CN103991998A - Heat recycling industrial sewage treatment process and device - Google Patents

Heat recycling industrial sewage treatment process and device Download PDF

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Publication number
CN103991998A
CN103991998A CN201410248861.1A CN201410248861A CN103991998A CN 103991998 A CN103991998 A CN 103991998A CN 201410248861 A CN201410248861 A CN 201410248861A CN 103991998 A CN103991998 A CN 103991998A
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CN
China
Prior art keywords
sewage
water
burner
separator
vapour
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Pending
Application number
CN201410248861.1A
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Chinese (zh)
Inventor
武中臣
孙勇
王希超
杜光勇
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Sino-German Taixing Plain Trade Co Ltd
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Sino-German Taixing Plain Trade Co Ltd
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Application filed by Sino-German Taixing Plain Trade Co Ltd filed Critical Sino-German Taixing Plain Trade Co Ltd
Priority to CN201410248861.1A priority Critical patent/CN103991998A/en
Publication of CN103991998A publication Critical patent/CN103991998A/en
Pending legal-status Critical Current

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Abstract

The invention relates to a heat recycling industrial sewage treatment process and device. The treatment process comprises process steps of preheating, vapor-liquid separation, secondary heating, sewage burning and condensed water evaporation, wherein the sewage burning and the condensed water evaporation both adopt the underwater burning way; the heat recycling industrial sewage treatment device mainly comprises a sewage burner, a steam compressor, a preheater, a separator, an evaporator, a condensed water tank, a condensed water burner, a sewage pump and a discharge pump. According to the heat recycling industrial sewage treatment process and device provided by the invention, the addition of any treatment agent is not required for treatment of industrial sewage, the selective restriction does not exist, heat recycling and low energy consumption are realized, the value of recovered condensed water vapor is close to the sewage treatment cost and no secondary pollution is caused.

