CN103918688A - Weeding composition containing benzobicylon and halosulfuron-methyl - Google Patents
Weeding composition containing benzobicylon and halosulfuron-methyl Download PDFInfo
- Publication number
- CN103918688A CN103918688A CN201410119307.3A CN201410119307A CN103918688A CN 103918688 A CN103918688 A CN 103918688A CN 201410119307 A CN201410119307 A CN 201410119307A CN 103918688 A CN103918688 A CN 103918688A
- Authority
- CN
- China
- Prior art keywords
- benzobicylon
- halosulfuronmethyl
- halosulfuron
- methyl
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
The invention relates to a weeding composition containing benzobicylon and halosulfuron-methyl. The weeding composition comprises active ingredients, namely benzobicylon and halosulfuron-methyl, wherein a weight part ratio of the benzobicylon to halosulfuron-methyl is (15:1)-(1:60). The weeding composition has an obvious synergistic effect on barnyard grass and dayflower, a weeding effect is improved, the herbicide controlling spectrum is widened, and the weeding composition is applied to controlling barnyard grass in paddy fields, annual broadleaf weeds and cyperaceae weeds.
Description
Technical field
The invention belongs to agriculture weeding technical field, be specifically related to a kind of Herbicidal composition for rice field that halosulfuronmethyl, benzobicylon be active ingredient of take, said composition has synergistic function, is applicable to prevent and kill off paddy field barnyard grass, annual broadleaf weed and sedge weed.
Background technology
Along with progressively eliminating of high-toxic pesticide, need efficient, low toxicity, safety, environment amenable pharmaceutical preparations, the long-term use of agricultural chemicals simultaneously produces the pesticide resistance of disease pest and weed, requirement to control medicament is also more and more higher, this just needs agricultural chemicals research staff to develop the pharmaceutical preparations of highly effective and safe, meets control requirement.Because China's agricultural chemicals initiative is at the early-stage, the pesticide species with independent intellectual property right can't be satisfied the demand, so the pesticide mixed preparation of development of new, is the only way of current Agrochemicals.
Halosulfuronmethyl (halosulfuron-methrl) is sulfonylurea wide spectrum selectivity inner-adsorption conduction-type herbicide, mainly by root system, be absorbed, also can absorb by cauline leaf, in weeds plant body, shift rapidly, suppress growth, weeds are dead gradually, can prevent and kill off annual broadleaf weed and sedge weed, are applicable to the crops such as corn, paddy rice.
Benzobicylon (benzobicyclon) is the novel double-octane class albinism paddy field post-emergence herbicide of Japanese SDS exploitation, to rice safety, high with Environmental compatibility, can effectively prevent and kill off the paddy field weeds such as barnyard grass, Monochoria vaginalis, firefly Lin, false rice, pondweed, annual broadleaf weed.
Weed killer herbicide is rationally composite is to improve preventive effect, expand herbicide spectrum or widen service time, delaying the speed of shift of weed community, reducing the resistance risk that the single use of agricultural chemicals brings, alleviate the pollution to environment, reduce a kind of effective ways of use cost and reduction herbicide residue.The inventor conducts in-depth research being mixed of halosulfuronmethyl, benzobicylon, on the basis of a large amount of formula indoor screening tests and field medicine effect test, find that halosulfuronmethyl, benzobicylon are mixed, within the scope of certain mixed ratio, barnyard grass, dayflower are shown to synergistic function, after further study, completed the present invention.
Summary of the invention
Technical scheme of the present invention is: a kind of Synergistic Herbicidal combinations, by active ingredient halosulfuronmethyl, benzobicylon and suitable insecticides adjuvant, formed, and the ratio of weight and number of halosulfuronmethyl and benzobicylon is 15:1~1:60.
Described Herbicidal combinations by certain technological means can excipient suspending agent, oil-suspending agent, water dispersible granules, wetting powder, effervescent tablet, granulae effervescentes, granule, etc. the formulation used in applicable agricultural, be convenient to its application, be applicable to prevent and treat paddy rice annual gramineous weed, broad leaved weed and sedge weed.
