CN103979996A - Preparation method of lightweight thermal-insulation decoration surface material for outer wall - Google Patents
Preparation method of lightweight thermal-insulation decoration surface material for outer wall Download PDFInfo
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- CN103979996A CN103979996A CN201410172942.8A CN201410172942A CN103979996A CN 103979996 A CN103979996 A CN 103979996A CN 201410172942 A CN201410172942 A CN 201410172942A CN 103979996 A CN103979996 A CN 103979996A
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- 239000000463 material Substances 0.000 title claims abstract description 96
- 238000009413 insulation Methods 0.000 title claims abstract description 23
- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- 238000005034 decoration Methods 0.000 title abstract description 7
- 239000002699 waste material Substances 0.000 claims abstract description 66
- 239000000919 ceramic Substances 0.000 claims abstract description 26
- 239000002689 soil Substances 0.000 claims abstract description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 238000004519 manufacturing process Methods 0.000 claims description 24
- 239000000758 substrate Substances 0.000 claims description 21
- 238000000498 ball milling Methods 0.000 claims description 9
- 238000000465 moulding Methods 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- 239000004411 aluminium Substances 0.000 claims description 4
- 238000010304 firing Methods 0.000 claims description 4
- 238000007639 printing Methods 0.000 claims description 4
- 239000003595 mist Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 abstract description 16
- 238000009826 distribution Methods 0.000 abstract description 4
- 238000002156 mixing Methods 0.000 abstract description 3
- 239000011148 porous material Substances 0.000 abstract description 3
- 239000002994 raw material Substances 0.000 abstract description 3
- 238000005245 sintering Methods 0.000 abstract description 3
- 238000010521 absorption reaction Methods 0.000 abstract description 2
- 239000004575 stone Substances 0.000 abstract description 2
- 239000008187 granular material Substances 0.000 abstract 15
- 239000008188 pellet Substances 0.000 abstract 15
- 238000005452 bending Methods 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 230000005484 gravity Effects 0.000 abstract 1
- 238000004062 sedimentation Methods 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 8
- 238000010276 construction Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 238000005187 foaming Methods 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000002344 surface layer Substances 0.000 description 3
- 238000005299 abrasion Methods 0.000 description 2
- 230000001680 brushing effect Effects 0.000 description 2
- 238000005253 cladding Methods 0.000 description 2
- 238000004134 energy conservation Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 239000002893 slag Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 235000019832 sodium triphosphate Nutrition 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 101710194948 Protein phosphatase PhpP Proteins 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000000378 calcium silicate Substances 0.000 description 1
- 229910052918 calcium silicate Inorganic materials 0.000 description 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
- 238000004814 ceramic processing Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
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- 239000006260 foam Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000012774 insulation material Substances 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 235000015250 liver sausages Nutrition 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 239000002910 solid waste Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
- 238000004017 vitrification Methods 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
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- Finishing Walls (AREA)
Abstract
The invention provides a preparation method of a lightweight thermal-insulation decoration surface material for outer wall, and the method is characterized by comprising the following steps: firstly, adopting ceramic green body waste material, Laiyang soil, sedimentation tank waste material, polished tile waste residue and the like as raw materials respectively at different mass ratios to obtain four types of pellet granules, namely A pellet granule, B pellet granule, C pellet granule and D pellet granule; then uniformly mixing the A pellet granule, the B pellet granule and the C pellet granule according to a mass ratio of A pellet granule to B pellet granule to C pellet granule of 1:2:1, then uniformly distributing the pellet granules in the concavo-convex mold, and paving the surface with a layer of D pellet granule as a base material, obtaining a green body under a pressure of 220 MPa after the process of second material distributing, wherein the mass ratio of the base material D pellet granule to the other three pellet granules is 1-3:10; and sequentially performing the process of drying, jet drawing patterns and sintering so as to obtain the lightweight thermal-insulation decoration surface material for outer wall. Test results show that the lightweight thermal-insulation decoration surface material for outer wall has characteristics of low specific gravity, uniform pore size distribution, low water absorption, high bending strength and low thermal conductivity. The decoration surface material has high wear resistance and enables demonstration of the appearance of stone.
Description
Technical field
The production method that the invention provides a kind of exterior wall light heat insulation facing material, belongs to ceramic processing technique field.
