CN103980641A - High-molecular grounding composite material - Google Patents

High-molecular grounding composite material Download PDF

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Publication number
CN103980641A
CN103980641A CN201310213830.8A CN201310213830A CN103980641A CN 103980641 A CN103980641 A CN 103980641A CN 201310213830 A CN201310213830 A CN 201310213830A CN 103980641 A CN103980641 A CN 103980641A
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CN
China
Prior art keywords
ground connection
sodium
grounding
molecular
composite material
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Pending
Application number
CN201310213830.8A
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Chinese (zh)
Inventor
黄晓光
潘延志
农志良
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Nanning City's Peace Must Be Believed Science And Technology Ltd Co
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Nanning City's Peace Must Be Believed Science And Technology Ltd Co
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Priority to CN201310213830.8A priority Critical patent/CN103980641A/en
Publication of CN103980641A publication Critical patent/CN103980641A/en
Pending legal-status Critical Current

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Abstract

The invention provides a high-molecular grounding composite material. The high-molecular grounding composite material is prepared from raw materials such as sodium carboxymethylcellulose, potassium chloride, anhydrous sodium sulfate, and sodium polyacrylate according to a certain weight ratio. The high-molecular grounding composite material is a high-quality grounding product which is stable in performance, high in water absorbing capacity, excellent in infiltrability, heat resistance characteristics, and shock resistance characteristics; possesses no toxicity or pollution performance; can be added in dry powder states; and possesses excellent protection effects on galvanization-free grounding bodies. The high-molecular grounding composite material accords with national high-quality soil environmental standards, is friendly to the environment and is safe, and is an ideal green environmental protection product. The high-molecular grounding composite material is high in stability, conductivity, corrosion resistance, moisture retention capacity, small in size, and light in weight; is convenient for transportation; and is capable of reducing transportation cost greatly; dissolving or lose is not easily caused; no dust is generated in transportation and construction processes; no health hazard on construction operators is caused; water and stirring equipment are needed for construction; and construction is convenient.

