CN104054743A - Insecticidal combination containing sulfoxaflor and dinotefuran - Google Patents
Insecticidal combination containing sulfoxaflor and dinotefuran Download PDFInfo
- Publication number
- CN104054743A CN104054743A CN201410303926.8A CN201410303926A CN104054743A CN 104054743 A CN104054743 A CN 104054743A CN 201410303926 A CN201410303926 A CN 201410303926A CN 104054743 A CN104054743 A CN 104054743A
- Authority
- CN
- China
- Prior art keywords
- mti
- fluorine pyridine
- worm amine
- pyridine worm
- amine nitrile
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to an insecticidal combination containing sulfoxaflor and dinotefuran. The effective components of the insecticidal combination are the sulfoxaflor and the dinotefuran which are compounded in a binary mode. The mass ratio of the sulfoxaflor and the dinotefuran is 1-50:50-1, the mass fraction ratio of the effective components of the sulfoxaflor and the dinotefuran in the insecticidal combination is 1% to 80%, and the remaining components are auxiliary components allowed and accepted in pesticide. The dosage form of the insecticidal combination comprises missible oil, suspending agents, wettable powder, water dispersible granules, emulsion oil in water, microemulsion, granula, microcapsule formulation and water aqua. By means of the insecticidal combination containing the sulfoxaflor and the dinotefuran, high effective broad-spectrum effect is achieved, and various piercing-sucking mouthpart-pests on various crops, such as wheat, rice, cotton, vegetables, fruit trees, tobacco leaves and the like can be effectively prevented and treated.
Description
Technical field
The present invention relates to agriculture chemical compounding technical field, particularly relate to a kind of Pesticidal combination that contains fluorine pyridine worm amine nitrile and MTI-446.
Background technology
Fluorine pyridine worm amine nitrile (sulfoxaflor, chemical name: [1-6-(trifluoromethyl) pyridin-3-yl] ethyl]-λ 4-sulfydryl cyanamide CAS: 946578-00-3), sulfoximide insecticides, fluorine pyridine worm amine nitrile is applicable to prevent and treat cotton fleahopper, aphid, aleyrodid, all suckings pest such as plant hopper and coccid; Efficiently, quick and the lasting period is long, can effectively prevent and treat to nicotinoids, chrysanthemum ester class the suction juice class pest of organophosphate and carbamate pesticide generation resistance.
MTI-446 (dinotefuran, chemical name: 1-methyl-2-nitro-3-(tetrahydrochysene-3-furfuryl) guanidine, CAS:165252 – 70 – 0) is the third generation nicotinic insecticide of Mitsui chemical company exploitation.MTI-446 have tag, strong, the quick-acting height of absorption in stomach toxicity and root, the feature such as the lasting period is long, insecticidal spectrum is wide, and to mammal, birds etc. are fool proof, to crop without poisoning, be mainly used in preventing and treating aphid, leafhopper, plant hopper, thrips, aleyrodid and the resistant strain thereof in the various crop such as wheat, paddy rice, cotton, vegetables, fruit tree, tobacco leaf, coleoptera, diptera and Lepidoptera, diptera, beetle order and total wing order insect are had efficiently simultaneously, and to blattaria, have efficiently from sanitary insect pests such as ant, houseflies.
In the real process of agricultural production, using chemical agent is the most effectively means of control plant pest, but the problem the most easily producing by chemical control insect is the generation of pest resistance to insecticide.And long-term use single chemical insecticide continuously high dose, easily cause the series of problems such as residual, environmental pollution of medicament.Reasonably chemical insecticide is composite or be mixed and have expansion insecticidal spectrum, improve control efficiency, extend the optimum period for applying fertilizer, reduce dosage, reduce poisoning, reduce residual, delay pest resistance and the positive feature such as drug-fast generation and development, pesticide compositional or to be mixed be one of the effective method the most addressing the above problem.We filter out fluorine pyridine worm amine nitrile and MTI-446 composite on the basis of lab screening and field trial, have obvious synergistic effect.And about fluorine pyridine worm amine nitrile and the composite Pesticidal combination of MTI-446 and application, there is no at present people reported.
