CN104031428A - Modified nanometer titanium dioxide with stable structure and high specific surface area and preparation method thereof - Google Patents
Modified nanometer titanium dioxide with stable structure and high specific surface area and preparation method thereof Download PDFInfo
- Publication number
- CN104031428A CN104031428A CN201410197377.0A CN201410197377A CN104031428A CN 104031428 A CN104031428 A CN 104031428A CN 201410197377 A CN201410197377 A CN 201410197377A CN 104031428 A CN104031428 A CN 104031428A
- Authority
- CN
- China
- Prior art keywords
- powder
- nano
- parts
- titanium dioxide
- surface area
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title claims description 7
- 239000004408 titanium dioxide Substances 0.000 title abstract description 8
- 239000000843 powder Substances 0.000 claims abstract description 39
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical class O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 28
- IANQTJSKSUMEQM-UHFFFAOYSA-N 1-benzofuran Chemical compound C1=CC=C2OC=CC2=C1 IANQTJSKSUMEQM-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229920000049 Carbon (fiber) Polymers 0.000 claims abstract description 9
- 229920002292 Nylon 6 Polymers 0.000 claims abstract description 9
- 239000004917 carbon fiber Substances 0.000 claims abstract description 9
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000005060 rubber Substances 0.000 claims abstract description 9
- 239000002023 wood Substances 0.000 claims abstract description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910021393 carbon nanotube Inorganic materials 0.000 claims abstract description 7
- 239000002041 carbon nanotube Substances 0.000 claims abstract description 7
- 239000000203 mixture Substances 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- 238000003756 stirring Methods 0.000 claims description 15
- 239000000377 silicon dioxide Substances 0.000 claims description 13
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 239000000725 suspension Substances 0.000 claims description 9
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 9
- LJRSZGKUUZPHEB-UHFFFAOYSA-N 2-[2-(2-prop-2-enoyloxypropoxy)propoxy]propyl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COC(C)COC(=O)C=C LJRSZGKUUZPHEB-UHFFFAOYSA-N 0.000 claims description 6
- 239000004743 Polypropylene Substances 0.000 claims description 6
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 6
- 239000003153 chemical reaction reagent Substances 0.000 claims description 6
- 230000008878 coupling Effects 0.000 claims description 6
- 238000010168 coupling process Methods 0.000 claims description 6
- 238000005859 coupling reaction Methods 0.000 claims description 6
- 239000000835 fiber Substances 0.000 claims description 6
- 239000012467 final product Substances 0.000 claims description 6
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 claims description 6
- 239000003595 mist Substances 0.000 claims description 6
- 239000011812 mixed powder Substances 0.000 claims description 6
- GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical compound CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 claims description 6
- 239000003921 oil Substances 0.000 claims description 6
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 claims description 6
- -1 polypropylene Polymers 0.000 claims description 6
- 229920001155 polypropylene Polymers 0.000 claims description 6
- 229920001296 polysiloxane Polymers 0.000 claims description 6
- 229910000077 silane Inorganic materials 0.000 claims description 6
- 239000004575 stone Substances 0.000 claims description 6
- 238000010792 warming Methods 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 3
- 239000005543 nano-size silicon particle Substances 0.000 claims description 3
- 230000010355 oscillation Effects 0.000 claims description 3
- 238000010298 pulverizing process Methods 0.000 claims description 3
- 229960001866 silicon dioxide Drugs 0.000 claims description 3
- 235000012239 silicon dioxide Nutrition 0.000 claims description 3
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 claims description 3
- 239000011248 coating agent Substances 0.000 abstract description 3
- 238000000576 coating method Methods 0.000 abstract description 3
- 239000004033 plastic Substances 0.000 abstract description 3
- 229920003023 plastic Polymers 0.000 abstract description 3
- 239000000463 material Substances 0.000 abstract 2
- 239000006087 Silane Coupling Agent Substances 0.000 abstract 1
- 230000032683 aging Effects 0.000 abstract 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 abstract 1
- 229910021502 aluminium hydroxide Inorganic materials 0.000 abstract 1
- 239000003973 paint Substances 0.000 abstract 1
- 239000011297 pine tar Substances 0.000 abstract 1
- 229940068124 pine tar Drugs 0.000 abstract 1
- 238000001179 sorption measurement Methods 0.000 abstract 1
- 239000000945 filler Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002114 nanocomposite Substances 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 239000012074 organic phase Substances 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 230000001699 photocatalysis Effects 0.000 description 1
- 239000011941 photocatalyst Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
Abstract
Disclosed modified nanometer titanium dioxide with a stable structure and a high specific surface area is characterized by being prepared from the following raw materials in parts by weight: 85-90 parts of nanometer titanium dioxide, 2-4 parts of carbon nanotube, 3-4 parts of plastic-wood poweder, 5.5-6.6 parts of nanometer aluminium hydroxide, 3-5 parts of crushed mekralon, 1-2 parts of a silane coupling agent KH-570, 6-7 parts of nylon 6 powder, 2.5-3.5 parts of carbon fiber powder, 4-5 parts of coumarone, 2-3 parts of pine tar and 2-3 parts of modified silicon dioxide. By adding plastic-wood powder, nylon 6 powder and coumarone and other compositions, the stability of the power is increased; by adding modified silicon dioxide, the stability and the adsorption property of the product are increased; carbon fiber powder is easy to disperse and helps to increase the specific surface area; after modified nanometer titanium dioxide is mixed with paint, the coating uniformity is stable, the ageing resistance is good; and also modified nanometer titanium dioxide can be used as a printing ink filling material or rubber or a plastic filling material.
