CN103937254B - The PE modified polyphenyl thioether material of a kind of automotive plastic parts low cost - Google Patents
The PE modified polyphenyl thioether material of a kind of automotive plastic parts low cost Download PDFInfo
- Publication number
- CN103937254B CN103937254B CN201410157603.2A CN201410157603A CN103937254B CN 103937254 B CN103937254 B CN 103937254B CN 201410157603 A CN201410157603 A CN 201410157603A CN 103937254 B CN103937254 B CN 103937254B
- Authority
- CN
- China
- Prior art keywords
- automotive plastic
- low cost
- plastic parts
- tetrafluoroethylene
- polyphenylene sulfide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Abstract
The invention belongs to polymeric material field, be specifically related to the PE modified polyphenyl thioether material of a kind of automotive plastic parts low cost, this material is made up of the raw material of following weight part: polyphenylene sulfide 100, recycle polyethylene 16-19, sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester 2-3, magnesium oxide 2-4, molybdenumdisulphide 3-5, barium stearate 2-4, methyltrimethoxy silane 1-3, kaolin powder 10-12, tetrafluoroethylene 10-15, epoxyoleic acid butyl ester 5-7, auxiliary agent 12-15; Present invention incorporates the advantage of the raw materials such as polyphenylene sulfide, polyethylene, tetrafluoroethylene, have good processing characteristics and mechanical property, the material of preparation is firm, low-temperature impact-resistant, heat-proof aging, electrical property is good, and chemical stability is good, has self lubricity, durable, can be widely used in and make all kinds of automotive plastic part, and reduce production cost, avoid the waste of resource.
Description
Technical field
The invention belongs to polymeric material field, be specifically related to PE modified polyphenyl thioether material of a kind of automotive plastic parts low cost and preparation method thereof.
Background technology
PPS resin has high strength, high rigidity, and rigidity reduces very little under the high temperature conditions, has outstanding fatigue performance and creep-resistant property; Being used widely in automobile component, is have good development potentiality and competitive capacity.But also there is the shortcoming that fragility is large, poor toughness, impact strength are low in polyphenylene sulfide, thus receives certain restriction in the application.
In order to improve the performance of PPS resin material, widening materials'use scope, needing to carry out modification to PPS resin material, each position of automobile can be widely used in.
Summary of the invention
The object of the invention is to, there is provided a kind of automotive plastic parts low cost PE modified polyphenyl thioether material, improve the performance of traditional polyphenyl thioether material, it is made to possess excellent mechanical property, specific environment for use can be adapted to, to achieve these goals, the technical solution used in the present invention is as follows:
The PE modified polyphenyl thioether material of a kind of automotive plastic parts low cost, it is characterized in that, material of the present invention is made up of the raw material of following weight part: polyphenylene sulfide 100, recycle polyethylene 16-19, sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester 2-3, magnesium oxide 2-4, molybdenumdisulphide 3-5, barium stearate 2-4, methyltrimethoxy silane 1-3, kaolin powder 10-12, tetrafluoroethylene 10-15, epoxyoleic acid butyl ester 5-7, auxiliary agent 12-15.
Described auxiliary agent is made up of the raw material of following weight part: clay 300-320, limestone powder 3-4, jade powder 20-24, tri (propylene glycol) diacrylate 3-4, ZrO
21-2, SnO
21-2, B
2o
35-7, sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester 2-3, aluminium hydroxide 8-10, Syzygium aromaticum stem oil 1-2, polyisobutene 1-2; Clay is put into calcining furnace to calcine 3-4 hour at 710-740 DEG C by preparation method, and cooling, puts into 10-12% hydrochloric acid soln and soak 1-2 hour, filter and take out, clean with clear water and dry, be ground into 200-400 order powder, mix with other remaining component, grinding distribution is even, to obtain final product.
The described PE modified polyphenyl thioether material of a kind of automotive plastic parts low cost, its preparation method is:
(1) after recycle polyethylene being cleaned oven dry, stir 10-15 minute with tetrafluoroethylene, barium stearate, epoxyoleic acid butyl ester, auxiliary agent mixed melting, send into twin screw extruder granulation, obtain A material;
(2) after polyphenylene sulfide, kaolin powder and other remaining component mixed meltings being stirred 5-8 minute, send into extruding pelletization in twin screw extruder, obtain B material;
(3), after A, B material being mixed, melt extrude granulation on the twin screw extruder, to obtain final product.
Present invention incorporates the advantage of the raw materials such as polyphenylene sulfide, polyethylene, tetrafluoroethylene, improve the performance of traditional polyphenyl thioether material, make it have good processing characteristics and mechanical property, the material of preparation is firm, low-temperature impact-resistant, heat-proof aging, electrical property is good, and chemical stability is good, there is self lubricity, durable, can meet specific environment for use condition, market application foreground is wide.