Description

Thermal cycling utilizes industrial sewage treatment technology and device
Technical field
The present invention relates to a kind of environmental protection technology and equipment, be specially a kind of thermal cycling and utilize industrial sewage treatment technology and device.
Background technology
Along with rapid development of economy, the sewage environmental pollution aggravation of the enterprise production process relevant to chemical industry, also more prevalent and serious to the harm of human health, in the sewage of wherein particularly discharging in fine chemical product (as pharmacy, dyestuff, daily use chemicals etc.) production process, the material that contains complex structure, poisonous and harmful and biological hard degradation, these wastewater treatment difficulty are very large.At present, the treatment technology of industrial sewage mainly contains following several.
1. the physical method such as filtration method, gravitational settling method and By Bubble-floating Method.Filtration method is to have impurity in the granular pellet layer trap water of hole, is mainly the suspended substance reducing in water; Gravitational settling method is to utilize the precipitable performance of suspended particle in water, and natural subsidence under the effect of gravity field, to reach solid-liquid separation; By Bubble-floating Method is to adsorb the attached method of carrying suspended particle and taking the water surface out of of wrapping up in of micro-bubble by generation.These three kinds of physical method techniques are simple, and convenient management, but can not be applicable to the removal of solubility sewage composition has significant limitation, and leach thing and have secondary pollution.
2. coagulant sedimentation.Coagulant sedimentation is to utilize coagulating agent industrial sewage to be carried out to a kind of method of purifying treatment.Coagulating agent has inorganic polymer flocculant, organic polymer coargulator and biopolymer flocculation agent three major types conventionally.What aspect water treatment, be most widely used at present, is poly-aluminium salt and the compound poly-aluminium salt in inorganic polymer flocculant.Polymerize aluminum chloride (PAC), polyaluminium sulfate (PAS) are industrial most widely used two kinds of poly-aluminium salt.Experiment showed, that PAC has efficient flocculating effect to processing petrochemical wastewater, not only go turbid rate high, little on the pH value impact of former water, after processing, the colourity of water is good, can be used as the flocculation agent of petrifaction sewage recycling.These polyblend aluminium flocculation agents are widely used for processing drinking water, process water, waste water of mine, oil-containing wastewater, domestic water, natural Huanghe water, the Changjiang river Yuan Shui, dyeing waste water etc.But the processing cost of this treatment process sewage per ton is high, throw out also can cause secondary pollution.
3. absorption method.Absorption method is to utilize sorbent material to process sewage.The more sorbent material of current industrial application has magnesium hydroxide, activated cellulose carbon (ACF) and novel sorbent material-chitosan and derivative thereof.Magnesium hydroxide is of wide application as acid industrial sewage treating agent, can, for papermaking and dyeing waste water, city domestic sewage, electroplating wastewater, fluoride waste etc., precipitate grain formation mud, and mud need filter and discharge.
4. biological process, is the organism utilizing in the metabolism Degradation and Transformation sewage of microorganism, makes it innoxious.Low by the biological process running cost of disposing of sewage, operational administrative is simple, but because microorganism there are certain requirements conditions such as nutritive substance, pH value, temperature, is difficult to adapt to that the chemical engineering sewage water yield is large, complicated component, toxicity are high, the feature of difficult degradation, and long processing period, there is secondary pollution in mud.
5. ion-exchange-resin process.Ion exchange resin (IER) is a kind of complex functionality macromolecular material that contains active group, and it is that crosslinked high-molecular copolymer introducing different properties ion-exchange group forms.Ion exchange resin has the functions such as exchange, selection, absorption and catalysis, in industrial sewage is processed, be mainly used in reclaiming heavy metal and your rare metal, purify toxic substance, remove acid or alkaline organic substance in organic sewage as phenol, acid and amine etc.At present, the ion exchange resin using in industrial sewage is processed has anionite-exchange resin, Zeo-karb, amphoteric ion-exchange resin, and range of application is little, has high input, and backwash meeting causes the very large waste of water resources.
6. membrane separation technique.In industrial sewage is processed, using membrane separating technology can be processed various sewage.Because Meteorological is high, treatment capacity is little, can only be used for specific scope.
Summary of the invention
The object of the invention is organic, the inorganics sewage that contains decomposing for the high density producing in current chemical industry, medicine and other fields production process, high salt, difficulty, a kind of sewage treatment process and device are provided, treating processes does not need to add any treatment agent, there is no selectivity restriction, heat recycle, energy consumption is low, non-secondary pollution.
For achieving the above object, the present invention has adopted following scheme: thermal cycling utilizes industrial sewage treatment technology, comprises the following steps:
1, preheating, the sewage in sewage lagoon is pumped into preheater by sump pump, when beginning, sewage does not have preheating directly to enter separator, in the time that the steam of sewage burner enters preheater, sewage obtains entering separator after heating, sewage temperature after preheating reaches 85 DEG C-100 DEG C, becomes water of condensation and enter condensate water pot after steam heat exchange.
2, vapor-liquid separation, the sewage that is preheated device heating enters separator, in separator, produce vapor-liquid separation, steam is extracted out by vapour compressor, after compressed intensification, sends into vaporizer, 80 DEG C-90 DEG C of temperature before vapour compression, compress latter 100 DEG C-110 DEG C, because of the effect of vapour compressor, in separator, present negative pressure, sewage evaporation temperature reduces, and vaporization efficiency improves.
