CN104040070B - The steel cord of full elastomer penetration - Google Patents

The steel cord of full elastomer penetration Download PDF

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Publication number
CN104040070B
CN104040070B CN201280066317.4A CN201280066317A CN104040070B CN 104040070 B CN104040070 B CN 104040070B CN 201280066317 A CN201280066317 A CN 201280066317A CN 104040070 B CN104040070 B CN 104040070B
Authority
CN
China
Prior art keywords
steel
steel wire
steel cord
cord
group
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201280066317.4A
Other languages
Chinese (zh)
Other versions
CN104040070A (en
Inventor
张钦霞
刘兴
朱宏桢
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bekaert NV SA
Original Assignee
Bekaert NV SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bekaert NV SA filed Critical Bekaert NV SA
Priority to CN201280066317.4A priority Critical patent/CN104040070B/en
Priority claimed from PCT/EP2012/075247 external-priority patent/WO2013107570A1/en
Publication of CN104040070A publication Critical patent/CN104040070A/en
Application granted granted Critical
Publication of CN104040070B publication Critical patent/CN104040070B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • DTEXTILES; PAPER
    • D07ROPES; CABLES OTHER THAN ELECTRIC
    • D07BROPES OR CABLES IN GENERAL
    • D07B1/00Constructional features of ropes or cables
    • D07B1/06Ropes or cables built-up from metal wires, e.g. of section wires around a hemp core
    • D07B1/0606Reinforcing cords for rubber or plastic articles
    • D07B1/0646Reinforcing cords for rubber or plastic articles comprising longitudinally preformed wires
    • DTEXTILES; PAPER
    • D07ROPES; CABLES OTHER THAN ELECTRIC
    • D07BROPES OR CABLES IN GENERAL
    • D07B1/00Constructional features of ropes or cables
    • D07B1/06Ropes or cables built-up from metal wires, e.g. of section wires around a hemp core
    • D07B1/0606Reinforcing cords for rubber or plastic articles
    • D07B1/062Reinforcing cords for rubber or plastic articles the reinforcing cords being characterised by the strand configuration
    • D07B1/0626Reinforcing cords for rubber or plastic articles the reinforcing cords being characterised by the strand configuration the reinforcing cords consisting of three core wires or filaments and at least one layer of outer wires or filaments, i.e. a 3+N configuration
    • DTEXTILES; PAPER
    • D07ROPES; CABLES OTHER THAN ELECTRIC
    • D07BROPES OR CABLES IN GENERAL
    • D07B2201/00Ropes or cables
    • D07B2201/20Rope or cable components
    • D07B2201/2047Cores
    • D07B2201/2052Cores characterised by their structure
    • D07B2201/2059Cores characterised by their structure comprising wires
    • D07B2201/206Cores characterised by their structure comprising wires arranged parallel to the axis
    • DTEXTILES; PAPER
    • D07ROPES; CABLES OTHER THAN ELECTRIC
    • D07BROPES OR CABLES IN GENERAL
    • D07B2401/00Aspects related to the problem to be solved or advantage
    • D07B2401/20Aspects related to the problem to be solved or advantage related to ropes or cables
    • D07B2401/2005Elongation or elasticity
    • D07B2401/201Elongation or elasticity regarding structural elongation

Landscapes

  • Ropes Or Cables (AREA)
  • Tires In General (AREA)

Abstract

A kind of steel cord (10) being suitable to strengthen elastomer, it includes first group and second group, twist spirally around first group with the cord lay pitch for second group, first group of first steel wire (12) including the first quantity, first quantity is in the range of between 3 and 8, second group of second steel wire (14) including the second quantity, second quantity is more than or equal to described first quantity, the lay pitch of the first steel wire (12) is more than 300mm, and the first steel wire (12) and the second steel wire (14) all carry out preforming.The steel cord PLE when 50N tensile stress is between 0.08% to 0.25%.Described steel cord has significantly deformation to realize full elastomer penetration, but also keeps processing characteristics and the function strengthened for elastomer.

