter of magnesia heavy and crisp as the sheet material of raw material, be unsuitable for doing floor.
Adopt the variation of strengthening plank colour image, texture natural beauty, beautiful, wear-resisting, safeguards and is simple and easy to arrange, relative price is cheap, but aspect expansion rate of water absorption and burst size of methanal, be difficult to fundamentally solve because water proofing property is poor and have a small amount of formaldehyde to discharge the negative issue bringing.
Application number is the preparation method that 200710144063.4 patents of invention disclose a kind of abrasion-proof resin fire-proof board, and base material is wherein two layers or above paper to be put into conventional resin carry out impregnation, then by drying, the mode of roll extrusion makes.The mode that adopts paper dipping in this patent, is having certain restriction aspect the intensity of PLASTIC LAMINATED, affected the range of application of this plate.
Summary of the invention
Object of the present invention is exactly to provide a kind of composite plate and its production and use in order to overcome the defect that above-mentioned prior art exists.This composite floor board had both had the decorative effect on traditional floor, had again rub resistance, fire prevention, waterproof, protection against the tide, the advantage such as indeformable, can be widely used in decorating waterproof and dampproof plate of high abrasion with floor, refrigerating box and freezer etc. and preparation method thereof.
For achieving the above object, the present invention is by the following technical solutions:
A kind of composite plate, comprises upper epidermis, sandwich layer, lower top layer from top to bottom successively, between adjacent each layer, interconnects, and described upper epidermis and/or lower top layer are wearing composite material.
The thickness on described upper or lower top layer is 0.5～5mm.
The thickness range of described sandwich layer is 1～40mm.
The total thickness of described composite plate is 2～50mm.
Described wearing composite material comprises wear-resisting fireprotection layer and nonwoven layer from outside to inside, and the thickness range of wear-resisting fireprotection layer is 0.3～4.5mm, and the thickness range of nonwoven layer is 0.2～0.5mm.
Described wear-resisting fireprotection layer is the abrasion-proof paper that the outer surface pressing of melamine decoration facial tissue has one deck to be made up of alundum (Al2O3).
Described sandwich layer is continuous fiber reinforced thermoplastic plastic composite, is made up of the component that comprises following weight portion: 40～70 parts of thermoplastics; 30～60 parts of continuous fibers.
Described thermoplastic is selected from one or more in polypropylene, polyethylene, PETG, polyamide 6, polyamide 66, polybutylene terephthalate (PBT) or polyvinyl chloride.
Described continuous fiber is selected from one or more in glass fibre, carbon fiber, aramid fiber, superhigh molecular weight polyethylene fibers or basalt fibre.
A preparation method for above-mentioned composite plate, comprises the following steps:
(1) prepare sandwich layer
(1a) be that the thermoplastic of 40～70 parts joins in extruder by weight portion, extrude film by staggered two extrusion dies, by tension-adjusting gear, the continuous super high-strength glass fibre of 30～60 weight portions is arranged in parallel and is become band, lead two extrusion dies place, the both sides of banded continuous fiber contact with two extrusion dies respectively, flood with the molten resin of extruding at die head place, by the continuous super high-strength glass fibre after dipping, guide-in roller pressure device, roll-in, the cooling continuous fiber reinforced thermoplastic composite material sheet material making as core material;
(1b) by multilayer continuous fiber reinforced thermoplastic composite material sheet material, according to the differently-oriented directivity of continuous fiber wherein by 0 °～90 ° laies, then make continuous fiber reinforced thermoplastic composite material sheet material by heat pressing forming machines hot pressing with after colding pressing, obtain sandwich layer;
(2) below wear-resisting fireprotection layer or above lay nonwoven layer, obtain respectively upper epidermis and lower top layer;
(3) according to each layer of upper epidermis, sandwich layer, lower top layer order lay, pass through former hot pressing, make the waterproof and dampproof plate of described high abrasion after cooling.
In described step (1b), the temperature of hot pressing is 160～260 DEG C, and pressure is 1～5MPa, and the time is 3min～15min;
The temperature of colding pressing described in described step (1b) is 15～25 DEG C, and pressure is 2～7MPa, and the time is 5～20min.