Summary of the invention
Based on above situation, the object of the invention is to provide a kind of new and effective agricultural insecticide composition, and high-efficiency broad spectrum can effectively be prevented and treated various suckings pest in the various crop such as wheat, paddy rice, cotton, vegetables, fruit tree, tobacco leaf.
Technical scheme of the present invention realizes by following measures:
A kind of Pesticidal combination that contains fluorine pyridine worm amine nitrile and MTI-446, in this Pesticidal combination, the mass ratio of active ingredient fluorine pyridine worm amine nitrile and MTI-446 is 1～50: 50～1, described Pesticidal combination of the present invention is through toxicity test experimental verification, the mass ratio of fluorine pyridine worm amine nitrile and MTI-446 is 1～10: 10～1 o'clock, synergistic effect was better.
The formulations of pesticide that described Pesticidal combination of the present invention can be prepared are missible oil, suspending agent, wetting powder, water dispersible granules, aqueous emulsion, microemulsion, granule, microcapsule formulations, aqua.Fluorine pyridine worm amine nitrile and the gross mass of MTI-446 in preparation account for 1%～80% of the whole quality of the pharmaceutical preparations, while wherein accounting for 1%～50%, and toxicity and residually reach good balance, cost is also lower.
The specific embodiments of the formulations of pesticide that Pesticidal combination of the present invention is mixed with is as follows:
Described Pesticidal combination is cream preparation, and the mass fraction of component is: 1～50 part of MTI-446; 1～50 part of fluorine pyridine worm amine nitrile; 10～30 parts of conventional emulsifiers; 20～50 parts of conventional solvents; 1～5 part of conventional synergist.The concrete production stage of this cream preparation is for first adding active ingredient MTI-446 and fluorine pyridine worm amine nitrile in solvent the oily liquids that becomes transparent and homogeneous after adding again emulsifier, synergist to stir after dissolving completely, filling, can be made into the cream preparation of the present composition.
Described Pesticidal combination is suspending agent, and the mass fraction of component is: 1～50 part of MTI-446; 1～50 part of fluorine pyridine worm amine nitrile; 5～20 parts of dispersants; 1～5 part of antifreezing agent; 0.1～2 part of thickener; 0.1～0.8 part of defoamer; 0～10 part of penetrating agent; 0.1～5 part of pH value conditioning agent; Water, surplus.The concrete production stage of this suspending agent is for first mixing other auxiliary agents, through high speed shear, mix, add active ingredient MTI-446 and fluorine pyridine worm amine nitrile, in ball crusher, abrading-ball is 2～3 hours, make a diameter all below 5mm, can be made into the suspending agent preparation of the present composition.
Described Pesticidal combination is wetting powder, and the mass fraction of component is: 1～50 part of MTI-446; 1～50 part of fluorine pyridine worm amine nitrile; 3～10 parts of dispersants; 1～5 part of wetting agent; Filler, surplus.The concrete production stage of this wetting powder is: by above-mentioned formula, active ingredient MTI-446 is mixed with fluorine pyridine worm amine nitrile and dispersant, wetting agent and filler, uniform stirring in stirred tank, after airslide disintegrating mill, mixing, can be made into the wetting powder of the present composition.
Described Pesticidal combination is water dispersible granules, and the mass fraction of component is: 1～50 part of MTI-446; 1～50 part of fluorine pyridine worm amine nitrile; 3～10 parts of dispersants; 1～10 part of wetting agent; 1～5 part of disintegrant; Filler surplus.The concrete production stage of this water dispersible granules is: by above-mentioned formula, active ingredient MTI-446 is mixed with fluorine pyridine worm amine nitrile and dispersant, wetting agent, disintegrant and filler, with micro jet, pulverize, through mediating, then add and in fluidized bed prilling dryer, carry out granulation, dry, screening by sample analysis, can be made into the water dispersible granules of the present composition.
