CN104004603A - Cleaner composition for cleaning surface of rubber and preparation method thereof - Google Patents
Cleaner composition for cleaning surface of rubber and preparation method thereof Download PDFInfo
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- CN104004603A CN104004603A CN201410225212.XA CN201410225212A CN104004603A CN 104004603 A CN104004603 A CN 104004603A CN 201410225212 A CN201410225212 A CN 201410225212A CN 104004603 A CN104004603 A CN 104004603A
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- alcohol
- carbonate
- acetic ester
- preparation
- colophonium powder
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Abstract
The invention discloses a cleaner composition for cleaning the surface of rubber and a preparation method thereof. The composition contains C2-C4 alcohol, C5-C9 acetate, rosin powder, gallic acid and soluble carbonate. The preparation method comprises the step of mixing C2-C4 alcohol, C5-C9 acetate, rosin powder, gallic acid and soluble carbonate. The cleaner composition disclosed by invention has excellent cleaning capacity and is environmental-friendly simultaneously.
Description
Technical field
The present invention relates to sanitising agent field, particularly, relate to a kind of cleanser compositions for clean rubber surface and preparation method thereof.
Background technology
Sanitising agent of the prior art is all generally sanitising agents of broad spectrum type, and the sanitising agent of broad spectrum type is undesirable to the cleaning effect of rubber surface, and easily rubber surface is caused to damage, thereby has aggravated the aging of rubber.Sanitising agent of the prior art contains more volatile objectionable impurities simultaneously, and for example methylene dichloride and trieline are harmful.
Therefore, designing a kind of sanitising agent for clean rubber surface with excellent cleaning capacity and environment-friendly type is this area urgent problem.
Summary of the invention
The object of the invention is to the undesirable and harmful defect of the cleaning effect of rubber surface, provides a kind of cleanser compositions for clean rubber surface with excellent cleaning capacity and environment-friendly type and preparation method thereof in order to overcome sanitising agent in prior art.
To achieve these goals, the invention provides a kind of cleanser compositions for clean rubber surface, wherein, the carbonate of the alcohol that described composition comprises C2-C4, the acetic ester of C5-C9, colophonium powder, gallic acid and solubility.
The present invention also provides a kind of preparation method of the cleanser compositions for clean rubber surface, and wherein, described method is that the carbonate of the acetic ester of the alcohol of C2-C4, C5-C9, colophonium powder, gallic acid and solubility is mixed.
By technique scheme, the present invention is mixed to get sanitising agent by alcohol, acetic ester, colophonium powder and carbonate that raw material is easy to get, and the raw material of this sanitising agent is to human body without injury, and environmental protection has excellent cleaning effect to rubber surface simultaneously.
Other features and advantages of the present invention are described in detail the embodiment part subsequently.
Embodiment
Below the specific embodiment of the present invention is elaborated.Should be understood that, embodiment described herein only, for description and interpretation the present invention, is not limited to the present invention.
The invention provides a kind of cleanser compositions for clean rubber surface, wherein, the carbonate of the alcohol that described composition comprises C2-C4, the acetic ester of C5-C9, colophonium powder, gallic acid and solubility.
In the present invention, the carbonate of the alcohol of C2-C4, the acetic ester of C5-C9 and solubility has wide range of choice, in order to make cleanser compositions there is excellent cleaning capacity, preferably, described acetic ester is n-Amyl acetate, described carbonate is salt of wormwood or sodium carbonate, and described alcohol is ethanol or propyl alcohol, and the particle diameter of described colophonium powder is 0.5-1.5mm.In order to make cleanser compositions have more excellent cleaning capacity, more preferably, described acetic ester is n-Amyl acetate, and described carbonate is sodium carbonate, and described alcohol is ethanol.
In the present invention, there is no particular limitation for the content of the carbonate of the alcohol to C2-C4, the acetic ester of C5-C9, colophonium powder, gallic acid and solubility, in order to make cleanser compositions there is excellent cleaning capacity, preferably, with respect to 100g alcohol, the content of described acetic ester is 0.5-5g, and the content of described carbonate is 0.5-2.5g, the content of described colophonium powder is 0.5-2.5g, and the content of described gallic acid is 4-10g.
The present invention also provides a kind of preparation method of the sanitising agent for clean rubber surface, and the method comprises mixes the carbonate of the acetic ester of the alcohol of C2-C4, C5-C9, colophonium powder and solubility.
