CN103981691B - A kind of Modification of Cotton Fabric method - Google Patents
A kind of Modification of Cotton Fabric method Download PDFInfo
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- CN103981691B CN103981691B CN201410217404.6A CN201410217404A CN103981691B CN 103981691 B CN103981691 B CN 103981691B CN 201410217404 A CN201410217404 A CN 201410217404A CN 103981691 B CN103981691 B CN 103981691B
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- cotton fabric
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Abstract
The invention discloses a kind of Modification of Cotton Fabric method, comprise the steps: by COTTON FABRIC first through chitosan derivatives modification, and then through Low Temperature Plasma Treating, finally carry out the test of reactive dyeing testing inspection.The present invention is by improving traditional COTTON FABRIC cation modifying technique, adopt the mode that chitosan hydroxyl derivative and Low Temperature Plasma Treating technology combine, modified fiber is strengthened the absorption of the dyestuff of the anionics such as REACTIVE DYES and binding ability, thus improve the dye-uptake of dyestuff, and dyeing uniformity and dyefastness all can meet related request.
Description
Technical field
The invention belongs to textile dyeing and finishing manufacture field, be specifically related to a kind of Modification of Cotton Fabric method.
Background technology
In cotton fabric by utilizing reactive dye dyeing course, dyestuff utilization rate is low, dyestuff runs off large, and REACTIVE DYES is the dyestuff of anionic, and there is certain repulsion between COTTON FABRIC, make dyestuff not easily upper dye, usually will add the neutral electrolyte such as glauber salt, salt to impel the upper dye of dyestuff, if do not add neutral electrolyte, then dye-uptake is low, Color is poor, does not reach desirable colored state.But electrolytical use environmental pollution is serious, and wastewater treatment difficulty is large.
The less salt of current REACTIVE DYES or salt-free dyeing technique by the REACTIVE DYES, the exploitation salt-free dyeing auxiliary that dye under exploitation salt-free conditions and can carry out chemical modification to strengthen the adsorption capacity to dyestuff to fiber.And the cation modifying of COTTON FABRIC is exactly one wherein.The cation modifying technology of COTTON FABRIC, cationizable group can be introduced on cotton fiber, by the introducing of cation group, reduce the Zeta potential on cotton fiber surface, the repulsion between original anionic dyes and fiber can be reduced, greatly improve the dye-uptake of anionic dyes, improve fiber to the absorption of dyestuff and binding ability, reduce the consumption of neutral electrolyte in dyeing course, dyeing can be carried out under less salt or salt-free state, thus minimizing discharge of wastewater, reduce the pollution to environment.
But currently used cation modifying method, there is the cation modifying agent adopted and have harmful effect to environment, or after with cation modifier process, cause uneven dyeing, the problems such as dyefastness is low, carry out modification as adopted epoxies nitrogen-containing compound and can cause certain pollution to environment, the cation modifying agent of picture quaternary ammonium salt then can be high because of reactivity, adsorb too fast and cause the uneven phenomenon that dyes, even if or adopt as this eco-friendly auxiliary agent of shitosan, but it can not be directly water-soluble, and must be dissolved in the acid solutions such as acetic acid and could use, cotton fiber is had a certain impact, though effect is improved but neither be very desirable simultaneously.
Summary of the invention
Goal of the invention: the many deficiencies existed for prior art, the invention provides a kind of Modification of Cotton Fabric method had fewer environmental impacts with better dye uniformity and dyefastness that can use under near-neutral sulfite deinking.
