CN104057215B - Welding anti-spattering agent for galvanized steel plate and galvanized oil-coated steel plate - Google Patents

Welding anti-spattering agent for galvanized steel plate and galvanized oil-coated steel plate Download PDF

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Publication number
CN104057215B
CN104057215B CN201310225956.7A CN201310225956A CN104057215B CN 104057215 B CN104057215 B CN 104057215B CN 201310225956 A CN201310225956 A CN 201310225956A CN 104057215 B CN104057215 B CN 104057215B
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agent
weight portion
splash
antioxidant
oil
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CN201310225956.7A
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CN104057215A (en
Inventor
李大东
胡树起
娄燕
罗立
周渝
余腾义
王云祥
许哲峰
彭俊
刘辉
钟鸣
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Pangang Group Panzhihua Steel and Vanadium Co Ltd
Pangang Group Panzhihua Iron and Steel Research Institute Co Ltd
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Pangang Group Panzhihua Steel and Vanadium Co Ltd
Pangang Group Panzhihua Iron and Steel Research Institute Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/36Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
    • B23K35/362Selection of compositions of fluxes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K2101/00Articles made by soldering, welding or cutting
    • B23K2101/18Sheet panels
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K2103/00Materials to be soldered, welded or cut
    • B23K2103/02Iron or ferrous alloys
    • B23K2103/04Steel or steel alloys

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Lubricants (AREA)
  • Arc Welding In General (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)

Abstract

The invention provides a welding anti-spattering agent for a galvanized steel plate and a galvanized oil-coated steel plate formed by coating of the welding anti-spattering agent on the galvanized steel plate. The welding anti-spattering agent contains 100 parts of machine oil, 0.2-5 parts of an anti-wear agent, 0.2-2 parts of an antioxidant, 0.5-2 parts of an antirust agent and 3-15 parts of Vaseline in parts by weight. The welding anti-spattering agent can form an antirust oil layer on the galvanized steel plate, so that the galvanized oil-coated steel plate has an anti-corrosion effect and an anti-welding-spattering effect.