In sandwich layer described in described step (1b), continuous fiber reinforced thermoplastic composite material sheet material is 3～5 layers, and also thickness is produced as required.
Former described in described step (3) is different and different according to the thickness of the waterproof and dampproof plate of high abrasion, is specially:
In described step (3), when the waterproof and dampproof plate thickness of high abrasion is during at 2～2.5mm, adopt roll-forming device roller molded, roll-in temperature is 180～260 DEG C, and briquetting pressure is at 1～10MPa, and the time is 2～5 seconds.
In described step (3), in the time that the waterproof and dampproof plate thickness of high abrasion is greater than 2.5mm and is less than or equal to 50mm, adopt compression molding device compression molding, mold pressing temperature is 180～260 DEG C, and briquetting pressure is at 1～10MPa, and the time is 5～20min.
The acting as of nonwoven layer in composite plate of the present invention: strengthen the waterproof and dampproof plate of high abrasion mechanical property, beautify the apparent etc. of the waterproof and dampproof plate of high abrasion.
A kind of above-mentioned composite plate is as the purposes of floor, refrigerating box or freezer sheet material.
Compared with prior art, the present invention has the following advantages and beneficial effect:
(1) the waterproof and dampproof plate of high abrasion of the present invention had both had the decorative effect on traditional floor, had again rub resistance, fire prevention, waterproof, protection against the tide, the advantage such as indeformable.
(2) the waterproof and dampproof plate of high abrasion of the present invention is long service life, uses the waterproof and dampproof plate of high abrasion of the present invention, concrete outstanding advantages aspect energy-saving and emission-reduction and environmental protection.
Brief description of the drawings
Fig. 1 is the structural representation of composite plate in the embodiment of the present invention;
In figure, 1 is that upper epidermis, 11 is that wear-resisting fireprotection layer, 12 is that nonwoven layer, 2 is that sandwich layer, 3 is lower top layer, and 31 is that wear-resisting fireprotection layer, 32 is nonwoven layer.
Detailed description of the invention
Below in conjunction with the drawings and specific embodiments, the present invention is described in detail.
Embodiment 1
A kind of composite plate, as shown in Figure 1, comprises upper epidermis 1, sandwich layer 2 and lower top layer 3, is followed successively by from top to bottom upper epidermis 1, sandwich layer 2, lower top layer 3, between adjacent each layer, interconnects, and He Xia top layer, upper strata is wearing composite material.
The thickness on upper and lower top layer is respectively 0.5mm, and core layer thickness is 1mm, gross thickness 2mm.
Upper epidermis 1 comprises wear-resisting fireprotection layer 11 and nonwoven layer 12 from top to bottom successively; Lower top layer 3 comprises wear-resisting fireprotection layer 31 and nonwoven layer 32 from down to up successively.The thickness range of wear-resisting fireprotection layer is 0.3mm, and the thickness range of nonwoven layer is 0.2mm.
Wear-resisting fireprotection layer 11,31 comprises the abrasion-proof paper that the outer surface pressing of melamine decoration facial tissue has one deck to be made up of alundum (Al2O3).
Sandwich layer 2 is continuous fiber reinforced thermoplastic plastic composite, is made up of the component that comprises following weight portion: 40 parts of thermoplastics, and 60 parts of continuous fibers, wherein thermoplastic is selected from polyethylene, and continuous fiber selects glass fibre.