3, second-heating, does not have separative sewage to send into vaporizer by sump pump in separator, with compressed vapour heat exchange, after being heated, returns in separator, and 85 DEG C-100 DEG C of the sewage temperatures after heating, compressed vapour enters condensate water pot after becoming water of condensation.
4, sewage burning, separator bottom high-concentration sewage is sent into sewage burner by discharge pump, the flame of 1050 DEG C-1300 DEG C burns under water, make high strong sewage evaporation and decompose, steam is extracted out by vapour compressor, after compressed intensification, sends into preheater, and residue is discharged by the auger of burner bottom, before vapour compression, 100 DEG C-110 DEG C of temperature, compress latter 120 DEG C-130 DEG C.
5, condensate evaporation, water of condensation in condensate water pot is sent into water of condensation burner by water pump, the flame of 1050 DEG C-1300 DEG C burns under water, make condensate evaporation, wherein a small amount of pollutent thoroughly decomposes, steam is sent into production system after being heated up by vapour compressor compression and is used, and compressed vapour temperature reaches 120 DEG C-130 DEG C.
Thermal cycling utilizes industrial sewage processing unit, mainly by sewage burner, vapour compressor, preheater, separator, vaporizer, condensate water pot, water of condensation burner, sump pump, discharge pump, condensate pump composition, sewage burner vapour outlet connects the first vapour compressor inlet mouth, the first vapour compressor air outlet connects preheater, the first sump pump water-in connects sewage lagoon, the first sump pump water outlet connects preheater water-in, preheater water outlet connects separator, preheater condensation-water drain connects condensate water pot, separator vapour outlet connects the second vapour compressor inlet mouth, the second vapour compressor air outlet connects vaporizer, separator water outlet connects the second sump pump water-in, the second sump pump water outlet connects vaporizer water-in, vaporizer water outlet connects separator water return outlet, evaporator condensation water out connects condensate water pot, the material pump inlet of running in of separator sludge outlet, discharge pump outlet connects sewage burner, condensate water pot outlet connects condensate pump import, condensate pump outlet connects water of condensation burner, water of condensation burner vapour outlet connects the 3rd vapour compressor inlet mouth, the 3rd vapour compressor air outlet connects production system.
Described sewage burner and water of condensation burner are submerged burner.
Owing to having adopted technique scheme, the progress that the present invention obtains is: processing industrial sewage does not need to add any treatment agent, there is no selectivity restriction, heat recycle, energy consumption is low, and the condensed steam of recovery is worth and approaches sewage disposal expense, and non-secondary pollution.
Brief description of the drawings
Fig. 1 is that thermal cycling of the present invention utilizes industrial sewage treatment technology schema,
Fig. 2 is that thermal cycling of the present invention utilizes industrial sewage processing unit structure iron.
In figure: 1, sewage burner, 2, the first vapour compressor, 3, preheater, 4, the first sump pump, 5, sewage lagoon, 6, separator, 7, the second vapour compressor, 8, vaporizer, 9, the second sump pump, 10, discharge pump, 11, condensate water pot, 12, condensate pump, 13, water of condensation burner, 14, the 3rd vapour compressor.
embodiment
Below with embodiment by reference to the accompanying drawings, the invention will be further described.
Embodiment 1
Certain Fine Chemical Works sewage, 3t/h thermal cycling utilizes industrial sewage treatment technology:
The 1st step, preheating, starts the first sump pump, the sewage of sewage lagoon is sent into preheater, sewage enters separator subsequently, starts discharge pump, and sewage is sent into sewage burner, start the gas burner system on burner, flame enters burner and burns under water, and sewage start vaporizer and decomposition start the first vapour compressor, after vapour compression in burner is heated up, send into preheater, the sewage of the preheater of then flowing through is heated.
The 2nd step, vapor-liquid separation, starts the second vapour compressor and the second sump pump, is preheated the sewage of device heating, produces vapor-liquid separation in separator, and steam is extracted out by the second vapour compressor, and compression is sent into vaporizer after heating up.
The 3rd step, second-heating, does not have separative sewage to send into vaporizer by the second sump pump in separator, with compressed vapour heat exchange, after being heated, return in separator, after compressed vapour heat exchange, becomes water of condensation, flows into condensate water pot.
The 4th step, sewage burning, separator bottom high-concentration sewage is sent into sewage burner by discharge pump, under flame interaction, high strong sewage evaporation and decomposition, steam is extracted out by vapour compressor, after compressed intensification, send into preheater, residue is discharged by the auger of burner bottom.
The 5th step, condensate evaporation, start condensate pump, water of condensation burner and the 3rd vapour compressor, water of condensation in condensate water pot is sent into water of condensation burner by water pump, flame burns under water, condensate evaporation, and wherein a small amount of pollutent thoroughly decomposes, steam is sent into production system after being heated up by vapour compressor compression and is used, and compressed vapour temperature can reach 115 DEG C-120 DEG C.
3t/h thermal cycling utilizes industrial sewage processing unit:
The first sump pump, the second sump pump, discharge pump all use DBY-50 surge pump, and condensate pump uses IRG50-160 Piping Centrifugal Pumps; The first vapour compressor, the second vapour compressor all use SR150 water vapour compression machine, and the 3rd vapour compressor uses SR200 water vapour compression machine; Preheater and vaporizer all use BR1.2-150 plate-type interchanger;
Separator adopts stainless steel to be welded, diameter of phi 1700; Condensate water pot adopts 1.6 stainless cylinder of steels; Sewage burner and water of condensation burner all use 3000 type submerged burners, assembling BT17GF gas burner system on it; All pipelines all use stainless steel tube.
This Fine Chemical Works sewage raw water quality situation is as table 1, and distilled water (water of condensation) the water quality situation obtaining after sewage disposal, as table 2, goes out residue composition as table 3. after sewage disposal
Table 1 sewage raw water quality situation:
?
Table 2 distilled water (water of condensation) water quality situation:
Table 3 residue composition:

