CN104032333B - A kind of closing down magnesium electrolysis bath of high current efficiency double collection magnesium room - Google Patents
A kind of closing down magnesium electrolysis bath of high current efficiency double collection magnesium room Download PDFInfo
- Publication number
- CN104032333B CN104032333B CN201410270112.9A CN201410270112A CN104032333B CN 104032333 B CN104032333 B CN 104032333B CN 201410270112 A CN201410270112 A CN 201410270112A CN 104032333 B CN104032333 B CN 104032333B
- Authority
- CN
- China
- Prior art keywords
- magnesium
- electrolysis bath
- closing down
- collection
- room
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Electrolytic Production Of Metals (AREA)
Abstract
The present invention relates to the closing down magnesium electrolysis bath of a kind of high current efficiency double collection magnesium room, it is characterised in that closing down magnesium electrolysis bath comprises minus plate, positive plate and collection magnesium room, the number of collection magnesium room is two, is separately positioned on the both sides of minus plate and positive plate, and two collection magnesium rooms are symmetric.The present invention changes the structure of tradition closing down magnesium electrolysis bath, uses two symmetrical collection magnesium rooms, takes to insert or the method for lower slotting cathode and anode between two collection magnesium rooms.This structural change electrolyte flow situation of closing down magnesium electrolysis bath, takes full advantage of the flow behavior of electrolyte, improves the separation efficiency of magnesium metal.Compared with former grooved, the magnesium metal separation efficiency of the most double collection magnesium rooms electrolysis bath is greatly improved, and effect is obvious.
Description
[technical field]
The present invention relates to cell technologies field, specifically, be a kind of high current efficiency double collection magnesium room
Closing down magnesium electrolysis bath.
[background technology]
Magnesium is the lightest non-ferrous metal, it is possible to the good and alloy of other metal composition high intensity, and not
The disconnected castability improved makes its application increasingly wider, is the useful supplement of conventional aluminum alloy etc..In U.S.
State, there is explosive growth in fields such as consumer electronics, automobile, medical treatment in magnesium alloy, has greatly replacement aluminum to close
The gesture of the conventional alloys such as gold.Magnesium serves not only as lightweighting materials and enjoys expectation, also as magnesium fuel cell
Electrode constituting material, have important application at battery industry.
China is magnesium resource big country, Ye Shi magnesium metal big producing country, but production method with Pidgeon process is mainly
Main.State's internal electrolysis production process equipment is backward, grooved is little, current efficiency and production efficiency is low, energy consumption
High.External electrolysis installation current intensity is big by contrast, and automaticity is high, and unit are magnesium metal produces
Amount height, power consumption is low.The current efficiency of the non-inductive windings closing down magnesium electrolysis bath that China runs at present is low, only 76～78
About %, magnesium metal separation efficiency is low, and whole magnesium eletrolysis is industrial and external gap is huge.
Based on the research to advanced magnesium eletrolysis technique, design and possess low-energy-consumption, the separation of high magnesium metal
The electrolysis bath of rate.Exploitation simultaneously has a magnesium eletrolysis key technology of China's independent intellectual property right, further with
Gas chemical industry organically combines, and forms every resource such as magnesium, gas chemical industry and mutually relies on, supports mutually
Industry chain of circular economy, reach the maximization of the utilization of resources and the optimization of economic benefit.
[summary of the invention]
It is an object of the invention to overcome the deficiencies in the prior art, it is provided that a kind of high current efficiency double collection magnesium room
Closing down magnesium electrolysis bath.
It is an object of the invention to be achieved through the following technical solutions:
A kind of closing down magnesium electrolysis bath of high current efficiency double collection magnesium room, closing down magnesium electrolysis bath comprises minus plate, positive plate and
Collection magnesium room, the number of collection magnesium room is two, is separately positioned on the both sides of minus plate and positive plate, and two
Collection magnesium room is symmetric.
Described minus plate and positive plate spacing are 0.03～0.08m.
Described minus plate is inserted into closing down magnesium electrolysis bath from electrolysis bath top or bottom.
Described positive plate is inserted into closing down magnesium electrolysis bath from electrolysis bath top or bottom.
Described minus plate is identical with height with the width of positive plate.
Described minus plate and the width of positive plate are in the range of 0.9～1.6m
Described minus plate and the height of positive plate are in the range of 2.0～3.0m
The thickness of described minus plate is 0.05～0.15m.
The thickness of described positive plate is 0.15～0.25m.
Compared with prior art, the positive effect of the present invention is:
The present invention changes the structure of tradition closing down magnesium electrolysis bath, uses two symmetrical collection magnesium rooms, two collection magnesium
Take between room to insert or the method for lower slotting cathode and anode.This structural change electrolysis mass flow of closing down magnesium electrolysis bath
Emotionally condition, takes full advantage of the flow behavior of electrolyte, improves the separation efficiency of magnesium metal.With former groove
Type is compared, and the magnesium metal separation efficiency of the most double collection magnesium rooms electrolysis bath is greatly improved, and effect is obvious.