In described preparation method, the carbonate of the alcohol of C2-C4, the acetic ester of C5-C9 and solubility has wide range of choice, in order to make cleanser compositions there is excellent cleaning capacity, preferably, described acetic ester is n-Amyl acetate, described carbonate is salt of wormwood or sodium carbonate, and described alcohol is ethanol or propyl alcohol, and the particle diameter of described colophonium powder is 0.5-1.5mm.In order to make cleanser compositions have more excellent cleaning capacity, more preferably, described acetic ester is n-Amyl acetate, and described carbonate is sodium carbonate, and described alcohol is ethanol.
In described preparation method, there is no particular limitation for the consumption of the carbonate of the alcohol to C2-C4, the acetic ester of C5-C9, colophonium powder, gallic acid and solubility, in order to make cleanser compositions there is excellent cleaning capacity, with respect to 100g alcohol, the consumption of described acetic ester is 0.5-5g, the consumption of described carbonate is 0.5-2.5g, and the consumption of described colophonium powder is 0.5-2.5g, and the consumption of described gallic acid is 4-10g.
In described preparation method, described mixing can be carried out also can under the condition not heating, carrying out under the condition of heating, and preferably, the temperature of described mixing is 20-30 DEG C.
In described preparation method, by in the acetic ester of the alcohol of C2-C4, C5-C9, colophonium powder and carbonate mixing process, raw material can be to be mixed together, also can be to mix according to certain filling order, preferably, filling order can be followed successively by alcohol, colophonium powder, acetic ester, Nutgalls acid plus carbonate.
Below will describe the present invention by embodiment.In following examples, the detection of contact angle is undertaken by the SLOOC optics contact angle instrument of Ke Nuo Industrial Co., Ltd of the U.S.; N-Amyl acetate is the product of way Chemical Co., Ltd. of upper Haixing County, sodium carbonate is the product of Henan Zhong Yuan Chemical Co., Ltd., the dehydrated alcohol of ethanol Shanghai Li Wang Chemical Co., Ltd., the product of colophonium powder Zhejiang Lv Feng gac company limited, the product that gallic acid is Nanjing Chemistry Reagent Co., Ltd..
Embodiment 1
At 20 DEG C, the colophonium powder that is 1mm by the particle diameter of 200g ethanol and 1g first mixes, and then once adds 1g n-Amyl acetate, 4g gallic acid and 1g sodium carbonate and mixes, and makes cleanser compositions A1.
Embodiment 2
At 20 DEG C, the colophonium powder that is 1mm by the particle diameter of 200g ethanol and 5g first mixes, and then once adds 10g n-Amyl acetate, 10g gallic acid and 5g sodium carbonate and mixes, and makes cleanser compositions A2.
Embodiment 3
At 20 DEG C, the colophonium powder that is 1mm by the particle diameter of 200g ethanol and 3g first mixes, and then once adds 5g n-Amyl acetate, 7g gallic acid and 3g sodium carbonate and mixes, and makes cleanser compositions A3.
Comparative example 1
Carry out according to the method for embodiment 3, difference is, do not add colophonium powder, makes cleanser compositions B1.
Comparative example 2
Carry out according to the method for embodiment 3, difference is, do not add n-Amyl acetate, makes cleanser compositions B2.
Comparative example 3
Carry out according to the method for embodiment 3, difference is, do not add sodium carbonate, makes cleanser compositions B3.
Comparative example 4
Carry out according to the method for embodiment 3, difference is, do not add gallic acid, makes cleanser compositions B4.
Comparative example 5
Carry out according to the method for embodiment 3, difference is that the consumption of colophonium powder is 7g, makes cleanser compositions B5.
Comparative example 6
Carry out according to the method for embodiment 3, difference is that the consumption of gallic acid is 15g, makes cleanser compositions B6.
Test case
Test case adopts same rubber peel is cut into the fritter that top surface area is identical, then the upper surface of each fritter uses above-mentioned A1-A3 and the B1-B6 of same amount to clean, then measure the contact angle of the fritter of the rubber peel after cleaning with SLOOC optics contact angle instrument, contact angle is less, lyophily is got on the surface of rubber peel, represent that its wettability is better, thereby the cleaning effect of explanation cleanser compositions is better.Detected result is in table 1.
Table 1
| ? | A1 | A2 | A3 | B1 | B2 | B3 | B4 | B5 | B6 |
| Contact angle | 10 | 8 | 9 | 35 | 31 | 34 | 39 | 27 | 30 |
As shown in Table 1, the contact angle of the rubber peel after A1-A3 cleans is significantly less than the contact angle of the rubber peel after B1-B6 cleans, thereby illustrates that cleanser compositions provided by the invention has excellent cleaning effect.
More than describe the preferred embodiment of the present invention in detail; but the present invention is not limited to the detail in above-mentioned embodiment, within the scope of technical conceive of the present invention; can carry out multiple simple variant to technical scheme of the present invention, these simple variant all belong to protection scope of the present invention.
