Background technology
Architectural pottery requires to have certain mechanical strength, and part building ceramics requires there is higher mechanical strength, to meet stressed service condition and processing request.Floor tile just requires to have higher mechanical strength, as compressive strength.The mechanical strength of floor tile depends mainly on material, structure, simultaneously relevant to its process.Ceramic material mechanical strength is less, substantially is not used for doing floor tile, and floor tile is often selected porcelain or Shi material, and with respect to ceramic material, the mechanical strength of porcelain or Shi material is high; Configuration aspects depends primarily on ceramic effect, floor tile for example, adopt fine and close stacked mode intensity just high than individual layer, and there is relation with size, for example 600 be multiplied by 600,800 and be multiplied by 800 or 1000 ceramic tiles that are multiplied by 1000 specifications, intensity is separately different, along with the raising of production technology, in the situation that meeting requirement of strength, it is large that the ceramic tile dimension that ceramic tile manufacturer produces just progressively becomes; The change of architectural pottery manufacturing condition (as maximum sintering temperature, temperature retention time, underburnt or burning etc.) is fairly obvious on the impact of floor tile mechanical strength, and therefore, intensity is also the important indicator of check current technology situation and product homogeneity.
So-called compressive strength, that is, material section is compressed (extruding) power effect and damaged maximum stress is called compressive strength, take MPa as unit representation.During test, require the parallel compression face nonparallelism of the samples such as floor tile two to be less than 0.1mm/cm, non-perpendicularity degree is less than 0.2mm/cm, and obvious crackle and other defect are forbidden to have in surface, and the compressive strength of ceramic tile can record with omnipotent material section testing machine.
Certainly, when the mechanical strength of general ceramic material is discussed, often will thoroughly discuss the chemical bond of material molecule, as covalency key or ion key material have larger hardness and intensity, and molecule key mechanical strength is often less.Using fracture strength (modulus of rupture) and as the mechanical strength of building ceramic tiles, detect index, regulation: Imitation Rock Porcelain Tiles fracture strength is not less than 35MPa in GB GB/T4100.1-2006; Shi porcelain Ceramic Tiles modulus of rupture average is not less than 30MPa; Thin Shi matter brick modulus of rupture average is not less than 22MPa; Shi matter brick modulus of rupture average is not less than 18MPa; The modulus of rupture average of pottery brick is not less than 15MPa.
In the ceramic tile of a kind of natural cavity stone imitation occurring at present, by special material and processing technology, can form and be similar to the hole stone texture structure that natural cavity stone is the same, can be used for substituting natural cavity stone as constructional materials.
In natural travertine stone-imitated tile, can be divided into two kinds, a kind of have a true hole, ceramic tile deliberately generates hole in process of production, for example adopt some to be heated and produce gas material as a part for fabric, the material generation gas that is heated when firing, thus gas distributes the hole on surface from fabric.This natural travertine stone-imitated tile and natural cavity stone are more approaching.Another natural travertine stone-imitated tile, on the basis of the first, use transparency material to fill the hole producing, thereby form a kind of hole that appears to have, but touch up the ceramic tile that there is no hole sensation, the benefit of this ceramic tile is, can be used as ground tile paving, and because hole is filled, can not shelter evil people and countenance evil practices, convenient for cleaning, the while has retained again the natural aesthetic feeling of hole stone.
At present upper market has above-mentioned two kinds of ceramic tiles selling, but in actual use, natural travertine stone-imitated tile is in building, especially the use aspect floor tile, a lot of places not as people's will have been there are, for example compressive strength a little less than, in internal construction due to natural travertine stone-imitated tile, there is hole, no matter whether this hole fills, it is uneven that the existence of hole makes ceramic tile on three-dimensional thickness, because the distribution of hole is random, therefore the existence of hole is also random to the stress influence of monoblock ceramic tile, the intensity of each piece ceramic tile of producing is also random, usually easily there is the ceramic tile insufficient strength of producing, cannot be for building central or transporting, in use procedure, there is the situation of fracture.