Description

Polymer ground connection mixture
Technical field
The present invention relates to a kind of electric resistance reducing grounding material, especially a kind of polymer ground connection mixture.
Background technology
Recent two decades comes, from the appearance of resistance-lowering material to use, indubitable, for the resistance that reduces grounding device has been brought into play larger effect.Along with the development of electric power network technique, friction reducer develops into physics friction reducer from chemical resistance-reducing agent again, and this can't but be a new leap.The friction reducer main component that existing market is sold is that Graphite Powder 99 or salt add charcoal.Because graphite, salt belong to the ionogen of Yi Rong, run off gradually in the underground immersion meeting that is subject to rainwater, underground water, and chlorion in salt also has corrosive nature to ground connector, also will be because electrolytical loss loses the resistance ability of falling gradually, therefore life-time service is difficult to ensure that it falls the effect of resistance.Meanwhile, the grounding for lightening engineering of the high Mountain area to the dangerously steep transport inconvenience of landform, and restricted place, working-yard, the said products cannot meet construction requirement, and expense is very high, weak effect.In order to solve the grounding for lightening engineering of the inconvenient high Mountain area of the dangerously steep transport of various high soil resistivity and landform, and restricted place, working-yard, just almost cannot reach without ground connection mixture the substation that engineering requires, electric railway, mobile base station, electric power send the earth works such as power transmission and transformation.
Summary of the invention
The object of this invention is to provide a kind of polymer ground connection mixture, its stable performance, nontoxic pollution-free, water-retaining capacity is strong, penetrating power good, heatproof characteristic and impact property excellence, is high quality ground connection product ground connector to good protection effect.
Polymer ground connection mixture be by macromolecule water absorbent material, electronic conductive material, ionic conductor etc. under solid-liquid state, through physical change form a kind of translucent gels body, be physical property environmental protection ground connection product.Its resistance mechanism of falling is, under liquid state from ground connector laterally soil ooze out, after within some minutes, solidifying, play a part to increase diffusing electrode contact area, because polymer ground connection mixture itself is a kind of good conductor, it is used between ground connector and soil, on the one hand can with metal ground connector close contact, reduce the contact resistance of ground connector and soil, enough large current flowing cross sections of formation.On the other hand, it can peripherad soil permeability, reduces the resistivity of soil, forms the low resistance region of a variation around ground connector, thereby significantly expand equivalent diameter and the useful length of ground connector, have positive effect to reducing contact resistance and spreading resistance.Can reach work-ing life more than 20 years, stable performance in its life cycle, does not need maintaining, still can have good ionogen performance and water-absorbent, keeps its good physical chemical mechanism.
The polymer ground connection mixture of my company research is physical property environmental protection ground connection mixture, be by macromolecule water absorbent material, electronic conductive material, ionic conductor etc. under solid-liquid state, a kind of translucent gels body forming through physical change.The features such as solidified nature that utilization itself has, adhesive power, shrinkability, chemical stability, after adding special additive, reach and form the very strong electrolysis free ion of conductive capability, in soil, make soil modification reach the object that reduces soil resistivity thereby permeate.
Bian of the present invention get technical scheme be:
A kind of polymer ground connection mixture, is characterized in that being prepared from by weight proportion by following raw material:
Xylo-Mucine 9-16 part
Repone K 12-18 part
Anhydrous sodium sulphate 25-36 part
White cement 3-6 part
Zinc sulfate 1-4 part
Sodium polyacrylate 20-50 part.
Described Xylo-Mucine is thickening material, and available tapioca (flour), sodium starch glycolate or sodium alginate substitute.
Described Repone K is sylvite ionogen, and available hydrogen potassium oxide, potassium sulfate or Potcrate substitute.
Described anhydrous sodium sulphate is sodium salt electrolyte, hydrophilizing agent, and available sodium carbonate, sodium-chlor or sodium bicarbonate substitute.
Described white cement is tackiness agent, solidifying agent, and available black cement, lime powder or terra alba substitute.
Described zinc sulfate is anticolodal, and available magnesium sulfate substitutes.
Described sodium polyacrylate is absorbent binder, and available polyacrylic acid or polyacrylic ester substitute.
Preparation method is:
1, the rate control of polymer ground connection composite formulations, weighing personnel, having confirmed that raw material can carry out the weighing of material after accurate, must carry out raw-material weighing in strict accordance with the ratio requiring on formula table and blowing order when weighing.
2, having weighed raw material arranges by release sequence (weighing the corresponding starting material packing bag of appropriate to the occasion use package material, in order to avoid clouding confuses).
3, when charging, charging personnel will check load weighted raw material again, and in order not to make any any mistakes, then blowing order is in accordance with regulations put into successively stirrer by raw material and stirred, and in fill process, control the speed of charging well, in order to avoid damage machine.Churning time is controlled at 15 to 20 minutes.B material does not need to stir.
4, sampling inspection at any time, the product through being up to the standards just can packaging and warehousing.
5, expect 0.64 kilogram of/bag of package encapsulation by 1.06 kilograms/bag, packing of product requirement A material, B.Wherein A material is: the mixture of Xylo-Mucine, Repone K, anhydrous sodium sulphate, white cement and zinc sulfate, B material is: sodium polyacrylate.By A material 10 bags, B material 10 bags are put into 25 liters of plastic tanks, build sealing.
6, by good order the plastic tank that the installs product finished product district that is deposited in.And carry out seal approach.
Advantage of the present invention and positively effect are:
1) nontoxic, the free from extraneous odour, corrosion-free, pollution-free of this product; Meet national high-quality soil environmental standard, Environmental Safety, is desirable Green Product.
2) good stability, not soluble and loss.
3) conductive capability is strong, has good electroconductibility.
4) antiseptic property is good, and penetrating power is strong, moisture retention good.
5) volume is little, lightweight, when transport and construction, can not produce dust, very clean; Can not produce the infringement in health to constructing operation personnel yet.Construction only needs to prepare water and stirring tool; Easy construction.
6) convenient transportation, reduces transportation cost greatly, and this product is not limited by or not place, easily takes care of.
Its stable performance of polymer ground connection mixture, nontoxic pollution-free, water-retaining capacity is strong, penetrating power good, heatproof characteristic and impact property excellence, is high quality ground connection product ground connector to good protection effect.
Embodiment
Polymer ground connection composite formulations table of the present invention
Equipment:
In order to obtain uniform finished product, need to use the stirrer that a capacity is 2-3 cubic meter, for the prepare ratio of (referring to example edition below) each composition of the production of polymer ground connection mixture must weigh with industrial scale, error is no more than ± and 5%.
embodiment 1
Formula table 1
Note: wherein A material is: the mixture of Xylo-Mucine, Repone K, anhydrous sodium sulphate, white cement and zinc sulfate
b material is: sodium polyacrylate
A material release sequence (by 1 ton of calculating of a stove):
Preparation method is:
1, the rate control of polymer ground connection composite formulations, weighing personnel, having confirmed that raw material can carry out the weighing of material after accurate, must carry out raw-material weighing in strict accordance with the ratio requiring on formula table and blowing order when weighing.
2, having weighed raw material arranges by release sequence (weighing the corresponding starting material packing bag of appropriate to the occasion use package material, in order to avoid clouding confuses).
3, when charging, charging personnel will check load weighted raw material again, and in order not to make any any mistakes, then blowing order is in accordance with regulations put into successively stirrer by raw material and stirred, and in fill process, control the speed of charging well, in order to avoid damage machine.Churning time is controlled at 15 to 20 minutes.B material does not need to stir.
4, sampling inspection at any time, the product through being up to the standards just can packaging and warehousing.
5, expect 0.64 kilogram of/bag of package encapsulation by 1.06 kilograms/bag, packing of product requirement A material, B.By A material 10 bags, B material 10 bags are put into 25 liters of plastic tanks, build sealing.
6, by good order the plastic tank that the installs product finished product district that is deposited in.And carry out seal approach.
embodiment 2
Formula table 2
A material release sequence (by 1 ton of calculating of a stove):
Preparation method is as embodiment 1.
embodiment 3
Formula table 3
A material release sequence (by 1 ton of calculating of a stove):
Preparation method is as embodiment 1.
embodiment 4
Formula table 4
A material release sequence (by 1 ton of calculating of a stove):
Preparation method is as embodiment 1.
embodiment 5
Formula table 5
A material release sequence (by 1 ton of calculating of a stove):
Preparation method is as embodiment 1.
The present invention formulates DL/T 380-2010 " grounded resistance reducing agent MAT'L specification ", GB 6566 " radioactive material nucleic limitation ", GB/T 16927 " high-voltage test techniques " (GB/T 16927.1-1997 according to national power industry standard, IEC 60060-1:1989, EQV, GB/T16927.2-1997, IEC 60060-2:1994, EQV), the standard-required such as NY 5010 " pollution-free food vegetables home environment condition " and DL/T 621 " ground connection of alternating-current electric device " carries out experimental test.The present invention all meets or exceeds Country family's standard.
Specific as follows:
The mixture test requirements document of table 1 polymer ground connection and test subject
Table 2 polymer ground connection mixture technical parameter