It should be noted that in addition, each concrete technical characterictic described in above-mentioned embodiment, in reconcilable situation, can combine by any suitable mode, for fear of unnecessary repetition, the present invention is to the explanation no longer separately of various possible array modes.
In addition, also can carry out arbitrary combination between various embodiment of the present invention, as long as it is without prejudice to thought of the present invention, it should be considered as content disclosed in this invention equally.
Claims (10)
1. for a cleanser compositions for clean rubber surface, it is characterized in that the carbonate of the alcohol that described composition comprises C2-C4, the acetic ester of C5-C9, colophonium powder, gallic acid and solubility.
2. composition according to claim 1, wherein, described acetic ester is n-Amyl acetate, and described carbonate is salt of wormwood or sodium carbonate, and described alcohol is ethanol or propyl alcohol, and the particle diameter of described colophonium powder is 0.5-1.5mm.
3. composition according to claim 2, wherein, described acetic ester is n-Amyl acetate, and described carbonate is sodium carbonate, and described alcohol is ethanol.
4. composition according to claim 1, wherein, with respect to 100g alcohol, the content of described acetic ester is 0.5-5g, and the content of described carbonate is 0.5-2.5g, and the content of described colophonium powder is 0.5-2.5g, and the content of described gallic acid is 4-10g.
5. for a preparation method for the cleanser compositions of clean rubber surface, it is characterized in that, the method comprises mixes the carbonate of the acetic ester of the alcohol of C2-C4, C5-C9, colophonium powder, gallic acid and solubility.
6. preparation method according to claim 5, wherein, described acetic ester is n-Amyl acetate, and described carbonate is salt of wormwood or sodium carbonate, and described alcohol is ethanol or propyl alcohol, and the particle diameter of described colophonium powder is 0.5-1.5mm.
7. preparation method according to claim 6, wherein, described acetic ester is n-Amyl acetate, and described carbonate is sodium carbonate, and described alcohol is ethanol.
8. preparation method according to claim 5, wherein, with respect to 100g alcohol, the consumption of described acetic ester is 0.5-5g, and the consumption of described carbonate is 0.5-2.5g, and the consumption of described colophonium powder is 0.5-2.5g, and the consumption of described gallic acid is 4-10g.
9. preparation method according to claim 5, wherein, the temperature of described mixing is 20-30 DEG C.
10. preparation method according to claim 5, wherein, by the acetic ester of the alcohol of C2-C4, C5-C9, colophonium powder and carbonate mixing process, filling order is followed successively by alcohol, colophonium powder, acetic ester, Nutgalls acid plus carbonate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201410225212.XA CN104004603A (en) | 2014-05-26 | 2014-05-26 | Cleaner composition for cleaning surface of rubber and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410225212.XA CN104004603A (en) | 2014-05-26 | 2014-05-26 | Cleaner composition for cleaning surface of rubber and preparation method thereof |
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| CN104004603A true CN104004603A (en) | 2014-08-27 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105647692A (en) * | 2016-02-22 | 2016-06-08 | 苏州龙腾万里化工科技有限公司 | Cleaning agent for rubber products |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4199483B2 (en) * | 2002-06-05 | 2008-12-17 | 株式会社金陽社 | Cleaning agent for printing |
| CN101368135A (en) * | 2007-08-15 | 2009-02-18 | 江苏海迅实业集团股份有限公司 | Rubber product detergent |
| CN101535464A (en) * | 2006-11-17 | 2009-09-16 | 西巴控股公司 | Premoistened cleaning disposable substrate |
| CN101981171A (en) * | 2008-04-07 | 2011-02-23 | 埃科莱布有限公司 | Ultra-concentrated liquid degreaser composition |
-
2014
- 2014-05-26 CN CN201410225212.XA patent/CN104004603A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4199483B2 (en) * | 2002-06-05 | 2008-12-17 | 株式会社金陽社 | Cleaning agent for printing |
| CN101535464A (en) * | 2006-11-17 | 2009-09-16 | 西巴控股公司 | Premoistened cleaning disposable substrate |
| CN101368135A (en) * | 2007-08-15 | 2009-02-18 | 江苏海迅实业集团股份有限公司 | Rubber product detergent |
| CN101981171A (en) * | 2008-04-07 | 2011-02-23 | 埃科莱布有限公司 | Ultra-concentrated liquid degreaser composition |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105647692A (en) * | 2016-02-22 | 2016-06-08 | 苏州龙腾万里化工科技有限公司 | Cleaning agent for rubber products |
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Application publication date: 20140827 |