Described Pesticidal combination is aqueous emulsion, and the mass fraction of component is: 1～50 part of MTI-446; 1～50 part of fluorine pyridine worm amine nitrile; 3～30 parts of emulsifier; 5～15 parts of solvents; 2～15 parts of stabilizing agents; 1～5 part of antifreezing agent; 0.1～8 part of defoamer; 0.2～2 part of thickener; Water, surplus.The concrete production stage of this aqueous emulsion is: first MTI-446 and fluorine pyridine worm amine nitrile, solvent and emulsifier, cosolvent are added together, make to be dissolved into uniform oil phase; By part water, antifreeze, other the insecticides adjuvant such as antimicrobial mixes into uniform water; When reactor high speed stirs, oil phase is added to water, slowly add water until reach phase inversion point, open clipper and carry out high speed shear, and add remaining water, shear about half an hour, form the aqueous emulsion of oil-in-water type, can be made into the aqueous emulsion of the present composition.
Described Pesticidal combination is microemulsion, and the mass fraction of component is: 1～50 part of MTI-446; 1～50 part of fluorine pyridine worm amine nitrile; 10～30 parts of emulsifier, 1～8 part of antifreezing agent, 0.5～10 part of stabilizing agent, 20～50 parts of conventional solvent cosolvents.MTI-446 and fluorine pyridine worm amine nitrile are dissolved completely with cosolvent, then add other compositions such as emulsifier, antifreezing agent stabilizing agent, evenly mix, finally add water, after fully stirring, can be made into microemulsion.
Described Pesticidal combination is granule, and the mass fraction of component is: 1～50 part of MTI-446; 1～50 part of fluorine pyridine worm amine nitrile; 1～10 part of wetting dispersing agent; 0.1～5 part of thickener; 0.1～5 part of defoamer; Castor oil, surplus is supplied.Each components such as active ingredient MTI-446 and fluorine pyridine worm amine nitrile, dispersant, stabilizing agent, defoamer and solvent are mixed in the ratio of formula, put into after the grinding of sand milling still, send in mixer for well-distribution and mix and get product.
Described Pesticidal combination is microcapsule formulations, and the mass fraction of component is: 1～50 part of MTI-446; 1～50 part of fluorine pyridine worm amine nitrile; 5～20 parts, urea; 5～20 parts, formaldehyde; 5～20 parts of emulsifying dispersants; 1～5 part of antifreezing agent; 0.1～2 part of thickener; 0.1～0.8 part of defoamer; Water, surplus.In being housed, the there-necked flask of agitating device adds urea and formaldehyde (amount of substance ratio is about l:1.5～2.0), left and right, pH value to 8～9 with sodium hydroxide solution regulator solution, then be warming up to 70～80 ℃, reaction obtains stable urea resin prepolymer.The former medicine of getting a certain amount of MTI-446 and fluorine pyridine worm amine nitrile is dissolved in cyclohexane, and adds emulsifying dispersant in solution, follows vigorous stirring, the O/W type stable emulsion that to be made into the aqueous solution of take containing emulsifying dispersant be water.Above-mentioned urea resin prepolymer is added in emulsion, regulate pH value, polymerization reaction take place under acid catalysis condition, is wrapped oil phase substance, forms microcapsule granule.Slowly heat up, solidify, temperature is controlled at 40～50 ℃, hardening time 1h.Selection adds appropriate auxiliary agent, the microcapsules that gets final product stablely.
Described Pesticidal combination is aqua, and the mass fraction of component is: 1～50 part of MTI-446; 1～50 part of fluorine pyridine worm amine nitrile; 0.1～30 part of wetting dispersing agent; 2～8 parts of antifreezing agents; 0.1～1 part of defoamer; 0.1～3 part of thickener; 5～15 parts of spreader-stickers; Water, surplus is supplied.By active ingredient MTI-446 and fluorine pyridine worm amine nitrile, dissolve completely with cosolvent, then add other compositions such as dispersant, antifreezing agent, defoamer, evenly mix, finally add water, after fully stirring, get final product to obtain finished product.
Wherein above-described emulsifier is selected from calcium dodecyl benzene sulfonate and aliphatic acid polyethenoxy ether, alkylphenol polyoxyethylene sulfosuccinate, styrylphenol polyoxyethylene ether, polyoxyethylene nonylphenol ether, castor oil polyoxyethylene ether, aliphatic acid polyethenoxy base ester, any or more than one any mixtures than forming in polyoxyethylene aliphatic alcohol ether.