Background technology
For a long time, building trade is the energy, resource consumption rich and influential family, environmental protection, material-saving, energy-conservation and consumption reduction are the primary goals of the sector Sustainable development, therefore development of new environmental protection and energy saving materials for wall, and the heat insulation effect that improves exterior wall has important realistic meaning to building energy conservation.Current wall body structure is mainly with organic heat-insulating and exterior wall finish material composition, and organic insulation material is inflammable, uses to construction and later stage and brings very large hidden danger; Exterior wall finish material weight is large, adopts cladding form, and executive cost is high, easily falls.Therefore need development to integrate the exterior wall finishing material of lightweight, insulation and decorate properties.
Pottery has a large amount of waste materials in process of production, the whole nation just has nearly 1,000 ten thousand tons every year, in aluminum oxide production process, can discharge waste red mud residues, the red mud of annual discharge is up to millions of tons, the technology that develops this type of waste material production stupalith both can realize material-saving target, can solve again the impact on environment aspect that the long-term accumulation of waste material brings.Chinese patent CN102295471A has announced and has mixed with polishing pitchers 60-100%, adulterant 0-40% (adulterant is selected one or more the mixture in china clay in powder, ceramic broken material and slag ash) and water, compression moulding, the expanded 2-12 hour of roasting at dry in tunnel furnace, preheating, 950-1100 DEG C, the panel density of acquisition is 0.45g/cm
3, thermal conductivity is 0.13W/ (mK), 30mm cubic compressive strength is 2.5MPa.Maturing temperature is low causes the intensity of vitreous material not low, and high-temperature time is long, and production efficiency is low, and after the mixing moulding that adds water in addition, green compact are yielding, broken.In Chinese patent CN101182232B, announced 30-90% vitrified tile polished waste material, be no more than 10% clay, 10-70% reclaims useless green compact or useless powder, appropriate sodium cellulose glycolate and tripoly phosphate sodium STPP add ball milling in ball mill; dry powder after spraying utilizes press to be pressed into plane section bar; after dry, 1185-1265 DEG C is burnt till, and density is greater than 1.3g/cm
3, strength at break > 800N (600mm × 600mm × 15mm), the proportion of sheet material is greater than water, and intensity is also low.Chinese patent CN102249694A has announced and has utilized the solid waste of ceramics factory and the mud that sewage work produces, and utilizes the foam performance of polishing slag (15-70%) to produce light ceramics, and proportion is 0.453-0.725g/cm
3, folding strength is 3-12MPa, the poor dimensional stability of pottery, and linear expansivity reaches 16.7-28.5%, and water-intake rate is up to 3.0-5.0%.Chinese patent CN102503507B has announced one and has utilized red mud for main raw material burns till at 600-1200 DEG C after ball mill mixing, after cutting, obtains red mud light-weight wall material, and this material also needs the construction of decoration aspect while use as external wall decorative material.
Above-mentioned the mentioned light material that does not adopt additional whipping agent and only utilize ceramic waste material to produce has distinct disadvantage; after major cause is to determine in the single basestocks with ceramic waste material preparation that air release, pore in high temperature vitreous process are grown up and the component of base substrate high temperature viscosity determines completely; restriction mutually between the pore structure (size, connective and distribution) of material and performance (proportion, water-intake rate, dimensional stability, heat insulation effect and mechanical property), is difficult to reach best effect.The decorate properties of the material of producing also has problems, main manifestations is the non-constant of surface abrasion resistance, production, packaging, transport and construction to material can bring very large difficulty, when this is because burns till, bubble easily floats and obviously grows up in high-temperature fusant, and the partially thin and inhomogeneous Surface Wear Resistance of Materials that causes of hole wall can reduce.Easily fluctuate with the variation of production technique and produce the ceramic waste material composition of selecting, this is by very large to the technogenic influence that adopts single distribution production light material, and it is unstable that the performance of product will become.