Description

The steel cord of full elastomer penetration
Technical field
The present invention relates to a kind of steel cord being suitable to strengthen elastomer, elastomer for example, rubber passes Send band, pneumatic tire, rubber hose, rubber synchronous belt and polyurethane synchronous belt.This steel curtain Line has Open architecture to allow full rubber osmosis.
Background technology
Steel cord with twisted steel filaments is well known in the art, particularly at rubber reinforcement In field, more particularly in pneumatic tire enhancing field.
A major requirement to steel cord is that the complete of elastomer (such as rubber) permeates.This meaning Taste rubber and have to be can penetrate between the element of steel cord and fill all possible sky Gap, to reduce the abrasion between element and stress, avoids dampness to move along steel cord simultaneously, should Dampness can cause corroding in a large number and can significantly reduce the life-span of steel cord and rubber.
In order to realize full rubber osmosis, prior art provides and makes steel wire deformation and construct open The solution of steel cord.WO95/16816A1 discloses in the case of not having additional energy Make the technology that steel wire deforms with becoming polygon.WO99/28547A1 discloses and makes steel wire at two The technology of curling in plane.WO02/088459A1 discloses and includes first group and the steel of second group Cord.Twist spirally around first group with the cord lay pitch for this second group.This first group includes First steel wire of one quantity.First quantity is in the range of between 3 to 8.Second group includes second Second steel wire of quantity.Second quantity is more than or equal to the first quantity.The lay pitch of the first steel wire is big In 300mm.At least one in second steel wire is into polygon ground preforming, to allow rubber Glue penetration.
Although prior art provides several side prepared open steel cord and allow rubber osmosis Method, but steel cord carries out the deformation of much degree and remains unknown with regard to obtaining full rubber osmosis 's.
Summary of the invention
The primary goal of the present invention is to provide to have and significantly deforms with the steel curtain realizing full rubber osmosis Line.
The second target of the present invention is to provide for not weakening the steel cord for elastomer enhancing The steel cord of the full rubber osmosis of energy in the case of processing characteristics and function.
According to the first aspect of the invention, it is desirable to a kind of product of protection, i.e. steel cord includes first Organizing and second group, twist spirally around first group with the cord lay pitch for second group, first group includes First steel wire of the first quantity, the first quantity is in the range of between 3 to 8, and second group includes Second steel wire of two quantity, the second quantity is more than or equal to the first quantity, the lay pitch of the first steel wire More than 300mm, the first steel wire and all preforming of the second steel wire.Steel cord is in 50N stretching PLE during power is between 0.08% to 0.25%.It is highly preferred that steel cord stretches at 50N PLE during tension force is between 0.10% to 0.18%.Second steel wire is when 50N tensile stress PLE be between 0.9% to 2.0%, between more preferably 1.0% to 1.2%, and first The steel wire PLE when 50N tensile stress is between 0.4% to 1.0%, more preferably Between 0.65% to 0.75%.First quantity is 4, and the second quantity is 6.First steel wire preformation Type is three-dimensional waveform, and this solid waveform preferred has the first curling and the second curling, simultaneously The plane at the first curling place differs with the plane of the second curling.Second steel wire is that polygon is pre- Molding.
Accompanying drawing explanation
Fig. 1 describes first preferred embodiment of the present invention.
Fig. 2 shows that the tensile stress of the steel cord for having different PLE and percentage elongation are bent Line.
Detailed description of the invention
Fig. 1 shows the steel cord combining the present invention, and wherein, steel cord 10 includes first group of steel Silk 12 and second group of steel wire 14.Second group with length of lay for steel cord around first group spirally Twisting.First group includes 4 first steel wires 12, and second group includes 6 second steel wires 14. The lay pitch of the first steel wire 12 is more than 300mm.First steel wire 12 and second steel wire 14 all preformations Type.Therefore, between steel wire, there is space.
