CN104031462A - Waste-paper deinking separating agent based on glucose alkyl glycoside - Google Patents
Waste-paper deinking separating agent based on glucose alkyl glycoside Download PDFInfo
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- CN104031462A CN104031462A CN201410229256.XA CN201410229256A CN104031462A CN 104031462 A CN104031462 A CN 104031462A CN 201410229256 A CN201410229256 A CN 201410229256A CN 104031462 A CN104031462 A CN 104031462A
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/64—Paper recycling
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Abstract
The invention discloses a waste-paper deinking separating agent based on glucose alkyl glycoside and relates to the technical field of paper surface treatment. The waste-paper deinking separating agent comprises a certain amount of cationic polymers, an anionic surfactant and an ampholytic surfactant. The anionic surfactant and the ampholytic surfactant are prepared by adopting natural plant raw materials, so that the purpose of environmental protection is realized.
Description
Technical field
The present invention relates to paper surface processing technology field, be specifically related to a kind of deinking separating agent based on glucose alkyl glycoside.
Background technology
The development that deepens continuously along with process of industrialization, in order to reach environmental protection and energy-conservation object, in printing industry, conventionally can recycle waste paper, waste paper after recovery needs effects on surface to carry out deinking processing, in prior art, conventionally adopt the catalytic hydrolysis reaction effect of alkaline matter, to the black particle on waste paper surface, carry out separated with Mierocrystalline cellulose, yet add again anion surfactant or nonionogenic tenside, make black particle with water or bubble disengagement system, realize the object of deinking, its weak point is, the tensio-active agent adding has potential safety hazard, and bio-refractory, can destroy environment structure.
Summary of the invention
In order to solve the problems of the technologies described above, the invention provides a kind of deinking separating agent based on glucose alkyl glycoside, by adding the tensio-active agent of glucose alkyl glycoside, it adopts the raw material of natural phant to prepare, and realizes the effect of environmental protection.
Technical scheme of the present invention is as follows:
Deinking separating agent based on glucose alkyl glycoside, comprise cationic polymers, anion surfactant and amphoterics, described cationic polymers is selected from cationic cellulose, cationic starch, cationic guar gum, propenoic acid dialkyl aminoalkyl ester, methylacrylic acid dialkyl aminoalkyl ester, vinylformic acid alkyl monosubstituted amino alkyl ester, methylacrylic acid alkyl monosubstituted amino alkyl ester, trialkyl methacryloxy alkylammonium salt, trialkyl acryloxyalkyl ammonium salt, diallyl quaternary ammonium salt, pyridinium salt, imidazole salts, quaternised pyrrole network alkane ketone and polyisobutene amido oxypropyl trimethyl ammonium chloride, dialkyl diallyl ammonium halide homopolymer and multipolymer, PEI or contain two quaternary ammoniums or the multipolymer of many quaternary ammoniums repeating unit,
Described anion surfactant is selected from alkyl-sulphate, sulfated alkyl ether, ammonium lauryl sulfate, lauryl polyethenoxy ether sodium sulfate, lauryl sulfate triethyl ammonium, laureth sulfuric acid triethylamine, dodecyltriethanolamine sulfate, laureth sulfuric acid trolamine, lauryl sulfate monoethanolamine, laureth sulfuric acid monoethanolamine, lauryl sulfate diethanolamine, laureth sulfuric acid diethanolamine, Glyceryl Monolaurate sodium sulfate, Sodium Lauryl Sulphate BP/USP, sodium laureth sulfate, lauryl potassium sulfate, laureth potassium sulfate, sodium lauryl sarcosinate, sodium lauroyl sareosine, lauryl sarkosine, cocoyl sarkosine, sodium cocosulfate, lauroyl ammonium sulfate, lauroyl sodium sulfate, cocoyl potassium sulfate, triethanolamine lauryl sulfate, triethanolamine lauryl sulfate, cocoyl sulfuric acid Monoethanolamine MEA BASF, lauryl sulfate Monoethanolamine MEA BASF, tridecyl benzene sulfonic acid sodium salt and Sodium dodecylbenzene sulfonate, an alkali metal salt, ammonium salt, amine salt, amino alkoxide, or alkaline earth salt: alkyl-sulphate, sulfated alkyl ether, alkylamidoalkyl ether sulfate, alkyl aryl polyether sulfate, glycerine-sulfuric acid, alkylsulfonate, alkyl-sulphate, alkylamide sulfonate, alkylaryl sulphonate, sulfonated α-olefin, alkane sulfonate, alkyl sulfo succinate, alkyl ether sulfo succinate, alkylamide sulfosuccinate, alkyl sulfoacetate, acyl sarcosinate, and acyl glutamate.