Summary of the invention
The object of this invention is to provide a kind of production method that can overcome above-mentioned defect, adopt multiple basestocks to mix the method for manufacturing pelletizing feed grain secondary material distributing, the material of manufacture has the production method of a kind of exterior wall light heat insulation facing material of lightweight, insulation, high strength, low water absorption and decorative effect.Its technical scheme is:
A production method for light heat insulation facing material for exterior wall, is characterized in that adopting following steps:
1) preparation of group's ball material grain: the quality of basestocks A is 60 parts of 10 parts, ceramic green waste material, 20 parts, Laiyang soil, 10 parts, settling tank waste material and waste residues of polished tiles than component; The quality of basestocks B is 25 parts, 25 parts, 10 parts, ceramic green waste material, Laiyang soil, 10 parts, settling tank waste material, 30 parts of waste residues of polished tiles and civilian ancestral soil than component; The quality of basestocks C is 50 parts of 25 parts, 15 parts, ceramic green waste material, Laiyang soil, 10 parts, settling tank waste material and waste residues of polished tiles than component; The quality of basestocks D is 58 parts of 5 parts, 10 parts, ceramic green waste material, Laiyang soil, 5 parts, settling tank waste material, 10 parts of waste residues of polished tiles, 12 parts, civilian ancestral soil and mountain aluminium red muds than component, above-mentioned each basestocks is added water respectively and carries out ball milling 12-16 hour, the mass ratio of water and basestocks is 38: 100, the group's of manufacture ball material grain;
2) moulding: basestocks A group ball material grain, basestocks B group's ball material grain and basestocks C group ball material grain are mixed with the mass ratio of 1: 2: 1, be distributed in concave-convex mold, and then lay one deck basestocks D in the above and roll into a ball ball material grain, the mass ratio of basestocks D group's ball material grain and above-mentioned three kinds of group's ball material grains is 1～3: 10, under the pressure of 220MPa, is pressed into base substrate;
3) dry: by step 2) base substrate that obtains 80～110 DEG C dry 15～30 minutes, obtain dry base substrate;
4) printing pattern: utilize ink-jet printer printing pattern once or repeatedly on dry base substrate basestocks D group ball material granulosa;
5) burn till: in roller kiln, burn till through 1170-1260 DEG C, firing period is 50～70 minutes, obtains exterior wall light heat insulation facing material.
The production method of light heat insulation facing material for described a kind of exterior wall, step 1) in, the basestocks adding after water for ball milling is rolled into a ball ball material grain by mist projection granulating, pelletizer or manual mode manufacture.
Compared with prior art, its advantage is in the present invention:
(1) make full use of ceramic industry waste residue and waste material foaming, the waste red mud residues that simultaneously utilizes Alumina Enterprise to discharge, realizes saving resource, turns waste into wealth;
(2) by the form of group's ball material proportioning, and group's ball material is made up of the ceramic industry waste residue and the waste material that contain foaming ingredient, ensure uniform in foaming, in pate dure process, the generation of bubble and the behavior meeting of growing up are subject to the collaborative constraint of base substrate skeleton, can realize the controllability that inner void distributes;
(3) dry base substrate is in the sintering procedure of roller kiln, various ball material grains can generate the different crafters in aperture, and utilize different basestocks Collaborative Control to crafters structure evolution process under vitrification point, the impact of the component difference that greatly reduces ceramic waste material and red mud raw material on production technique and material property;
(4) by the proportioning of group's ball material grain, improve the porosity of material, proportion I is lightening material own wt greatly, directly adopts bonding method in construction process, but not cladding form is significantly saved artificial and Master Cost;
(5) exterior wall burning till is not communicated with the hole of light heat insulation facing material internal, thermal conductivity is low, can realize heat insulation effect, can ensure the strength of materials and the cohesive strength with external wall thereof simultaneously, water-intake rate is low reduces the destruction that rain erosion and freeze-thaw cycle bring, thereby ensures long service life under weather condition;
(6) by the mode of secondary material distributing, arrange the high group's ball material grain of red mud content at surface layer, utilize the high feature of sodium element content in red mud, make to produce the high-content glassiness in the inherent sintering process of base substrate, and the composition of regulation and control group ball material grain can be controlled high temperature bubble and generate and the process of growing up, make surface layer hole wall even, form the effect structure of similar multicellular glass, can ensure the wear resisting property of material, secondary material distributing is conducive to surface layer simultaneously has good coupling with base substrate and glaze on thermal expansivity, contributes to realize surface decoration effect;
(7) use of ink-jet printer can improve the naturalness of outward appearance and decorative effect, realizes the aesthetic of exterior wall light heat insulation facing material.
Embodiment
Embodiment 1, adopts following steps:
Step 1) preparation of group's ball material grain: the quality of basestocks A is 60 parts of 10 parts, ceramic green waste material, 20 parts, Laiyang soil, 10 parts, settling tank waste material and waste residues of polished tiles than component; The quality of basestocks B is 25 parts, 25 parts, 10 parts, ceramic green waste material, Laiyang soil, 10 parts, settling tank waste material, 30 parts of waste residues of polished tiles and civilian ancestral soil than component; The quality of basestocks C is 50 parts of 25 parts, 15 parts, ceramic green waste material, Laiyang soil, 10 parts, settling tank waste material and waste residues of polished tiles than component; The quality of basestocks D is 58 parts of 5 parts, 10 parts, ceramic green waste material, Laiyang soil, 5 parts, settling tank waste material, 10 parts of waste residues of polished tiles, 12 parts, civilian ancestral soil and mountain aluminium red muds than component, above-mentioned each basestocks is added water respectively and carries out ball milling 12 hours, the mass ratio of water and basestocks is 38: 100, the group's of manufacture ball material grain.The basestocks adding after water for ball milling is manufactured a ball material grain by the mode of mist projection granulating.