Described solvent is dimethylbenzene or biodiesel, toluene, diesel oil, methyl alcohol, ethanol, n-butanol, isopropyl alcohol, turpentine-based vegetable oil code name is ND-45, solvent naphtha, dimethyl formamide, dimethyl sulfoxide (DMSO), one or more in water equal solvent are arbitrarily than the mixture forming.
It is LG-3, GY-D1252, GY-D1256, SNWGF-01 that described dispersant is selected from polycarboxylate code name, lignosulfonates code name is 201107,201108, alkylphenol polyoxyethylene methyl ether condensate sulfate, alkylsulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol polyoxyethylene, polyoxyethylene carboxylate, aliphatic amine polyoxyethylene ether, one or more in fatty acid glyceride APEO.
Described wetting agent is selected from lauryl sodium sulfate, calcium dodecyl benzene sulfonate, and Nekal BX, moistening bleeding agent F, alkylbenzenesulfonate polyoxyethylene triphen is phosphenylic acid salt dimly, spaonin powder, silkworm excrement, one or more in soapberry powder.
Described disintegrant is selected from bentonite, urea, ammonium sulfate, aluminium chloride, citric acid, succinic acid, one or more in sodium bicarbonate.
Described thickener is selected from xanthans, carboxymethyl cellulose, carboxyethyl cellulose, methylcellulose, Magnesiumaluminumsilicate, in polyvinyl alcohol one or more.
Described stabilizing agent is selected from sodium citrate, a kind of in resorcinol.
Described antifreezing agent is selected from ethylene glycol, propane diols, one or more in glycerine.
Described defoamer is selected from silicone oil, silicone compound, C
10-20saturated fat acid compounds, C
8-10one or more of fatty alcohol.
Described filler is selected from kaolin, diatomite, bentonite, attapulgite, white carbon, starch, one or more in precipitated calcium carbonate.
The present invention be take the compounded pesticides that active ingredient is MTI-446 and fluorine pyridine worm amine nitrile and is had obvious synergistic effect, delay the drug-fast generation in key, and reduced one-tenth and produced cost and use cost, high-efficiency broad spectrum, can effectively prevent and treat various suckings pest in the various crop such as wheat, paddy rice, cotton, vegetables, fruit tree, tobacco leaf.
Embodiment
For making technical scheme of the present invention, object and advantage are clearer, and the present invention describes with following specific embodiment, but the present invention is not limited to these examples.The mode that effect experiment of the present invention adopts indoor biometrics and field trial to combine, if no special instructions, the ratio of below mentioning is all ratio of quality and the number of copies.
Embodiment: MTI-446 proportioning co-toxicity experiments different from fluorine pyridine worm amine nitrile.
1.1 reagent agent
95% the former medicine of MTI-446,95% the former medicine of fluorine pyridine worm amine nitrile, above-mentioned former medicine provides by research and development department of extra large rel medicine company limited company.
1.2 test targets
Frankliniella occidentalis: be placed in temperature 27-29 ℃, relative moisture 50% left and right is raised and set up population with sword bean angle in the incubator of periodicity of illumination 16/8h (L/D) in raising bottle, get grow consistent 3 age nymph test.
1.3 experimental procedure
1.3.1 medicament preparation
First use the former medicine of acetone solution, according to the result of preliminary experiment, two appropriate former medicines are made into several different proportionings, then it is stand-by with acetone, each processing to be diluted to respectively to several concentration gradients.
1.3.2 chemicals treatment
Adopt leaf dipping method to measure.Preprepared wild cabbage leaf (2 ㎝ * 3 ㎝) was soaked for 10 seconds in liquid, take out nature and dry to surface without washmarking, with writing brush, choose into Frankliniella occidentalis nymph in 3 age, examination worm is moved to (28
2) ℃, in the culture dish of relative moisture 75%, normally cultivate.Every processing repeats for 4 times, 20 examination worms of every repetition.
1.4 control time
48h investigation examination worm death condition after processing (judgement examination worm death standard is that Frankliniella occidentalis and medicine leaf are poured on black paper, touches polypide with writing brush, and that can not creep is considered as death), records total borer population and dead borer population.
