CN104046192A - Self-polishing antifouling paint and manufacturing method thereof - Google Patents
Self-polishing antifouling paint and manufacturing method thereof Download PDFInfo
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- CN104046192A CN104046192A CN201410305970.2A CN201410305970A CN104046192A CN 104046192 A CN104046192 A CN 104046192A CN 201410305970 A CN201410305970 A CN 201410305970A CN 104046192 A CN104046192 A CN 104046192A
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- parts
- antifouling paint
- self
- polyethyleneglycol
- self polishing
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Abstract
The invention provides a self-polishing antifouling paint which is prepared from the following raw materials in parts by weight: 228-250 parts of methyl methacrylate, 16-20 parts of polyethyleneglycol diacrylate, 132-140 parts of tributyltin acrylate, 24-28 parts of polyethyleneglycol, 190-210 parts of cuprous oxide, 120-150 parts of zinc oxide, 110-125 parts of titanium white and 150-180 parts of xylene. The manufacturing method comprises the following steps: heating to copolymerize the methyl methacrylate, polyethyleneglycol diacrylate, tributyltin acrylate and polyethyleneglycol, dissolving the obtained copolymer in the xylene, adding the other powders, grinding and screening to obtain the self-polishing antifouling paint. When the paint is applied to the ship bottom, the obtained coated film has favorable self-polishing performance in water.
Description
Technical field
The present invention relates to the making method of coating, be specifically related to a kind of self polishing copolymer antifouling paint.
Background technology
In ship coating, easily the microorganism of periphtic algae in water, causes hull rough, affects route speed.
Summary of the invention
The object of this invention is to provide a kind of self polishing copolymer antifouling paint, solve one or more problem of the prior art.
According to an aspect of the present invention, a kind of self polishing copolymer antifouling paint is provided, comprise the raw material of following parts by weight: 228～250 parts of methyl methacrylates, 16～20 parts of polyethyleneglycol diacrylates, 132～140 parts of tributyl tin acrylic acid esters, 24～28 parts of polyoxyethylene glycol, 190～210 parts, Red copper oxide, 120～150 parts, zinc oxide, 110～125 parts of titanium dioxides, 150～180 parts of dimethylbenzene.
According to another aspect of the present invention, the making method of a kind of self polishing copolymer antifouling paint provided by the invention, first by methyl methacrylate, polyethyleneglycol diacrylate, tributyl tin acrylic acid ester and polyoxyethylene glycol heating copolymerization, obtaining multipolymer is dissolved in dimethylbenzene, add other powders, grinding sieves obtains a kind of self polishing copolymer antifouling paint again.
The present invention is coated on to hull bottom, and gained film is good from polishability in water.
Embodiment
Embodiment 1:
The invention provides a kind of self polishing copolymer antifouling paint, comprise following raw material: methyl methacrylate 228kg, polyethyleneglycol diacrylate 16kg, tributyl tin acrylic acid ester 132kg, polyoxyethylene glycol 24kg, Red copper oxide 190kg, zinc oxide 120kg, titanium dioxide 110kg, dimethylbenzene 150kg.
A kind of self polishing copolymer antifouling paint provided by the invention, first by methyl methacrylate, polyethyleneglycol diacrylate, tributyl tin acrylic acid ester and polyoxyethylene glycol heating copolymerization, obtain multipolymer and be dissolved in dimethylbenzene, then add other powders, grinding sieves obtains a kind of self polishing copolymer antifouling paint.The present invention is coated on to hull bottom, and gained film is good from polishability in water.
Embodiment 2:
The invention provides a kind of self polishing copolymer antifouling paint, comprise following raw material: methyl methacrylate 250kg, polyethyleneglycol diacrylate 20kg, tributyl tin acrylic acid ester 140kg, polyoxyethylene glycol 28kg, Red copper oxide 210kg, zinc oxide 150kg, titanium dioxide 125kg, dimethylbenzene 180kg.
A kind of self polishing copolymer antifouling paint provided by the invention, first by methyl methacrylate, polyethyleneglycol diacrylate, tributyl tin acrylic acid ester and polyoxyethylene glycol heating copolymerization, obtain multipolymer and be dissolved in dimethylbenzene, then add other powders, grinding sieves obtains a kind of self polishing copolymer antifouling paint.The present invention is coated on to hull bottom, and gained film is good from polishability in water.
Embodiment 3:
The invention provides a kind of self polishing copolymer antifouling paint, comprise following raw material: methyl methacrylate 240kg, polyethyleneglycol diacrylate 18kg, tributyl tin acrylic acid ester 136kg, polyoxyethylene glycol 26kg, Red copper oxide 200kg, zinc oxide 135kg, titanium dioxide 120kg, dimethylbenzene 165kg.