Step 2) moulding: basestocks A group ball material grain, basestocks B group's ball material grain and basestocks C group ball material grain are mixed with the mass ratio of 1: 2: 1, be distributed in concave-convex mold, and then lay one deck basestocks D in the above and roll into a ball ball material grain, the mass ratio of basestocks D group's ball material grain and above-mentioned three kinds of group's ball material grains is 1: 10, under the pressure of 220MPa, is pressed into base substrate;
Step 3) dry: by step 2) base substrate that obtains 80 DEG C dry 30 minutes, obtain dry base substrate;
Step 4) spray patterns: utilize ink-jet printer secondary air brushing glaze on dry base substrate basestocks D group ball material granulosa, form pattern;
Step 5) burn till: in roller kiln, burn till through 1260 DEG C, firing period is 50 minutes, obtains exterior wall light heat insulation facing material.
Embodiment 2, adopts following steps:
Step 1) preparation of group's ball material grain: the quality of basestocks A is 60 parts of 10 parts, ceramic green waste material, 20 parts, Laiyang soil, 10 parts, settling tank waste material and waste residues of polished tiles than component; The quality of basestocks B is 25 parts, 25 parts, 10 parts, ceramic green waste material, Laiyang soil, 10 parts, settling tank waste material, 30 parts of waste residues of polished tiles and civilian ancestral soil than component; The quality of basestocks C is 50 parts of 25 parts, 15 parts, ceramic green waste material, Laiyang soil, 10 parts, settling tank waste material and waste residues of polished tiles than component; The quality of basestocks D is 58 parts of 5 parts, 10 parts, ceramic green waste material, Laiyang soil, 5 parts, settling tank waste material, 10 parts of waste residues of polished tiles, 12 parts, civilian ancestral soil and mountain aluminium red muds than component, above-mentioned each basestocks is added water respectively and carries out ball milling 16 hours, the mass ratio of water and basestocks is 38: 100, the group's of manufacture ball material grain.The basestocks adding after water for ball milling is manufactured a ball material grain by the mode of pelletizer.
Step 2) moulding: basestocks A group ball material grain, basestocks B group's ball material grain and basestocks C group ball material grain are mixed with the mass ratio of 1: 2: 1, be distributed in concave-convex mold, and then lay one deck basestocks D in the above and roll into a ball ball material grain, the mass ratio of basestocks D group's ball material grain and above-mentioned three kinds of group's ball material grains is 3: 10, under the pressure of 220MPa, is pressed into base substrate;
Step 3) dry: by step 2) base substrate that obtains 110 DEG C dry 15 minutes, obtain dry base substrate;
Step 4) spray patterns: utilize ink-jet printer secondary air brushing glaze on dry base substrate basestocks D group ball material granulosa, form pattern;
Step 5) burn till: in roller kiln, burn till through 1170 DEG C, firing period is 70 minutes, obtains exterior wall light heat insulation facing material.
The test data of twice embodiment gained finishing material of the present invention and existing dalle is as shown in the table:
| Material | Proportion (g/cm 3) | Thermal conductivity (W/ (mK)) | Flexural strength (MPa) | Water-intake rate |
| Embodiment 1 | 0.83 | 0.089 | 16 | 0.2％ |
| Embodiment 2 | 0.55 | 0.043 | 12 | 0.09％ |
| Plasterboard | ≤1.0 | ～0.30 | ≥1.5 | Meet water decomposition |
| Calcium silicate board | ≥1.40 | ～0.20 | ≥12 | ≥30％ |
| Polyurethane sheet | 0.04～0.06 | 0.02～0.026 | 0.2～0.3 | ≤3％ |
| Polystyrene board | 0.018～0.025 | 0.039～0.042 | ≥0.1 | ≤1.7％ |
Test data shows, the exterior wall that the present invention makes is little with light heat insulation facing material proportion, even aperture distribution, and water-intake rate is low, and flexural strength is high, and thermal conductivity is low.Surface abrasion resistance is high, and can show the outward appearance of stone material.