Described suspending agent formulation by weight percentage consists of: halosulfuronmethyl 0.01~40%, and benzobicylon 0.1~40%, dispersant 0.1~15%, wetting agent 0.1-15%, thickener 0.1~2%, deionized water carrier complements to 100%.Concrete production stage is: active ingredient and other auxiliary agent are mixed, through high speed shear, disperse, in sand mill after sand milling, form high dispersive, stable suspension system in water-medium, make suspending agent.
Described oil-suspending agent formulation by weight percentage consists of: halosulfuronmethyl 0.01~30%, benzobicylon 0.1~40%, dispersant 0.1~15%, wetting agent 0.1-15%, thickener 0.1~2%, liquid-carrier complements to 100%.Concrete production stage is: active ingredient and other auxiliary agent are mixed, through high speed shear, disperse, in sand mill after sand milling, form high dispersive, stable suspension system in non-water-medium, make oil-suspending agent.
Described dosage form of water dispersible granule by weight percentage consists of: halosulfuronmethyl 0.01~80%, benzobicylon 0.1~80%, dispersant 0.1~15%, wetting agent 0.1~10%, disintegrant 0.1~10%, solid carrier complements to 100%.Concrete production stage is: active ingredient and other auxiliary agent are mixed, with micro jet, pulverize, through mediating, then add in fluidized bed prilling dryer and carry out granulation, dry, screening, make water dispersible granules.
Described wetting powder formulation by weight percentage consists of: halosulfuronmethyl 0.01~80%, benzobicylon 0.1~80%, dispersant 0.1~15%, wetting agent 0.1~15%, solid carrier complements to 100%.Concrete production stage is: active ingredient and other auxiliary agent are mixed, after mechanical disintegration, again through air-flow crushing, mix, make wetting powder.
Described granule formulation by weight percentage consists of: halosulfuronmethyl 0.01~5%, benzobicylon 0.1~20%, binding agent 0.1~30%, dispersant 0.1~15%, wetting agent 0.1~10%, solid carrier complements to 100%.Concrete production stage is: active ingredient and other auxiliary agent are mediated through mixing and water adding, use comminutor pinch out and be shaped, by fluid-bed drying, screening for particle, make granule afterwards.
Described effervescent tablet formulation by weight percentage consists of: halosulfuronmethyl 0.01~80%, benzobicylon 0.1~80%, dispersant 0.1~15%, wetting agent 0.1~10%, solid acid 0.1~30%, carbonate 0.1~30%, binding agent 0.1~10%, flowing regulator 0.1~10%, solid carrier complements to 100%.Active ingredient, wetting agent, dispersant, solid acid, carbonate, flowing regulator and filler are fully mixed, then with low temperature micronizer, be crushed to 0.3~5 μ m, then the binding agent that adds water furnishing pasty state, after stirring, use tablet press machine film-making, finally by drying, whole grain, detect, pack after, make effervescent tablet.
Described granulae effervescentes formulation by weight percentage consists of: halosulfuronmethyl 0.01~80%, benzobicylon 0.1~80%, dispersant 0.1~15%, wetting agent 0.1~10%, solid acid 0.1~30%, carbonate 0.1~30%, binding agent 0.1~10%, flowing regulator 0.1~10%, solid carrier complements to 100%.Active ingredient, wetting agent, dispersant, solid acid, carbonate, flowing regulator and filler are fully mixed; then with low temperature micronizer, be crushed to 0.3~5 μ m; then the binding agent that adds water furnishing pasty state; after stirring, use granulator granulation; finally by drying, whole grain, detect, pack after, make granulae effervescentes.
Described defoamer can be one or more in silicone compound, epoxidized soybean oil, methyl alcohol, silicone oil etc.
Described antifreezing agent can be one or more in glycerine, propane diols, diethylene glycol (DEG), urea etc.
Described wetting agent can be one or more in lauryl sodium sulfate, neopelex, sodium butylnaphthalenesulfonate, sodium alkyl sulfonate, the withered powder of tea, spaonin powder, soapberry powder etc.