Above-mentioned composite plate preparation method, comprises the following steps:
(1) prepare sandwich layer
(1a) be that the thermoplastic of 40 parts joins in extruder by weight portion, extrude film by staggered two extrusion dies, by tension-adjusting gear, the continuous super high-strength glass fibre of 60 weight portions is arranged in parallel and is become band, lead two extrusion dies place, the both sides of banded continuous fiber contact with two extrusion dies respectively, flood with the molten resin of extruding at die head place, by the continuous super high-strength glass fibre after dipping, guide-in roller pressure device, roll-in, the cooling continuous fiber reinforced thermoplastic composite material sheet material that makes;
(1b) by multilayer continuous fiber reinforced thermoplastic composite material sheet material, according to the differently-oriented directivity of continuous fiber wherein by 0 °～90 ° laies, then make continuous fiber reinforced thermoplastic composite material sheet material by heat pressing forming machines hot pressing with after colding pressing, obtain sandwich layer; In sandwich layer, continuous fiber reinforced thermoplastic composite material sheet material is 3～5 layers; Wherein the temperature of hot pressing is 160 DEG C, and pressure is 1MPa, and the time is 3min; The temperature of colding pressing is 15 DEG C, and pressure is 2MPa, and the time is 5min;
(2) lay nonwoven layer (12,32) below wear-resisting fireprotection layer (11,31) or above, obtains upper epidermis 1 and lower top layer 3;
(3) according to each layer of upper epidermis 1, sandwich layer 2, lower top layer 3 order lay, pass through former hot pressing, make composite plate after cooling, in the present embodiment, the thickness of composite plate is 2mm, adopts roll-forming device roller molded, and roll-in temperature is 180 DEG C, briquetting pressure is at 10MPa, and the time is 2 seconds; .
Embodiment 2
A kind of composite plate, as shown in Figure 1, comprises upper epidermis 1, sandwich layer 2 and lower top layer 3, is followed successively by from top to bottom upper epidermis 1, sandwich layer 2, lower top layer 3, between adjacent each layer, interconnects, and He Xia top layer, upper strata is wearing composite material.
The thickness on upper and lower top layer is respectively 1.3mm, and core layer thickness is 2mm, gross thickness 4.6mm.Upper epidermis 1 comprises wear-resisting fireprotection layer 11 and nonwoven layer 12 from top to bottom successively; Lower top layer 3 comprises wear-resisting fireprotection layer 31 and nonwoven layer 32 from down to up successively.The thickness range of wear-resisting fireprotection layer is 1mm, and the thickness range of nonwoven layer is 0.3mm.
Wear-resisting fireprotection layer 11,31 comprises the abrasion-proof paper that the outer surface pressing of melamine decoration facial tissue has one deck to be made up of alundum (Al2O3).
Sandwich layer 2 is continuous fiber reinforced thermoplastic plastic composite, is made up: thermoplastic of the component that comprises following weight portion: 70 parts, and continuous fiber: 30 parts.
Thermoplastic selects PETG.
Continuous fiber selects carbon fiber.
The preparation method of above-mentioned composite plate, comprises the following steps:
(1) prepare sandwich layer
(1a) be that the thermoplastic of 70 parts joins in extruder by weight portion, extrude film by staggered two extrusion dies, by tension-adjusting gear, the continuous super high-strength glass fibre of 30 weight portions is arranged in parallel and is become band, lead two extrusion dies place, the both sides of banded continuous fiber contact with two extrusion dies respectively, flood with the molten resin of extruding at die head place, by the continuous super high-strength glass fibre after dipping, guide-in roller pressure device, roll-in, the cooling continuous fiber reinforced thermoplastic composite material sheet material that makes;
(1b) by multilayer continuous fiber reinforced thermoplastic composite material sheet material, according to the differently-oriented directivity of continuous fiber wherein by 0 °～90 ° laies, then make continuous fiber reinforced thermoplastic composite material sheet material by heat pressing forming machines hot pressing with after colding pressing, in sandwich layer 2, continuous fiber reinforced thermoplastic composite material sheet material is 3～5 layers; Wherein the temperature of hot pressing is 260 DEG C, and pressure is 5MPa, and the time is 15min; The temperature of colding pressing is 25 DEG C, and pressure is 7MPa, and the time is 20min;
(2) lay nonwoven layer 12,32 below wear-resisting fireprotection layer 11,31 or above, obtains upper epidermis 1 and lower top layer 3;
(3) according to each layer of upper epidermis 1, sandwich layer 2, lower top layer 3 order lay, pass through former hot pressing, make composite plate after cooling; In the present embodiment, the thickness of composite plate is 4.6mm, adopts compression molding device compression molding, and mold pressing temperature is 260 DEG C, and briquetting pressure is at 5MPa, and the time is 5min.
Embodiment 3
A kind of composite plate, as shown in Figure 1, comprises upper epidermis 1, sandwich layer 2 and lower top layer 3, is followed successively by from top to bottom upper epidermis 1, sandwich layer 2, lower top layer 3, between adjacent each layer, interconnects, and He Xia top layer, upper strata is wearing composite material.