The specific embodiment
Below in conjunction with the accompanying drawing in the embodiment of the present invention, technical scheme in the embodiment of the present invention is clearly and completely described, example of the present invention is shown in the drawings, although describe the present invention in connection with these embodiment, should be appreciated that it does not really want to limit the invention to these embodiment.On the contrary, this invention is intended to cover replacement, modification and the equivalents can be included in the spirit and scope that claims limit.In addition, in to the following detailed description of the embodiment of the present invention, a lot of details have been proposed so that the present invention is thoroughly understood.Yet, persons of ordinary skill in the art will recognize that and not have these details also can implement the present invention.In other example, for fuzzy aspect of the present invention unnecessarily, do not describe known method, process, parts in detail.
The some parts of below describing in detail is according to module, parts, structure etc. and to representing to propose with other symbol in Structure Design Software.These descriptions and expression be that technician that pottery is manufactured uses, for the essence of its work being conveyed to most effectively to other technician's of this field means.Verified, be mainly the reason for public use, it is easily sometimes that these structures or component are called to layer, piece, element, area, density etc.
Yet, should keep firmly in mind, all these should be associated with suitable physical quantity with similar term and be only the marks that facilitates that is applicable to this tittle.Unless specialized, otherwise as described below, institute is apparent, should understand in whole the present invention, term used is discussed, as " association " or " process " or " stack " or " needs " or " determining " or " repetition " or " execution " or " detection " or " guiding " etc., refer to action and the process of ceramic structure or ceramic manufacturing equipment.
Fig. 1 has shown natural cavity stone imitation ceramic tile longitudinal cross-section structure chart.
In Fig. 1, show natural cavity stone imitation ceramic tile 100 longitudinal cross-sections, described longitudinal cross-section shows initial bed 110, and is layered in the precoat 120 on initial bed 110, there are at least two kinds of structures in described precoat, is respectively transparent porcelain portion 122 and opaque porcelain portion 121.Porcelain portion mainly becomes as Inorganic Non-metallic Materials, when being greater than 95%, the components by weight percent of Inorganic Non-metallic Materials just can be referred to as porcelain portion, in general preparation process, in porcelain portion, the components by weight percent of Inorganic Non-metallic Materials is greater than 99%, or in porcelain portion, be all Inorganic Non-metallic Materials, it should be noted that, natural cavity stone imitation ceramic tile in reality, the distributed random of the porcelain portion 122 of printing opacity in precoat 120, and shape, not of uniform size, be similar to the aesthetic appearance of natural cavity stone.
The needed raw material of preparation of initial bed is comparatively general, can just can prepare with reference to prior art processes.
The raw material of the preparation of lighttight porcelain portion is also comparatively general, in most disclosed technology, also realized the formula of preparing printing opacity porcelain portion now, for example a kind of comparatively general formula is: albite 50~70%, burn talcum: 10~14%, brium carbonate: 6~10%, zinc oxide: 0~3%, calcite: 6~8%, boric acid: 6~12%, and can comprise a small amount of other components that do not affect transparent effect, in printing opacity porcelain portion, the weight of each component adds up to 100%, can obtain by conventional burning process.
The natural cavity stone imitation ceramic tile that the invention process exemplifies can adopt existing production technology to prepare.
Fig. 2 has shown natural cavity stone imitation ceramic tile plane schematic top plan view.
In Fig. 2, show natural cavity stone imitation ceramic tile 100 planes and overlook form, what in the embodiment of the present invention, show is foursquare natural cavity stone imitation ceramic tile, but according to actual conditions, natural cavity stone imitation ceramic tile can also be the regular shapes such as rectangle.
There is geometric adjacent edge mid point line 130 in the square natural cavity stone imitation ceramic tile that the embodiment of the present invention shows, and geometrical center point 131.
Fig. 3 has shown common natural cavity stone imitation ceramic tile hole distribution schematic diagram.
In Fig. 3, show common square natural cavity stone imitation ceramic tile 100 hole distributions, described square natural cavity stone imitation ceramic tile is of a size of size conventional in building, such as 600CM*600CM, 800CM*800CM, 1000CM*1000CM etc., in Fig. 3, schematically mark geometric two the adjacent edge mid point lines 130 of this square natural cavity stone imitation ceramic tile 100, and the geometrical center point 131 certainly existing, in this figure, not marking, particular location can be with reference to shown in figure 2.It needs to be noted, the adjacent edge mid point line 130 of described sign is set as the long tape region that width is 1CM, and it is the center of circle that geometrical center point 131 is set as take described geometrical center point, the border circular areas that the 1CM of take is radius.