Description

Splash-proof welding agent for galvanized steel plain sheet and zinc-plated oiling steel plate
Technical field
The present invention relates to a kind of splash-proof welding agent for galvanized steel plain sheet, and described by being coated with galvanized steel plain sheet Splash-proof welding agent and the zinc oiling steel plate that formed.
Background technology
Galvanized steel plain sheet a large amount of production and sellings in common iron and steel metallurgical production enterprise, it is mainly used in household electrical appliances and produces. In order to reach improve corrosion proof purpose, galvanizing surface take Passivation Treatment or coating organic film, or take zinc-plated after The production technology of electrostatic spraying antirust oil.Zinc-plated oiling steel plate is mainly used in household appliances enterprise and passes through to shape and welding production micro-wave oven , during resistance salient point Welding, often welding spark splashing particle and is sticky in zinc-plated oiling surface of steel plate in cavity, Clear up difficult on resistance salient point weldering flow production line by hand, the coating quality of impact micro-wave oven work chamber internal surface.
The anti-welding spark splashing agent product that existing market is sold is a lot, and it is anti-that such as CN1644302A discloses a kind of welding Splashing agent, described preventing splash agent is made up of following raw materials according:Benzyl alcohol, titanium do, calcium nitrate, ferrovanadium aluminium, Zinc Oxide, mangaic acid iron, many Base cellulose.CN1526509A discloses a kind of Water-based rustproof splash proof adherent for metal welding, and it is by following raw materials Make:C12~185~9 parts of aliphatic acid polyethenoxy (9) ether, C3~90~18 part of alkylphenol-polyethenoxy (10) ether, C10~18Alkyl 2~20 parts of diglycollic amide, water add to 100 parts.CN102205471A discloses one kind and prevents splash agent, and it is mainly used in stainless steel Prevent splash from sticking together during composite plate welding, be made up of following raw materials according:Benzyl alcohol 40~50%, titanium do 10~15%, micron order oxygen Change calcium and magnesia mixture 15~20%, zinc oxide 5~8%, mangaic acid iron 6~8%, many bases cellulose 10~15%.
Anti- welding spark splashing agent product disclosed in above-mentioned document, is substantially all using spraying before welding or brushing in weldering Near seam, play the purpose avoiding welding spark to splash.But above-mentioned document is all not directed on galvanized steel plain sheet can be formed anti- Rust oil reservoir, is capable of the splash-proof welding agent of Anti-welding spatter again.
Content of the invention
It is an object of the invention to provide one kind can form antirust oil reservoir on galvanized steel plain sheet, so that zinc-plated oiling steel plate Not only there is etch-proof effect, also there is the splash-proof welding agent of the effect of Anti-welding spatter, and by galvanized steel plain sheet The upper zinc-plated oiling steel plate being coated with described splash-proof welding agent and being formed.
Present inventors discovered unexpectedly that, during zinc-plated oiling Plate Production, by conventional antirust oil (Main component includes machinery oil, antiwear additive, antioxidant and antirust agent)The middle vaseline adding certain content, can be effectively Solve the problems, such as that the welding spark splashing particle that conventional oil reservoir occurs is sticky in zinc-plated oiling surface of steel plate, obtain Anti-welding spatter The zinc-plated oiling steel plate of function admirable.
Thus, the present invention provides a kind of splash-proof welding agent for galvanized steel plain sheet, and wherein, described splash-proof welding agent contains There are machinery oil, antiwear additive, antioxidant, antirust agent and vaseline;And the machinery oil with respect to 100 weight portions, described antiwear additive For 0.2~5 weight portion, described antioxidant is 0.2~2 weight portion, and described antirust agent is 0.5~2 weight portion, described vaseline For 3~15 weight portions.
The present invention also provides a kind of zinc-plated oiling steel plate, and wherein, this zinc-plated oiling steel plate passes through to be coated with galvanized steel plain sheet Above-mentioned splash-proof welding agent and formed.
According to the present invention for galvanized steel plain sheet splash-proof welding agent, it has advantages below:
1)Do not change original galvanized steel plain sheet production technology, do not increase equipment.
2)Do not change corrosion resisting property and the mechanical property of zinc-plated oiling steel plate.
3)Reaching and no splashing viscous glutinous or dabbed with hand and wipe the purpose all coming off, to meet resistance salient point welding procedure quality Requirement.
Additionally, other features and advantages of the present invention will be described in detail in subsequent specific embodiment part.
Specific embodiment
Hereinafter the specific embodiment of the present invention is described in detail.It should be appreciated that it is described herein concrete Embodiment is merely to illustrate and explains the present invention, is not limited to the present invention.
Splash-proof welding agent provided by the present invention for galvanized steel plain sheet contains machinery oil, antiwear additive, antioxidant, antirust Agent and vaseline;And the machinery oil with respect to 100 weight portions, described antiwear additive is 0.2~5 weight portion, and described antioxidant is 0.2~2 weight portion, described antirust agent is 0.5~2 weight portion, and described vaseline is 3~15 weight portions.