Described amphoterics is selected from: (C8-C24) alkylamidoalkyl (C3-C8) alkyl betaine, sulphobetaine, (C8-C24) alkylamidoalkyl (C6-C8) alkyl sulphobetaine, (C8-C24) alkyl both sexes monoacetate, (C8-C24) alkyl both sexes diacetate esters, (C8-C24) alkyl both sexes one propionic ester, (C8-C24) alkyl both sexes dipropionate and phosphorus trimethyl-glycine, cocounut oil alanine, cocounut oil imino-diacetic propionic acid, octyl group imino-diacetic propionic acid, bay imino-diacetic Sodium Propionate, lauryl alanine, lauryl aminobutyric acid, cocounut oil alanine sodium, cocounut oil aminobutyric acid sodium, cocounut oil imino-diacetic Sodium Propionate, octadecyl alanine, octyl group Sodium Glycinate and hexadecyl Padil potassium, and their mixture.
As preferably, the content of described anion surfactant is 5%-50%, and the content of described amphoterics is 0.1%-15%.
Further, the weight ratio of described anion surfactant and described amphoterics is 0.1 to 1.
Beneficial effect: the present invention, by above technology, can not only promote treatment effect, increases the whiteness of finished paper, and environment is played a protective role.
Embodiment
Below the technical scheme in the embodiment of the present invention is clearly and completely described, obviously, described embodiment is only the present invention's part embodiment, rather than whole embodiment.Embodiment based in the present invention, those of ordinary skills, not making the every other embodiment obtaining under creative work prerequisite, belong to the scope of protection of the invention.
Embodiment 1
Deinking separating agent based on glucose alkyl glycoside, content is 20%-50% cationic polymers, content is the amphoterics that 5%-15% anion surfactant and content are 5%-15%, and described cationic polymers is selected from cationic cellulose, cationic starch, cationic guar gum, propenoic acid dialkyl aminoalkyl ester, methylacrylic acid dialkyl aminoalkyl ester, vinylformic acid alkyl monosubstituted amino alkyl ester;
Described anion surfactant is selected from alkyl-sulphate, sulfated alkyl ether, ammonium lauryl sulfate, lauryl polyethenoxy ether sodium sulfate, lauryl sulfate triethyl ammonium, laureth sulfuric acid triethylamine, dodecyltriethanolamine sulfate, laureth sulfuric acid trolamine, lauryl sulfate monoethanolamine, laureth sulfuric acid monoethanolamine, lauryl sulfate diethanolamine, laureth sulfuric acid diethanolamine, Glyceryl Monolaurate sodium sulfate, Sodium Lauryl Sulphate BP/USP, sodium laureth sulfate, lauryl potassium sulfate, laureth potassium sulfate, sodium lauryl sarcosinate, sodium lauroyl sareosine, lauryl sarkosine.
Described amphoterics is selected from: (C8-C24) alkylamidoalkyl (C3-C8) alkyl betaine, sulphobetaine, (C8-C24) alkylamidoalkyl (C6-C8) alkyl sulphobetaine, (C8-C24) alkyl both sexes monoacetate, (C8-C24) alkyl both sexes diacetate esters, (C8-C24) alkyl both sexes one propionic ester, (C8-C24) alkyl both sexes dipropionate and phosphorus trimethyl-glycine, and their mixture.
In deinking process, utilize the catalytic hydrolysis solution reaction of alkali, cationic polymers can be by the Mierocrystalline cellulose in waste paper and black particle breakdown, then add anion surfactant or nonionogenic tenside, anion surfactant or nonionogenic tenside can be by black particle with water or bubble disengagements, thereby realize black particle with cellulosic thoroughly separated, described deinking separating agent, through Technidyne Color Touch ERIC950 type residual ink determinator, test, according to international standard, ISO-22754-2008 measures, Deinking Efficiency is compared with promoting 75%-78% in prior art, the whiteness of finished paper has promoted more than at least 60%.