Claims (3)

1. thermal cycling utilizes industrial sewage treatment technology, it is characterized in that: technique comprises the following steps:
1), preheating, the sewage in sewage lagoon is pumped into preheater by sump pump, when beginning, sewage does not have preheating directly to enter separator, in the time that the steam of sewage burner enters preheater, sewage obtains entering separator after heating, sewage temperature after preheating reaches 85 DEG C-100 DEG C, becomes water of condensation and enter condensate water pot after steam heat exchange;
2), vapor-liquid separation, the sewage that is preheated device heating enters separator, in separator, produce vapor-liquid separation, steam is extracted out by vapour compressor, after compressed intensification, sends into vaporizer, 80 DEG C-90 DEG C of temperature before vapour compression, compress latter 100 DEG C-110 DEG C, because of the effect of vapour compressor, in separator, present negative pressure, sewage evaporation temperature reduces, and vaporization efficiency improves;
3), second-heating, in separator, do not have separative sewage to send into vaporizer by sump pump, with compressed vapour heat exchange, return in separator after heated, 85 DEG C-100 DEG C of the sewage temperatures after heating, compressed vapour enters condensate water pot after becoming water of condensation;
4), sewage burning, separator bottom high-concentration sewage is sent into sewage burner by discharge pump, the flame of 1050 DEG C-1300 DEG C burns under water, make high strong sewage evaporation and decompose, steam is extracted out by vapour compressor, after compressed intensification, sends into preheater, and residue is discharged by the auger of burner bottom, before vapour compression, 100 DEG C-110 DEG C of temperature, compress latter 120 DEG C-130 DEG C;
5), condensate evaporation, water of condensation in condensate water pot is sent into water of condensation burner by water pump, the flame of 1050 DEG C-1300 DEG C burns under water, make condensate evaporation, wherein a small amount of pollutent thoroughly decomposes, steam is sent into production system after being heated up by vapour compressor compression and is used, and compressed vapour temperature reaches 120 DEG C-130 DEG C.
2. thermal cycling utilizes industrial sewage processing unit, mainly by sewage burner (1), vapour compressor (2, 7, 14), preheater (3), separator (6), vaporizer (8), condensate water pot (11), water of condensation burner (13), sump pump (4, 9), discharge pump (10), condensate pump (12) composition, it is characterized in that: sewage burner (1) vapour outlet connects the first vapour compressor (2) inlet mouth, the first vapour compressor (1) air outlet connects preheater (3), the first sump pump (4) water-in connects sewage lagoon (5), the first sump pump (4) water outlet connects preheater (3) water-in, preheater (3) water outlet connects separator (6), preheater (3) condensation-water drain connects condensate water pot (11), separator (6) vapour outlet connects the second vapour compressor (7) inlet mouth, the second vapour compressor (7) air outlet connects vaporizer (8), separator (6) water outlet connects the second sump pump (9) water-in, the second sump pump (9) water outlet connects vaporizer (8) water-in, vaporizer (8) water outlet connects separator (6) water return outlet, vaporizer (8) condensation-water drain connects condensate water pot (11), separator (6) sludge outlet connects discharge pump (10) import, discharge pump (10) outlet connects sewage burner (1), condensate water pot (11) outlet connects condensate pump (12) import, condensate pump (12) outlet connects water of condensation burner (13), water of condensation burner (13) vapour outlet connects the 3rd vapour compressor (14) inlet mouth, the 3rd vapour compressor (14) air outlet connects production system.
3. thermal cycling according to claim 2 utilizes industrial sewage processing unit, it is characterized in that: described sewage burner (1) and water of condensation burner (13) are submerged burner.
CN201410248861.1A 2014-06-06 2014-06-06 Heat recycling industrial sewage treatment process and device Pending CN103991998A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105060597A (en) * 2015-07-30 2015-11-18 天津霍普环保科技有限公司 Purification treatment device for high-salinity organic wastewater
CN105413201A (en) * 2015-11-03 2016-03-23 上海尧兴投资管理有限公司 Self-cleaned evaporator and sewage purification system

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103708669A (en) * 2014-01-02 2014-04-09 德州布兰森药业有限公司 Industrial sewage treatment system

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103708669A (en) * 2014-01-02 2014-04-09 德州布兰森药业有限公司 Industrial sewage treatment system

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105060597A (en) * 2015-07-30 2015-11-18 天津霍普环保科技有限公司 Purification treatment device for high-salinity organic wastewater
CN105413201A (en) * 2015-11-03 2016-03-23 上海尧兴投资管理有限公司 Self-cleaned evaporator and sewage purification system

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Application publication date: 20140820