Described dispersant can be alkylphenol polyoxyethylene formaldehyde condensation products, naphthalenesulfonate formaldehyde condensation compound, to one or more in methoxyl group fatty acyl amido benzene sulfonic acid, lignosulfonates, polycarboxylate, alkylphenol polyoxyethylene sulphate, alkyl benzene sulfonate calcium salt, fatty acid ester sulphate, alkylphenol polyoxyethylene, fatty alcohol-polyoxyethylene ether etc.
Described disintegrant can be one or more in sodium carboxymethyl starch, low-substituted hydroxypropyl cellulose, Ac-Di-Sol, PVPP, shitosan, sodium alginate sodium bicarbonate, magnesium chloride, aluminium chloride, sodium chloride, urea, ammonium sulfate, bentonite etc.
Described thickener can be one or more in polyvinyl acetate, xanthans, gelatin, gum Arabic, aluminium-magnesium silicate, phenolic resins, CMC, sodium alginate etc.
Described solid carrier can be one or more in precipitated calcium carbonate, potter's clay, kaolin, diatomite, bentonite, white carbon, clay, attapulgite, talcum powder, quartz sand etc.
Described mixed fertilizer can be the fertilizer carrier that urea, composite fertilizer etc. exist with particle form.
Described liquid-carrier can be one or more in exquisite soybean oil, corn oil, rapeseed oil, turpentine oil, methyl oleate, cocoa butter, palm wet goods.
Described deionized water is industrialization deionized water.
Described binding agent can be one or more in sucrose, polyvinyl alcohol, polyethylene glycol, sodium carboxymethylcellulose, calcium carboxymethylcellulose, carboxy-propyl cellulose, dextrin, amylodextrin, polyvinylpyrrolidone, viscosity kaolin, paraffin, rosin etc.
Described solid acid can be one or more in citric acid, succinic acid, maleic acid, fumaric acid, tartaric acid, oxalic acid, malonic acid, malic acid, succinic acid, hexanedioic acid, boric acid, phosphoric acid, benzoic acid, sulfamic acid, salicylic acid, glutamic acid, phenylacetic acid, nicotinic acid or sorbic acid etc.
Described carbonate can be one or more in sodium carbonate, potash, ammonium carbonate, calcium carbonate, lithium carbonate, sodium bicarbonate, saleratus, lithium bicarbonate, sodium sesquicarbonate, bicarbonate tripotassium or bicarbonate three ammoniums etc.
Described flowing regulator can be one or more in calcium stearate, dolomol, barium stearate, titanium dioxide, talcum powder, Stepanol MG, polysorbate, wheat starch or Sodium Benzoate etc.
The frequency of administration of the present composition and amount of application have small variations with crops, weeds, weather condition variation, can be by using suitable dosage to reach the object of effective control.
Herbicidal combinations provided by the invention, is applicable to prevent and kill off paddy field barnyard grass, annual broadleaf weed and sedge weed.
Herbicidal combinations provided by the invention has following beneficial effect:
1, Herbicidal combinations provided by the invention, has synergistic function, especially to barnyard grass, dayflower.
2, Herbicidal combinations provided by the invention, has expanded the herbicide spectrum of halosulfuronmethyl and benzobicylon single dose, disposablely can solve paddy field barnyard grass, annual broadleaf weed and sedge weed.
3, provided by the invention is Herbicidal combinations, can reduce the resistance risk that the single halosulfuronmethyl of long-term use or benzobicylon produce, and extends the service life of medicament, the comprehensive regulation important in inhibiting to Weed Resistance.
Embodiment
In order to make object of the present invention, technical scheme and advantage more short and sweet, the present invention describes with following specific embodiment, but the present invention only limits to absolutely not these examples.The following stated is only the good embodiment of the present invention, only for describing the present invention, can not be interpreted as limitation of the scope of the invention.It should be pointed out that all any modifications of making within the spirit and principles in the present invention, be equal to replacement and improvement etc., within all should being included in protection scope of the present invention.
In these embodiments, unless otherwise indicated, all percentage is all weight percentage.