Embodiment 2
Deinking separating agent based on glucose alkyl glycoside, all the other are identical with embodiment 1, institute's difference is, described deinking separating agent comprises that content is 5%-30% cationic polymers, content is the amphoterics that 5%-10% anion surfactant and content are 0.1%-10%, described cationic polymers is selected from trialkyl methacryloxy alkylammonium salt, trialkyl acryloxyalkyl ammonium salt, diallyl quaternary ammonium salt, pyridinium salt, imidazole salts, quaternised pyrrole network alkane ketone and polyisobutene amido oxypropyl trimethyl ammonium chloride, dialkyl diallyl ammonium halide homopolymer and multipolymer, PEI or contain two quaternary ammoniums or the multipolymer of many quaternary ammoniums repeating unit.
Described anion surfactant is selected from cocoyl sarkosine, sodium cocosulfate, lauroyl ammonium sulfate, lauroyl sodium sulfate, cocoyl potassium sulfate, triethanolamine lauryl sulfate, triethanolamine lauryl sulfate, cocoyl sulfuric acid Monoethanolamine MEA BASF, lauryl sulfate Monoethanolamine MEA BASF, tridecyl benzene sulfonic acid sodium salt and Sodium dodecylbenzene sulfonate, an alkali metal salt, ammonium salt, amine salt, amino alkoxide, or alkaline earth salt: alkyl-sulphate, sulfated alkyl ether, alkylamidoalkyl ether sulfate, alkyl aryl polyether sulfate, glycerine-sulfuric acid, alkylsulfonate, alkyl-sulphate, alkylamide sulfonate, alkylaryl sulphonate, sulfonated α-olefin, alkane sulfonate, alkyl sulfo succinate, alkyl ether sulfo succinate, alkylamide sulfosuccinate, alkyl sulfoacetate, acyl sarcosinate, and acyl glutamate.
Described amphoterics is selected from: cocounut oil alanine, cocounut oil imino-diacetic propionic acid, octyl group imino-diacetic propionic acid, bay imino-diacetic Sodium Propionate, lauryl alanine, lauryl aminobutyric acid, cocounut oil alanine sodium, cocounut oil aminobutyric acid sodium, cocounut oil imino-diacetic Sodium Propionate, octadecyl alanine, octyl group Sodium Glycinate and hexadecyl Padil potassium, and their mixture, through Technidyne Color Touch ERIC950 type residual ink determinator, test, according to international standard, ISO-22754-2008 measures, Deinking Efficiency has more and has a certain upgrade compared with the Deinking Efficiency in embodiment 1, compared to existing technology, can promote 80%-85%, more than the whiteness of finished paper has promoted 65%-70%.
Embodiment 3
Deinking separating agent based on glucose alkyl glycoside, comprise cationic polymers, anion surfactant and amphoterics, all the other are identical with embodiment 1, institute's difference is, described cationic polymers is selected from propenoic acid dialkyl aminoalkyl ester, methylacrylic acid dialkyl aminoalkyl ester, vinylformic acid alkyl monosubstituted amino alkyl ester, methylacrylic acid alkyl monosubstituted amino alkyl ester, trialkyl methacryloxy alkylammonium salt, trialkyl acryloxyalkyl ammonium salt, quaternised pyrrole network alkane ketone and polyisobutene amido oxypropyl trimethyl ammonium chloride, dialkyl diallyl ammonium halide homopolymer and multipolymer, PEI or contain two quaternary ammoniums or the multipolymer of many quaternary ammoniums repeating unit,
Described anion surfactant is selected from alkyl-sulphate, sulfated alkyl ether, ammonium lauryl sulfate, lauryl polyethenoxy ether sodium sulfate, lauryl sulfate triethyl ammonium, laureth sulfuric acid triethylamine, laureth sulfuric acid diethanolamine, Glyceryl Monolaurate sodium sulfate, Sodium Lauryl Sulphate BP/USP, sodium laureth sulfate, lauryl potassium sulfate, laureth potassium sulfate, sodium lauryl sarcosinate, sodium lauroyl sareosine, lauryl sarkosine, cocoyl sarkosine, sodium cocosulfate, lauroyl ammonium sulfate, lauroyl sodium sulfate, cocoyl potassium sulfate, triethanolamine lauryl sulfate, triethanolamine lauryl sulfate, cocoyl sulfuric acid Monoethanolamine MEA BASF, lauryl sulfate Monoethanolamine MEA BASF, tridecyl benzene sulfonic acid sodium salt and Sodium dodecylbenzene sulfonate, an alkali metal salt, ammonium salt, amine salt, amino alkoxide, or alkaline earth salt: alkyl-sulphate, alkyl-sulphate, alkylamide sulfonate, alkylaryl sulphonate alkane sulfonate, alkyl sulfo succinate, alkyl ether sulfo succinate, alkylamide sulfosuccinate, alkyl sulfoacetate, acyl sarcosinate, and acyl glutamate.