The thickness on upper and lower top layer is respectively 2.4mm, and core layer thickness is 15mm, gross thickness 19.8mm.Upper epidermis 1 comprises wear-resisting fireprotection layer 11 and nonwoven layer 12 from top to bottom successively; Lower top layer 3 comprises wear-resisting fireprotection layer 31 and nonwoven layer 32 from down to up successively.The thickness range of wear-resisting fireprotection layer is 2mm, and the thickness range of nonwoven layer is 0.4mm.
Wear-resisting fireprotection layer 11,31 comprises the abrasion-proof paper that the outer surface pressing of melamine decoration facial tissue has one deck to be made up of alundum (Al2O3).
Sandwich layer 2 is continuous fiber reinforced thermoplastic plastic composite, is made up: thermoplastic of the component that comprises following weight portion: 50 parts, and continuous fiber: 50 parts.
Thermoplastic is selected from polypropylene, and continuous fiber selects glass fibre.
The preparation method of above-mentioned composite plate, comprises the following steps:
(1) prepare sandwich layer
(1a) be that the thermoplastic of 50 parts joins in extruder by weight portion, extrude film by staggered two extrusion dies, by tension-adjusting gear, the continuous super high-strength glass fibre of 50 weight portions is arranged in parallel and is become band, lead two extrusion dies place, the both sides of banded continuous fiber contact with two extrusion dies respectively, flood with the molten resin of extruding at die head place, by the continuous super high-strength glass fibre after dipping, guide-in roller pressure device, roll-in, the cooling continuous fiber reinforced thermoplastic composite material sheet material that makes;
(1b) by multilayer continuous fiber reinforced thermoplastic composite material sheet material, according to the differently-oriented directivity of continuous fiber wherein by 0 °～90 ° laies, then make continuous fiber reinforced thermoplastic composite material sheet material by heat pressing forming machines hot pressing with after colding pressing, obtain sandwich layer 2; In sandwich layer 2, continuous fiber reinforced thermoplastic composite material sheet material gross thickness is 15.5mm; Wherein the temperature of hot pressing is 190 DEG C, and pressure is 3MPa, and the time is 10min; The temperature of colding pressing is 20 DEG C, and pressure is 3MPa, and the time is 10min.
(2) lay nonwoven layer 12,32 below wear-resisting fireprotection layer 11,31 or above, obtains upper epidermis 1 and lower top layer 2;
(3) according to each layer of upper epidermis 1, sandwich layer 2, lower top layer 3 order lay, pass through former hot pressing, make composite plate after cooling; Wherein the thickness of composite plate is 20mm, adopts the compression molding of roll-forming equipment, and hot pressing temperature is 190 DEG C, and briquetting pressure is at 3MPa, and the time is 10min.
Embodiment 4
A kind of composite plate, as shown in Figure 1, comprises upper epidermis 1, sandwich layer 2 and lower top layer 3, is followed successively by from top to bottom upper epidermis 1, sandwich layer 2, lower top layer 3, between adjacent each layer, interconnects, and He Xia top layer, upper strata is wearing composite material.
The thickness on upper and lower top layer is 5mm, and core layer thickness is 30mm, gross thickness 40mm.
Upper epidermis 1 comprises wear-resisting fireprotection layer 11 and nonwoven layer 12 from top to bottom successively; Lower top layer 3 comprises wear-resisting fireprotection layer 31 and nonwoven layer 32 from down to up successively.The thickness range of wear-resisting fireprotection layer is 4.5mm, and the thickness range of nonwoven layer is 0.5mm.
Wear-resisting fireprotection layer 11,31 comprises the abrasion-proof paper that the outer surface pressing of melamine decoration facial tissue has one deck to be made up of alundum (Al2O3).
Sandwich layer 2 is continuous fiber reinforced thermoplastic plastic composite, is made up: thermoplastic of the component that comprises following weight portion: 40 parts, and continuous fiber: 60 parts, wherein thermoplastic is polyvinyl chloride, and continuous fiber is aramid fiber.