According to the present invention, the composition content of described splash-proof welding agent within the above range when, can be effectively zinc-plated Antirust oil reservoir can be formed on steel plate, and the antirust oil reservoir of this formation not only has the function of anti-corrosion, and also can have Effect prevents spatter, thus improving quality and the yield rate of zinc-plated oiling steel plate.In order to more effectively improve Anti-welding spatter Effect, improves quality and the yield rate of zinc-plated oiling steel plate, preferably with respect to the machinery oil of 100 weight portions, described antiwear additive is 0.5~4 weight portion, described antioxidant is 0.5~1.5 weight portion, and described antirust agent is 1~2 weight portion, and described vaseline is 5~10 weight portions.
In the present invention, to described machinery oil, there is no particular limitation, can be the machinery in antirust oil commonly used in the art Lubricating oil.Described machinery oil typically refers to petroleum oil fractions through dewaxing, solvent refining and general matter obtained by clay treatment The lubricating oil of amount.This machinery oil is according to 50 DEG C of kinematic viscosity brands.Machinery oil used in the present invention is preferably in 50 DEG C of fortune Kinetic viscosity is 7~13mm2·s-1, the more preferably kinematic viscosity at 50 DEG C is 10mm2·s-1Machinery oil.As such machine The machinery oil that tool oil can be No. 10 with the trade mark known in the field, this No. 10 machinery oil known in this field is in 50 DEG C of motion Viscosity is generally in 7~13mm2·s-1In the range of.
According to the present invention, described antiwear additive is various antiwear additives commonly used in this field.Under preferable case, described antiwear additive For one or more of Type Phosphate Antiwear Additives and sulfuration three polybutene.Can be for example ability as described Type Phosphate Antiwear Additives Low corrosion phosphate LYCO-P30 well known to domain.
According to the present invention, to consider in terms of reduction steel plate oxidation rate, preferably described antioxidant is di-t-butyl Paracresol and/or fourth pentane phosphordithiic acid fat zinc salt.More preferably BHT.
According to the present invention, to consider in terms of anti-corrosion, preferably described antirust agent is petroleum sodium sulfonate and/or mahogany acid Barium.More preferably petroleum sodium sulfonate.
According to the present invention, the surface tension preventing splash agent from reduction, preventing from preventing splash agent produces foam aspect to consider, excellent Described splash-proof welding agent is selected also to contain defoamer.In the present invention, to described defoamer, there is no particular limitation, can be ability The various defoamers that domain is commonly used.But under preferable case, described defoamer is dimethicone and/or methylbenzene silicone oil;More excellent Elect dimethicone as.
Under preferable case, with respect to the machinery oil of 100 weight portions, the usage amount of described defoamer is 0.001~0.005 weight Amount part;More preferably 0.002~0.005 weight portion.
According to the present invention, by adding the above-mentioned defoamer of specified volume in described splash-proof welding agent, enable to To prevent splash agent and avoid bubbling, improve the coating performance that prevents splash agent.
According to the present invention, from reduce as far as possible the condensation point preventing splash agent, improve mobility, improve oil atomizing effect in terms of come Consider, preferably described splash-proof welding agent also contains pour-point depressant.In the present invention, to described pour-point depressant, there is no particular limitation, permissible For various pour-point depressants commonly used in this field.But under preferable case, described pour-point depressant is one of alkylnaphthalene and polyolefin etc. Or it is multiple;Alkylnaphthalene T801 that for example can be well known in the art as described alkylnaphthalene.
Under preferable case, with respect to the machinery oil of 100 weight portions, the consumption of described pour-point depressant is 0.1~1.0 weight portion; More preferably 0.4~1.0 weight portion.
According to the present invention, by adding the above-mentioned pour-point depressant of specified volume in described splash-proof welding agent, enable to To prevent splash agent there is high mobility, and oil atomizing effect is good.
According to the present invention, from order that to consider in terms of easy the absorption on surface of steel plate that prevent splash agent, preferably described welding Prevent splash agent and also contain adsorbent.In the present invention, to described adsorbent, there is no particular limitation, can be commonly used in this field Various adsorbents.But under preferable case, described adsorbent is sulfuration oleic acid and/or sulfuration haco oil;More preferably sulfuration oleic acid.
Under preferable case, with respect to the machinery oil of 100 weight portions, consumption 0.1~0.5 weight portion of described adsorbent;More It is preferably 0.2~0.5 weight portion.
According to the present invention, by adding the above-mentioned adsorbent of specified volume in described splash-proof welding agent, enable to To the effect that there is easy absorption in surface of steel plate that prevents splash agent.
According to the present invention, for the preparation method of splash-proof welding agent of the present invention, there is no particular limitation, as long as will be upper State each composition to be sufficiently mixed and be prepared into liquid.Under preferable case, after can first vaseline being melted, then enter with other compositions Row mixing.
The present invention also provides a kind of zinc-plated oiling steel plate, and this zinc-plated oiling steel plate passes through to be coated with the present invention on galvanized steel plain sheet Splash-proof welding agent and formed.
In the present invention, the not special restriction of method to above-mentioned coating, can be using various paintings commonly used in this field The method of cloth, such as spin-coating method, electrostatic spray etc..For the condition being coated with, there is no particular limitation, as long as flying anti-for welding The two-sided Weight control of coating oil film splashing agent is in 1~4g/m2?.
Hereinafter will be described the present invention by embodiment.
In following examples and comparative example, vaseline is purchased from packet header the Yellow River petrochemical industry Co., Ltd;No. 10 machinery oil purchases From Changzhou Qin Bang lubricating oil Co., Ltd, model L-AN10,50 DEG C of kinematic viscosity is 10mm2/s.
Embodiment 1-6
According to the composition in table 1 and content, each composition is mixed, during mixing, after first vaseline being melted again with other Composition is mixed, and so stirring 5 minutes, obtain splash-proof welding agent.
By in the oil groove of injection Electrostatic greasing unit, when zinc-plated coil of strip is when taking the lead to enter in Electrostatic greasing unit, start The normal oiling of Electrostatic greasing unit, two-sided painting weight of oil reaches 1g/m to setup control galvanized steel plain sheet up and down2~4g/m2(Wherein, real Applying example 1 is 1g/m2, embodiment 2 is 2g/m2, embodiment 3 is 3g/m2, embodiment 4 is 4g/m2, embodiment 5 is 2g/m2, embodiment 6 is 2g/m2), galvanized steel strip volume press after setting speed passes through electrostatic spraying room and forms mixing of even application antirust oil and vaseline Close oil film.Normally batched after Electrostatic greasing unit, obtain the zinc-plated oiling steel plate A1~A6 of anti-spatter.
Comparative example 1
Method according to embodiment 1 is carried out, and does not except for the difference that add vaseline in splash-proof welding agent, obtain coating fluid and Zinc-plated oiling steel plate B1.Additionally, the concrete composition of coating fluid and content are shown in Table 1.
Comparative example 2
Method according to embodiment 4 is carried out, and does not except for the difference that add vaseline in splash-proof welding agent, obtain coating fluid and Zinc-plated oiling steel plate B2.Additionally, the concrete composition of coating fluid and content are shown in Table 1.
Table 1
Note:()Interior numerical value represents used weight portion.
- expression does not use
Embodiment 7
The corrosion resistance of zinc-plated oiling steel plate A1~A6 and B1~B2 obtained above is checked according to GB/T10125-1997 《Artificial atmosphere corrosion test-salt spray test》Neutral salt spray test carry out.
Its concrete grammar is:Zinc-plated oiling steel plate A1~A6 and B1~B2 is respectively cut as 150mm × 75mm × 1.0mm Size after, use adhesive tape edge sealing, obtain style.Sample is put in salt spray test chamber, and test face and vertical direction be in 15 °~ 30 ° of angles.Test temperature is 35 ± 2 DEG C, and test(ing) medium is the NaCl aqueous solution of concentration 50g/L, pH value 6.5, salt fog settling amount:1 ~2ml/h.80cm2.Open within every 2 hours chamber taking-up sample to be observed, control sample corrosion situation of change.By contrast The corrosion understanding zinc-plated oiling steel plate A1~A6, considerably less than zinc-plated oiling steel plate B1~B2, illustrates zinc-plated oiling steel plate A1~A6 There is good corrosion resistance.
Embodiment 8
Welding splash-proof test is carried out to zinc-plated oiling steel plate A1~A6 and B1~B2 obtained above.
Anti- spatter test is using the serious CO of spatter2Protection weldering is tested(Carbon dioxide gas arc welding Be welding method the most serious of splashing, molten metal particles splashing amount is big, splash and stick to weldment surface, in addition with weldment table Metallurgical binding in face).Concrete process of the test:Zinc-plated oiling steel plate is placed on CO2On the welding bead side of protection weldering test plate (panel)(Level Distance about 10mm), it is observed that molten metal particles are rolled after being splashed on zinc-plated oiling steel plate A1~A6 in welding process Dynamic do not glue glutinous, and molten metal particles be splashed to zinc-plated oiling steel plate B1~B2 upper after stopping immediately being sticky in together, and postwelding Also cannot be scratched using hand and remove.
In addition, welding to zinc-plated oiling steel plate A1~A6 and B1~B2 using energy storage salient point welding machine, test anti-splashing Performance, deliberately improves the charging voltage of energy storage salient point welding machine, artificially causes the experimental condition of aggravation that splashes, and result displays that melting Metallic particles be splashed to zinc-plated oiling steel plate A1~A6 upper after do not glue glutinous, anti-spatter is respond well, and molten metal particles Be splashed to zinc-plated oiling steel plate B1~B2 upper after stop immediately being sticky in together, and postwelding also cannot be scratched using hand and remove.
By above-described embodiment and comparative example, it is coated with the zinc-plated oiling steel plate of splash-proof welding agent of the present invention not Only can have good etch-proof effect, also there is the effect of good Anti-welding spatter.
The preferred embodiment of the present invention described in detail above, but, the present invention is not limited in above-mentioned embodiment Detail, in the range of the technology design of the present invention, multiple simple variant can be carried out to technical scheme, this A little simple variant belong to protection scope of the present invention.It is further to note that described in above-mentioned specific embodiment Each particular technique feature, in the case of reconcilable, can be combined by any suitable means, in order to avoid not Necessary repetition, the present invention no longer separately illustrates to various possible combinations.
Additionally, can also be combined between the various different embodiment of the present invention, as long as it is without prejudice to this The thought of invention, it equally should be considered as content disclosed in this invention.