Description
Technical field
The present invention relates to industrial filler field, particularly modified nano-titanium dioxide of a kind of Stability Analysis of Structures high-specific surface area and preparation method thereof.
Background technology
Because nano titanium oxide has good anti-ultraviolet property, good weathering resistance, chemical resistance, thermotolerance, photocatalytic, thermostability, the feature such as harmless, be widely used in pigment as industries such as coating, rubber, plastics, papermaking, also as photocatalyst, photoelectric cell, ultraviolet screening agent etc., be widely used simultaneously; Hydroxyl is contained on titanium dioxide nano-particle surface, and very easily the moisture in absorbed air, presents hydrophilic nmature, thereby is difficult for being dispersed in organic phase, causes existing between TiO 2 particles and organism serious phenomenon of phase separation.Therefore, when preparing titanium dioxide/polymer nanocomposites, first will carry out surface modification to nano-titania particle, its object is exactly to reduce the surface energy of nano titanium oxide, improves the surface properties of titanium dioxide, reduces the surface polarity of particle.So it is very necessary developing a kind of method of producing high-quality modified nano-titanium dioxide.
Summary of the invention
The object of this invention is to provide modified nano-titanium dioxide of a kind of Stability Analysis of Structures high-specific surface area and preparation method thereof.
In order to realize object of the present invention, the present invention passes through following scheme implementation:
A modified nano-titanium dioxide for Stability Analysis of Structures high-specific surface area, is made by the raw material of following weight part: nano titanium oxide 85-90, carbon nanotube 2-4, mould wood powder 3-4, nano-aluminum hydroxide 5.5-6.6, pulverize polypropylene fibre 3-5, Silane coupling reagent KH-570 1-2, nylon 6 powder 6-7, carbon fiber powder 2.5-3.5, coumarone 4-5, Stockholm tar 2-3, improved silica 2-3;
Described improved silica is made by the raw material of following weight part: silicon-dioxide 55-60, nano medical stone powder 2-4, nano silicone micro mist 4-6, tri (propylene glycol) diacrylate 5-7,1-hydroxyethyl-2-oil-based imidazoline 1-2, cobalt naphthenate 3-4, glycidyl acrylate 3-5, EDETATE SODIUM 2-4, water 50-60; First preparation method adds nano silicon, nano medical stone powder, nano silicone micro mist, 1-hydroxyethyl-2-oil-based imidazoline, water to stir, form suspension, at 55-60 ℃, dry to water content 2-3%, then add immediately tri (propylene glycol) diacrylate, cobalt naphthenate, glycidyl acrylate, be heated to 130-150 ℃, mix and blend 25-35 minute, be cooled to room temperature, then add all the other remaining components, under 1200-1500 rev/min of condition, stir 1-2 hour, at 60-70 ℃, dry, grind and get final product.