A kind of self polishing copolymer antifouling paint provided by the invention, first by methyl methacrylate, polyethyleneglycol diacrylate, tributyl tin acrylic acid ester and polyoxyethylene glycol heating copolymerization, obtain multipolymer and be dissolved in dimethylbenzene, then add other powders, grinding sieves obtains a kind of self polishing copolymer antifouling paint.The present invention is coated on to hull bottom, and gained film is good from polishability in water.
More than statement is only optimal way of the present invention, it should be pointed out that to those skilled in the art, without departing from the concept of the premise of the invention, can also make some distortion and improvement, within these also should be considered as protection scope of the present invention.
Claims (2)
1. a self polishing copolymer antifouling paint, it is characterized in that, comprise the raw material of following parts by weight: 228～250 parts of methyl methacrylates, 16～20 parts of polyethyleneglycol diacrylates, 132～140 parts of tributyl tin acrylic acid esters, 24～28 parts of polyoxyethylene glycol, 190～210 parts, Red copper oxide, 120～150 parts, zinc oxide, 110～125 parts of titanium dioxides, 150～180 parts of dimethylbenzene.
2. a kind of manufacture method of self polishing copolymer antifouling paint described in claim 1, it is characterized in that, first by methyl methacrylate, polyethyleneglycol diacrylate, tributyl tin acrylic acid ester and polyoxyethylene glycol heating copolymerization, obtaining multipolymer is dissolved in dimethylbenzene, add other powders, grinding sieves obtains self polishing copolymer antifouling paint again.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410305970.2A CN104046192A (en) | 2014-06-30 | 2014-06-30 | Self-polishing antifouling paint and manufacturing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410305970.2A CN104046192A (en) | 2014-06-30 | 2014-06-30 | Self-polishing antifouling paint and manufacturing method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104046192A true CN104046192A (en) | 2014-09-17 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410305970.2A Pending CN104046192A (en) | 2014-06-30 | 2014-06-30 | Self-polishing antifouling paint and manufacturing method thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN104046192A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104610826A (en) * | 2015-01-16 | 2015-05-13 | 中国船舶重工集团公司第七二五研究所 | Hydrolytic self-polishing antifouling zinc acrylate paint and preparation method thereof |
| CN106987191A (en) * | 2017-04-13 | 2017-07-28 | 江苏大使同丰涂料有限公司 | A kind of nontoxic ship bottom antifouling paint of self-grind type and preparation method thereof |
| CN107459856A (en) * | 2017-10-09 | 2017-12-12 | 江苏海晟涂料有限公司 | A kind of ship self polishing copolymer antifouling paint and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4407997A (en) * | 1980-10-29 | 1983-10-04 | The International Paint Company Limited | Marine paint |
| US5919840A (en) * | 1996-08-22 | 1999-07-06 | Elf Atochem, S.A. | (Meth) acrylic resin compositions for marine antifouling paints and corresponding paint compositions |
| CN102732122A (en) * | 2012-07-24 | 2012-10-17 | 中国科学院理化技术研究所 | Long-acting self-polishing antifouling paint and preparation method thereof |
| CN103131289A (en) * | 2013-02-28 | 2013-06-05 | 海洋化工研究院有限公司 | Preparation and application of self-polishing antifouling coating matrix resin |
-
2014
- 2014-06-30 CN CN201410305970.2A patent/CN104046192A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4407997A (en) * | 1980-10-29 | 1983-10-04 | The International Paint Company Limited | Marine paint |
| US5919840A (en) * | 1996-08-22 | 1999-07-06 | Elf Atochem, S.A. | (Meth) acrylic resin compositions for marine antifouling paints and corresponding paint compositions |
| CN102732122A (en) * | 2012-07-24 | 2012-10-17 | 中国科学院理化技术研究所 | Long-acting self-polishing antifouling paint and preparation method thereof |
| CN103131289A (en) * | 2013-02-28 | 2013-06-05 | 海洋化工研究院有限公司 | Preparation and application of self-polishing antifouling coating matrix resin |
Non-Patent Citations (1)
| Title |
|---|
| 化学工业出版社: "《精细化工产品大全（上卷）》", 31 January 2005, 化学工业出版社 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104610826A (en) * | 2015-01-16 | 2015-05-13 | 中国船舶重工集团公司第七二五研究所 | Hydrolytic self-polishing antifouling zinc acrylate paint and preparation method thereof |
| CN104610826B (en) * | 2015-01-16 | 2017-06-20 | 中国船舶重工集团公司第七二五研究所 | A kind of hydrolysis-type zinc acrylate resin self polishing copolymer antifouling paint and preparation method thereof |
| CN106987191A (en) * | 2017-04-13 | 2017-07-28 | 江苏大使同丰涂料有限公司 | A kind of nontoxic ship bottom antifouling paint of self-grind type and preparation method thereof |
| CN107459856A (en) * | 2017-10-09 | 2017-12-12 | 江苏海晟涂料有限公司 | A kind of ship self polishing copolymer antifouling paint and preparation method thereof |
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| PB01 | Publication | ||
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| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20140917 |