[accompanying drawing explanation]
The present invention is further described with embodiment below in conjunction with the accompanying drawings.
Fig. 1 is prototype magnesium electrolytic-bath structure schematic diagram；A is outside drawing, and b is cross sectional representation
Fig. 2 is the most double collection magnesium rooms cell construction schematic diagrams；A is outside drawing, and b is cross sectional representation
Fig. 3 is closing down magnesium electrolysis bath former grooved Flow Field Distribution schematic diagram；
Fig. 4 is the most double collection magnesium rooms electrolysis bath Flow Field Distribution schematic diagrams；
Fig. 5 is closing down magnesium electrolysis bath former grooved magnesium metal flow schematic diagram；
Fig. 6 is the most double collection magnesium rooms electrolysis bath magnesium metal flow schematic diagrams；
Label in accompanying drawing is respectively as follows: 1, anode, and 2, negative electrode, 3, tank house, 4, collection magnesium room
[detailed description of the invention]
The detailed description of the invention of the closing down magnesium electrolysis bath of a kind of high current efficiency of the present invention presented below double collection magnesium room.
Embodiment 1
Refer to accompanying drawing 2, a kind of the most double integrate the magnesium room cell construction basic element of character as anode 1, negative electrode 2,
Tank house 3 and two collection magnesium rooms 4.Described minus plate and positive plate spacing are 0.07m, negative electrode and anode
Being inserted into closing down magnesium electrolysis bath from electrolysis bath top, negative electrode is identical with height with the width of anode, and width is 1m,
Being highly 2.2m, minus plate thickness is 0.05m, and positive plate thickness is 0.15m.
By electric field, thermal field, magnetic field, flow field analysis, upper slotting cathode type closing down magnesium electrolysis bath thermal balance is good,
Electrolyte temperature is 700 DEG C, and electrolyte flow status is good, and magnesium metal separation rate is substantially improved.Calculate
To electrolysis bath Flow Field Distribution such as Fig. 4: the mobility status of magnesium metal such as Fig. 6:
Efficiently double collection magnesium rooms electrolysis bath as figure shows, magnesium metal is symmetrical along with electrolyte separately flows into two, left and right
Collection magnesium room, and finally collect in the electrolyte levels collecting magnesium room.Exist in tank house almost without magnesium metal,
Magnesium metal separation rate is high.
Comparative example 1
Refer to accompanying drawing 1, prototype magnesium electrolytic-bath structure basic element of character anode 1, negative electrode 2, tank house 3 and
Collection magnesium room 4.
Compared with former grooved, the most double collection magnesium rooms electrolysis bath thermal balance is good, and electrolyte temperature controls 700
About DEG C, basic technological parameters remains stable.The rate of magnesium metal first separation simultaneously increases to 96% from 17%,
Separation efficiency is greatly improved.
The above is only the preferred embodiment of the present invention, it is noted that general for the art
Logical technical staff, without departing from the inventive concept of the premise, it is also possible to make some improvements and modifications,
These improvements and modifications also should be regarded as in protection scope of the present invention.
Claims (5)
1. the closing down magnesium electrolysis bath of high current efficiency double collection magnesium room, it is characterised in that closing down magnesium electrolysis bath comprises negative electrode
Plate, positive plate and collection magnesium room, the number of collection magnesium room is two, is separately positioned on the two of minus plate and positive plate
Side, and two collection magnesium rooms be symmetric；
Described minus plate is inserted into closing down magnesium electrolysis bath from electrolysis bath top or bottom；
Described positive plate is inserted into closing down magnesium electrolysis bath from electrolysis bath top or bottom；
Described minus plate is identical with height with the width of positive plate；
Described minus plate and the height of positive plate are in the range of 2.0～3.0m.
The closing down magnesium electrolysis bath of a kind of high current efficiency the most as claimed in claim 1 double collection magnesium room, it is characterised in that
Described minus plate and positive plate spacing are 0.03～0.08m.
The closing down magnesium electrolysis bath of a kind of high current efficiency the most as claimed in claim 1 double collection magnesium room, it is characterised in that
Described minus plate and the width of positive plate are in the range of 0.9～1.6m.
The closing down magnesium electrolysis bath of a kind of high current efficiency the most as claimed in claim 1 double collection magnesium room, it is characterised in that
The thickness of described minus plate is 0.05～0.15m.