In order to realize full rubber osmosis, the steel cord PLE when 50N tensile stress is 0.08% Between 0.25%.It is highly preferred that the PLE that steel cord is when 50N tensile stress is 0.10% Between 0.18%.In the manufacture process of tire, in calendering operation, steel cord is in 8N To the effect of the tensile stress of 12N, wherein, in calendering operation, steel cord is incorporated into rubber In gum base body.In order to ensure being constantly present the space for rubber osmosis between steel wire, steel curtain The line PLE when 50N tensile stress is not lower than 0.08%, because the lowest PLE meaning In calendering operation opening between steel wire under the tensile stress effect of 8N to 12N can close Close.On the one hand, although bigger steel cord PLE can bring more preferable rubber permeability, but The upper limit of steel cord PLE is about 0.25%.Steel cord strengthens thing as tension and is embedded in In pneumatic tire, and the steel cord that PLE is more than 0.25% means the most open steel cord, This first can be the most loose and cause trouble in the structure of steel cord due to steel cord;Secondly can be at wheel Causing trouble in the manufacture process of tire, such as casing ply is coarse or spacing is uneven, and this will cause The inhomogeneities of tire and the dynamic balancing of destruction tire;3rd, it is impossible in tire, produce foot Enough intensity, because big PLE means the biggest percentage elongation, and in phase The steel cord under conditions of Tong with big PLE can not produce and have the steel cord one of little PLE The intensity of sample.Therefore, the PLE of steel cord should be between 0.08% to 0.25%, more preferably Ground is between 0.10% to 0.18%.
Based on similar reasoning, in order to obtain preferable steel cord PLE, deposit for steel wire At upper and lower bound.Second steel wire PLE when 50N tensile stress should be 0.9% to 2.0% Between, between more preferably 1.0% to 1.2%, and the first steel wire is when 50N tensile stress PLE be between 0.4% to 1.0%, between more preferably 0.65% to 0.75%.Compare For, the PLE of the second steel wire needs bigger than the first steel wire, to form sky between the second steel wire Gap, thus realize full rubber osmosis.
The contrast test carrying out 4+6 × 0.30mm steel cord demonstrates above reasoning equally.
Fig. 2 shows that the tensile stress of the steel cord for having different PLE and percentage elongation are bent Line, wherein, line 22 represents the steel cord that PLE is 0.08%, and it is 0.14% that line 24 represents PLE Steel cord, line 26 represents the steel cord that PLE is 0.25%.These three lines have identical Slope, because three steel cords have identical elastic modelling quantity;And structural elongation is different, because of Open difference for steel cord.Therefore, line 22,24 and 26 are parallel to each other and stagger.? In the case of identical percentage elongation E, line 22 can produce the power of F2, and line 24 can produce F4 Power, line 26 can produce the power of F6.Therefore, the PLE steel cord more than 0.25% can not produce It is sufficiently used for the power of enhancing by polymer.
In order to compensate the decline from F2 to F4 power caused due to the increase of PLE, permissible Use high-tensile steel wires or super high-tensile steel wires, even special high-tensile steel wires. In above-mentioned contrast test, use tensile strength higher than 3800-2000 × d (steel wire diameter (mm)) high-tensile steel wires of MPa is up to the steel curtain of 175GPa to obtain elastic modelling quantity Line.
Being three-dimensional waveform by the first preshaping of wire, more preferably this solid waveform has first Curling and the second curling, the plane at the first curling place is different from the plane of the second curling simultaneously. Owing to the first steel wire is positioned at the inside of steel cord, and do not twist or with the sth. made by twisting more than 300mm Away from twisting, therefore the three-dimensional waveform on the first steel wire guarantees to be constantly present sky between the first steel wire Gap is to realize full rubber osmosis.