Claims (8)

1. a kind of splash-proof welding agent for galvanized steel plain sheet is it is characterised in that described splash-proof welding agent is by machinery oil, wear-resistant Agent, antioxidant, antirust agent and vaseline composition;And the machinery oil with respect to 100 weight portions, described antiwear additive is 0.2~5 weight Amount part, described antioxidant is 0.2~2 weight portion, and described antirust agent is 0.5~2 weight portion, and described vaseline is 3~15 weights Amount part;
Wherein, described antiwear additive is sulfuration three polybutene, and described antioxidant is BHT, and described antirust agent is stone Oily sodium sulfonate and/or barium mahogany sulfonate.
2. splash-proof welding agent according to claim 1, wherein, with respect to the machinery oil of 100 weight portions, described antiwear additive For 0.5~4 weight portion, described antioxidant is 0.5~1.5 weight portion, and described antirust agent is 1~2 weight portion, described vaseline For 5~10 weight portions.
3. splash-proof welding agent according to claim 1 and 2, wherein, described machinery oil 50 DEG C kinematic viscosity be 7~ 13mm2·s-1.
4. a kind of splash-proof welding agent for galvanized steel plain sheet is it is characterised in that described splash-proof welding agent is by machinery oil, wear-resistant Agent, antioxidant, antirust agent, defoamer and vaseline composition;And the machinery oil with respect to 100 weight portions, described antiwear additive is 0.2~5 weight portion, described antioxidant is 0.2~2 weight portion, and described antirust agent is 0.5~2 weight portion, and described vaseline is 3~15 weight portions, described defoamer is 0.001~0.005 weight portion;
Wherein, described antiwear additive is sulfuration three polybutene, and described antioxidant is BHT, and described antirust agent is stone Oily sodium sulfonate and/or barium mahogany sulfonate, described defoamer is dimethicone and/or methylbenzene silicone oil.
5. a kind of splash-proof welding agent for galvanized steel plain sheet is it is characterised in that described splash-proof welding agent is by machinery oil, wear-resistant Agent, antioxidant, antirust agent, pour-point depressant and vaseline composition;And the machinery oil with respect to 100 weight portions, described antiwear additive is 0.2~5 weight portion, described antioxidant is 0.2~2 weight portion, and described antirust agent is 0.5~2 weight portion, and described vaseline is 3~15 weight portions, described pour-point depressant is 0.1~1.0 weight portion;
Wherein, described antiwear additive is sulfuration three polybutene, and described antioxidant is BHT, and described antirust agent is stone Oily sodium sulfonate and/or barium mahogany sulfonate, described pour-point depressant is one or more of alkylnaphthalene and polyolefin.
6. a kind of splash-proof welding agent for galvanized steel plain sheet is it is characterised in that described splash-proof welding agent is by machinery oil, wear-resistant Agent, antioxidant, antirust agent, adsorbent and vaseline composition;And the machinery oil with respect to 100 weight portions, described antiwear additive is 0.2~5 weight portion, described antioxidant is 0.2~2 weight portion, and described antirust agent is 0.5~2 weight portion, and described vaseline is 3~15 weight portions, described adsorbent is 0.1~0.5 weight portion;
Wherein, described antiwear additive is sulfuration three polybutene, and described antioxidant is BHT, and described antirust agent is stone Oily sodium sulfonate and/or barium mahogany sulfonate, described adsorbent is sulfuration oleic acid and/or sulfuration haco oil.
7. a kind of splash-proof welding agent for galvanized steel plain sheet is it is characterised in that described splash-proof welding agent is by machinery oil, wear-resistant Agent, antioxidant, antirust agent, defoamer, pour-point depressant, adsorbent and vaseline composition;And the machinery with respect to 100 weight portions Oil, described antiwear additive is 0.2~5 weight portion, and described antioxidant is 0.2~2 weight portion, and described antirust agent is 0.5~2 weight Part, described vaseline be 3~15 weight portions, described defoamer be 0.001~0.005 weight portion, described pour-point depressant be 0.1~ 1.0 weight portions, described adsorbent is 0.1~0.5 weight portion;
Wherein, described antiwear additive is sulfuration three polybutene, and described antioxidant is BHT, and described antirust agent is stone Oily sodium sulfonate and/or barium mahogany sulfonate, described defoamer is dimethicone and/or methylbenzene silicone oil, and described pour-point depressant is alkane One or more of base naphthalene and polyolefin, described adsorbent is sulfuration oleic acid and/or sulfuration haco oil.
8. a kind of zinc-plated oiling steel plate is it is characterised in that this zinc-plated oiling steel plate passes through to be coated with claim on galvanized steel plain sheet Splash-proof welding agent described in any one in 1-7 and formed.
CN201310225956.7A 2013-06-07 2013-06-07 Welding anti-spattering agent for galvanized steel plate and galvanized oil-coated steel plate Active CN104057215B (en)