The closing down magnesium electrolysis bath of a kind of high current efficiency the most as claimed in claim 1 double collection magnesium room, it is characterised in that
The thickness of described positive plate is 0.15～0.25m.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410270112.9A CN104032333B (en) | 2014-06-17 | 2014-06-17 | A kind of closing down magnesium electrolysis bath of high current efficiency double collection magnesium room |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410270112.9A CN104032333B (en) | 2014-06-17 | 2014-06-17 | A kind of closing down magnesium electrolysis bath of high current efficiency double collection magnesium room |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104032333A CN104032333A (en) | 2014-09-10 |
| CN104032333B true CN104032333B (en) | 2016-09-21 |
Family
ID=51463320
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410270112.9A Active CN104032333B (en) | 2014-06-17 | 2014-06-17 | A kind of closing down magnesium electrolysis bath of high current efficiency double collection magnesium room |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104032333B (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU507669A1 (en) * | 1974-09-06 | 1976-03-25 | Всесоюзный научно-исследовательский и проектный институт алюминиевой, магниевой и электродной промышленности | Electrolyzer to get magnesium |
| US4058448A (en) * | 1976-06-23 | 1977-11-15 | Muzhzhavlev Konstantin Dmitrie | Diaphragmless electrolyzer for producing magnesium and chlorine |
| CN1807697A (en) * | 2005-12-28 | 2006-07-26 | 中国科学院长春应用化学研究所 | Process for preparing rare earth-magnesium intermediate alloy by compound cathode molten salt electrolysis |
| CN200955069Y (en) * | 2006-06-14 | 2007-10-03 | 贵阳铝镁设计研究院 | Magnesium-guide-tank type magnesium electrolytic tank |
| TW201418524A (en) * | 2012-11-05 | 2014-05-16 | Univ Nat Yunlin Sci & Tech | Apparatus and method for electrolytically producing magnesium |
-
2014
- 2014-06-17 CN CN201410270112.9A patent/CN104032333B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU507669A1 (en) * | 1974-09-06 | 1976-03-25 | Всесоюзный научно-исследовательский и проектный институт алюминиевой, магниевой и электродной промышленности | Electrolyzer to get magnesium |
| US4058448A (en) * | 1976-06-23 | 1977-11-15 | Muzhzhavlev Konstantin Dmitrie | Diaphragmless electrolyzer for producing magnesium and chlorine |
| CN1807697A (en) * | 2005-12-28 | 2006-07-26 | 中国科学院长春应用化学研究所 | Process for preparing rare earth-magnesium intermediate alloy by compound cathode molten salt electrolysis |
| CN200955069Y (en) * | 2006-06-14 | 2007-10-03 | 贵阳铝镁设计研究院 | Magnesium-guide-tank type magnesium electrolytic tank |
| TW201418524A (en) * | 2012-11-05 | 2014-05-16 | Univ Nat Yunlin Sci & Tech | Apparatus and method for electrolytically producing magnesium |
Non-Patent Citations (2)
| Title |
|---|
| 7500安培无隔板工业镁电解槽试验研究(上);上海第二冶炼厂;《轻金属》;19780131(第1期);第29-32页 * |
| 氧化镁直接电解制取金属镁的槽型和工艺研究;沙录昌;《轻金属》;19940831(第8期);第41-44页 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104032333A (en) | 2014-09-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106894055B (en) | The continuous aluminium frame anode aluminium cell of built-in conductor | |
| WO2014019513A3 (en) | Rare earth metal, rare earth metal alloy and method for the preparation of same by molten salt electrolysis | |
| CN103290433B (en) | Device and the technique thereof of pure titanium are prepared in a kind of pair of electrolyzer fused salt electrolysis | |
| CN104037468B (en) | A kind of method reclaiming manganese and copper resource from waste and old lithium ion battery | |
| CN103668322B (en) | A kind of steamalloy waste recovery copper, the method for nickel | |
| CN104878413B (en) | Method for utilizing titaniferous electric furnace slag for direct electrolysis to produce low-titanium-aluminum alloy | |
| CN205099767U (en) | Electrolytic cell assembly with extensive rare refractory metal of continuous production | |
| CN105734615B (en) | A kind of method that thermoelectricity reduction prepares Titanium in fluoride smelt salt | |
| CN104032329B (en) | Upper slotting cathode type closing down magnesium electrolysis bath | |
| CN104032333B (en) | A kind of closing down magnesium electrolysis bath of high current efficiency double collection magnesium room | |
| CN102839394A (en) | Method for rapidly preparing tree-like nano-iron with multi-level structure | |
| WO2012092868A1 (en) | Magnesium chloride electrolysis apparatus and electrolysis method | |
| CN102534688B (en) | High-current baffleless magnesium electrolytic tank | |
| CN2931501Y (en) | Aluminum electrolysis bath cathode heterotype electric steel rod | |
| CN203582982U (en) | Forced heat transfer type aluminum electrolytic tank | |
| CN104032330A (en) | Cathode structure of magnesium electrolysis bath | |
| CN107475539B (en) | A kind of method that gaseous state electrochemistry prepares Titanium | |
| CN203065592U (en) | Copper electrolysis bath | |
| CN106435648A (en) | Method for preparing molybdenum through high temperature electrolysis fusion of molybdenum concentrate | |
| CN202576606U (en) | Lead-steel layered combined electrode | |
| CN205934047U (en) | Anode rod and steel claw connection structure | |
| CN202465897U (en) | Alumina electrolysis bath device | |
| CN103184476A (en) | Technique adopting basic magnesium carbonate to produce rare-earth magnesium alloy | |
| CN104775133A (en) | Baffleless magnesium electrolytic cell and use method thereof | |
| CN205474019U (en) | Novel ion membrane electrolytic cell |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |