CN103949153B - A kind of method and device utilizing light to help Fenton's reaction purifying smoke - Google Patents
A kind of method and device utilizing light to help Fenton's reaction purifying smoke Download PDFInfo
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- CN103949153B CN103949153B CN201410166086.5A CN201410166086A CN103949153B CN 103949153 B CN103949153 B CN 103949153B CN 201410166086 A CN201410166086 A CN 201410166086A CN 103949153 B CN103949153 B CN 103949153B
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- luminous energy
- fenton
- warehouse
- reaction
- energy storehouse
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- 238000006243 chemical reaction Methods 0.000 title claims abstract description 101
- 238000000034 method Methods 0.000 title claims abstract description 51
- 239000000779 smoke Substances 0.000 title claims abstract description 37
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 claims abstract description 54
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims abstract description 34
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 25
- 238000004140 cleaning Methods 0.000 claims abstract description 25
- 239000008187 granular material Substances 0.000 claims abstract description 20
- 229910002092 carbon dioxide Inorganic materials 0.000 claims abstract description 18
- 239000001569 carbon dioxide Substances 0.000 claims abstract description 17
- 239000001117 sulphuric acid Substances 0.000 claims abstract description 17
- 235000011149 sulphuric acid Nutrition 0.000 claims abstract description 17
- 239000007788 liquid Substances 0.000 claims description 71
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 49
- 238000000746 purification Methods 0.000 claims description 44
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 40
- 239000003546 flue gas Substances 0.000 claims description 31
- 239000012028 Fenton's reagent Substances 0.000 claims description 24
- 239000007789 gas Substances 0.000 claims description 24
- 229910052751 metal Inorganic materials 0.000 claims description 24
- 239000002184 metal Substances 0.000 claims description 24
- 239000007921 spray Substances 0.000 claims description 19
- 239000003344 environmental pollutant Substances 0.000 claims description 16
- 231100000719 pollutant Toxicity 0.000 claims description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- 229910001868 water Inorganic materials 0.000 claims description 16
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 13
- 229910052799 carbon Inorganic materials 0.000 claims description 13
- 238000010521 absorption reaction Methods 0.000 claims description 12
- 239000004215 Carbon black (E152) Substances 0.000 claims description 11
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 11
- 229930195733 hydrocarbon Natural products 0.000 claims description 11
- 150000002430 hydrocarbons Chemical class 0.000 claims description 11
- 238000005286 illumination Methods 0.000 claims description 10
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 claims description 10
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 claims description 9
- 229920001429 chelating resin Polymers 0.000 claims description 9
- 239000012530 fluid Substances 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 9
- 238000012544 monitoring process Methods 0.000 claims description 9
- 239000012286 potassium permanganate Substances 0.000 claims description 9
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 claims description 8
- 239000011248 coating agent Substances 0.000 claims description 8
- 238000000576 coating method Methods 0.000 claims description 8
- 239000003456 ion exchange resin Substances 0.000 claims description 8
- 229920003303 ion-exchange polymer Polymers 0.000 claims description 8
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 8
- 230000003287 optical effect Effects 0.000 claims description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 6
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 claims description 6
- 230000000737 periodic effect Effects 0.000 claims description 6
- 150000002978 peroxides Chemical class 0.000 claims description 6
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 5
- 229910052740 iodine Inorganic materials 0.000 claims description 5
- 239000011630 iodine Substances 0.000 claims description 5
- 238000004448 titration Methods 0.000 claims description 5
- 229940061720 alpha hydroxy acid Drugs 0.000 claims description 4
- 150000001280 alpha hydroxy acids Chemical class 0.000 claims description 4
- 229910000366 copper(II) sulfate Inorganic materials 0.000 claims description 4
- 239000004310 lactic acid Substances 0.000 claims description 4
- 235000014655 lactic acid Nutrition 0.000 claims description 4
- SPAGIJMPHSUYSE-UHFFFAOYSA-N Magnesium peroxide Chemical compound [Mg+2].[O-][O-] SPAGIJMPHSUYSE-UHFFFAOYSA-N 0.000 claims description 3
- 239000003708 ampul Substances 0.000 claims description 3
- 239000000919 ceramic Substances 0.000 claims description 3
- 230000007797 corrosion Effects 0.000 claims description 3
- 238000005260 corrosion Methods 0.000 claims description 3
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 claims description 3
- 239000010453 quartz Substances 0.000 claims description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- PFUVRDFDKPNGAV-UHFFFAOYSA-N sodium peroxide Chemical compound [Na+].[Na+].[O-][O-] PFUVRDFDKPNGAV-UHFFFAOYSA-N 0.000 claims description 2
- LHJQIRIGXXHNLA-UHFFFAOYSA-N calcium peroxide Chemical compound [Ca+2].[O-][O-] LHJQIRIGXXHNLA-UHFFFAOYSA-N 0.000 claims 2
- OQVYMXCRDHDTTH-UHFFFAOYSA-N 4-(diethoxyphosphorylmethyl)-2-[4-(diethoxyphosphorylmethyl)pyridin-2-yl]pyridine Chemical compound CCOP(=O)(OCC)CC1=CC=NC(C=2N=CC=C(CP(=O)(OCC)OCC)C=2)=C1 OQVYMXCRDHDTTH-UHFFFAOYSA-N 0.000 claims 1
- 239000004343 Calcium peroxide Substances 0.000 claims 1
- 235000019402 calcium peroxide Nutrition 0.000 claims 1
- 235000019504 cigarettes Nutrition 0.000 claims 1
- 150000002500 ions Chemical class 0.000 claims 1
- 229920005989 resin Polymers 0.000 claims 1
- 239000011347 resin Substances 0.000 claims 1
- 239000000428 dust Substances 0.000 abstract description 11
- 238000005516 engineering process Methods 0.000 abstract description 9
- 238000002485 combustion reaction Methods 0.000 abstract description 6
- 238000004519 manufacturing process Methods 0.000 abstract description 6
- 229910000831 Steel Inorganic materials 0.000 abstract description 5
- 239000010959 steel Substances 0.000 abstract description 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract description 3
- 229920001131 Pulp (paper) Polymers 0.000 abstract description 3
- 239000004568 cement Substances 0.000 abstract description 3
- 239000000460 chlorine Substances 0.000 abstract description 3
- 229910052801 chlorine Inorganic materials 0.000 abstract description 3
- 239000002906 medical waste Substances 0.000 abstract description 3
- 239000010813 municipal solid waste Substances 0.000 abstract description 2
- 239000000243 solution Substances 0.000 description 25
- 239000003245 coal Substances 0.000 description 20
- 235000010269 sulphur dioxide Nutrition 0.000 description 19
- 239000000126 substance Substances 0.000 description 17
- -1 hydroxyl radical free radical Chemical class 0.000 description 13
- 238000012360 testing method Methods 0.000 description 11
- 238000006477 desulfuration reaction Methods 0.000 description 10
- 230000023556 desulfurization Effects 0.000 description 8
- 239000011593 sulfur Substances 0.000 description 8
- 229910052717 sulfur Inorganic materials 0.000 description 8
- 238000007254 oxidation reaction Methods 0.000 description 7
- 230000008569 process Effects 0.000 description 7
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 6
- 230000003647 oxidation Effects 0.000 description 6
- 230000008901 benefit Effects 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 238000012423 maintenance Methods 0.000 description 5
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 4
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 4
- 238000009303 advanced oxidation process reaction Methods 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 239000003500 flue dust Substances 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000003203 everyday effect Effects 0.000 description 3
- 239000003517 fume Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 238000007781 pre-processing Methods 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 241000790917 Dioxys <bee> Species 0.000 description 2
- GCNLQHANGFOQKY-UHFFFAOYSA-N [C+4].[O-2].[O-2].[Ti+4] Chemical compound [C+4].[O-2].[O-2].[Ti+4] GCNLQHANGFOQKY-UHFFFAOYSA-N 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 229910001882 dioxygen Inorganic materials 0.000 description 2
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- 239000000835 fiber Substances 0.000 description 2