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CN106141501B (en) * 2016-07-25 2018-10-02 南京尚易环保科技有限公司 A kind of environmental-friendly water-base metal welding base metal protective agent and preparation method thereof
JP6471306B2 (en) * 2016-08-16 2019-02-20 株式会社弘輝 Solder composition
CN107414344A (en) * 2017-08-02 2017-12-01 合肥安力电力工程有限公司 A kind of splash-proof welding agent for alloy-steel plate and preparation method thereof
JP7154824B2 (en) * 2018-05-30 2022-10-18 ミネベアミツミ株式会社 motor

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GB1205626A (en) * 1967-11-16 1970-09-16 Lester Thomas Bowers Inhibition of spatter in metal welding operations
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CN101422852A (en) * 2007-11-01 2009-05-06 濮阳市信宇石油机械化工有限公司 CO2 protection welding-spark splattering prevention agent
CN101745749A (en) * 2008-12-19 2010-06-23 中冶焊接科技有限公司 Coating welding wire and preparation method thereof

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JPS5846399B2 (en) * 1976-12-13 1983-10-15 日栄工業株式会社 Spatter adhesion prevention agent
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Publication number Priority date Publication date Assignee Title
GB1205626A (en) * 1967-11-16 1970-09-16 Lester Thomas Bowers Inhibition of spatter in metal welding operations
CN1481964A (en) * 2003-07-29 2004-03-17 沪东中华造船(集团)有限公司 Weld anti-spatter compound
CN101422852A (en) * 2007-11-01 2009-05-06 濮阳市信宇石油机械化工有限公司 CO2 protection welding-spark splattering prevention agent
CN101745749A (en) * 2008-12-19 2010-06-23 中冶焊接科技有限公司 Coating welding wire and preparation method thereof

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