1.5 data statistics and analysis
According to investigation statistics, calculate the corrected mortality that each is processed.And adopt the abundant method of Sun Yun to calculate the co-toxicity coefficient (CTC value) of mixture with reference to NY/T1 154.7-2006.If contrast lethality <5%, does not proofread and correct, contrast lethality, between 5%-20%, is proofreaied and correct by formula 2, contrast lethality >20%, and test need be reformed.
The logarithm value of drug concentration (mg/L) of take is independent variable X, and the probability value of corrected mortality of take is dependent variable y, sets up respectively virulence regression equation formula, adopts DPS software to calculate the LC of single dose and each proportioning mixture
50according to the abundant method of Sun Yun, calculate co-toxicity coefficient (CTC).Co-toxicity coefficient CTC, computing formula is as follows: (take MTI-446 as standard medicament, its toxicity index is 100):
The LC of toxicity index (the TI)=MTI-446 of fluorine pyridine worm amine nitrile
50the LC of/fluorine pyridine worm amine nitrile
50* 100
The LC of true toxicity index (ATI)=MTI-446 of M
50the LC of/M
50* 100
TI * P fluorine pyridine worm amine nitrile of TI * P MTI-446+fluorine pyridine worm amine nitrile of theoretical toxicity index (TTI)=MTI-446 of M
TTI * 100 of the ATI/M of the co-toxicity coefficient of M (CTC)=M
In formula:
M is MTI-446 and the mixture of the different proportionings of fluorine pyridine worm amine nitrile
P MTI-446 is MTI-446 shared ratio in mixture
P fluorine pyridine worm amine nitrile is fluorine pyridine worm amine nitrile shared ratio in mixture.
2.1 toxicity test results
Table 1 MTI-446 and the indoor measurement result of fluorine pyridine worm amine nitrile to thrips
As can be seen from the table, by active ingredient MTI-446 and fluorine pyridine worm amine nitrile in proportion composite co-toxicity coefficient be all greater than 120, show certain synergistic effect, the synergistic effect that wherein MTI-446 and fluorine pyridine worm amine nitrile are 1:10～10:1 is the most obvious.Result of the test shows, MTI-446 and fluorine pyridine worm amine nitrile is composite that thrips is all had to higher activity under indoor conditions, and suggestion is carried out further field control effectiveness test to suitable proportion 1:10～10:1 left and right mixture preparation, to evaluate its field practical application effect.
3, the experimental result of field trial control Frankliniella occidentalis, cotton aphid
3.1 field experiment control Frankliniella occidentalis tests
3.1.1 test method
Test in Liquan capsicum ground, Xianyang, Shanxi province city, thrips is contained the phase of sending out and carries out.Use WF-16 type knapsack hand sprayer, shower nozzle is single fan nozzle, and operating pressure is 0.2-0.4Mpa, and spray amount is 0.36-0.48L/min, carries out routine spraying, makes every effort to evenly thoughtful during spray medicine.
Duration of test weather is good, and daily mean temperature is 17.8～25.4 ℃.Dispenser same day is without rain.
3.1.2 investigation method
Investigation insect population radix before dispenser,, the sampling of 5 of every communities, total the number of thrips in every some random searching plant middle and upper part l0 piece spends, same method is ld after dispenser, 5d, 10d checks the remaining borer population of living, and calculates insect population decline rate and control efficiency.
3.1.3 drug effect computational methods
Insect population decline rate (%)=(larva number after medicine prelarva number-medicine)/medicine prelarva number * 100
Preventive effect (%)=(treatment region insect population decline rate-contrast insect population decline rate)/(100-check plot insect population decline rate) * 100.
3.1.4 poisoning investigation method
Within 1,5,10 day after medicine, observe chili growth situation, range estimation medicament to capsicum without poisoning.
3.1.5 field control effectiveness test result
As can be seen from Table 2, the Mixed Pharmacy of different proportion, by different consumptions, carry out field experiment, after medicine, its control efficiency to thrips is better than contrasting medicament, with MTI-446 and the composite control of fluorine pyridine worm amine nitrile thrips instant effect, efficiency time is long, and control efficiency is good, and insecticidal effect increases progressively along with the increase of consumption.This is mixed, and can effectively control the harm of thrips to host, to the raising of quality of vegetable with increase production significantly, has stronger popularizing value.