The modified nano-titanium dioxide of a kind of Stability Analysis of Structures high-specific surface area of the present invention, by following concrete steps, made:
(1) nano titanium oxide, carbon nanotube, pulverizing polypropylene fibre, carbon fiber powder are mixed and added in shredder, with the speed of 1500-2000 rev/min, grind 15-20 minute, obtain mixed powder stand-by;
(2) will mould wood powder, nano-aluminum hydroxide, nylon 6 powder, Stockholm tar and put into mixing machine, be warming up between 80-90 ℃, insulated and stirred half an hour, continue to add Silane coupling reagent KH-570, coumarone, continue to be warming up to 130-160 ℃, stir and pour out after 15-20 minute, cooling after, grind to obtain rubber powder;
(3) mixed powder is mixed with rubber powder, add suitable quantity of water, stir, sonic oscillation 1-2 hour at 80 ℃, then continues to grind 20-30 minute, forms suspension stand-by;
(4) suspension is mixed with improved silica, stir 10-15 minute under 800-1000 rev/min, dry, put into nano grinder and pulverize and get final product.
The invention has the beneficial effects as follows: the present invention moulds the formulas such as wood powder, nylon 6 powder, coumarone by interpolation, increased the stability of powder, having added again improved silica has increased stability and the adsorptivity of product, carbon fiber powder is easy to disperse, increase specific surface area, after mixing with coating, film uniform and stable, resistance to deterioration is good, also can be used as ink filler or rubber or plastic filler.
Specific embodiments
Below by specific examples, the present invention is described in detail.
A modified nano-titanium dioxide for Stability Analysis of Structures high-specific surface area, by following weight part (kilogram) raw material make: nano titanium oxide 85, carbon nanotube 2, mould wood powder 3, nano-aluminum hydroxide 5.5, pulverize polypropylene fibre 3, Silane coupling reagent KH-570 1, nylon 6 powder 6, carbon fiber powder 2.5, coumarone 4, Stockholm tar 2, improved silica 2;
Described improved silica by following weight part (kilogram) raw material make: silicon-dioxide 55, nano medical stone powder 2, nano silicone micro mist 4, tri (propylene glycol) diacrylate 5,1-hydroxyethyl-2-oil-based imidazoline 1, cobalt naphthenate 3, glycidyl acrylate 3, EDETATE SODIUM 2, water 50; First preparation method adds nano silicon, nano medical stone powder, nano silicone micro mist, 1-hydroxyethyl-2-oil-based imidazoline, water to stir, form suspension, at 55-60 ℃, dry to water content 2-3%, then add immediately tri (propylene glycol) diacrylate, cobalt naphthenate, glycidyl acrylate, be heated to 130-150 ℃, mix and blend 25-35 minute, be cooled to room temperature, then add all the other remaining components, under 1200-1500 rev/min of condition, stir 1-2 hour, at 60-70 ℃, dry, grind and get final product.
The modified nano-titanium dioxide of a kind of Stability Analysis of Structures high-specific surface area of the present invention, by following concrete steps, made:
(1) nano titanium oxide, carbon nanotube, pulverizing polypropylene fibre, carbon fiber powder are mixed and added in shredder, with the speed of 1500-2000 rev/min, grind 15-20 minute, obtain mixed powder stand-by;
(2) will mould wood powder, nano-aluminum hydroxide, nylon 6 powder, Stockholm tar and put into mixing machine, be warming up between 80-90 ℃, insulated and stirred half an hour, continue to add Silane coupling reagent KH-570, coumarone, continue to be warming up to 130-160 ℃, stir and pour out after 15-20 minute, cooling after, grind to obtain rubber powder;
(3) mixed powder is mixed with rubber powder, add suitable quantity of water, stir, sonic oscillation 1-2 hour at 80 ℃, then continues to grind 20-30 minute, forms suspension stand-by;
(4) suspension is mixed with improved silica, stir 10-15 minute under 800-1000 rev/min, dry, put into nano grinder and pulverize and get final product.