Embodiment
Embodiment
The present embodiment material is made up of the raw material of following weight part: polyphenylene sulfide 100, recycle polyethylene 18, sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester 3, magnesium oxide 4, molybdenumdisulphide 5, barium stearate 4, methyltrimethoxy silane 3, kaolin powder 12, tetrafluoroethylene 15, epoxyoleic acid butyl ester 6, auxiliary agent 15.Polyphenylene sulfide used by this example is high molecular weight crosslinked PPS resin, weight-average molecular weight 3.0-5 × 105.
Described auxiliary agent is made up of the raw material of following weight part: clay 300, limestone powder 4, jade powder 20, tri (propylene glycol) diacrylate 3, ZrO
22, SnO
21, B
2o
35, sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester 3, aluminium hydroxide 8, Syzygium aromaticum stem oil 2, polyisobutene 2; Clay is put into calcining furnace to calcine 4 hours at 740 DEG C by preparation method, cooling, puts into 12% hydrochloric acid soln and soaks 2 hours, filter and take out, and clean with clear water and dry, be ground into 400 order powder, mix with other remaining component, grinding distribution is even, to obtain final product.
The described PE modified polyphenyl thioether material of a kind of automotive plastic parts low cost, its preparation method is:
(1) after recycle polyethylene being cleaned oven dry, stir 12 minutes with tetrafluoroethylene, barium stearate, epoxyoleic acid butyl ester, auxiliary agent mixed melting, send into twin screw extruder granulation, obtain A material;
(2) after polyphenylene sulfide, kaolin powder and other remaining component mixed meltings being stirred 8 minutes, send into extruding pelletization in twin screw extruder, obtain B material;
(3), after A, B material being mixed, melt extrude granulation on the twin screw extruder, to obtain final product.
The performance test results of material of the present invention is: performance index of the present invention;
Tensile strength (MPa) 162
Elongation at break (%) 2.6
Flexural strength (MPa) 232
Modulus in flexure (MPa) 10500
Notched Izod impact strength (KJ/m2) 10.4.
Claims (2)
1. the PE modified polyphenyl thioether material of automotive plastic parts low cost, it is characterized in that, this material is made up of the raw material of following weight part: polyphenylene sulfide 100, recycle polyethylene 16-19, sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester 2-3, magnesium oxide 2-4, molybdenumdisulphide 3-5, barium stearate 2-4, methyltrimethoxy silane 1-3, kaolin powder 10-12, tetrafluoroethylene 10-15, epoxyoleic acid butyl ester 5-7, auxiliary agent 12-15;
Described auxiliary agent is made up of the raw material of following weight part: clay 300-320, limestone powder 3-4, jade powder 20-24, tri (propylene glycol) diacrylate 3-4, ZrO
21-2, SnO
21-2, B
2o
35-7, sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester 2-3, aluminium hydroxide 8-10, Syzygium aromaticum stem oil 1-2, polyisobutene 1-2; Clay is put into calcining furnace to calcine 3-4 hour at 710-740 DEG C by preparation method, and cooling, puts into 10-12% hydrochloric acid soln and soak 1-2 hour, filter and take out, clean with clear water and dry, be ground into 200-400 order powder, mix with other remaining component, grinding distribution is even, to obtain final product.
2. the PE modified polyphenyl thioether material of a kind of automotive plastic parts low cost as claimed in claim 1, its manufacture craft is:
(1) after recycle polyethylene being cleaned oven dry, stir 10-15 minute with tetrafluoroethylene, barium stearate, epoxyoleic acid butyl ester, auxiliary agent mixed melting, send into twin screw extruder granulation, obtain A material;
(2) after polyphenylene sulfide, kaolin powder and other remaining component mixed meltings being stirred 5-8 minute, send into extruding pelletization in twin screw extruder, obtain B material;
(3), after A, B material being mixed, melt extrude granulation on the twin screw extruder, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410157603.2A CN103937254B (en) | 2014-04-18 | 2014-04-18 | The PE modified polyphenyl thioether material of a kind of automotive plastic parts low cost |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410157603.2A CN103937254B (en) | 2014-04-18 | 2014-04-18 | The PE modified polyphenyl thioether material of a kind of automotive plastic parts low cost |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103937254A CN103937254A (en) | 2014-07-23 |
| CN103937254B true CN103937254B (en) | 2016-04-20 |
Family
ID=51185145
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410157603.2A Active CN103937254B (en) | 2014-04-18 | 2014-04-18 | The PE modified polyphenyl thioether material of a kind of automotive plastic parts low cost |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103937254B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104292716B (en) * | 2014-09-29 | 2016-07-06 | 苏州博利迈新材料科技有限公司 | Plasticising toughened polyethylene composition and preparation method thereof |
| CN109721794B (en) * | 2017-10-31 | 2022-06-07 | 合肥杰事杰新材料股份有限公司 | Polyethylene composite material for corrugated pipe and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101838462A (en) * | 2010-04-13 | 2010-09-22 | 四川中物材料有限责任公司 | Glass-fiber reinforced polyphenyl thioether composite material with humidity resistance and high resistivity and preparation method thereof |
| CN102876039A (en) * | 2012-10-08 | 2013-01-16 | 合肥杰事杰新材料股份有限公司 | Wear-resistant and high-toughness polyphenylene sulfide composite material and preparation method thereof |
-
2014
- 2014-04-18 CN CN201410157603.2A patent/CN103937254B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101838462A (en) * | 2010-04-13 | 2010-09-22 | 四川中物材料有限责任公司 | Glass-fiber reinforced polyphenyl thioether composite material with humidity resistance and high resistivity and preparation method thereof |
| CN102876039A (en) * | 2012-10-08 | 2013-01-16 | 合肥杰事杰新材料股份有限公司 | Wear-resistant and high-toughness polyphenylene sulfide composite material and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103937254A (en) | 2014-07-23 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103937252B (en) | A kind of automotive plastic parts nano-graphite modified polyphenyl thioether material | |
| CN103937254B (en) | The PE modified polyphenyl thioether material of a kind of automotive plastic parts low cost | |
| CN103937248B (en) | A kind of automotive plastic parts heatproof nano aluminum alumina modified polyphenyl thioether material | |
| CN103937246B (en) | A kind of toughness reinforcing low temperature resistant modified polyphenyl thioether material for automotive plastic parts | |
| CN103951961A (en) | Temperature-resistant polyvinyl chloride modified polyphenyl ether material for automobile plastic component | |
| CN103937253B (en) | A kind of automotive plastic parts bisphenol-a polycarbonate modified polyphenyl thioether material | |
| CN103965631A (en) | Polyropylene fiber modified polyphenyl thioether material for automobile plastic part | |
| CN103951977B (en) | A kind of automotive plastic parts glass microballon modified polyphenyl thioether material | |
| CN103937247A (en) | Polyphenyl ether modified polyphenylene sulfide material for automotive plastic part | |
| CN103937250A (en) | Soft impact-resistant modified polyphenylene sulfide material for automotive plastic parts | |
| CN103937245B (en) | A kind of moistureproof ABS modified polyphenyl ether material for automotive plastic parts | |
| CN103937203A (en) | Polyvinyl chloride modified polyphenylene oxide material for automobile plastic parts | |
| CN103937206A (en) | Polypropylene modified polyphenyl ether material for automobile plastic parts | |
| CN103965636A (en) | Flame-retardant polypropylene modified polyphenylene sulfide material for car plastic parts | |
| CN103937249B (en) | A kind of automotive plastic parts isotatic polypropylene modified polyphenyl thioether material | |
| CN103937216A (en) | Shell powder modified polyphenyl ether material for auto plastic parts | |
| CN103937244A (en) | Polyolefin modified polyphenyl ether material for automobile plastic parts | |
| CN103937255B (en) | A kind of automotive plastic parts modified polyphenyl thioether material containing rattan wood skin powder | |
| CN103965635A (en) | Polytetrafluoroethylene modified polyphenyl thioether material for automobile plastic part | |
| CN103965634A (en) | Shock-proof and oil-proof modified polyphenyl thioether material for automobile plastic part | |
| CN103756319A (en) | EVA modified polyphenylene sulfide material for automobile plastic parts | |
| CN103965632A (en) | Expanded graphite modified polyphenyl thioether material for car plastic parts | |
| CN103965609A (en) | Modified polyphenyl thioether material containing rose ethereal oil for automobile plastic part | |
| CN103965628A (en) | Medical stone powder modified polyphenylene oxide material for automobile plastic part | |
| CN103937207A (en) | Wear-resistant modified polyphenyl ether material for automotive plastic parts |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20190605 Address after: 242000 Gao Yang village, Huayang Town, Jixi County, Xuancheng, Anhui (National Grain Reserve Bank) Patentee after: Jixi Yuan Dao agricultural industry Science and Technology Ltd. Address before: 241000 Anhui Yijiang Wuhu high tech Development Zone Service Outsourcing Industrial Park B7-1 Patentee before: Wuhu Kaiaoer Environmental Science and Technology Co., Ltd. |