The preparation method of above-mentioned composite plate, comprises the following steps:
(1) prepare sandwich layer
(1a) be that the thermoplastic of 40 parts joins in extruder by weight portion, extrude film by staggered two extrusion dies, by tension-adjusting gear, the continuous aramid fiber of 60 weight portions is arranged in parallel and is become band, lead two extrusion dies place, the both sides of banded continuous fiber contact with two extrusion dies respectively, flood with the molten resin of extruding at die head place, by the continuous aramid fiber after dipping, guide-in roller pressure device, roll-in, the cooling continuous fiber reinforced thermoplastic composite material sheet material that makes;
(1b) by multilayer continuous fiber reinforced thermoplastic composite material sheet material, according to the differently-oriented directivity of continuous fiber wherein by 0 °～90 ° laies, then make continuous fiber reinforced thermoplastic composite material sheet material by heat pressing forming machines hot pressing with after colding pressing, in sandwich layer 2, continuous fiber reinforced thermoplastic composite material sheet material gross thickness is 32mm; Wherein the temperature of hot pressing is 200 DEG C, and pressure is 3MPa, and the time is 15min; The temperature of colding pressing is 25 DEG C, and pressure is 7MPa, and the time is 20min;
(2) lay nonwoven layer 12,32 below wear-resisting fireprotection layer 11,31 or above, obtains upper epidermis 1 and lower top layer 3;
(3) according to each layer of upper epidermis 1, sandwich layer 2, lower top layer 3 order lay, pass through former hot pressing, make composite plate after cooling; In the present embodiment, the thickness of composite plate is 40mm, adopts compression molding device compression molding, and mold pressing temperature is 220 DEG C, and briquetting pressure is at 5MPa, and the time is 20min.
Embodiment 5
A kind of composite plate, as shown in Figure 1, comprises upper epidermis 1, sandwich layer 2 and lower top layer 3, is followed successively by from top to bottom upper epidermis 1, sandwich layer 2, lower top layer 3, between adjacent each layer, interconnects, and He Xia top layer, upper strata is wearing composite material.
The thickness on upper and lower top layer is 5mm, and core layer thickness is 40mm, gross thickness 50mm.
Upper epidermis 1 comprises wear-resisting fireprotection layer 11 and nonwoven layer 12 from top to bottom successively; Lower top layer 3 comprises wear-resisting fireprotection layer 31 and nonwoven layer 32 from down to up successively.The thickness range of wear-resisting fireprotection layer is 4.5mm, and the thickness range of nonwoven layer is 0.5mm.
Wear-resisting fireprotection layer 11,31 comprises the abrasion-proof paper that the outer surface pressing of melamine decoration facial tissue has one deck to be made up of alundum (Al2O3).
Sandwich layer 2 is continuous fiber reinforced thermoplastic plastic composite, is made up: thermoplastic of the component that comprises following weight portion: 70 parts, and continuous fiber: 30 parts, wherein thermoplastic is polypropylene, and continuous fiber is glass fibre.
The preparation method of above-mentioned composite plate, comprises the following steps:
(1) prepare sandwich layer
(1a) be that the thermoplastic of 70 parts joins in extruder by weight portion, extrude film by staggered two extrusion dies, by tension-adjusting gear, the continuous glass fibre of 30 weight portions is arranged in parallel and is become band, lead two extrusion dies place, the both sides of banded continuous fiber contact with two extrusion dies respectively, flood with the molten resin of extruding at die head place, by the continuous glass fibre after dipping, guide-in roller pressure device, roll-in, the cooling continuous fiber reinforced thermoplastic composite material sheet material that makes;
(1b) by multilayer continuous fiber reinforced thermoplastic composite material sheet material, according to the differently-oriented directivity of continuous fiber wherein by 0 °～90 ° laies, then make continuous fiber reinforced thermoplastic composite material sheet material by heat pressing forming machines hot pressing with after colding pressing, in sandwich layer 2, continuous fiber reinforced thermoplastic composite material sheet thickness is 42mm; Wherein the temperature of hot pressing is 190 DEG C, and pressure is 5MPa, and the time is 15min; The temperature of colding pressing is 15 DEG C, and pressure is 5MPa, and the time is 20min;
(2) lay nonwoven layer 12,32 below wear-resisting fireprotection layer 11,31 or above, obtains upper epidermis 1 and lower top layer 3;
(3) according to each layer of upper epidermis 1, sandwich layer 2, lower top layer 3 order lay, pass through former hot pressing, make composite plate after cooling; In the present embodiment, the thickness of composite plate is 50mm, adopts compression molding device compression molding, and mold pressing temperature is 200 DEG C, and briquetting pressure is at 10MPa, and the time is 20min.