Claims (11)

1. a steel cord (10), it includes first group and second group, described second group with The cord lay pitch is twisted spirally around described first group, and described first group includes the of the first quantity One steel wire (12), described first quantity is in the range of between 3 to 8, and described second group includes Second steel wire (14) of the second quantity, described second quantity is more than or equal to described first quantity, The lay pitch of described first steel wire (12) is more than 300mm, described first steel wire (12) and institute State the second steel wire (14) and all carry out preforming, it is characterised in that described steel cord (10) exists PLE during 50N tensile stress is between 0.08% to 0.25%.
Steel cord the most according to claim 1, wherein, described steel cord (10) exists PLE during 50N tensile stress is between 0.10% to 0.18%.
Steel cord the most according to claim 1, wherein, described second steel wire (14) PLE when 50N tensile stress is between 0.9% to 2.0%.
Steel cord the most according to claim 3, wherein, described second steel wire (14) PLE when 50N tensile stress is between 1.0% to 1.2%.
Steel cord the most according to claim 1, wherein, described first steel wire (12) PLE when 50N tensile stress is between 0.4% to 1.0%.
Steel cord the most according to claim 5, wherein, described first steel wire (12) PLE when 50N tensile stress is between 0.65% to 0.75%.
Steel cord the most according to claim 1, wherein said first quantity is 4.
Steel cord the most according to claim 7, wherein said second quantity is 6.
Steel cord the most according to claim 1, wherein, described first steel wire (12) It is pre-formed as three-dimensional waveform.
Steel cord the most according to claim 9, wherein, described three-dimensional waveform has the One curling and the second curling, this first curling is positioned at the plane that the plane with the second curling differs In.
11. steel cords according to claim 1, wherein, described second steel wire (14) In polygon preforming.
CN201280066317.4A 2012-01-18 2012-12-12 The steel cord of full elastomer penetration Expired - Fee Related CN104040070B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201280066317.4A CN104040070B (en) 2012-01-18 2012-12-12 The steel cord of full elastomer penetration

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
CN2012070520 2012-01-18
CNPCT/CN2012/070520 2012-01-18
CN201280066317.4A CN104040070B (en) 2012-01-18 2012-12-12 The steel cord of full elastomer penetration
PCT/EP2012/075247 WO2013107570A1 (en) 2012-01-18 2012-12-12 Steel cord with full elastomer penetration

Publications (2)

Publication Number Publication Date
CN104040070A CN104040070A (en) 2014-09-10
CN104040070B true CN104040070B (en) 2016-09-21

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Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3032978B1 (en) * 2015-02-19 2017-10-27 Michelin & Cie MULTITORON 1XN STRUCTURE CABLE FOR PNEUMATIC PROTECTION FRAME
CN106758437A (en) * 2017-01-19 2017-05-31 江苏兴达钢帘线股份有限公司 It is a kind of(4+3)The superhigh intensity steel cord of structure

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6445884A (en) * 1987-05-04 1989-02-20 Bekaert Sa Nv Compact cord made of steel
JPH0698341B2 (en) * 1990-05-02 1994-12-07 住友ゴム工業株式会社 Steel cord for tire
JPH07189146A (en) * 1993-12-25 1995-07-25 Bridgestone Metarufua Kk Steel cord for reinforcing rubber product
CN1133075A (en) * 1993-12-15 1996-10-09 贝克特股份有限公司 Open steel cord structure
CN1247133A (en) * 1998-09-10 2000-03-15 韩国轮胎株式会社 Steel-made tyre cord of radial tyre
CN1505719A (en) * 2001-04-26 2004-06-16 �����ʩ���عɷݹ�˾ Steel cord for reinforcing rubber articles
CN102812177A (en) * 2010-03-23 2012-12-05 贝卡尔特公司 Open off-the-road cord with preformed filaments

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0673672A (en) * 1992-08-24 1994-03-15 Tokyo Seiko Co Ltd Steel cord for reinforcing rubber

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6445884A (en) * 1987-05-04 1989-02-20 Bekaert Sa Nv Compact cord made of steel
JPH0698341B2 (en) * 1990-05-02 1994-12-07 住友ゴム工業株式会社 Steel cord for tire
CN1133075A (en) * 1993-12-15 1996-10-09 贝克特股份有限公司 Open steel cord structure
JPH07189146A (en) * 1993-12-25 1995-07-25 Bridgestone Metarufua Kk Steel cord for reinforcing rubber product
CN1247133A (en) * 1998-09-10 2000-03-15 韩国轮胎株式会社 Steel-made tyre cord of radial tyre
CN1505719A (en) * 2001-04-26 2004-06-16 �����ʩ���عɷݹ�˾ Steel cord for reinforcing rubber articles
CN102812177A (en) * 2010-03-23 2012-12-05 贝卡尔特公司 Open off-the-road cord with preformed filaments

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Granted publication date: 20160921