Described amphoterics is selected from: (C8-C24) alkylamidoalkyl (C3-C8) alkyl betaine, sulphobetaine, (C8-C24) alkylamidoalkyl (C6-C8) alkyl sulphobetaine, lauryl aminobutyric acid, cocounut oil alanine sodium, cocounut oil aminobutyric acid sodium, cocounut oil imino-diacetic Sodium Propionate, octadecyl alanine, octyl group Sodium Glycinate and hexadecyl Padil potassium, and their mixture, mentioned deinking separating agent in the present embodiment, adopt Technidyne Color Touch ERIC950 type residual ink determinator, according to international standard, ISO-22754-2008 measures, Deinking Efficiency has more and has a certain upgrade compared with the Deinking Efficiency in embodiment 1, compared to existing technology, can promote 83% left and right, but the whiteness of finished paper has had lifting by a relatively large margin, common deinking separating agent compared to existing technology, reached between 80%-85%.
Above-described is only the preferred implementation of the deinking separating agent based on glucose alkyl glycoside disclosed in this invention; should be understood that; for the person of ordinary skill of the art; without departing from the concept of the premise of the invention; can also make some distortion and improvement, these all belong to protection scope of the present invention.
Claims (3)
1. the deinking separating agent based on glucose alkyl glycoside, comprise cationic polymers, described cationic polymers is selected from cationic cellulose, cationic starch, cationic guar gum, propenoic acid dialkyl aminoalkyl ester, methylacrylic acid dialkyl aminoalkyl ester, vinylformic acid alkyl monosubstituted amino alkyl ester, methylacrylic acid alkyl monosubstituted amino alkyl ester, trialkyl methacryloxy alkylammonium salt, trialkyl acryloxyalkyl ammonium salt, diallyl quaternary ammonium salt, pyridinium salt, imidazole salts, quaternised pyrrole network alkane ketone and polyisobutene amido oxypropyl trimethyl ammonium chloride, dialkyl diallyl ammonium halide homopolymer and multipolymer, PEI or contain two quaternary ammoniums or the multipolymer of many quaternary ammoniums repeating unit, it is characterized in that, also comprise:
---anion surfactant, described anion surfactant is selected from alkyl-sulphate, sulfated alkyl ether, ammonium lauryl sulfate, lauryl polyethenoxy ether sodium sulfate, lauryl sulfate triethyl ammonium, laureth sulfuric acid triethylamine, dodecyltriethanolamine sulfate, laureth sulfuric acid trolamine, lauryl sulfate monoethanolamine, laureth sulfuric acid monoethanolamine, lauryl sulfate diethanolamine, laureth sulfuric acid diethanolamine, Glyceryl Monolaurate sodium sulfate, Sodium Lauryl Sulphate BP/USP, sodium laureth sulfate, lauryl potassium sulfate, laureth potassium sulfate, sodium lauryl sarcosinate, sodium lauroyl sareosine, lauryl sarkosine, cocoyl sarkosine, sodium cocosulfate, lauroyl ammonium sulfate, lauroyl sodium sulfate, cocoyl potassium sulfate, triethanolamine lauryl sulfate, triethanolamine lauryl sulfate, cocoyl sulfuric acid Monoethanolamine MEA BASF, lauryl sulfate Monoethanolamine MEA BASF, tridecyl benzene sulfonic acid sodium salt and Sodium dodecylbenzene sulfonate, an alkali metal salt, ammonium salt, amine salt, amino alkoxide, or alkaline earth salt: alkyl-sulphate, sulfated alkyl ether, alkylamidoalkyl ether sulfate, alkyl aryl polyether sulfate, glycerine-sulfuric acid, alkylsulfonate, alkyl-sulphate, alkylamide sulfonate, alkylaryl sulphonate, sulfonated α-olefin, alkane sulfonate, alkyl sulfo succinate, alkyl ether sulfo succinate, alkylamide sulfosuccinate, alkyl sulfoacetate, acyl sarcosinate, and acyl glutamate.