In Fig. 3, also schematically mark transparent porcelain portion 122 and opaque porcelain portion 121, shown in transparent porcelain portion 122 shapes, not of uniform size, and on described square natural cavity stone imitation ceramic tile 100 random distribution, form the aesthetic appearance be similar to natural cavity stone.In Fig. 3, the transparent formed hole of porcelain portion 122 is in the one side random distribution at the artificial ceramic tile of described square 100 precoat places, comprise that being distributed in two sets in the determined long tape regional extent of adjacent edge mid point line 130 that width is 1CM, and be likely distributed in described geometrical center point for the center of circle, the border circular areas that the 1CM of take is radius.
According to research, find, for for example square, the regular geometric figure natural cavity stone imitation ceramic tile of rectangle etc., because the distribution of hole is random, therefore the bright formed hole distribution of porcelain portion 122 is set in the determined long tape regional extent of adjacent edge mid point line 130 that width is 1CM at two, thereby make the stress local distribution of described natural cavity stone imitation ceramic tile uneven, especially in described long tape regional extent, the threshold that can meet with stresses is than obviously reducing outside described long tape regional extent, in local or whole pressurized, because meeting with stresses in long tape regional extent reaches Hooke effect threshold, cause deformation to surpass the whole deformation values of described natural cavity stone imitation ceramic tile, last described natural cavity stone imitation ceramic tile part or the irreversible breakage of whole generation, make the intensity of described natural cavity stone imitation ceramic tile lower than the intensity of general polished glazed tile, manufacturing, cannot effective guarantee ceramic tile in transportation and use procedure and even the quality of building.
Fig. 4 has shown natural cavity stone imitation ceramic tile hole distribution schematic diagram in one embodiment of the invention.
By the analysis of causes that existing conventional natural cavity stone imitation ceramic tile is easily ruptured, in conjunction with Hooke effect, set up natural cavity stone imitation ceramic tile stress distribution model, calculating is each point upper stress and stressing conditions on natural cavity stone imitation ceramic tile precoat, draw the hole preferred distribution of natural cavity stone imitation ceramic tile, can effectively alleviate the impact of hole on natural cavity stone imitation ceramic tile intensity.
In Fig. 4, show natural cavity stone imitation ceramic tile hole distribution in one embodiment of the invention.The hole of described natural cavity stone imitation ceramic tile is obviously little compared with the density beyond region two distributions of setting in the determined long tape cross-point region of adjacent edge mid point line 130 that width is 1CM.
According to stress distribution model, calculate and learn, article two, setting the determined long tape overlay area of adjacent edge mid point line 130 and the described geometrical center point that width is 1CM is the center of circle, the border circular areas that the 1CM of take is radius, it is the concentrated region of stress distribution, if by reducing the density of this region hole, can obviously improve the intensity in described region.
Therefore, design in desirable stress distribution model, set in the determined long tape of adjacent edge mid point line 130 region that width are 1CM and described geometrical center point is the center of circle for described two, the determined long tape region of adjacent edge mid point line 130 and described geometrical center point that the area that has hole in the border circular areas that the 1CM of take is radius is 1CM divided by described two setting width are the center of circle, the gross area of the border circular areas that the 1CM of take is radius, draw the density that has hole on adjacent edge mid point line, be labeled as ρ
mid point line; The gross area by the hole area existing on monoblock natural cavity stone imitation ceramic tile precoat divided by monoblock natural cavity stone imitation ceramic tile precoat, draws ceramic tile ensemble average hole density, is labeled as ρ
on average.
Therefore,, according to stress distribution model, on the adjacent edge mid point line of described natural cavity stone imitation ceramic tile, there is the density p of hole
mid point linebe less than described ceramic tile ensemble average hole density p
on averagetime, just can improve the intensity of natural cavity stone imitation ceramic tile.
Preferably, described ρ
mid point linebe less than described ρ
on average/ 2.
Preferably, described ρ
mid point linebe less than described ρ
on average/ 3.
Preferably, described ρ
mid point linebe less than described ρ
on average/ 4.
Preferably, natural cavity stone imitation ceramic tile geometrical center point place is without hole.
Preferably, described ρ
mid point line=0, and, on natural cavity stone imitation ceramic tile adjacent edge mid point line, there is not hole.