Claims (7)

1. a polymer ground connection mixture, is characterized in that being prepared from by weight proportion by following raw material:
Xylo-Mucine 9-16 part
Repone K 12-18 part
Anhydrous sodium sulphate 25-36 part
White cement 3-6 part
Zinc sulfate 1-4 part
Sodium polyacrylate 20-50 part.
2. polymer ground connection mixture as claimed in claim 1, is characterized in that: described Xylo-Mucine is thickening material, and available tapioca (flour), sodium starch glycolate or sodium alginate substitute.
3. polymer ground connection mixture as claimed in claim 1, is characterized in that: described Repone K is sylvite ionogen, and available hydrogen potassium oxide, potassium sulfate or Potcrate substitute.
4. polymer ground connection mixture as claimed in claim 1, is characterized in that: described anhydrous sodium sulphate is sodium salt electrolyte, hydrophilizing agent, and available sodium carbonate, sodium-chlor or sodium bicarbonate substitute.
5. polymer ground connection mixture as claimed in claim 1, is characterized in that: described white cement is tackiness agent, solidifying agent, and available black cement, lime powder or terra alba substitute.
6. polymer ground connection mixture as claimed in claim 1, is characterized in that: described zinc sulfate is anticolodal, and available magnesium sulfate substitutes.
7. polymer ground connection mixture as claimed in claim 1, is characterized in that: described sodium polyacrylate is absorbent binder, and available polyacrylic acid or polyacrylic ester substitute.
CN201310213830.8A 2013-05-31 2013-05-31 High-molecular grounding composite material Pending CN103980641A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310213830.8A CN103980641A (en) 2013-05-31 2013-05-31 High-molecular grounding composite material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201310213830.8A CN103980641A (en) 2013-05-31 2013-05-31 High-molecular grounding composite material

Publications (1)

Publication Number Publication Date
CN103980641A true CN103980641A (en) 2014-08-13

Family

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Family Applications (1)

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CN201310213830.8A Pending CN103980641A (en) 2013-05-31 2013-05-31 High-molecular grounding composite material

Country Status (1)

Country Link
CN (1) CN103980641A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107140885A (en) * 2017-05-12 2017-09-08 卢国友 A kind of leakproof protection against electric shock coating formula and its application method
CN107429163A (en) * 2015-03-30 2017-12-01 日本制纸株式会社 Soil solidification composition
CN107622813A (en) * 2017-08-31 2018-01-23 嘉兴嘉合电力设备有限公司 Soil friction reducer

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107429163A (en) * 2015-03-30 2017-12-01 日本制纸株式会社 Soil solidification composition
CN107140885A (en) * 2017-05-12 2017-09-08 卢国友 A kind of leakproof protection against electric shock coating formula and its application method
CN107622813A (en) * 2017-08-31 2018-01-23 嘉兴嘉合电力设备有限公司 Soil friction reducer

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Application publication date: 20140813