The composite plate making in embodiment 1～5 is carried out to performance test, and test result is in table 1:
Table 1
Test data from table 1 can find out, the mechanical property such as the hot strength of composite floor board prepared by the present invention, bending strength, bending modulus is better, has outstanding crocking resistance simultaneously.
Composite plate prepared by above-described embodiment is as the purposes of floor, refrigerating box or freezer sheet material.
The above-mentioned description to embodiment is can understand and apply the invention for ease of those skilled in the art.Person skilled in the art obviously can easily make various amendments to these embodiment, and General Principle described herein is applied in other embodiment and needn't passes through performing creative labour.Therefore, the invention is not restricted to the embodiment here, those skilled in the art are according to announcement of the present invention, and not departing from improvement and the amendment that category of the present invention makes all should be within protection scope of the present invention.
Claims (10)
1. a composite plate, is characterized in that: comprise successively from top to bottom upper epidermis, sandwich layer, lower top layer, described upper epidermis and/or lower top layer are wearing composite material.
2. composite plate according to claim 1, is characterized in that: the thickness on described upper or lower top layer is 0.5～5mm;
Or the thickness range of described sandwich layer is 1～40mm;
Or the total thickness of described composite plate is 2～50mm.
3. composite plate according to claim 1, it is characterized in that: described wearing composite material comprises wear-resisting fireprotection layer and nonwoven layer from outside to inside, wherein, the thickness range of wear-resisting fireprotection layer is 0.3～4.5mm, and the thickness range of nonwoven layer is 0.2～0.5mm.
4. composite plate according to claim 3, is characterized in that: described wear-resisting fireprotection layer is the abrasion-proof paper that the outer surface pressing of melamine decoration facial tissue has one deck to be made up of alundum (Al2O3).
5. composite plate according to claim 1, is characterized in that: described sandwich layer is continuous fiber reinforced thermoplastic plastic composite, is made up of the component that comprises following weight portion: 40～70 parts of thermoplastics; 30～60 parts of continuous fibers.
6. composite plate according to claim 5, is characterized in that: described thermoplastic is selected from one or more in polypropylene, polyethylene, PETG, polyamide 6, polyamide 66, polybutylene terephthalate (PBT) or polyvinyl chloride;
Or described continuous fiber is selected from one or more in glass fibre, carbon fiber, aramid fiber, superhigh molecular weight polyethylene fibers or basalt fibre.
7. a preparation method for arbitrary described composite plate in claim 1-6, is characterized in that: comprise the following steps:
(1) prepare sandwich layer
(1a) be that the thermoplastic of 40～70 parts joins in extruder by weight portion, extrude film by staggered two extrusion dies, by tension-adjusting gear, the continuous super high-strength glass fibre of 30～60 weight portions is arranged in parallel and is become band, lead two extrusion dies place, the both sides of banded continuous fiber contact with two extrusion dies respectively, flood with the molten resin of extruding at die head place, by the continuous super high-strength glass fibre after dipping, guide-in roller pressure device, roll-in, the cooling continuous fiber reinforced thermoplastic composite material sheet material making as core material;
(1b) by multilayer continuous fiber reinforced thermoplastic composite material sheet material, according to the differently-oriented directivity of continuous fiber wherein by 0 °～90 ° laies, then make continuous fiber reinforced thermoplastic composite material sheet material by heat pressing forming machines hot pressing with after colding pressing, obtain sandwich layer;
(2) below wear-resisting fireprotection layer or above lay nonwoven layer, obtain respectively upper epidermis and lower top layer;
(3) according to each layer of upper epidermis, sandwich layer, lower top layer order lay, pass through former hot pressing, make the waterproof and dampproof plate of described high abrasion after cooling.