In order to verify described hole stress distribution model, and described ρ
mid point line, described ρ
on averagethe corresponding relation of proportionate relationship and natural cavity stone imitation ceramic tile intensity, by requiring the test of actual production natural cavity stone imitation ceramic tile design test to test above-mentioned according to above-mentioned parameter, and does test comparison with general natural cavity stone imitation ceramic tile.
In order to express easily, to above-mentioned, according to above-mentioned parameter, require actual production natural cavity stone imitation ceramic tile with sample A, sample B, sample C, sample D, sample E and sample F, to indicate respectively, comparative example indicates with G.Described sample all requires to manufacture according to embodiment design parameter:
The ρ of sample A
on averagetool is 75.66%, the ρ of sample A
mid point linebe 67.29%;
The ρ of sample B
on averagetool is 76.01%, the ρ of sample B
mid point linebe 34.89%;
The ρ of sample C
on averagetool is 76.48%, the ρ of sample C
mid point linebe 22.97%;
The ρ of sample D
on averagetool is 75.87%, the ρ of sample D
mid point linebe 11.35%;
The ρ of sample E
on averagetool is 75.99%, the ρ of sample E
mid point linebe 33.47%, and natural cavity stone imitation ceramic tile geometrical center point place is without hole;
The ρ of sample F
on averagetool is 72.08%, the ρ of sample F
mid point linebe 0%;
Comparative example G is the natural cavity stone imitation ceramic tile of common production, and parameter is as follows:
The ρ of comparative example G
on averagetool is 76.46%, the ρ of sample G
mid point linebe 79.52%.
Every kind of sample is 6, in order to coordinate omnipotent material section testing machine test material size, according to three of standard ceramic tile kinds of size 600CM*600CM, 800CM*800CM, 1000CM*1000CM Scalings, be 600MM*600MM, 800MM*800MM, tri-kinds of sizes of 1000MM*1000MM, each 2 of every kind of sizes, prepare according to normal process and pattern.
Sample is all processed and is polished through surface finish, and fineness reaches 4, and all samples corner N/D, surperficial flawless, and dimensional tolerance meets afore mentioned rules, and the parallel compression face nonparallelism of sample two is less than 0.1MM/CM, and non-perpendicularity is less than 0.2MM/CM.
Testing equipment is full sized brick Special universal material section testing machine, adjustable 600MM*600MM, 800MM*800MM, 1000MM*1000MM third gear full sized brick test size.
Strength calculation formula is:
Intensity (MPa)=rupture load (KN)/sample precoat area (MM
2).
Table 1 sample A table with test results
The average strength of sample A is: 30.16MPa.
Table 2 sample B table with test results
The average strength of sample B is: 31.7MPa.
Table 3 sample C table with test results
The average strength of sample C is: 32.15MPa.
Table 4 sample D table with test results
The average strength of sample D is: 34.75MPa.
Table 5 sample E table with test results
The average strength of sample E is: 33.03MPa.
Table 6 sample F table with test results
The average strength of sample F is: 38.62MPa.
Table 7 comparative sample G table with test results
The average strength of comparative sample G is: 27.7MPa.
Table 8 test result summary sheet
According to testing experiment, possessing the embodiment of the present invention requires the sample A of parameter to F, to test the average strength of obtaining, with the average strength of common natural cavity stone imitation ceramic tile comparative sample G, shown to exist the density p of hole on the adjacent edge mid point line of described natural cavity stone imitation ceramic tile and graphics set central point
mid point linebe less than described ceramic tile ensemble average hole density p
on averagetime, just can improve the intensity of natural cavity stone imitation ceramic tile.And along with there being the density p of hole on the adjacent edge mid point line of described natural cavity stone imitation ceramic tile and graphics set central point
mid point linemore level off to 0, described intensity level is higher, and sample F and comparative sample G comparison, exceeded 10.92MPa, and on the adjacent edge mid point line of described natural cavity stone imitation ceramic tile, has the density p of hole
in point linein close situation, if described natural cavity stone imitation ceramic tile geometrical center point place is without hole, more than improving natural cavity stone imitation ceramic tile intensity 1MPa.
Know-why of the present invention has below been described in conjunction with specific embodiments.These are described is in order to explain principle of the present invention, and can not be interpreted as by any way limiting the scope of the invention.Explanation based on herein, those skilled in the art does not need to pay performing creative labour can associate other specific embodiment of the present invention, within these modes all will fall into protection scope of the present invention.