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- 239000001257 hydrogen Substances 0.000 description 2
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- 230000001590 oxidative effect Effects 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- 239000013618 particulate matter Substances 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 230000007096 poisonous effect Effects 0.000 description 2
- 150000003254 radicals Chemical group 0.000 description 2
- 230000004044 response Effects 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- 239000002912 waste gas Substances 0.000 description 2
- UPLPHRJJTCUQAY-WIRWPRASSA-N 2,3-thioepoxy madol Chemical compound C([C@@H]1CC2)[C@@H]3S[C@@H]3C[C@]1(C)[C@@H]1[C@@H]2[C@@H]2CC[C@](C)(O)[C@@]2(C)CC1 UPLPHRJJTCUQAY-WIRWPRASSA-N 0.000 description 1
- 208000032170 Congenital Abnormalities Diseases 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 235000019738 Limestone Nutrition 0.000 description 1
- 206010058467 Lung neoplasm malignant Diseases 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 206010034972 Photosensitivity reaction Diseases 0.000 description 1
- 206010036590 Premature baby Diseases 0.000 description 1
- 238000009621 Solvay process Methods 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 238000003916 acid precipitation Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 208000006673 asthma Diseases 0.000 description 1
- 230000007698 birth defect Effects 0.000 description 1
- 239000003738 black carbon Substances 0.000 description 1
- 230000002612 cardiopulmonary effect Effects 0.000 description 1
- 230000005800 cardiovascular problem Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
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- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- TXKMVPPZCYKFAC-UHFFFAOYSA-N disulfur monoxide Inorganic materials O=S=S TXKMVPPZCYKFAC-UHFFFAOYSA-N 0.000 description 1
- 238000005367 electrostatic precipitation Methods 0.000 description 1
- 239000012717 electrostatic precipitator Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 230000005802 health problem Effects 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000002440 industrial waste Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 201000005202 lung cancer Diseases 0.000 description 1
- 208000020816 lung neoplasm Diseases 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 239000011859 microparticle Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 208000023504 respiratory system disease Diseases 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical compound S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
- 239000004291 sulphur dioxide Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
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- 239000010936 titanium Substances 0.000 description 1
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- 210000003437 trachea Anatomy 0.000 description 1
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/50—Sulfur oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Treating Waste Gases (AREA)
Abstract
The invention discloses a kind of method and device utilizing light to help Fenton's reaction purifying smoke, the method is that light helps Fenton's reaction that granule dust is converted into carbon dioxide, sulfur dioxide becomes sulphuric acid, this device includes luminous energy storehouse and cleaning position, therefore, the interests of the retrieval of sulfuric acid of this device exceed the operating cost of equipment itself, and user can obtain more profit.Additionally, this technology is very flexible, it can be included into the existing system of coal-burning boiler for improving its effectiveness, or replaces original old system completely.The present invention is the most applicable at any coal-burning boiler industrial market, including cement plant, steel plant, trash burning factory of municipal government, clinical waste combustion plant, chlorine maker, paper pulp and paper production factory etc..
Description
(1) technical field:
The present invention relates to a kind of luminous energy purification method and device, a kind of utilize light to help Fenton's reaction purifying smoke
Method and device.
(2) background technology:
Under the form of China's economic sustained and rapid development, energy resource consumption demand steeply rises；Only as a example by coal, reform
Since exploitation, the demand incremental change of annual coal is about 8～12%, and the maximum dirt disease produced with this is exactly serious air
Pollute.
The China of today is one of the most serious country of atmospheric pollution in the world (being only second to India).Not long ago in state of China
The theme proposing ' eliminating the trouble of common people's cardiopulmonary ' special in the regular meeting of business institute；Pollution administration has been combined with people's state, the people's livelihood
Come, make a decision to forgo and pollute the medicated cap of big country.Chinese Government determine not only to soar economically also will in the environment for country,
The people, offspring or even the world make positive contribution.On the road of China Reconstructs, new cleaning fuel is by reserves and state
Border politics restriction and the replacement kinetic energy that domestic industry demand is main cannot be become.Therefore during, coal can be the most still
The kinetic energy energy that state is main.Constantly increase exhibition along with industrial requirement and mean that atmospheric pollution will be more serious, effectively alleviate with anti-
Pollution treatment dye will be a heavy problem forever.
It is known that serious atmospheric pollution can bring the irreversible disaster of all of biology on the earth, and pollute
Air is mainly derived from the industrial fumes containing a large amount of poisonous and harmful substances.These noxious fume overwhelming majority is by coal burning
Produced by during.But, there is no absolute cleaning coal in the world, only produce because of the difference of geological conditions is poisonous
The coal resources that content of material proportion is different.Such as, the coal that NORTH CHINA is produced is the low-sulfur coal of high-quality, and sulfur content only has 1%
～2%；And its sulfur content of coal that Yunnan, Guizhou and Inner Mongol are produced can reach more than 5%.According to measuring and calculating: in Chinese industrial flue dust
Sulfur dioxide annual emissions be up to more than 20,000,000 tons.In the city of 113 atmospheric pollution keypoint treatments, there are 40 cities
SO2 emissions exceed the secondary standard line of country's formulation, and 39 cities are even inferior to country's grade III Standard line！By air
Pollute the Acid Rain Pollution caused and wreak havoc the territory of China 1/3rd.The fastest pollution gone together therewith of industrial process speedup refers to
Number will be the highest, and relevant department can be the most difficult to the control of environment.
Chinese over nearly 20 years continual technical research is carried out in flue dust desulfurization.Dioxy is controlled with flue gas desulfurization technique
The pollution changing sulfur is an important step in Environmental Protection in China application.Just calculate with low-sulfur coal (sulfur content 1%): combustion one
Ton coal can produce the sulfur dioxide of 16 kilograms (1600x1%, kilogram).One medium-sized coal-burning boiler about burn every day 150～
The coal of 200 tons；That is the sulfur dioxide of 2.4～3.2 tons can be produced every day.Current desulfurization technology includes coal mixture stone
Ash or additive；Calcium and ebullated bed limestone dry desulfurization is directly sprayed in stove；And calcium alkaline process, ammonia-soda process, sodium alkali, magnesium alkaline process
Deng wet desulphurization.Eliminating through practical proof for many years and market economy technology, the only technical equipment of minority actually enters combustion
Coal industry boiler applications.Wherein with spiral board towers units for currently mainly application.Spiral board towers units is in the nineties
For flue gas desulfurization and the dedusting of coal-fired industry boiler after technological transformation.The advantage of this device is connecing of flue gas and liquid
Contacting surface is long-pending greatly, simple in construction, resistance are less, stable for main feature.Its shortcoming is then that existing technology desulfuration efficiency is put down
All only reach 60～80%, and cost is very big.The operating cost of desulfurization now is 0.3 yuan every watt, and one medium-sized by 12,000
Megawatt the annual operating cost in coal-burning power plant be 44,300,000 yuan；And the cost of its desulfurizer is 3.6 hundred million yuan！
Huge puts and runs with the crisis really making medium-sized and small enterprises face work factory.
Except sulfur dioxide, healthy impact has been caused at present and has paid close attention to widely by PM2.5.What is particulate matter
2.5(PM2.5)？They refer to be combined in small pieces of solid or the liquid substance that diameter in earth atmosphere is less than 2.5 microns.Particulate matter
Compositions can cause obvious visual effect, such as flue dust, it by sulfur dioxide, nitrogen oxides, carbon monoxide, Mineral Dusts, have
Machine material and elemental carbon composition, also referred to as black carbon or coal smoke.Due to the existence of sulfur, granule is moisture absorption, and SO2 meeting
It is converted into sulphuric acid under high humility and low temperature.This will cause visibility reduction, yellow air, ozone and the suction sense of twinge.People
The impact that class sucks particle matter with animal has been extensively studied；What PM2.5 caused health problem includes asthma, lung
Cancer, cardiovascular problems, respiratory system disease, birth defect and premature death.
Granular material discharged the most strictly supervised in most industry country.Due to environmental problem, most industries is all
Need to carry out the operation of certain dust collecting system, granular material discharged to control.These systems include that (eddy flow removes centrifugal deduster
Dirt device), fiber filter cleaner unit (sack cleaner), wet scrubber and electrostatic precipitator.But, cheap cleaner
Efficiency is the lowest, and typically less than 80%；Good equipment such as electrostatic precipitation, right efficiency may be up to 99%, but also has it fatal
Shortcoming: (1) equipment is huge, consumption steel is many, needs high-voltage transforming and rectifying installation, therefore investment is high.(2) efficiency of dust collection is by dust specific resistance
Restriction, the general contrast resistance dust less than 104～105 ohm every centimeter or more than 1010～1011 ohm every centimeter, if
Not taking certain measure, efficiency of dust collection will be affected. and (3) do not possess off-line maintenance function, and once equipment breaks down, or
Run in spite of illness, or can only shutdown maintenance.Sum it up, it is all very that any effective percentage is built with maintenance cost except the equipment of PM
High.
China also has been presented for the restriction (see table) to particulate in air discharge, and each factory and enterprise is the most all pressed fixed
Cleaner.But huge maintenance expense makes medium-sized and small enterprises unable to make ends meet really.Therefore development one is inexpensive and effective
Dust arrester also should be the task of top priority.
| PM10 | PM2.5 | |
| Every year | 70 micrograms/cubic meter | 35 micrograms/cubic meter |
| Daily (24 hours) | 150 micrograms/cubic meter | 75 micrograms/cubic meter |
(3) summary of the invention:
It is an object of the invention to provide a kind of method and device utilizing light to help Fenton's reaction purifying smoke, utilize light to help
Fenton's reaction (Fenton Reaction) and the hydroxyl radical free radical that produces includes two to the pollutant getting rid of in fire coal boiler fume
Sulfur oxide and microparticle.Hydroxyl radical free radical can be easy Oxidative demage organic pollution, be referred to as high-level oxidation technology process
Process (Advanced Oxidation Processes, AOPs).The design of AOPs is a kind of method of chemistry, a kind of more effective
Technology.Utilizing light to help Fenton's reaction that granule dust is converted into carbon dioxide, sulfur dioxide becomes sulphuric acid, therefore, and this
The interests of device filtration system retrieval of sulfuric acid exceed the operating cost of equipment itself, and user can obtain more profit.Additionally,
This technology is very flexible, and it can be included into the existing system of coal-burning boiler for improving its effectiveness, or replaces completely
Old system originally.This filtration system is the most applicable at any coal-burning boiler industrial market, including cement plant, steel plant, municipal administration
Fu Feiwuranshaochang, clinical waste combustion plant, chlorine maker, paper pulp and paper production factory etc..
Technical scheme: a kind of method utilizing light to help Fenton's reaction purifying smoke, it is characterised in that include with
Lower step:
(1) add in reaction vessel containing Fenton reagent and use Alpha-hydroxy acid for adjusting pH value to less than or equal to 3 molten
Liquid, described Fenton reagent comprises metal system and the hydrogen peroxide that light can be occurred to help Fenton's reaction；
Described solution allocation hydrogen peroxide is 3%～5% with the mass percent of water；
Hydrogen peroxide and metal system mol ratio are more than or equal to 10；
(2) according to the optical absorption peak of metal system, illumination system is set；
(3) flue gas is passed through reaction vessel, makes the pollutant in flue gas be fully contacted with Fenton reagent and react；
(4) after reacting, solution is derived, and periodic monitor derives the concentration of Fenton reagent in solution, according to the feelings of monitoring
Condition, adds the new solution containing Fenton reagent and makes solution composition in reaction vessel keep stable；
(5) purified gas discharges reaction vessel.
Metal system in step described above (1) is Fe (II)/F (III) system or Cu (I)/Cu (II) system；Work as gold
When genus system is Fe (II)/F (III) system, then illumination be wavelength be the ultraviolet light of 200nm～400nm；When metal system is Cu
(I) during/Cu (II) system, illumination be wavelength be the visible ray of 600nm～800nm.
Fe described above (II)/F (III) system is less than the FeSO of 20 nanometers by diameter4And Fe3O4Granule is constituted.
Cu described above (I)/Cu (II) system is less than the Cu of 20 nanometers by diameter2O and CuSO4Granule is constituted.
Hydrogen peroxide in step described above (1) is that diameter is less than the Magnesium dioxide of 50 nanometers, sodium peroxide or peroxide
Change generation after calcium reacts in described solution.
'alpha '-hydroxy acids described above is glycolic, acetone acid or lactic acid.
In step described above (3), the pollutant in flue gas are sulfur dioxide, carbon granule, carbon monoxide or Hydrocarbon
In at least one, sulfur dioxide be oxidized to sulfur trioxide and be dissolved in solution formed sulphuric acid, carbon granule is oxidized to titanium dioxide
Carbon, carbon monoxide is oxidized to carbon dioxide, and Hydrocarbon is broken down into carbon dioxide and water.
The mode being fully contacted in step described above (3) is that gas is passed directly into liquid or adds in reaction vessel
At least one in spray equipment.
When pollutant in step described above (3) include sulfur dioxide, add step (3 ') after step (3) and utilize city
Described metal system material is reclaimed in the Amberlite IRC748 ion exchange resin coating absorption selling DOW chemical company,
By the solution purification containing sulphuric acid.
In step described above (3), flue gas have passed through pretreatment before being passed through reaction vessel, and preprocessing process eliminates
The diameter solid particle more than 10 microns in flue gas.
In step described above (6), the consumption of the hydrogen peroxide in Fenton reagent passes through periodic collection sample by closely
Monitoring, and use iodine/potassium permanganate (I/KMnO4) titrimetry observe peroxide consumption rate.
A kind of device realizing the above-mentioned method utilizing light to help Fenton's reaction purifying smoke, including luminous energy storehouse, described luminous energy
Storehouse includes drawing water in luminous energy warehouse, luminous energy storehouse air inlet, gas outlet, luminous energy storehouse, luminous energy storehouse inlet, gas-liquid mixed passage, luminous energy storehouse
Pump, luminous energy storehouse liquid outlet, luminous energy storehouse spray equipment and light irradiation apparatus, described luminous energy storehouse air inlet and gas outlet, luminous energy storehouse are arranged on
The top of luminous energy warehouse, described luminous energy storehouse inlet is arranged on the middle part of luminous energy warehouse, and described luminous energy storehouse liquid outlet is arranged on light
The bottom of energy warehouse, described gas-liquid mixed passage, luminous energy storehouse spray equipment and light irradiation apparatus are positioned at luminous energy warehouse, gas-liquid mixed
The input of passage connects luminous energy storehouse air inlet, and the outfan of gas-liquid mixed passage 2-4 is positioned at luminous energy warehouse bottom close at the bottom of storehouse
Position, described luminous energy storehouse suction pump connects the outfan bottom luminous energy warehouse and the input of luminous energy storehouse spray equipment by pipeline
End.
Arranging luminous energy storehouse liquid level meter on the sidewall of luminous energy warehouse described above, luminous energy warehouse top arranges the maintenance of luminous energy storehouse
Lid.
Light irradiation apparatus described above is quartz ampoule uviol lamp or visible lamp.
The device utilizing light to help Fenton's reaction purifying smoke described above also includes cleaning position, and described cleaning position includes purifying
Warehouse, purification plate, fluid flow control bolt and cleaning position liquid outlet, and described purification warehouse is placed luminous energy warehouse, described luminous energy
Storehouse liquid outlet stretches in purification warehouse, and described fluid flow controls bolt and is arranged on the liquid outlet of luminous energy storehouse, and described luminous energy storehouse goes out liquid
Mouth is positioned at above purification plate, and described purification plate is fixed in cleaning position body, and described cleaning position liquid outlet is arranged at the bottom of purification warehouse
Portion.
Purification plate described above is corrosion resistant plate or ceramic wafer, and purification plate is coated with commercially available DOW chemical company
Amberlite IRC748 ion exchange resin coating.
The operation principle of the present invention:
In luminous energy storehouse, help Fenton's reaction and catalysis/oxidation reaction that dust is changed into carbon dioxide by making to use up,
Sulphur Dioxide is become sulphuric acid.Fenton's reaction is a simple photosensitized oxidation/reduction catalysts reaction, the master of Fenton's reaction
Wanting feature is that it produces active oxygen (ROS), particularly hydroxyl radical free radical.Hydroxyl radical free radical is maximally effective active oxygen, and it is permissible
Aoxidize any organic (including biomolecule) and inorganic matrix at its periphery.Its original chemical reaction is Fe (II) and H2O2
Reaction generates Fe (III) and OH (see Fig. 3), and reduction Fe (III) to Fe (II) needs heat or the energy of light.There is no substrate and the end
Thing and in the case of having luminous energy, has three dominant mechanisms (see Fig. 4-6).Light helps the efficiency of Fenton's reaction to depend primarily on H2O2
Concentration, Fe (II)/H2O2Ratio, pH value, the intensity of response time and UV light.The chemical characteristic of pollutant, physical characteristic,
Initial concentration and temperature, also have important impact to final efficiency.
Dust (main component of haze) in flue gas burns incomplete coal the most exactly, and the organic substance contained in coal exists
Producing imflammable gas after decomposes, also referred to as " volatile matter " (VOC), it is by various Hydrocarbon, hydrogen, an oxygen
Change the mixed gas of the compound compositions such as carbon.When coal combustion condition is the most up to standard or volatile matter high coal (colm) burning time easy
Produce the carbon granules that uncombusted is minimum, be commonly called as " black smoke "；And produce the carbon such as more VOC such as carbon monoxide, multiring aromatic hydrocarbon, aldehydes
Pollutant are closed in hydrogenation.
The chemical principle of AOPs system be hydroxyl radical free radical have high chemical reactivity and its very
High oxidizing potential.The generation of hydroxyl radical free radical can utilize the method for oxidation of biography, such as hydrogen peroxide or ozone and ultraviolet spoke
Penetrate/or the combination of catalyst.High intensity UV lamp and Fenton's reaction can react with any organic and inorganic molecule and decompose.
Any organic carbon-containing molecule being present in flue gas can be oxidized to CO when it is through bin2, other heavy metals and inorganic ore deposit
Thing then can be deposited in the fiber removal of mercury filter in our discharge duct.Hydroxyl radical free radical and the dominant response of organic substance
It is exactly can be by organic substance decomposition progressively.Hydroxyl radical free radical and Hydrocarbon first reaction in flue gas in luminous energy storehouse
Being to remove a hydrogen atom in its molecular structure (R), then form water and alkyl diradical (R) (see Fig. 7), second anti-
Should be that alkyl diradical (R) reacts rapidly formation peroxy radical (see Fig. 8), more again through many with molecular oxygen
Step, ultimately generates carbon dioxide and water.Hydroxyl radical free radical can be with Quick Oxidation SO2So that industrial utilize at Fenton's reaction
The reason waste gas containing sulfur dioxide is possibly realized, SO2With hydroxyl radical free radical effect, form SO3, form sulphuric acid the most in the solution
(see Figure 10).
Additionally, the generation of hydroxyl radical free radical is also by other light reaction, such as ozone/ultraviolet or peroxidating dioxy
Changing titanium/hydrogen/solar radiation also to be able to realize, it is high (from 63 to 10 that the feature of Fenton's reaction is exactly its reaction rate constant5),
And other luminous energy reaction such as reaction of ozone/ultraviolet, speed constant is only 10-6Left and right.Flue gas in trachea with 6 meters per second
Speed before, without high reaction efficiency, any chemical reaction all methods are carried out.
The technical program is also added into 'alpha '-hydroxy acids to improve the volume of production of OH.Glycolic, acetone acid and lactic acid all may be used
To add in luminous energy storehouse, help speed up the speed of Fenton's reaction and the formation of hydroxyl radical free radical.'alpha '-hydroxy acids is not own
It is not involved in Fenton's reaction, but it can stablize the formation of OH to increase the yield of OH.It can also keep the pH value in storehouse
Less than 3 to guarantee that luminous energy storehouse has the light reaction environment of optimum.
Due to the corrosivity of the sulphuric acid (sulphuric acid of 20%～70% concentration its corrosivity ratio 98% different according to intensity
The sulphuric acid of concentrations above is taller), so storehouse has been coated with the Teflon of 2～3 millimetersWith anticorrosion.
The superiority of the present invention: 1, the advantage of nano material is that its surface area is big, and between molecule, electronic shell transfers mutually
Very fast, can make to accelerate as chemical reaction velocity index；Especially in optical field, the work of the least luminous energy of diameter of nanometer
Property is the biggest with momentum.So wanting that the flue gas making flow velocity the fastest produces any chemical reaction, the advantage of nanotechnology is could not
Fixed.The redox reaction of self is spontaneous, has the characteristic of catalyst, so without often attaching, consumption is few, very
Economy.2, this invention desulfurization benefit can reach 99.99%, and be manufactured into and run all on 50% left side of current desulfurization technology
The right side, and in the case of there is no any extra charge, solve the removal problem of PM2.5.Equipment occupation of land is little, transformation is simple.This
Invention is set up and is helped in the principle of Fenton's reaction at light, and is eliminating SO2With achieve immense success on flue dust.Of the present invention set
Standby it is principle based on AOPs-Fenton's reaction and successful industrialized unit.The method of the invention be one more economical, higher
The mode controlling air pollution of effect, it is not necessary to any extra manufacture and operating cost.It is existing that it can be included into coal-burning boiler
Some dust pelletizing systems are for improving its effectiveness, it is also possible to replace original old system completely.The present invention is the most applicable at other
Industrial market, including cement plant, steel plant, trash burning factory of municipal government, clinical waste combustion plant, chlorine maker, paper pulp
With paper production factory etc..On the premise of following strictly rule of operation, technique can be protected continuity and use by 15～20 years without entering
Row is engineered, Tong Bu can carry out maintaining with the coal-burning boiler run.
This device clean-up effect detection test report is as follows:
1, the present invention is for purifying the test report of vehicle exhaust:
Examination criteria (method) and use instrument
Testing result
Unit: milligram/cubic meter
2, the present invention is for the test report (test site is certain boiler room) of purification boiler waste gas:
Examination criteria (method) and use instrument:
Testing result unit: milligram/cubic meter
Remarks: standard value is according to " thermoelectricity field atmosphere pollutants emission standards " (GB13223-2011)
3, the present invention is for the test report (test site is certain power plant and certain steel mill) of purifying industrial waste gases
Examination criteria (method) and use instrument
Testing result
Unit: milligram/cubic meter
4, present invention test report of sulfur dioxide in purifying smoke
(4) accompanying drawing explanation:
Fig. 1 is the structural representation in the luminous energy storehouse in a kind of device utilizing light to help Fenton's reaction purifying smoke involved by the present invention
Figure.
Fig. 2 is the luminous energy storehouse in a kind of device utilizing light to help Fenton's reaction purifying smoke involved by the present invention and cleaning position
Combinative structure schematic diagram.
Fig. 3 is that in a kind of method utilizing light to help Fenton's reaction purifying smoke involved by the present invention, light helps Fe in Fenton's reaction
(II) reaction equation of Fe (III) it is oxidized to.
Fig. 4 is that in a kind of method utilizing light to help Fenton's reaction purifying smoke involved by the present invention, light helps in Fenton's reaction first
Plant Fe (III) and be reduced to the reaction equation of Fe (II).
Fig. 5 is that in a kind of method utilizing light to help Fenton's reaction purifying smoke involved by the present invention, light helps in Fenton's reaction second
Plant Fe (III) and be reduced to the reaction equation of Fe (II).
Fig. 6 is that in a kind of method utilizing light to help Fenton's reaction purifying smoke involved by the present invention, light helps in Fenton's reaction the 3rd
Plant Fe (III) and be reduced to the reaction equation of Fe (II).
Fig. 7 is that in a kind of method utilizing light to help Fenton's reaction purifying smoke involved by the present invention, light helps hydroxyl in Fenton's reaction
Free radical forms water and the chemical equation of alkyl diradical with hydrocarbon reaction
Fig. 8 is that in a kind of method utilizing light to help Fenton's reaction purifying smoke involved by the present invention, light helps alkyl in Fenton's reaction
Free radical and molecular oxygen react the chemical equation forming peroxy radical.
Fig. 9 is C in a kind of method utilizing light to help Fenton's reaction purifying smoke involved by the present invention2H6It is broken down into titanium dioxide
Carbon and the chemical equation of water.
Figure 10 is the oxidation of sulfur dioxide in a kind of method utilizing light to help Fenton's reaction purifying smoke involved by the present invention
Learn reaction equation.
Wherein, 1-1 is for purifying warehouse, and 1-2 is purification plate, and 1-3 is that fluid flow controls bolt, and 1-4 is cleaning position liquid outlet,
Gas outlet, 2-1 luminous energy storehouse, 2-2 is luminous energy storehouse air inlet, and 2-3 is luminous energy storehouse inlet, and 2-4 is gas-liquid mixed passage, and 2-5 is light
Energy storehouse suction pump, 2-6 is luminous energy storehouse liquid outlet, and 2-7 is luminous energy storehouse liquid level meter, and 2-8 is luminous energy storehouse spray equipment, and 2-9 is luminous energy
Storehouse access cover, 2-10 is light irradiation apparatus, and 2-11 is luminous energy warehouse.
(5) detailed description of the invention:
Embodiment 1: a kind of method utilizing light to help Fenton's reaction purifying smoke, it is characterised in that comprise the following steps:
(1) add in reaction vessel containing Fenton reagent and use Alpha-hydroxy acid for adjusting pH value to less than or equal to 3 molten
Liquid, described Fenton reagent comprises metal system and the hydrogen peroxide that light can be occurred to help Fenton's reaction；
Described solution allocation hydrogen peroxide is 5% with the mass percent of water；
Hydrogen peroxide and metal system mol ratio are about 30:1；
(2) according to the optical absorption peak of metal system, illumination system is set；
(3) flue gas is passed through reaction vessel, makes the pollutant in flue gas be fully contacted with Fenton reagent and react；
(4) after reacting, solution is derived, and periodic monitor derives the concentration of Fenton reagent in solution, according to the feelings of monitoring
Condition, adds the new solution containing Fenton reagent and makes solution composition in reaction vessel keep stable；
(5) purified gas discharges reaction vessel.
Metal system in step described above (1) is Fe (II)/F (III) system, then illumination be wavelength be 200nm～
The ultraviolet light of 400nm.
Fe described above (II)/F (III) system is less than the FeSO of 20 nanometers by diameter4And Fe3O4Granule is constituted.
'alpha '-hydroxy acids described above is lactic acid.
In step described above (3), the pollutant in flue gas are sulfur dioxide, carbon granule, carbon monoxide and nytron
Thing, sulfur dioxide is oxidized to sulfur trioxide and is dissolved in solution formation sulphuric acid, and carbon granule is oxidized to carbon dioxide, carbon monoxide
Being oxidized to carbon dioxide, Hydrocarbon is broken down into carbon dioxide and water.
The mode being fully contacted in step described above (3) is that gas is passed directly into liquid and adds in reaction vessel
Spray equipment.
When pollutant in step described above (3) include sulfur dioxide, add step (3 ') after step (3) and utilize city
Described metal system material is reclaimed in the Amberlite IRC748 ion exchange resin coating absorption selling DOW chemical company,
By the solution purification containing sulphuric acid.
In step described above (3), flue gas have passed through pretreatment before being passed through reaction vessel, and preprocessing process eliminates
The diameter solid particle more than 10 microns in flue gas.
In step described above (6), the consumption of the hydrogen peroxide in Fenton reagent collected sample quilt by every 10 hours
Close monitoring, and use iodine/potassium permanganate (I/KMnO4) titrimetry to observe the consumption rate of peroxide.
A kind of device realizing the above-mentioned method utilizing light to help Fenton's reaction purifying smoke, including luminous energy storehouse, described luminous energy
Storehouse includes that luminous energy warehouse 2-11, luminous energy storehouse air inlet 2-2, luminous energy storehouse gas outlet 2-1, luminous energy storehouse inlet 2-3, gas-liquid mixed are logical
Road 2-4, luminous energy storehouse suction pump 2-5, luminous energy storehouse liquid outlet 2-6, luminous energy storehouse spray equipment 2-8 and light irradiation apparatus 2-10, described light
Energy storehouse air inlet 2-2 and luminous energy storehouse gas outlet 2-1 is arranged on the top of luminous energy warehouse 2-11, and described luminous energy storehouse inlet 2-3 sets
Putting the middle part at luminous energy warehouse 2-11, described luminous energy storehouse liquid outlet 2-6 is arranged on the bottom of luminous energy warehouse 2-11, and described gas-liquid is mixed
Close passage 2-4, luminous energy storehouse spray equipment 2-8 and light irradiation apparatus 2-10 and be positioned at luminous energy warehouse 2-11, gas-liquid mixed passage 2-4's
Input connects luminous energy storehouse air inlet 2-2, and the outfan of gas-liquid mixed passage 2-4 is positioned at luminous energy warehouse 2-11 bottom close at the bottom of storehouse
Position, described luminous energy storehouse suction pump 2-5 connects the outfan bottom luminous energy warehouse 2-11 and luminous energy storehouse spray dress by pipeline
Put the input of 2-8；
Arrange luminous energy storehouse liquid level meter 2-7, luminous energy warehouse 2-11 top on the sidewall of luminous energy warehouse 2-11 described above to arrange
Luminous energy storehouse access cover 2-9.
Light irradiation apparatus 2-10 described above is quartz ampoule uviol lamp.
The device utilizing light to help Fenton's reaction purifying smoke described above also includes cleaning position, and described cleaning position includes purifying
Warehouse 1-1, purification plate 1-2, fluid flow control bolt 1-3 and cleaning position liquid outlet 1-4, and described purification warehouse 1-1 places light
Can warehouse 2-11, described luminous energy storehouse liquid outlet 2-6 stretch in purification warehouse 1-1, described fluid flow controls bolt 1-3 and is arranged on light
On energy storehouse liquid outlet 2-6, described luminous energy storehouse liquid outlet 2-6 is positioned at above purification plate 1-2, and described purification plate 1-2 is fixed on purification
In warehouse 1-1, described cleaning position liquid outlet 1-4 is arranged on bottom purification warehouse 1-1.
Purification plate 1-2 described above is corrosion resistant plate, painting commercially available DOW chemical company on purification plate 1-2
Amberlite IRC748 ion exchange resin coating.
The device method of work of purifying smoke in the present embodiment:
As a example by 15 tons of coal-burning boilers for about 30 tons of coals of burning every day:
The method of work in luminous energy storehouse:
(1) diameter of luminous energy warehouse 2-11 and height are respectively 2.7 meters and 2.25 meters；
(2) inject the water of 5725 liters to luminous energy warehouse 2-11, add the 35%H of 817 liters2O2With the FeSO of 64 kilograms4
(FeSO4:H2O2=1:5w/w)；
(3) arrange 4 1000W widebands in luminous energy warehouse 2-11, wavelength is 200nm to 400nm, optical absorption peak value is equal to
UV light (the FeSO of 365nm4At 365nm, there is the highest absorptance)；
(4) luminous energy storehouse spray equipment 2-8 is opened；
(5) flue gas eliminating PM10 is passed through luminous energy warehouse 2-11 from luminous energy storehouse air inlet 2-2, at gas-liquid mixed passage
With liquid haptoreaction at 2-4, after gas emersion liquid level, the drop contact with luminous energy storehouse spray equipment 2-8 ejection reacts again, makes
It is carbon dioxide, wherein, flue gas that Hydrocarbon in flue gas is decomposed into carbon dioxide and water, carbon granule and Oxidation of Carbon Monoxide
In common Hydrocarbon include C2H6(see Fig. 9) can be decomposed in luminous energy storehouse；
(6) after reacting, solution is derived from luminous energy storehouse liquid outlet 2-6, hydrogen peroxide (H2O2) consumption by every 10 little
Time sample collection by close monitoring, and use iodine/potassium permanganate (I/KMnO4) titrimetry observe peroxide consumption
Rate, according to the SO in flue gas2And CO2Content, dosing pump will supplement hydrogen peroxide to luminous energy warehouse 2-11 from receiver；
(7) purified gas is discharged luminous energy warehouse 2-11 from luminous energy storehouse gas outlet 2-1.
From the point of view of industrial test data according to described in the present embodiment 15 tons of coal-burning boilers, the method for the invention has reached
The PM2.5 clearance of 95.4% (from 105 micrograms/cubic meter to 5 micrograms/cubic meter), and desulfuration efficiency can reach
99.99%, even if as the SO in flue gas2During content up to 2000 milligram/cubic metre, can also be by flue gas by this method
SO2Substantially completely remove.The present invention can also use calorifics Fenton's reaction to reach required technical specification.
The method of work of cleaning position:
(1) the mixing liquid containing sulphuric acid in luminous energy warehouse 2-11 flows into from luminous energy storehouse liquid outlet 2-6 and purifies warehouse 1-1
In, the control of 1-3 is fastened in flow velocity liquid body flow-control；
(2) mixing liquid flows through purification plate 1-2, and the Amberlite IRC748 ion exchange resin on purification plate 1-2 is coated with
Layer catches the impurity in mixing liquid and Fe (II)/F (III) system；
(3) sulfuric acid mixed solution after purifying flows out from cleaning position liquid outlet 1-4.
Sulfuric acid mixed solution after the purification that step (3) obtains can purify the bright sulfur acid obtaining 98% on the spot, and purification plate is caught
The metal system (Fe (II) in the present embodiment/F (III) system) grasped can also recycle.
Embodiment 2:
A kind of method utilizing light to help Fenton's reaction purifying smoke, it is characterised in that comprise the following steps:
(1) add in reaction vessel containing Fenton reagent and use Alpha-hydroxy acid for adjusting pH value to less than or equal to 3 molten
Liquid, described Fenton reagent comprises metal system and the hydrogen peroxide that light can be occurred to help Fenton's reaction；
Described solution allocation hydrogen peroxide is 4% with the mass percent of water；
Hydrogen peroxide and metal system mol ratio are 10:1；
(2) according to the optical absorption peak of metal system, illumination system is set；
(3) flue gas is passed through reaction vessel, makes the pollutant in flue gas be fully contacted with Fenton reagent and react；
(4) after reacting, solution is derived, and periodic monitor derives the concentration of Fenton reagent in solution, according to the feelings of monitoring
Condition, adds the new solution containing Fenton reagent and makes solution composition in reaction vessel keep stable；
(5) purified gas discharges reaction vessel.
Metal system in step described above (1) is Cu (I)/Cu (II) system, illumination be wavelength be 600nm～
The visible ray of 800nm.
Cu described above (I)/Cu (II) system is less than the Cu of 20 nanometers by diameter2O and CuSO4Granule is constituted.
Hydrogen peroxide in step described above (1) is that diameter is less than the Magnesium dioxide of 50 nanometers and reacts in described solution
Rear generation.
'alpha '-hydroxy acids described above is glycolic.
In step described above (3), the pollutant in flue gas are sulfur dioxide, carbon granule, carbon monoxide and nytron
Thing, sulfur dioxide is oxidized to sulfur trioxide and is dissolved in solution formation sulphuric acid, and carbon granule is oxidized to carbon dioxide, carbon monoxide
Being oxidized to carbon dioxide, Hydrocarbon is broken down into carbon dioxide and water.
The mode being fully contacted in step described above (3) is that gas is passed directly into liquid and adds in reaction vessel
Enter spray equipment.
When pollutant in step described above (3) include sulfur dioxide, add step (3 ') after step (3) and utilize city
Described metal system material is reclaimed in the Amberlite IRC748 ion exchange resin coating absorption selling DOW chemical company,
By the solution purification containing sulphuric acid.
In step described above (3), flue gas have passed through pretreatment before being passed through reaction vessel, and preprocessing process eliminates
The diameter solid particle more than 10 microns in flue gas.
In step described above (6), the consumption of the hydrogen peroxide in Fenton reagent collected sample quilt by every 12 hours
Close monitoring, and use iodine/potassium permanganate (I/KMnO4) titrimetry to observe the consumption rate of peroxide.
A kind of device realizing the above-mentioned method utilizing light to help Fenton's reaction purifying smoke, including luminous energy storehouse, described luminous energy
Storehouse includes that luminous energy warehouse 2-11, luminous energy storehouse air inlet 2-2, luminous energy storehouse gas outlet 2-1, luminous energy storehouse inlet 2-3, gas-liquid mixed are logical
Road 2-4, luminous energy storehouse suction pump 2-5, luminous energy storehouse liquid outlet 2-6, luminous energy storehouse spray equipment 2-8 and light irradiation apparatus 2-10, described light
Energy storehouse air inlet 2-2 and luminous energy storehouse gas outlet 2-1 is arranged on the top of luminous energy warehouse 2-11, and described luminous energy storehouse inlet 2-3 sets
Putting the middle part at luminous energy warehouse 2-11, described luminous energy storehouse liquid outlet 2-6 is arranged on the bottom of luminous energy warehouse 2-11, and described gas-liquid is mixed
Close passage 2-4, luminous energy storehouse spray equipment 2-8 and light irradiation apparatus 2-10 and be positioned at luminous energy warehouse 2-11, gas-liquid mixed passage 2-4's
Input connects luminous energy storehouse air inlet 2-2, and the outfan of gas-liquid mixed passage 2-4 is positioned at luminous energy warehouse 2-11 bottom close at the bottom of storehouse
Position, described luminous energy storehouse suction pump 2-5 connects the outfan bottom luminous energy warehouse 2-11 and luminous energy storehouse spray dress by pipeline
Put the input of 2-8；
Arrange luminous energy storehouse liquid level meter 2-7, luminous energy warehouse 2-11 top on the sidewall of luminous energy warehouse 2-11 described above to arrange
Luminous energy storehouse access cover 2-9.
Light irradiation apparatus 2-10 described above is visible lamp.
The device utilizing light to help Fenton's reaction purifying smoke described above also includes cleaning position, and described cleaning position includes purifying
Warehouse 1-1, purification plate 1-2, fluid flow control bolt 1-3 and cleaning position liquid outlet 1-4, and described purification warehouse 1-1 places light
Can warehouse 2-11, described luminous energy storehouse liquid outlet 2-6 stretch in purification warehouse 1-1, described fluid flow controls bolt 1-3 and is arranged on light
On energy storehouse liquid outlet 2-6, described luminous energy storehouse liquid outlet 2-6 is positioned at above purification plate 1-2, and described purification plate 1-2 is fixed on purification
In warehouse 1-1, described cleaning position liquid outlet 1-4 is arranged on bottom purification warehouse 1-1.
Purification plate 1-2 described above is ceramic wafer, painting commercially available DOW chemical company on purification plate 1-2
Amberlite IRC748 ion exchange resin coating.
In the present embodiment, one of advantage using Cu (I)/Cu (II) system is, Cu2The optical absorption peak value of O exists
600nm, CuSO4Optical absorption peak value at 700nm, be all in the least visible region (600-800nm, near-infrared) of harm.
Claims (13)
1. one kind utilizes the method that light helps Fenton's reaction purifying smoke, it is characterised in that comprise the following steps:
(1) add in reaction vessel containing Fenton reagent and use Alpha-hydroxy acid for adjusting pH value to the solution less than or equal to 3, institute
State Fenton reagent and comprise metal system and the hydrogen peroxide that light can be occurred to help Fenton's reaction；
Described solution allocation hydrogen peroxide is 3%～5% with the mass percent of water；
Hydrogen peroxide and metal system mol ratio are more than or equal to 10；
(2) according to the optical absorption peak of metal system, illumination system is set；
(3) flue gas is passed through reaction vessel, makes the pollutant in flue gas be fully contacted with Fenton reagent and react；Described cigarette
Pollutant in gas are at least one in sulfur dioxide, carbon granule, carbon monoxide or Hydrocarbon, and sulfur dioxide is oxidized
For sulfur trioxide and be dissolved in solution formed sulphuric acid, carbon granule is oxidized to carbon dioxide, and carbon monoxide is oxidized to carbon dioxide,
Hydrocarbon is broken down into carbon dioxide and water；
(4) after reacting, solution is derived, and periodic monitor derives the concentration of Fenton reagent in solution, according to the situation of monitoring, adds
Adding the new solution containing Fenton reagent makes solution composition in reaction vessel keep stable；
(5) purified gas discharges reaction vessel.
A kind of method utilizing light to help Fenton's reaction purifying smoke, it is characterised in that described step
(1) metal system in is Fe (II)/Fe (III) system or Cu (I)/Cu (II) system；When metal system is Fe (II)/Fe
(III) during system, then illumination be wavelength be the ultraviolet light of 200nm～400nm；When metal system is Cu (I)/Cu (II) system,
Illumination be wavelength be the visible ray of 600nm～800nm, described Cu (I)/Cu (II) system by diameter less than the Cu of 20 nanometers2O and
CuSO4Granule is constituted.
A kind of method utilizing light to help Fenton's reaction purifying smoke, it is characterised in that described Fe
(II)/Fe (III) system is less than the FeSO of 20 nanometers by diameter4And Fe3O4Granule is constituted.
A kind of method utilizing light to help Fenton's reaction purifying smoke, it is characterised in that described step
(1) hydrogen peroxide in is that diameter is less than the Magnesium dioxide of 50 nanometers, sodium peroxide or calper calcium peroxide and reacts in described solution
Rear generation.
A kind of method utilizing light to help Fenton's reaction purifying smoke, it is characterised in that described α-hydroxyl
Base acid is glycolic, acetone acid or lactic acid.