The specific surface area of the modified nano-titanium dioxide that the present embodiment obtains obviously increases
| Sample | Former nano titanium oxide | Modified nano-titanium dioxide |
| Specific surface area/m 2/g | 80-200 | 140-260 |
Claims (2)
1. the modified nano-titanium dioxide of a Stability Analysis of Structures high-specific surface area, it is characterized in that, by the raw material of following weight part, made: nano titanium oxide 85-90, carbon nanotube 2-4, mould wood powder 3-4, nano-aluminum hydroxide 5.5-6.6, pulverize polypropylene fibre 3-5, Silane coupling reagent KH-570 1-2, nylon 6 powder 6-7, carbon fiber powder 2.5-3.5, coumarone 4-5, Stockholm tar 2-3, improved silica 2-3;
Described improved silica is made by the raw material of following weight part: silicon-dioxide 55-60, nano medical stone powder 2-4, nano silicone micro mist 4-6, tri (propylene glycol) diacrylate 5-7,1-hydroxyethyl-2-oil-based imidazoline 1-2, cobalt naphthenate 3-4, glycidyl acrylate 3-5, EDETATE SODIUM 2-4, water 50-60; First preparation method adds nano silicon, nano medical stone powder, nano silicone micro mist, 1-hydroxyethyl-2-oil-based imidazoline, water to stir, form suspension, at 55-60 ℃, dry to water content 2-3%, then add immediately tri (propylene glycol) diacrylate, cobalt naphthenate, glycidyl acrylate, be heated to 130-150 ℃, mix and blend 25-35 minute, be cooled to room temperature, then add all the other remaining components, under 1200-1500 rev/min of condition, stir 1-2 hour, at 60-70 ℃, dry, grind and get final product.
2. a kind of modified nano-titanium dioxide of Stability Analysis of Structures high-specific surface area according to claim 1, is characterized in that, by following concrete steps, is made:
(1) nano titanium oxide, carbon nanotube, pulverizing polypropylene fibre, carbon fiber powder are mixed and added in shredder, with the speed of 1500-2000 rev/min, grind 15-20 minute, obtain mixed powder stand-by;
(2) will mould wood powder, nano-aluminum hydroxide, nylon 6 powder, Stockholm tar and put into mixing machine, be warming up between 80-90 ℃, insulated and stirred half an hour, continue to add Silane coupling reagent KH-570, coumarone, continue to be warming up to 130-160 ℃, stir and pour out after 15-20 minute, cooling after, grind to obtain rubber powder;
(3) mixed powder is mixed with rubber powder, add suitable quantity of water, stir, sonic oscillation 1-2 hour at 80 ℃, then continues to grind 20-30 minute, forms suspension stand-by;
(4) suspension is mixed with improved silica, stir 10-15 minute under 800-1000 rev/min, dry, put into nano grinder and pulverize and get final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410197377.0A CN104031428B (en) | 2014-05-12 | 2014-05-12 | A kind of modified nano-titanium dioxide of Stability Analysis of Structures high-specific surface area and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410197377.0A CN104031428B (en) | 2014-05-12 | 2014-05-12 | A kind of modified nano-titanium dioxide of Stability Analysis of Structures high-specific surface area and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104031428A true CN104031428A (en) | 2014-09-10 |
| CN104031428B CN104031428B (en) | 2016-06-08 |
Family
ID=51462435
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410197377.0A Expired - Fee Related CN104031428B (en) | 2014-05-12 | 2014-05-12 | A kind of modified nano-titanium dioxide of Stability Analysis of Structures high-specific surface area and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104031428B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115895274A (en) * | 2022-11-24 | 2023-04-04 | 惠州市众恺新材料有限公司 | High-reflection organic silicon composite material composition and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5330953A (en) * | 1992-06-20 | 1994-07-19 | Tioxide Specialties Limited | Preparation of anatase titanium dioxide |
| US20080098932A1 (en) * | 2004-07-30 | 2008-05-01 | Degussa Gmbh | Dispersion containing titanium dioxide |
| CN102352135A (en) * | 2011-08-15 | 2012-02-15 | 无锡豪普钛业有限公司 | Silicon oxide coated titanium dioxide pigment and coating technology |
| EP1989264B1 (en) * | 2006-01-30 | 2012-09-05 | Kronos International, Inc. | Titanium dioxide pigment featuring great opacity, and method for the production thereof |
| CN102993783A (en) * | 2012-10-10 | 2013-03-27 | 道奇威（成都）科技有限公司 | Organic surface modification method for anatase titanium dioxide for polyester synthesis |
-
2014
- 2014-05-12 CN CN201410197377.0A patent/CN104031428B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5330953A (en) * | 1992-06-20 | 1994-07-19 | Tioxide Specialties Limited | Preparation of anatase titanium dioxide |