8. preparation method according to claim 7, is characterized in that: in described step (1b), the temperature of hot pressing is 160～260 DEG C, and pressure is 1～5MPa, and the time is 3min～15min;
The temperature of colding pressing in described step (1b) is 15～25 DEG C, and pressure is 2～7MPa, and the time is 5～20min;
In described step (1b) center core layer, continuous fiber reinforced thermoplastic composite material sheet material is 3～5 layers.
9. preparation method according to claim 7, is characterized in that: former described in described step (3) is different and different according to the thickness of the waterproof and dampproof plate of high abrasion;
When the waterproof and dampproof plate thickness of high abrasion is during at 2～2.5mm, adopt roll-forming device roller molded, roll-in temperature is 180～260 DEG C, and briquetting pressure is at 1～10MPa, and the time is 2～5 seconds;
In the time that the waterproof and dampproof plate thickness of high abrasion is greater than 2.5mm and is less than or equal to 50mm, adopt compression molding device compression molding, mold pressing temperature is 180～260 DEG C, and briquetting pressure is at 1～10MPa, and the time is 5～20min.
In a claim 1-6 arbitrary described composite plate as the purposes of floor, refrigerating box or freezer sheet material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310090162.4A CN104057678B (en) | 2013-03-20 | 2013-03-20 | Waterproof and dampproof composite plate of a kind of high abrasion and its production and use |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310090162.4A CN104057678B (en) | 2013-03-20 | 2013-03-20 | Waterproof and dampproof composite plate of a kind of high abrasion and its production and use |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104057678A true CN104057678A (en) | 2014-09-24 |
| CN104057678B CN104057678B (en) | 2017-10-03 |
Family
ID=51545734
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310090162.4A Active CN104057678B (en) | 2013-03-20 | 2013-03-20 | Waterproof and dampproof composite plate of a kind of high abrasion and its production and use |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104057678B (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104963481A (en) * | 2015-08-03 | 2015-10-07 | 大亚(江苏)地板有限公司 | Anti-cracking floor heating solid wood composite floor and production method thereof |
| CN106379013A (en) * | 2016-11-01 | 2017-02-08 | 王长坤 | Glass-plastic ecological plate for decoration |
| CN106633581A (en) * | 2016-12-13 | 2017-05-10 | 安庆市吉美装饰材料有限责任公司 | Production method of fireproof composite board |
| CN107263996A (en) * | 2016-04-06 | 2017-10-20 | 江苏奇科技有限公司 | Cold Chain Logistics case interior lining panel PP decorating films surface attaching process |
| CN109677098A (en) * | 2018-12-18 | 2019-04-26 | 振石集团华美新材料有限公司 | A kind of extrusion coating paper technique for thermoplastic fiberglass reinforced plate surface |
| CN109795513A (en) * | 2017-11-17 | 2019-05-24 | 上海杰事杰新材料(集团)股份有限公司 | A kind of articulated car composite floor board and preparation method thereof |
| WO2020264492A1 (en) * | 2019-06-27 | 2020-12-30 | TekModo OZ Holdings, LLC | Composite laminate resin and fiberglass structure |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001074605A2 (en) * | 2000-04-03 | 2001-10-11 | Lg Chem Ltd. | Abrasion resistant laminate |
| CN1724255A (en) * | 2004-05-28 | 2006-01-25 | 潘诺拉姆工业国际公司 | Fiber-reinforced decorative laminate |
| CN102218828A (en) * | 2011-05-27 | 2011-10-19 | 常州市宏发纵横新材料科技股份有限公司 | Method for preparing continuous fiber multiaxial fabric reinforced thermoplastic composite material |
| CN202519970U (en) * | 2012-04-23 | 2012-11-07 | 浙江欣捷建设有限公司 | Glass fiber reinforced sandwich construction formwork |
-
2013
- 2013-03-20 CN CN201310090162.4A patent/CN104057678B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001074605A2 (en) * | 2000-04-03 | 2001-10-11 | Lg Chem Ltd. | Abrasion resistant laminate |
| CN1724255A (en) * | 2004-05-28 | 2006-01-25 | 潘诺拉姆工业国际公司 | Fiber-reinforced decorative laminate |