Technical scheme: a kind of Modification of Cotton Fabric method, comprises the steps:
(1) by COTTON FABRIC first through chitosan derivatives modification:
Adopt concentration to be the chitosan derivatives of 0.2%-3%, 80 DEG C time, COTTON FABRIC is put into and wherein flood 10min, then pad, then under the condition of 80-100 DEG C, by COTTON FABRIC preliminary drying 5-10min;
(2) Low Temperature Plasma Treating:
COTTON FABRIC after chitosan derivatives modification is carried out Low Temperature Plasma Treating, described Cement Composite Treated by Plasma is low-tempreture oxygen plasma, processing power 100W, air pressure 30Pa, processing time is 1-5min, it is last under temperature is the condition of 120-150 DEG C, bake 2-3min, obtain required COTTON FABRIC;
(3) reactive dyeing testing inspection test:
A. there is salt dyeing: compound concentration is the reactive golden yellow RGBN of 2%o.w.f; bath raio 1:30; dye liquor temperature is risen to 60 DEG C; the COTTON FABRIC of non-modified process is put into dye liquor, after dyeing 10min, add glauber salt 30g/L; continue dyeing 15min; add soda ash 15g/L, fixation 30min under 60 DEG C of conditions, then neutralize through overpickling, soap and wash;
B. salt-free dyeing: preparation dyeing concentration is the reactive golden yellow RGBN of 2%o.w.f; bath raio 1:30; dye liquor temperature is risen to 60 DEG C; the COTTON FABRIC after modification is put into dye liquor; dyeing 25min; add soda ash 15g/L, fixation 30min under 60 DEG C of conditions, then neutralizes through overpickling, soap and wash;
Whether the K/S value c. both test contrasts, see up to standard.
As optimization: described chitosan derivatives is can the chitosan hydroxyl derivative of direct water-soluble use.
As optimization: described chitosan hydroxyl derivative is hydroxypropyl chitosan.
As optimization: the pick-up that a described leaching one is rolled is 80%-100%.
Beneficial effect: advantage of the present invention is as follows:
1. the present invention is by improving traditional COTTON FABRIC cation modifying technique, adopt the mode that chitosan hydroxyl derivative and Low Temperature Plasma Treating technology combine, modified fiber is strengthened the absorption of the dyestuff of the anionics such as REACTIVE DYES and binding ability, thus improve the dye-uptake of dyestuff, and dyeing uniformity and dyefastness all can meet related request.
2. the present invention is as a kind of Modification of Cotton Fabric method, greatly reduces the electrolyte consumption in Dyeing with Reactive Dyes, can realize salt-free dyeing, decrease the pollution to environment, meets the environmental protection concept advocated now.
3. the chitosan hydroxyl derivative used in the present invention directly can dissolve use with water, and shitosan different from the past carries out the characteristic that modification need use in acid condition, decreases the damage to COTTON FABRIC, simultaneously effect improved also clearly.
4. the present invention is while use chitosan hydroxyl derivative carries out modification, combines lower temperature plasma technology, further increases the dye-uptake of REACTIVE DYES, makes salt-free dyeing treatment effect more obvious, dyeing uniformity also be improved significantly.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention will be described in detail.
Specific embodiment 1:
A kind of Modification of Cotton Fabric method, comprises the steps:
(1) by COTTON FABRIC first through chitosan derivatives modification:
Adopt concentration to be the chitosan derivatives of 0.2%, COTTON FABRIC put into 80 DEG C time and wherein flood 10min, then pad, pick-up is 80%, then under the condition of 80 DEG C, by COTTON FABRIC preliminary drying 5min;
(2) Low Temperature Plasma Treating:
COTTON FABRIC after chitosan derivatives modification is carried out Low Temperature Plasma Treating, described Cement Composite Treated by Plasma is low-tempreture oxygen plasma, processing power 100W, air pressure 30Pa, processing time is 1min, it is last under temperature is the condition of 120 DEG C, bake 2min, obtain required COTTON FABRIC;
(3) reactive dyeing testing inspection test:
A. there is salt dyeing: compound concentration is the reactive golden yellow RGBN of 2%o.w.f; bath raio 1:30; dye liquor temperature is risen to 60 DEG C; the COTTON FABRIC of non-modified process is put into dye liquor, after dyeing 10min, add glauber salt 30g/L; continue dyeing 15min; add soda ash 15g/L, fixation 30min under 60 DEG C of conditions, then through overpickling neutralization and the post processing such as to soap;
B. salt-free dyeing: preparation dyeing concentration is the reactive golden yellow RGBN of 2%o.w.f; bath raio 1:30; dye liquor temperature is risen to 60 DEG C; the COTTON FABRIC after modification is put into dye liquor; dyeing 25min; add soda ash 15g/L, fixation 30min under 60 DEG C of conditions, then through overpickling neutralization and the post processing such as to soap;
Whether the K/S value c. both test contrasts, see up to standard.The K/S value of both tests is carried out contrast and is found, the COTTON FABRIC after modification adopts salt-free dyeing technique substantially identical with the surperficial color depth of the normal dyeing gained fabric of the COTTON FABRIC of non-modified process.Fabric face after observation modification cotton dyeing, and measure washable, rub resistance, sweat stain and the color fastness to water of fabric.DYED FABRICS pure color light, color are even, colourless flower.Washable, rub resistance, sweat stain and color fastness to water all reach more than 4 grades.