A kind of method utilizing light to help Fenton's reaction purifying smoke, it is characterised in that described step
(3) mode being fully contacted in is that gas is passed directly into liquid or adds at least in spray equipment in reaction vessel
Kind.
A kind of method utilizing light to help Fenton's reaction purifying smoke, it is characterised in that described step
(3), when the pollutant in include sulfur dioxide, add step (3 ') after step (3) and utilize Amberlite IRC 748 ion
The absorption of exchanger resin coating reclaims described metal system material, by the solution purification containing sulphuric acid.
A kind of method utilizing light to help Fenton's reaction purifying smoke, it is characterised in that described step
(4), in, the consumption of the hydrogen peroxide in Fenton reagent by close monitoring, and uses iodine/height by periodic collection sample
Potassium manganate (I/KMnO4) titrimetry observes the consumption rate of peroxide.
9. realizing a device for method described in claim 1, including luminous energy storehouse, described luminous energy storehouse includes luminous energy warehouse, luminous energy
Storehouse air inlet, gas outlet, luminous energy storehouse, luminous energy storehouse inlet, gas-liquid mixed passage, luminous energy storehouse suction pump, luminous energy storehouse liquid outlet, light
Energy storehouse spray equipment and light irradiation apparatus, described luminous energy storehouse air inlet and gas outlet, luminous energy storehouse are arranged on the top of luminous energy warehouse, institute
Stating luminous energy storehouse inlet and be arranged on the middle part of luminous energy warehouse, described luminous energy storehouse liquid outlet is arranged on the bottom of luminous energy warehouse, described
Gas-liquid mixed passage, luminous energy storehouse spray equipment and light irradiation apparatus are positioned at luminous energy warehouse, and the input of gas-liquid mixed passage connects
Luminous energy storehouse air inlet, the outfan of gas-liquid mixed passage is positioned at luminous energy warehouse bottom close to the position at the bottom of storehouse, and described luminous energy storehouse is taken out
Water pump connects the outfan bottom luminous energy warehouse and the input of luminous energy storehouse spray equipment by pipeline.
Device the most according to claim 9, it is characterised in that luminous energy storehouse liquid level is set on the sidewall of described luminous energy warehouse
Device, luminous energy warehouse top arranges luminous energy storehouse access cover.
11. devices according to claim 9, it is characterised in that described light irradiation apparatus is quartz ampoule uviol lamp or visible ray
Lamp.
12. devices according to claim 9, it is characterised in that the described device utilizing light to help Fenton's reaction purifying smoke is also
Including cleaning position, described cleaning position includes purifying warehouse, purification plate, fluid flow control bolt and cleaning position liquid outlet, described only
Changing and place luminous energy warehouse on warehouse, described luminous energy storehouse liquid outlet stretches in purification warehouse, and described fluid flow controls bolt and is arranged on
On the liquid outlet of luminous energy storehouse, described luminous energy storehouse liquid outlet is positioned at above purification plate, and described purification plate is fixed in cleaning position body, described
Cleaning position liquid outlet is arranged on bottom purification warehouse.
13. devices according to claim 12, it is characterised in that described purification plate is corrosion resistant plate or ceramic wafer, purification plate
On scribble Amberlite IRC 748 ion exchange resin coating.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410166086.5A CN103949153B (en) | 2014-04-23 | 2014-04-23 | A kind of method and device utilizing light to help Fenton's reaction purifying smoke |
| PCT/CN2015/000269 WO2015161673A1 (en) | 2014-04-23 | 2015-04-17 | Method and equipment for purifying flue gas by utilizing photo-fenton reaction |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410166086.5A CN103949153B (en) | 2014-04-23 | 2014-04-23 | A kind of method and device utilizing light to help Fenton's reaction purifying smoke |
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| Publication Number | Publication Date |
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| CN103949153A CN103949153A (en) | 2014-07-30 |
| CN103949153B true CN103949153B (en) | 2017-01-04 |
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| CN201410166086.5A Expired - Fee Related CN103949153B (en) | 2014-04-23 | 2014-04-23 | A kind of method and device utilizing light to help Fenton's reaction purifying smoke |
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| Country | Link |
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| CN (1) | CN103949153B (en) |
| WO (1) | WO2015161673A1 (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103949128B (en) * | 2014-04-23 | 2016-08-17 | 林小晓 | A kind of method and device purifying the flue gas containing dust |
| CN103949153B (en) * | 2014-04-23 | 2017-01-04 | 林小晓 | A kind of method and device utilizing light to help Fenton's reaction purifying smoke |
| CN105688641B (en) * | 2016-01-22 | 2018-05-04 | 浙江工业大学 | Treatment system and treatment method for bubbling type ultraviolet/Fenton oxidized organic waste gas |
| CN105536481B (en) * | 2016-01-22 | 2018-06-26 | 浙江工业大学 | Circulating spraying type ultraviolet Fenton oxidation organic waste gas treatment system and treatment method |
| CN107185398A (en) * | 2017-03-22 | 2017-09-22 | 傅国琳 | A kind of system and its method of work for administering boiler smoke |
| CN107486000A (en) * | 2017-10-19 | 2017-12-19 | 广东佳德环保科技有限公司 | A kind of dioxin in flue gas removal device and technique |
| CN113046148B (en) * | 2021-03-11 | 2022-04-19 | 北方民族大学 | Method for removing sulfur content in coal by photo-Fenton oxidation |
| CN114191907A (en) * | 2022-01-13 | 2022-03-18 | 卓宇轩 | Peculiar smell processing system |
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| BRPI1015030A2 (en) * | 2009-04-14 | 2016-04-12 | Groupe Conseil Procd Inc | method of reducing the content of water-soluble volatile organic compounds in a gas |
| CN102008882A (en) * | 2010-11-22 | 2011-04-13 | 上海电力学院 | Fenton reagent for denitration of power plant smoke and denitration method by using the same |
| CN102166471B (en) * | 2011-02-25 | 2013-01-30 | 东南大学 | Heterogeneous-Photo-Fenton-based integrated smoke gas purification system |
| CN103706238B (en) * | 2013-12-20 | 2017-05-10 | 华中科技大学 | System and method for removing SO2, NO and Hg in smoke on the basis of heterogeneous Fenton |
| CN103949128B (en) * | 2014-04-23 | 2016-08-17 | 林小晓 | A kind of method and device purifying the flue gas containing dust |
| CN103949153B (en) * | 2014-04-23 | 2017-01-04 | 林小晓 | A kind of method and device utilizing light to help Fenton's reaction purifying smoke |
| CN104084015B (en) * | 2014-04-23 | 2016-01-20 | 林小晓 | A kind of system of purifying contaminated air and method of work thereof |
| CN103949144B (en) * | 2014-04-23 | 2016-09-21 | 林小晓 | A kind of method and device purifying the flue gas containing sulfur dioxide |
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2014
- 2014-04-23 CN CN201410166086.5A patent/CN103949153B/en not_active Expired - Fee Related
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- 2015-04-17 WO PCT/CN2015/000269 patent/WO2015161673A1/en active Application Filing
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| WO2015161673A1 (en) | 2015-10-29 |
| CN103949153A (en) | 2014-07-30 |
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