CN104045987A - Formula and production process of glass fiber-reinforced plastic composite material - Google Patents

Formula and production process of glass fiber-reinforced plastic composite material Download PDF

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Publication number
CN104045987A
CN104045987A CN201410308076.0A CN201410308076A CN104045987A CN 104045987 A CN104045987 A CN 104045987A CN 201410308076 A CN201410308076 A CN 201410308076A CN 104045987 A CN104045987 A CN 104045987A
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China
Prior art keywords
glass fiber
composite material
production process
felt
formula
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Pending
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CN201410308076.0A
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Chinese (zh)
Inventor
储斌
周顺福
陈勇
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Anhui Hang Da Environmental Protection Technology Co Ltd
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Anhui Hang Da Environmental Protection Technology Co Ltd
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Priority to CN201410308076.0A priority Critical patent/CN104045987A/en
Publication of CN104045987A publication Critical patent/CN104045987A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a formula and production process of a glass fiber-reinforced plastic composite material. The production process comprises the following steps: a) impregnating: firstly mixing 10-20% of calcium carbonate and 10-20% of unsaturated polyester resin to obtain resin glue solution, placing the resin glue solution in a material trough, then feeding 65-75% of glass fiber yarns and/or glass fiber felt into the material trough from a creel in a manner that each fiber corresponds to one hole, thus ensuring adequate impregnation, wherein the lateral strength is improved by adoption of thick felt and one-way felt process; 2) preforming: guiding the impregnated fiberglass yarn and/or glass fiber felt into a preforming area by a performing guide mold and preforming; 3) carrying out heating curing, wherein full wrapped three-stage electric heating is carried out in a heat curing zone; and 4) drawing and cooling. According to the formula and the production process of the glass fiber-reinforced plastic composite material, by a reasonable formula system and the production process, the degree of cure of the resin system is increased to improve the strength of the product and thus a series of requirements of a cooling tower structural frame, such as requirement on the strength, are met.