Specific embodiment 2:
A kind of Modification of Cotton Fabric method, comprises the steps:
(1) by COTTON FABRIC first through chitosan derivatives modification:
Adopt concentration to be the chitosan derivatives of 3%, COTTON FABRIC put into 80 DEG C time and wherein flood 10min, then pad, pick-up is 100%, then under the condition of 100 DEG C, by COTTON FABRIC preliminary drying 10min;
(2) Low Temperature Plasma Treating:
COTTON FABRIC after chitosan derivatives modification is carried out Low Temperature Plasma Treating, described Cement Composite Treated by Plasma is low-tempreture oxygen plasma, processing power 100W, air pressure 30Pa, processing time is 5min, it is last under temperature is the condition of 150 DEG C, bake 3min, obtain required COTTON FABRIC;
(3) reactive dyeing testing inspection test:
A. there is salt dyeing: compound concentration is the reactive golden yellow RGBN of 2%o.w.f; bath raio 1:30; dye liquor temperature is risen to 60 DEG C; the COTTON FABRIC of non-modified process is put into dye liquor, after dyeing 10min, add glauber salt 30g/L; continue dyeing 15min; add soda ash 15g/L, fixation 30min under 60 DEG C of conditions, then neutralize through overpickling, soap and wash;
B. salt-free dyeing: preparation dyeing concentration is the reactive golden yellow RGBN of 2%o.w.f; bath raio 1:30; dye liquor temperature is risen to 60 DEG C; the COTTON FABRIC after modification is put into dye liquor; dyeing 25min; add soda ash 15g/L, fixation 30min under 60 DEG C of conditions, then neutralizes through overpickling, soap and wash;
Whether the K/S value c. both test contrasts, see up to standard.The K/S value of both tests is carried out contrast and is found, the COTTON FABRIC after modification adopts salt-free dyeing technique compared with the normal dyeing of the COTTON FABRIC of non-modified process, and surperficial color depth improves 49.35%.Fabric face after observation modification cotton dyeing, and measure washable, rub resistance, sweat stain and the color fastness to water of fabric.DYED FABRICS pure color light, color are even, colourless flower.Washable, rub resistance, sweat stain and color fastness to water all reach more than 4 grades.But feel starts slightly to decline.
Wherein, described chitosan derivatives is can the chitosan hydroxyl derivative of direct water-soluble use.
Specific embodiment 3:
A kind of Modification of Cotton Fabric method, comprises the steps:
(1) by COTTON FABRIC first through chitosan derivatives modification:
Adopt concentration to be the chitosan derivatives of 2.5%, COTTON FABRIC put into 80 DEG C time and wherein flood 10min, then pad, pick-up is 90%, then under the condition of 90 DEG C, by COTTON FABRIC preliminary drying 8min;
(2) Low Temperature Plasma Treating:
COTTON FABRIC after chitosan derivatives modification is carried out Low Temperature Plasma Treating, described Cement Composite Treated by Plasma is low-tempreture oxygen plasma, processing power 100W, air pressure 30Pa, processing time is 3min, it is last under temperature is the condition of 135 DEG C, bake 2.5min, obtain required COTTON FABRIC;
(3) reactive dyeing testing inspection test:
A. there is salt dyeing: compound concentration is the reactive golden yellow RGBN of 2%o.w.f; bath raio 1:30; dye liquor temperature is risen to 60 DEG C; the COTTON FABRIC of non-modified process is put into dye liquor, after dyeing 10min, add glauber salt 30g/L; continue dyeing 15min; add soda ash 15g/L, fixation 30min under 60 DEG C of conditions, then neutralize through overpickling, soap and wash;
B. salt-free dyeing: preparation dyeing concentration is the reactive golden yellow RGBN of 2%o.w.f; bath raio 1:30; dye liquor temperature is risen to 60 DEG C; the COTTON FABRIC after modification is put into dye liquor; dyeing 25min; add soda ash 15g/L, fixation 30min under 60 DEG C of conditions, then neutralizes through overpickling, soap and wash;
Whether the K/S value c. both test contrasts, see up to standard.The K/S value of both tests is carried out contrast and is found, the COTTON FABRIC after modification adopts salt-free dyeing technique compared with the normal dyeing of the COTTON FABRIC of non-modified process, and surperficial color depth improves 43.68%.Fabric face after observation modification cotton dyeing, and measure washable, rub resistance, sweat stain and the color fastness to water of fabric.DYED FABRICS pure color light, color are even, colourless flower.Washable, rub resistance, sweat stain and color fastness to water all reach more than 4 grades.
Wherein, described chitosan derivatives is hydroxypropyl chitosan.
Claims (1)
1. a Modification of Cotton Fabric method, is characterized in that: comprise the steps:
(1) by COTTON FABRIC first through chitosan derivatives modification:
Adopt concentration to be the chitosan derivatives of 0.2%-3%, 80 DEG C time, COTTON FABRIC is put into and wherein flood 10min, then pad, then under the condition of 80-100 DEG C, by COTTON FABRIC preliminary drying 5-10min;
(2) Low Temperature Plasma Treating:
COTTON FABRIC after chitosan derivatives modification is carried out Low Temperature Plasma Treating, described Cement Composite Treated by Plasma is low-tempreture oxygen plasma, processing power 100W, air pressure 30Pa, processing time is 1-5min, it is last under temperature is the condition of 120-150 DEG C, bake 2-3min, obtain required COTTON FABRIC;
(3) reactive dyeing testing inspection test:
A. there is salt dyeing: compound concentration is the reactive golden yellow RGBN of 2%o.w.f; bath raio 1:30; dye liquor temperature is risen to 60 DEG C; the COTTON FABRIC of non-modified process is put into dye liquor, after dyeing 10min, add glauber salt 30g/L; continue dyeing 15min; add soda ash 15g/L, fixation 30min under 60 DEG C of conditions, then neutralize through overpickling, soap and wash;
B. salt-free dyeing: preparation dyeing concentration is the reactive golden yellow RGBN of 2%o.w.f; bath raio 1:30; dye liquor temperature is risen to 60 DEG C; the COTTON FABRIC after modification is put into dye liquor; dyeing 25min; add soda ash 15g/L, fixation 30min under 60 DEG C of conditions, then neutralizes through overpickling, soap and wash;
Whether the K/S value c. both test contrasts, see up to standard;
Described chitosan derivatives is can the chitosan hydroxyl derivative of direct water-soluble use;
Described chitosan hydroxyl derivative is hydroxypropyl chitosan;
The pick-up that a described leaching one is rolled is 80%-100%.
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CN105040402A (en) * | 2015-03-05 | 2015-11-11 | 中霖中科环境科技(安徽)股份有限公司 | Method of purifying bacteria in sewage with cotton fibers after chitosan stem grafting |
CN105220481B (en) * | 2015-10-20 | 2018-08-28 | 浙江三德纺织服饰有限公司 | A kind of dedicated Antistatic Fabric of infant-wear |
CN105369587B (en) * | 2015-12-15 | 2017-09-29 | 南通大学 | A kind of method dyed after superhigh molecular weight polyethylene fibers surface treatment |
CN107675324A (en) * | 2017-09-30 | 2018-02-09 | 宁波市鄞州区超锐食品科技有限公司 | Absorb water gas permeability fabric |
CN109056392A (en) * | 2018-06-27 | 2018-12-21 | 凯盛家纺股份有限公司 | A kind of colouring method of natural dye |
CN109355939A (en) * | 2018-10-31 | 2019-02-19 | 宁波广源纺织品有限公司 | A kind of cotton fiber fabric modified dyeing method |
CN110080021A (en) * | 2019-05-13 | 2019-08-02 | 江阴职业技术学院 | A kind of colouring method of cellulose base fiber fabric |
CN110604502B (en) * | 2019-09-18 | 2021-08-10 | 界首市双鑫纺织有限公司 | Mildew-proof towel with high washability and preparation method thereof |
CN115162002B (en) * | 2022-07-21 | 2023-11-24 | 苏州大学 | Full-biological-based cotton fabric and dyeing and finishing method thereof |
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