| US20080098932A1 (en) * | 2004-07-30 | 2008-05-01 | Degussa Gmbh | Dispersion containing titanium dioxide |
| EP1989264B1 (en) * | 2006-01-30 | 2012-09-05 | Kronos International, Inc. | Titanium dioxide pigment featuring great opacity, and method for the production thereof |
| CN102352135A (en) * | 2011-08-15 | 2012-02-15 | 无锡豪普钛业有限公司 | Silicon oxide coated titanium dioxide pigment and coating technology |
| CN102993783A (en) * | 2012-10-10 | 2013-03-27 | 道奇威（成都）科技有限公司 | Organic surface modification method for anatase titanium dioxide for polyester synthesis |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115895274A (en) * | 2022-11-24 | 2023-04-04 | 惠州市众恺新材料有限公司 | High-reflection organic silicon composite material composition and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104031428B (en) | 2016-06-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104031425B (en) | Modified nanometer titanium dioxide with bacteriostatic and antibacterial effects and preparation method thereof | |
| CN104403266B (en) | Calcium carbonate powder modifying agent containing amino resins | |
| CN105925012B (en) | A kind of preparation method of modified superfine powdered whiting | |
| CN104151871B (en) | A kind of porous surface modified nano-titanium dioxide and preparation method thereof | |
| CN104031430B (en) | A kind ofly improve dispersed modified nano-titanium dioxide and preparation method thereof | |
| CN104028245B (en) | A kind of have modified nano-titanium dioxide of better adsorption effect and preparation method thereof | |
| CN102643072B (en) | Nanometer inorganic non-sticking water-based paint and preparation method thereof | |
| CN104031428B (en) | A kind of modified nano-titanium dioxide of Stability Analysis of Structures high-specific surface area and preparation method thereof | |
| CN104140692B (en) | Modified nano-titanium dioxide that a kind of hydrophobic effect is good and preparation method thereof | |
| CN104031429B (en) | A kind of surface-modified nano titanium dioxide with antiageing effect and preparation method thereof | |
| CN104151873B (en) | Modified nano-titanium dioxide of a kind of safety and environmental protection and preparation method thereof | |
| CN104031426B (en) | Surface-modified nanometer titanium dioxide and preparation method thereof | |
| CN104177655B (en) | Modified nano-titanium dioxide that a kind of scattered uvioresistant is effective and preparation method thereof | |
| CN104151870B (en) | Good modified nano-titanium dioxide of a kind of sticking power and preparation method thereof | |
| CN104151874B (en) | Modified nano-titanium dioxide of a kind of wear-resisting enhancing and preparation method thereof | |
| CN102220037B (en) | Method for preparing modified pyrophyllite rubber reinforcing agent | |
| CN104151872B (en) | A kind of surface-modified nano titanium dioxide with high temperature resistant soda acid and preparation method thereof | |
| CN104151875B (en) | A kind of strengthened surface-modified nano titanium dioxide and preparation method thereof | |
| CN104151868A (en) | Modified nano-titanium dioxide with reinforced photocatalytic effect and preparation method thereof | |
| CN104031431B (en) | Modified nano-titanium dioxide that a kind of consistency is good and preparation method thereof | |
| CN106349761A (en) | Abrasion-resistant composite calcium carbonate and preparation method thereof | |
| CN105111790A (en) | Anti-aging effect enhanced modified calcium carbonate and preparation method therefor | |
| CN104151869B (en) | A kind of have modified nano-titanium dioxide of good toughness moisture effect and preparation method thereof | |
| CN104031292B (en) | Modified nanometer titanium dioxide with improved ultraviolet-ray shielding property and preparation method thereof | |
| CN107778752A (en) | A kind of anti-aging modified SBS/coal dust composite and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20160302 Address after: 238131 Anhui Province, Ma'anshan City Industrial Park in Qingxi Hanshan County Applicant after: Zhang Jiajun Address before: 200120 Shanghai City, Pudong New Area Jinhai Road No. 2360 Applicant before: Gu Yu |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20190723 Address after: 528000 Jialiyuan Business and Trade Center, No. 4 Xingye Road, Shunjiang Community Resident Committee, Beijiao Town, Shunde District, Foshan City, Guangdong Province Patentee after: Guangdong Shiquan Ultrafine Technology Co.,Ltd. Address before: 238131 Anhui Province, Ma'anshan City Industrial Park in Qingxi Hanshan County Patentee before: Zhang Jiajun |
|
| TR01 | Transfer of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160608 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |