CN104043413A - Modified adsorbing material for phenol wastewater - Google Patents
Modified adsorbing material for phenol wastewater Download PDFInfo
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- CN104043413A CN104043413A CN201410292190.9A CN201410292190A CN104043413A CN 104043413 A CN104043413 A CN 104043413A CN 201410292190 A CN201410292190 A CN 201410292190A CN 104043413 A CN104043413 A CN 104043413A
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Abstract
The invention discloses a modified adsorbing material for phenol wastewater. The modified adsorbing material is characterized by comprising the following substances in parts by weight: 6-14 parts of acrylate, 5-9 parts of initiator, 14-26 parts of ethanol, 9-10 parts of ammonia water, 1-2 parts of gallic acid, 25-30 parts of lauryl methacrylate, 12-16 parts of methyl methacrylate, 14-19 parts of fibrous aquatic stone, 6-10 parts of compound adhesive, 25-31 parts of carpesium abrotanoides straw powder, 1-2 parts of maleic anhydride grafted polypropylene, 6-9 parts of polyethylene glycol terephthalate and 9-15 parts of calcium sulfate. The modified adsorbing material has the beneficial effects that the problem of poor biocompatibility of simple resin adsorbents is solved by preparing a porous spongy composite material by taking fiber base materials as carriers to bear polymer materials, and microorganisms can be loaded on the composite material to complete degradation of phenol.
Description
Technical field
The present invention relates to a kind of industrial wastewater sorbing material that is rich in phenol.
Background technology
Waste water containing phenol is common high toxicity, organic wastewater with difficult degradation thereby, be mainly derived from the production processes such as petroleum refining, Coal Chemical Industry, dyestuff, papermaking, agricultural chemicals, medicine, have discharge capacity large, pollute wide, endanger the features such as serious, its toxicity not only can hinder hydrobiological growth and reproduction, and meeting harm humans health, early oneself is classified as among the lists of 129 kinds of preferential monitoring pollutants by American National Environmental Protection Agency phenolic compound.Emphasis in the water pollution control of phenolic waste water Ye Shi China.For many years, various processing methods are applied in the processing procedure of phenolic waste water.Wherein, absorption method is the most frequently used in laboratory or industrial production and the higher processing method of efficiency, but the adsorptive selectivity of this physical treatment method is poor, and processing cost is higher, is also easy to cause secondary pollution simultaneously; Biological degradation method is a kind of practicality, economic, eco-friendly treatment technology, but it has a fatal weakness, holds load impact that can't stand high concentration phenol, can not directly be used for processing the phenolic waste water of high concentration.
In in the past twenties years, many researchers are own through having spent great effort to study different microorganism Pyrogentisinic Acids' degraded, and biological degradation method is also own through quite ripe in the degradation technique of phenol.But in traditional biodegradation technique, the carrier material itself that major part plays fixation to microorganism only plays a supporting medium, Pyrogentisinic Acid own does not have suction-operated.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of industrial wastewater sorbing material that is rich in phenol.
For solving the problems of the technologies described above, the technical solution used in the present invention is:
A kind of phenolic waste water modified absorbing material, is characterized in that, comprises the material of following parts by weight: acrylate 6-14 part, initator 5-9 part, ethanol 14-26 part, ammoniacal liquor 9-10 part, gallic acid 1-2 part, lauryl methacrylate 25-30 part, methyl methacrylate 12-16 part, fiber Shui nationality stone 14-19 part, composite adhesive 6-10 part, turnip stalk powder 25-31 part, maleic anhydride inoculated polypropylene 1-2 part, PETG 6-9 part, calcium sulfate 9-15 part.
The invention has the beneficial effects as follows: taking fiber-like base material as carrier, carrying Polymer materialspreparation obtains the spongy composite of porous, improved the poor problem of simple resinae adsorbing agent biological compatibility, can be on composite loading microorganisms complete the degraded of phenol; Extend service life, not only reduced use cost, and avoided secondary pollution; Expand the scope of application of biological degradation method.
Detailed description of the invention
Embodiment 1
A kind of phenolic waste water modified absorbing material, is characterized in that, comprises the material of following parts by weight: acrylate 6-14 part, initator 5-9 part, ethanol 14-26 part, ammoniacal liquor 9-10 part, gallic acid 1-2 part, lauryl methacrylate 25-30 part, methyl methacrylate 12-16 part, fiber Shui nationality stone 14-19 part, composite adhesive 6-10 part, turnip stalk powder 25-31 part, maleic anhydride inoculated polypropylene 1-2 part, PETG 6-9 part, calcium sulfate 9-15 part.
Claims (1)
1. a phenolic waste water modified absorbing material, is characterized in that, comprises the material of following parts by weight: acrylate 6-14 part, initator 5-9 part, ethanol 14-26 part, ammoniacal liquor 9-10 part, gallic acid 1-2 part, lauryl methacrylate 25-30 part, methyl methacrylate 12-16 part, fiber Shui nationality stone 14-19 part, composite adhesive 6-10 part, turnip stalk powder 25-31 part, maleic anhydride inoculated polypropylene 1-2 part, PETG 6-9 part, calcium sulfate 9-15 part.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410292190.9A CN104043413A (en) | 2014-06-26 | 2014-06-26 | Modified adsorbing material for phenol wastewater |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410292190.9A CN104043413A (en) | 2014-06-26 | 2014-06-26 | Modified adsorbing material for phenol wastewater |
Publications (1)
| Publication Number | Publication Date |
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| CN104043413A true CN104043413A (en) | 2014-09-17 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
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| CN201410292190.9A Withdrawn CN104043413A (en) | 2014-06-26 | 2014-06-26 | Modified adsorbing material for phenol wastewater |
Country Status (1)
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| CN (1) | CN104043413A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104445448A (en) * | 2014-10-30 | 2015-03-25 | 青岛昌安达药业有限公司 | Wastewater treatment agent used in chemical engineering companies |
| CN106238017A (en) * | 2016-09-24 | 2016-12-21 | 北京益净环保设备科技有限公司 | Feature board for absorbing multiring aromatic hydrocarbon and preparation method thereof |
| CN106268697A (en) * | 2016-09-24 | 2017-01-04 | 北京益净环保设备科技有限公司 | Granule adsorbent for Adsorption of Pyridine and preparation method thereof |
| CN106268698A (en) * | 2016-09-24 | 2017-01-04 | 北京益净环保设备科技有限公司 | Feature board for Adsorption of Pyridine and preparation method thereof |
| CN106311181A (en) * | 2016-09-24 | 2017-01-11 | 北京益净环保设备科技有限公司 | Particle adsorption agent for polycyclic aromatic hydrocarbon adsorption and preparation method thereof |
-
2014
- 2014-06-26 CN CN201410292190.9A patent/CN104043413A/en not_active Withdrawn
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104445448A (en) * | 2014-10-30 | 2015-03-25 | 青岛昌安达药业有限公司 | Wastewater treatment agent used in chemical engineering companies |
| CN106238017A (en) * | 2016-09-24 | 2016-12-21 | 北京益净环保设备科技有限公司 | Feature board for absorbing multiring aromatic hydrocarbon and preparation method thereof |
| CN106268697A (en) * | 2016-09-24 | 2017-01-04 | 北京益净环保设备科技有限公司 | Granule adsorbent for Adsorption of Pyridine and preparation method thereof |
| CN106268698A (en) * | 2016-09-24 | 2017-01-04 | 北京益净环保设备科技有限公司 | Feature board for Adsorption of Pyridine and preparation method thereof |
| CN106311181A (en) * | 2016-09-24 | 2017-01-11 | 北京益净环保设备科技有限公司 | Particle adsorption agent for polycyclic aromatic hydrocarbon adsorption and preparation method thereof |
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Legal Events
| Date | Code | Title | Description |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C04 | Withdrawal of patent application after publication (patent law 2001) | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20140917 |