---amphoterics, described amphoterics is selected from: (C8-C24) alkylamidoalkyl (C3-C8) alkyl betaine, sulphobetaine, (C8-C24) alkylamidoalkyl (C6-C8) alkyl sulphobetaine, (C8-C24) alkyl both sexes monoacetate, (C8-C24) alkyl both sexes diacetate esters, (C8-C24) alkyl both sexes one propionic ester, (C8-C24) alkyl both sexes dipropionate and phosphorus trimethyl-glycine, cocounut oil alanine, cocounut oil imino-diacetic propionic acid, octyl group imino-diacetic propionic acid, bay imino-diacetic Sodium Propionate, lauryl alanine, lauryl aminobutyric acid, cocounut oil alanine sodium, cocounut oil aminobutyric acid sodium, cocounut oil imino-diacetic Sodium Propionate, octadecyl alanine, octyl group Sodium Glycinate and hexadecyl Padil potassium, and their mixture.
2. the deinking separating agent based on glucose alkyl glycoside according to claim 1, is characterized in that, the content of described anion surfactant is 5%-50%, and the content of described amphoterics is 0.1%-15%.
3. the deinking separating agent based on glucose alkyl glycoside according to claim 2, is characterized in that, the weight ratio of described anion surfactant and described amphoterics is 0.1 to 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201410229256.XA CN104031462A (en) | 2014-05-28 | 2014-05-28 | Waste-paper deinking separating agent based on glucose alkyl glycoside |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410229256.XA CN104031462A (en) | 2014-05-28 | 2014-05-28 | Waste-paper deinking separating agent based on glucose alkyl glycoside |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108485368A (en) * | 2018-05-07 | 2018-09-04 | 句容市兴武包装有限公司 | A kind of efficient neutral deinking agent and preparation method thereof |
| CN112010912A (en) * | 2020-09-11 | 2020-12-01 | 中国石油大学(华东) | Alkyl glycoside surfactant for drilling fluid, preparation method thereof and application of alkyl glycoside surfactant in drilling fluid |
Citations (2)
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|---|---|---|---|---|
| CN1185818A (en) * | 1995-04-05 | 1998-06-24 | 花王株式会社 | Deinking method |
| CN1230236A (en) * | 1996-06-03 | 1999-09-29 | 花王株式会社 | Deinking process |
-
2014
- 2014-05-28 CN CN201410229256.XA patent/CN104031462A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1185818A (en) * | 1995-04-05 | 1998-06-24 | 花王株式会社 | Deinking method |
| CN1230236A (en) * | 1996-06-03 | 1999-09-29 | 花王株式会社 | Deinking process |
Non-Patent Citations (2)
| Title |
|---|
| 张光华: "《表面活性剂在造纸中的应用技术》", 30 April 2001, 中国轻工业出版社 * |
| 颜进华: "《造纸化学品技术》", 31 August 2009 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108485368A (en) * | 2018-05-07 | 2018-09-04 | 句容市兴武包装有限公司 | A kind of efficient neutral deinking agent and preparation method thereof |
| CN112010912A (en) * | 2020-09-11 | 2020-12-01 | 中国石油大学(华东) | Alkyl glycoside surfactant for drilling fluid, preparation method thereof and application of alkyl glycoside surfactant in drilling fluid |
| CN112010912B (en) * | 2020-09-11 | 2021-08-31 | 中国石油大学(华东) | Alkyl glycoside surfactant for drilling fluid, preparation method thereof and application of alkyl glycoside surfactant in drilling fluid |
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Application publication date: 20140910 |