| CN102218828A (en) * | 2011-05-27 | 2011-10-19 | 常州市宏发纵横新材料科技股份有限公司 | Method for preparing continuous fiber multiaxial fabric reinforced thermoplastic composite material |
| CN202519970U (en) * | 2012-04-23 | 2012-11-07 | 浙江欣捷建设有限公司 | Glass fiber reinforced sandwich construction formwork |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104963481A (en) * | 2015-08-03 | 2015-10-07 | 大亚(江苏)地板有限公司 | Anti-cracking floor heating solid wood composite floor and production method thereof |
| CN104963481B (en) * | 2015-08-03 | 2019-01-29 | 大亚(江苏)地板有限公司 | Anticracking floor-heating solid-wood composite floor and its production method |
| CN107263996A (en) * | 2016-04-06 | 2017-10-20 | 江苏奇科技有限公司 | Cold Chain Logistics case interior lining panel PP decorating films surface attaching process |
| CN106379013A (en) * | 2016-11-01 | 2017-02-08 | 王长坤 | Glass-plastic ecological plate for decoration |
| CN106633581A (en) * | 2016-12-13 | 2017-05-10 | 安庆市吉美装饰材料有限责任公司 | Production method of fireproof composite board |
| CN109795513A (en) * | 2017-11-17 | 2019-05-24 | 上海杰事杰新材料(集团)股份有限公司 | A kind of articulated car composite floor board and preparation method thereof |
| CN109677098A (en) * | 2018-12-18 | 2019-04-26 | 振石集团华美新材料有限公司 | A kind of extrusion coating paper technique for thermoplastic fiberglass reinforced plate surface |
| WO2020264492A1 (en) * | 2019-06-27 | 2020-12-30 | TekModo OZ Holdings, LLC | Composite laminate resin and fiberglass structure |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104057678B (en) | 2017-10-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104057678A (en) | High wear-resistant waterproof moisture-proof composite board and preparation method and application thereof | |
| CN1960865B (en) | Thermoplastic compound plate-shaped material, method for manufacturing the same and articles manufactured using the same | |
| CN110792879B (en) | Processing technology of vacuum heat insulation plate without fear of surface damage | |
| CN101700701A (en) | Method for producing foam honeycomb core | |
| CN201024633Y (en) | Composite decoration layer abrasive-proof plastic floor | |
| CA3172885A1 (en) | Polyester laminated building boards with improved surface characteristics | |
| US20160361891A1 (en) | Waterproof board and its manufacturing method | |
| CN101649671B (en) | Fireproofing decorative gypsum board and production method thereof | |
| CN104018665A (en) | Building template material and preparing method of building template material | |
| CN104929333A (en) | Waterproof panel and manufacturing method thereof | |
| CN102328464A (en) | Honeycomb core plate of composite plate and manufacturing process thereof | |
| CN101806129A (en) | Metal-straw fireproof thermal insulating decoration board and manufacture method thereof | |
| CN201295962Y (en) | Composite fireproof board taking wood-plastic composite board as base material | |
| CN103692502B (en) | As the manufacture method of the non-woven fabrics enhancement mode laminated veneer lumber of decoration bar section base material | |
| CN207332219U (en) | A kind of plate | |
| CN106142804A (en) | A kind of production technology and equipments of CFRT reinforced plastics cellular board | |
| CN202242128U (en) | Alveolate core plate of composite plate | |
| KR101086022B1 (en) | Gypsum board packing paper and method of producing the same | |
| CN208884920U (en) | A kind of MULTILAYER COMPOSITE ecological board | |
| CN205314435U (en) | Do not have steamed fire -retardant polyethylene and mould wooden steel composite sheet | |
| CN211172877U (en) | Weight reduction structure of plastic plate | |
| CN203174786U (en) | Extruded polystyrene compound insulation fireproof plate | |
| KR100524404B1 (en) | Fiber formed stuff and the manufacturing method thereof | |
| CN209831980U (en) | Novel bamboo-wood mixed particle board | |
| CN207974288U (en) | The PVC wood plastic exterior wall of alternative lightgage steel joist separates |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| PP01 | Preservation of patent right |
Effective date of registration: 20230620 Granted publication date: 20171003 |
|
| PP01 | Preservation of patent right |