3.2 field experiment control cotton aphid tests
3.2.1 test method
Test Zhang Wuzhuan village, the careless villages and small towns Cotton Fields in Chengwu County and carry out, soil is clay, middle fertility, the cultivation condition of each community, water and fertilizer management uniformity.Cotton variety is transgenic cotton against pests Lumianyan 15.
3.2.2 investigation method
5 samplings of experimental plot inner opposite angle line, fix 4 strains at every, and every strain is 3 of upper, middle and lower leaf fixedly, 60 leaves of fixing investigation 20 strain altogether, and 1d before medicine and after dispenser, 3d, 7d checks the remaining borer population of living, and calculates insect population decline rate and control efficiency.
3.2.3 drug effect computational methods
Insect population decline rate (%)=(larva number after medicine prelarva number-medicine)/medicine prelarva number * 100
Preventive effect (%)=(treatment region insect population decline rate-contrast insect population decline rate)/(100-check plot insect population decline rate) * 100.
3.2.4 poisoning investigation method
Within 7 days after medicine, observe cotton growth situation, range estimation medicament to cotton without poisoning.
3.2.5 field control effectiveness test result
The Mixed Pharmacy of different proportion, tests by different consumptions as can be seen from Table 3, and after medicine, it is all better than contrasting medicament to the control of aphid.The insecticidal effect of MTI-446 and fluorine pyridine worm amine nitrile increases progressively with the increase of dosage.According to field range estimation, within the scope of test dose, plant growth is normal, and the poisoning phenomenon to cotton does not all appear in each treatment agent, illustrates that it is safe to cotton.Advise that the insecticide different from the mechanism of action mixes use to delay the generation of pest resistance to insecticide.
To sum up described in indoor biometrics and twice field experiment result, of the present inventionly take MTI-446 and fluorine pyridine worm amine nitrile and carry out two yuan of composite Pesticidal combinations as active ingredient, to thrips, the insects such as aphid show good control efficiency, to target crop safety, compare with single dose, Pesticidal combination of the present invention has mechanism of action uniqueness, unit consumption is few, quick-acting is good, lasting period is long, the plurality of advantages such as effect field is more wide in range, to plant insect pest, can there is better control, so, in research and development of the present invention and promotion conference, produce very large economic worth, to vast vegetables, the protection tool of the increasing both production and income of the peasant household in fruit tree producing region and local environment is of great significance.
Claims (4)
1. a Pesticidal combination that contains fluorine pyridine worm amine nitrile and MTI-446, it is characterized in that: active ingredient fluorine pyridine worm amine nitrile and two yuan of the MTI-446 of this Pesticidal combination are composite, all the other are auxiliary element, and wherein the mass ratio of active ingredient fluorine pyridine worm amine nitrile and MTI-446 is 1～50: 50～1.
2. Pesticidal combination according to claim 1, is characterized in that: fluorine pyridine worm amine nitrile and the gross weight of MTI-446 in preparation account for 1%～80% of the whole quality of the pharmaceutical preparations.
3. Pesticidal combination according to claim 3, is characterized in that: fluorine pyridine worm amine nitrile and the gross weight of MTI-446 in preparation account for 1%～50% of the whole quality of the pharmaceutical preparations.