Claims (2)
1. a production method for light heat insulation facing material for exterior wall, is characterized in that adopting following steps:
1) preparation of group's ball material grain: the quality of basestocks A is 60 parts of 10 parts, ceramic green waste material, 20 parts, Laiyang soil, 10 parts, settling tank waste material and waste residues of polished tiles than component; The quality of basestocks B is 25 parts, 25 parts, 10 parts, ceramic green waste material, Laiyang soil, 10 parts, settling tank waste material, 30 parts of waste residues of polished tiles and civilian ancestral soil than component; The quality of basestocks C is 50 parts of 25 parts, 15 parts, ceramic green waste material, Laiyang soil, 10 parts, settling tank waste material and waste residues of polished tiles than component; The quality of basestocks D is 58 parts of 5 parts, 10 parts, ceramic green waste material, Laiyang soil, 5 parts, settling tank waste material, 10 parts of waste residues of polished tiles, 12 parts, civilian ancestral soil and mountain aluminium red muds than component, above-mentioned each basestocks is added water respectively and carries out ball milling 12-16 hour, the mass ratio of water and basestocks is 38: 100, the group's of manufacture ball material grain;
2) moulding: basestocks A group ball material grain, basestocks B group's ball material grain and basestocks C group ball material grain are mixed with the mass ratio of 1: 2: 1, be distributed in concave-convex mold, and then lay one deck basestocks D in the above and roll into a ball ball material grain, the mass ratio of basestocks D group's ball material grain and above-mentioned three kinds of group's ball material grains is 1～3: 10, under the pressure of 220MPa, is pressed into base substrate;
3) dry: by step 2) base substrate that obtains 80～110 DEG C dry 15～30 minutes, obtain dry base substrate;
4) printing pattern: utilize ink-jet printer printing pattern once or repeatedly on dry base substrate basestocks D group ball material granulosa;
5) burn till: in roller kiln, burn till through 1170～1260 DEG C, firing period is 50～70 minutes, obtains exterior wall light heat insulation facing material.
2. the production method of light heat insulation facing material for a kind of exterior wall as claimed in claim 1, is characterized in that: step 1) in, the basestocks adding after water for ball milling is rolled into a ball ball material grain by mist projection granulating, pelletizer or manual mode manufacture.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104727450A (en) * | 2015-02-15 | 2015-06-24 | 宁夏黑金科技有限公司 | High-strength microcrystal foaming fireproof heat preservation plate produced by using argil and production technology thereof |
| CN104788118A (en) * | 2015-02-15 | 2015-07-22 | 宁夏黑金科技有限公司 | High-strength microcrystal foaming fireproof thermal-insulation plate produced by using aeolian sand, and production process thereof |
| CN108585780A (en) * | 2018-05-07 | 2018-09-28 | 山东理工大学 | Utilize the method for the spontaneous brewed standby high intensity low heat conductivity construction material of red mud tile polished waste |
| CN110698220A (en) * | 2019-11-12 | 2020-01-17 | 山东理工大学 | Method for firing lightweight porcelain plate for exterior wall decoration by using roller kiln |
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| CN102503507A (en) * | 2011-10-19 | 2012-06-20 | 山东理工大学 | Novel preparation method of red mud light-weight wall material |
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| CN104727450A (en) * | 2015-02-15 | 2015-06-24 | 宁夏黑金科技有限公司 | High-strength microcrystal foaming fireproof heat preservation plate produced by using argil and production technology thereof |
| CN104788118A (en) * | 2015-02-15 | 2015-07-22 | 宁夏黑金科技有限公司 | High-strength microcrystal foaming fireproof thermal-insulation plate produced by using aeolian sand, and production process thereof |
| CN104727450B (en) * | 2015-02-15 | 2016-10-05 | 宁夏黑金科技有限公司 | Utilize high intensity crystallite foaming fire preventing and heat insulating board and production technology thereof that potter's clay produces |
| CN108585780A (en) * | 2018-05-07 | 2018-09-28 | 山东理工大学 | Utilize the method for the spontaneous brewed standby high intensity low heat conductivity construction material of red mud tile polished waste |
| CN110698220A (en) * | 2019-11-12 | 2020-01-17 | 山东理工大学 | Method for firing lightweight porcelain plate for exterior wall decoration by using roller kiln |
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| CN103979996B (en) | 2015-05-27 |
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Effective date of registration: 20190619 Address after: 255100 South Road of Building Materials City, Zichuan District, Zibo City, Shandong Province Patentee after: Zibo Jinshiwang ceramic science and Technology Group Co. Ltd. Address before: 255100 Zibo Zichuan Yangzhai Building Material City, Zibo City, Shandong Province, Jinshiwang Science and Technology Ceramics Co., Ltd. Co-patentee before: Yuan Dongfeng Patentee before: Yao Qiheng |