Description

Glass fiber reinforced plastics composite material formula and production technique thereof
Technical field
The present invention relates to matrix material and processing work Technology field, particularly a kind of glass fiber reinforced plastics composite material formula and production technique thereof.
Background technology
In the prior art, the structural framing of cooling tower mostly adopts wood, steel construction, and its drawback is that weight is large, perishable, difficult processing, the wasting of resources.
Such as adopting hand, former cooling tower water trough floor sticks with paste technique, its process is: the resin compound that first brushing contains solidifying agent on mould, the fabric that paving one deck is cut out on request thereon again, by brush, pressure roller or scraper produce press fabrics, a direction is caught up with bubble only from centre to both sides, make woven fiber glass laminating closely, then brushing resin compound and paving second layer fabric, said process is until reach desired thickness repeatedly.Glass reinforced plastic hand is stuck with paste the shortcoming of technique: production efficiency is low, speed is slow, the production cycle is long, not too applicable for large in batches product; Quality product is stable not.Because the impact event constant product quality of operator's level of skill difference and production environment condition is poor; Production environment is poor, and smell is large, adds man-hour dust many.
Summary of the invention
The object of this invention is to provide a kind of high performance glass fiber reinforced plastics composite material formula and production technique thereof, to meet a series of requirements such as intensity of cooling tower structure framework.
For achieving the above object, the invention provides a kind of glass fiber reinforced plastics composite material formula, comprise by weight percentage glass fiber yarn and/or glass mat 65-75%, water-ground limestone 10-20%, unsaturated polyester resin 10-20%.
Wherein preferably comprise by weight percentage glass fiber yarn and/or glass mat 70%, water-ground limestone 15%, unsaturated polyester resin 15%.
Glass fiber reinforced plastics composite material formula of the present invention, has increased the proportion that glass fibre strengthens system, has improved product strength.
The present invention also provides a kind of glass fiber reinforced plastics composite material production technique, comprises the following steps:
1) dipping: first the water-ground limestone of 10-20% and 10-20% unsaturated polyester resin are mixed into resin adhesive liquid, and resin adhesive liquid is placed in hopper, then 65-75% glass fiber yarn and/or glass mat are entered to hopper by one hole of creel, guarantee fully to soak into, and adopt thick felt and unidirectional felt technique, improve transverse strength;
2) premolding: the glass fiber yarn after dipping and/or glass mat import mould by premolding and import pre-forming area, carry out premolding;
3) be heating and curing: behind pre-forming area, enter heated cure zone, heated cure zone adopts the electrically heated of full parcel syllogic, and first section of temperature is 100-120 ℃, and two sections of temperature are 120-150 ℃, three sections of temperature are 160-180 ℃, and whole process set time is 1.5-2.0min;
4) draw cooling: from solidifying heating zone, draw out by towing mechanism, centre arranges cooling section, and pulling speed is according to section bar size, shape adjustments, normal velocity range 30-60CM/min.
As a further improvement on the present invention, premolding imports mould and at section bar corner place, adopts outside small arc-shaped, inner great circle arc transition.Hollow square tube and channel steel type timber die are reasonable in design, the outside small arc-shaped that adopts at section bar corner place, and inner great circle arc transition, increases corner's thickness, improves product weak part intensity.
Premolding imports the reasonable in design, practical of mould, accurately leads, and can reject material unnecessary on glass.The electrically heated temperature of heated cure zone syllogic, can adjust according to envrionment temperature.Pulling speed, according to section bar size, shape adjustments, makes products solidifying abundant.
The present invention's glass fiber reinforced plastics composite material production technique also, have that production efficiency is high, technique is easy to the advantages such as control, constant product quality, also have that high-level efficiency, power consumption are low, the little feature of contaminative, by the dipping of resin adhesive liquid, bonding and moulding process, finally formed the section bar with certain textural property.
Glass fiber reinforced plastics composite material of the present invention is for the production of the structural framing of cooling tower, adopt unsaturated polyester resin and other subsidiary material as curing system, use glass fiber yarn and/or glass mat as strongthener, production high-performance compounded linear material, by rational formula system and production technique, improve the degree of cure of resin system to improve the intensity of product, thereby meet a series of requirements such as intensity of cooling tower structure framework.
Accompanying drawing explanation
Fig. 1 is that premolding of the present invention imports mould at the structural representation at section bar corner place.
Embodiment
Describe the preferred technical solution of the present invention below in detail.
Glass fiber reinforced plastics composite material formula of the present invention, comprises glass fiber yarn and/or glass mat 65-75% by weight percentage, water-ground limestone 10-20%, unsaturated polyester resin 10-20%.
Wherein preferably comprise by weight percentage glass fiber yarn and/or glass mat 70%, water-ground limestone 15%, unsaturated polyester resin 15%.
Glass fiber reinforced plastics composite material formula of the present invention, has increased the proportion that glass fibre strengthens system, has improved product strength.
The present invention also provides a kind of glass fiber reinforced plastics composite material production technique, comprises the following steps:
1) dipping: first the water-ground limestone of 10-20% and 10-20% unsaturated polyester resin are mixed into resin adhesive liquid, and resin adhesive liquid is placed in hopper, then 65-75% glass fiber yarn and/or glass mat are entered to hopper by one hole of creel, guarantee fully to soak into, and adopt thick felt and unidirectional felt technique, improve transverse strength;
2) premolding: the glass fiber yarn after dipping and/or glass mat import mould by premolding and import pre-forming area, carry out premolding;
3) be heating and curing: behind pre-forming area, enter heated cure zone, heated cure zone adopts the electrically heated of full parcel syllogic, and first section of temperature is 100-120 ℃, and two sections of temperature are 120-150 ℃, three sections of temperature are 160-180 ℃, and whole process set time is 1.5-2.0min;
4) draw cooling: from solidifying heating zone, draw out by towing mechanism, centre arranges cooling section, and pulling speed is according to section bar size, shape adjustments, normal velocity range 30-60CM/min.
Wherein, premolding imports mould and at section bar corner place, adopts outside small arc-shaped, inner great circle arc transition.Hollow square tube and channel steel type timber die are reasonable in design, the outside small arc-shaped that adopts at section bar corner place, and inner great circle arc transition, increases corner's thickness, improves product weak part intensity.
Premolding imports the reasonable in design, practical of mould, accurately leads, and can reject material unnecessary on glass.The electrically heated temperature of heated cure zone syllogic, can adjust according to envrionment temperature.Pulling speed, according to section bar size, shape adjustments, makes products solidifying abundant.
The present invention's glass fiber reinforced plastics composite material production technique also, have that production efficiency is high, technique is easy to the advantages such as control, constant product quality, also have that high-level efficiency, power consumption are low, the little feature of contaminative, by the dipping of resin adhesive liquid, bonding and moulding process, finally formed the section bar with certain textural property.
Glass fiber reinforced plastics composite material of the present invention is for the production of the structural framing of cooling tower, adopt unsaturated polyester resin and other subsidiary material as curing system, use glass fiber yarn and/or glass mat as strongthener, production high-performance compounded linear material, by rational formula system and production technique, improve the degree of cure of resin system to improve the intensity of product, thereby meet a series of requirements such as intensity of cooling tower structure framework.

Claims (4)

1. a glass fiber reinforced plastics composite material formula, is characterized in that: comprise by weight percentage glass fiber yarn and/or glass mat 65-75%, water-ground limestone 10-20%, unsaturated polyester resin 10-20%.
2. glass fiber reinforced plastics composite material formula as claimed in claim 1, is characterized in that: comprise by weight percentage glass fiber yarn and/or glass mat 70%, water-ground limestone 15%, unsaturated polyester resin 15%.
3. a glass fiber reinforced plastics composite material production technique, is characterized in that comprising the following steps:
1) dipping: first the water-ground limestone of 10-20% and 10-20% unsaturated polyester resin are mixed into resin adhesive liquid, and resin adhesive liquid is placed in hopper, then 65-75% glass fiber yarn and/or glass mat are entered to hopper by one hole of creel, guarantee fully to soak into, and adopt thick felt and unidirectional felt technique, improve transverse strength;
2) premolding: the glass fiber yarn after dipping and/or glass mat import mould by premolding and import pre-forming area, carry out premolding;
3) be heating and curing: behind pre-forming area, enter heated cure zone, heated cure zone adopts the electrically heated of full parcel syllogic, and first section of temperature is 100-120 ℃, and two sections of temperature are 120-150 ℃, three sections of temperature are 160-180 ℃, and whole process set time is 1.5-2.0min;
4) draw cooling: from solidifying heating zone, draw out by towing mechanism, centre arranges cooling section, and pulling speed is according to section bar size, shape adjustments, normal velocity range 30-60CM/min.
4. glass fiber reinforced plastics composite material production technique as claimed in claim 1, is characterized in that: premolding imports mould and at section bar corner place, adopts outside small arc-shaped, inner great circle arc transition.
CN201410308076.0A 2014-07-01 2014-07-01 Formula and production process of glass fiber-reinforced plastic composite material Pending CN104045987A (en)

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CN201410308076.0A CN104045987A (en) 2014-07-01 2014-07-01 Formula and production process of glass fiber-reinforced plastic composite material

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Application Number Priority Date Filing Date Title
CN201410308076.0A CN104045987A (en) 2014-07-01 2014-07-01 Formula and production process of glass fiber-reinforced plastic composite material

Publications (1)

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CN104045987A true CN104045987A (en) 2014-09-17

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104387735A (en) * 2014-10-20 2015-03-04 南通时瑞塑胶制品有限公司 GRP open-web plate, as well as pultrusion method and application thereof
CN104760299A (en) * 2015-03-17 2015-07-08 哈尔滨工程大学 Fiber-felt-reinforced composite material solar energy assembly frame and preparation method thereof
CN104973678A (en) * 2015-06-27 2015-10-14 宁波淳源环保科技有限公司 Biofilm carrier support for sewage processing device
CN105885456A (en) * 2016-04-01 2016-08-24 安徽冠廷科技有限公司 Production technology of glass fiber composite channel steel
CN108325751A (en) * 2017-12-29 2018-07-27 浙江德创环保科技股份有限公司 A kind of wet electrical dust precipitator FRP Wall and preparation method thereof
CN112677514A (en) * 2020-12-24 2021-04-20 安徽航达环保科技有限公司 Preparation method of glass fiber reinforced plastic water collector

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1338636A (en) * 2000-08-16 2002-03-06 袁忠宝 Moulded glass steel case of kilowatt-hour meter and its making method
CN1358622A (en) * 2001-12-23 2002-07-17 张国志 Method for making multi-cavity hollow profile glass fibre reinforced plastic material
CN1394734A (en) * 2002-07-29 2003-02-05 中国葵星橡胶(深圳)有限公司 Production method of glass fibre reinforced plastic product and its equipment
CN101871219A (en) * 2010-05-27 2010-10-27 北京泛亚电通工贸有限责任公司 High-strength polyester composite well cover as well as formula and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1338636A (en) * 2000-08-16 2002-03-06 袁忠宝 Moulded glass steel case of kilowatt-hour meter and its making method
CN1358622A (en) * 2001-12-23 2002-07-17 张国志 Method for making multi-cavity hollow profile glass fibre reinforced plastic material
CN1394734A (en) * 2002-07-29 2003-02-05 中国葵星橡胶(深圳)有限公司 Production method of glass fibre reinforced plastic product and its equipment
CN101871219A (en) * 2010-05-27 2010-10-27 北京泛亚电通工贸有限责任公司 High-strength polyester composite well cover as well as formula and preparation method thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104387735A (en) * 2014-10-20 2015-03-04 南通时瑞塑胶制品有限公司 GRP open-web plate, as well as pultrusion method and application thereof
CN104760299A (en) * 2015-03-17 2015-07-08 哈尔滨工程大学 Fiber-felt-reinforced composite material solar energy assembly frame and preparation method thereof
CN104973678A (en) * 2015-06-27 2015-10-14 宁波淳源环保科技有限公司 Biofilm carrier support for sewage processing device
CN105885456A (en) * 2016-04-01 2016-08-24 安徽冠廷科技有限公司 Production technology of glass fiber composite channel steel
CN108325751A (en) * 2017-12-29 2018-07-27 浙江德创环保科技股份有限公司 A kind of wet electrical dust precipitator FRP Wall and preparation method thereof
CN112677514A (en) * 2020-12-24 2021-04-20 安徽航达环保科技有限公司 Preparation method of glass fiber reinforced plastic water collector

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Application publication date: 20140917