4. according to the Pesticidal combination described in claim 1 or 2 or 3, it is characterized in that: the formulation of this Pesticidal combination is missible oil, suspending agent, wetting powder, water dispersible granules, aqueous emulsion, microemulsion, granule, microcapsule formulations, aqua
.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410303926.8A CN104054743A (en) | 2014-06-30 | 2014-06-30 | Insecticidal combination containing sulfoxaflor and dinotefuran |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410303926.8A CN104054743A (en) | 2014-06-30 | 2014-06-30 | Insecticidal combination containing sulfoxaflor and dinotefuran |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104054743A true CN104054743A (en) | 2014-09-24 |
Family
ID=51542903
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410303926.8A Pending CN104054743A (en) | 2014-06-30 | 2014-06-30 | Insecticidal combination containing sulfoxaflor and dinotefuran |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104054743A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104304302A (en) * | 2014-09-30 | 2015-01-28 | 青岛康和食品有限公司 | Efficient pesticide containing flubendiamide, dinotefuran, sulfoxaflor and sulfur fluoride oxime ether |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102077835A (en) * | 2011-03-10 | 2011-06-01 | 陕西汤普森生物科技有限公司 | Insecticidal composition containing sulfoxaflor |
| CN102246804A (en) * | 2011-04-30 | 2011-11-23 | 江西海科瑞特作物科学有限公司 | Insecticidal composition containing sufoxaflor and neonicotine compounds |
| CN103688978A (en) * | 2013-12-13 | 2014-04-02 | 广西田园生化股份有限公司 | Ultralow-volume solution containing sulfoxaflor and nicotine pesticide |
| CN103704257A (en) * | 2013-12-30 | 2014-04-09 | 孙蒙蒙 | Insecticidal combination containing sulfoxaflor |
-
2014
- 2014-06-30 CN CN201410303926.8A patent/CN104054743A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102077835A (en) * | 2011-03-10 | 2011-06-01 | 陕西汤普森生物科技有限公司 | Insecticidal composition containing sulfoxaflor |
| CN102246804A (en) * | 2011-04-30 | 2011-11-23 | 江西海科瑞特作物科学有限公司 | Insecticidal composition containing sufoxaflor and neonicotine compounds |
| CN103688978A (en) * | 2013-12-13 | 2014-04-02 | 广西田园生化股份有限公司 | Ultralow-volume solution containing sulfoxaflor and nicotine pesticide |
| CN103704257A (en) * | 2013-12-30 | 2014-04-09 | 孙蒙蒙 | Insecticidal combination containing sulfoxaflor |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104304302A (en) * | 2014-09-30 | 2015-01-28 | 青岛康和食品有限公司 | Efficient pesticide containing flubendiamide, dinotefuran, sulfoxaflor and sulfur fluoride oxime ether |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103636661A (en) | Insecticide composition containing bifenthrin and flonicamid | |
| CN103190433A (en) | Pesticide composition with spirotetramat and dinotefuran | |
| CN104054736A (en) | Insecticidal combination containing sulfoxaflor and spirotetramat | |
| CN103271035A (en) | Insecticide composition containing flonicamid and pyriproxyfen | |
| CN102972430A (en) | Insecticidal composition containing thiamethoxam and acetamiprid | |
| CN103609573A (en) | Insecticidal composition containing spinetoram and spirotetramat | |
| CN103355324A (en) | Insecticidal composition containing fipronil and pyriproxyfen | |
| CN103168787A (en) | Insecticidal composition containing lufenuron and cyantraniliprole | |
| CN103355297A (en) | Insecticidal composition containing methoxyfenozide and flubendiamide | |
| CN103004818A (en) | Insecticide composition containing fipronil and spirotetramat | |
| CN103719139A (en) | Insecticide composition containing dinotefuran and diafenthiuron | |
| CN104054743A (en) | Insecticidal combination containing sulfoxaflor and dinotefuran | |
| CN103202311A (en) | Insecticide composition containing dinotefuran and novaluron | |
| CN103636642A (en) | Insecticide composition containing chlorantraniliprole and bistrifluron | |
| CN104488890A (en) | Nematicidal compound containing fluensulfone and fludioxonil | |
| CN103609571A (en) | Emamectin benzoate and abamectin containing pesticidal composition | |
| CN103355302A (en) | Insecticidal composition containing flubendiamide and pyriproxyfen | |
| CN104137849A (en) | Nematode killing composition containing iprodione and dinotefuran | |
| CN103190407A (en) | Insecticide composition containing methoxyfenozide and chlorfenapyr | |
| CN103503870A (en) | Mite killing composition containing cyflumetofen and chlorfenapyr | |
| CN103651473A (en) | Insecticidal combination containing metaflumizone and cyantraniliprole | |
| CN103609584A (en) | Insecticidal composition containing thiacloprid and flonicamid | |
| CN103814921A (en) | Insecticidal composition containing spirotetramat and fufenozide | |
| CN103190434A (en) | Pesticide composition with clothianidin and spirotetramat | |
| CN103598183A (en) | Insecticidal composition containing spinetoram and chlorfenapyr |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20140924 |