Embodiment mono-: benzobicylon and halosulfuronmethyl and the toxicity test being mixed to 2 leaf phase barnyard grasses thereof.
Table 1, benzobicylon and halosulfuronmethyl and the regression relation and the synergy that are mixed to the dose-response of 2 leaf phase barnyard grasses.
According to the abundant method of Sun Yun, co-toxicity coefficient is greater than two yuan of 120 expressions and is mixed target is shown as to synergistic function, by table 1, learnt, benzobicylon and halosulfuronmethyl in 60:1,30:1,15:1,10:1,5:1,1:1,1:5,1:10,1:15, ratio to the co-toxicity coefficient of barnyard grass all more than 120, as can be seen here, benzobicylon and halosulfuronmethyl show as synergistic function to barnyard grass under test ratio and in proportion.
Embodiment bis-: benzobicylon and halosulfuronmethyl and be mixed to 2 the leaf phase dayflower toxicity test.
Table 2, benzobicylon and halosulfuronmethyl and be mixed to 2 the leaf phase dayflower regression relation and the synergy of dose-response.
According to the abundant method of Sun Yun, co-toxicity coefficient is greater than two yuan of 120 expressions and is mixed target is shown as to synergistic function, by table 2 learn benzobicylon and halosulfuronmethyl in 60:1,30:1,15:1,10:1,5:1,1:1,1:5,1:10,1:15 ratio to the co-toxicity coefficient of dayflower all more than 130, as can be seen here, benzobicylon and halosulfuronmethyl show as synergistic function to dayflower under test ratio and in proportion.Embodiment tri-(halosulfuronmethyl benzobicylon water dispersible granules).
Above-mentioned material is added in cone-type mixer and mixed together; by airslide disintegrating mill, pulverize; material after pulverizing mixes through cone-type mixer again; mixed fineness of materials 98% is by 600 mesh standard sieves; add and in kneader, be kneaded into plasticity material; finally this material is put into Squeezinggranulator extruder grain, granulation is by the halosulfuronmethyl benzobicylon water dispersible granules that makes corresponding percentage by weight after being dried, sieving.
Embodiment tetra-(halosulfuronmethyl benzobicylon wetting powder).
Above-mentioned material is added in cone-type mixer and mixed together, by airslide disintegrating mill, pulverize, material after pulverizing mixes through cone-type mixer again, and mixed fineness of materials 98%, by 600 mesh standard sieves, obtains the halosulfuronmethyl benzobicylon wetting powder of corresponding percentage by weight.
Embodiment five (halosulfuronmethyl benzobicylon suspending agent).
Above-mentioned formula is pulverized in proportion in advance, then added in sand mill and grind, after high shear mixing, allotment makes the halosulfuronmethyl benzobicylon suspending agent of corresponding percentage by weight.
Embodiment six (halosulfuronmethyl benzobicylon oil-suspending agent).
Above-mentioned material (except organobentonite) is joined in reactor mixer together, stir 2 hours, open pan feeding valve at the bottom of still, material is injected to stage sand grinding machine to be ground, fineness of materials 98% after grinding is by discharging after 1-5um, material is put into high-shear emulsifying still together with the organobentonite good with prior dissolving again, can be made into the halosulfuronmethyl benzobicylon oil-suspending agent of the good corresponding percentage by weight of flowing to property after emulsification.
Embodiment seven (halosulfuronmethyl benzobicylon granule).
Active ingredient and other auxiliary agent are mediated through mixing and water adding, use comminutor pinch out and be shaped, by fluid-bed drying, screening for particle, make granule afterwards.
Embodiment eight: the field efficacy contrast to paddy field barnyard grass, annual broadleaf weed and sedge weed of benzobicylon and halosulfuronmethyl composition.
Table 3, benzobicylon and halosulfuronmethyl composition are to paddy field barnyard grass, annual broadleaf weed and the contrast of sedge weed field efficacy.
Benzobicylon, the impact of halosulfuronmethyl composition mixed fertilizer particle on transplant field rice tillering number.
Table 4, benzobicylon, halosulfuronmethyl composition mixed fertilizer particle affect application form to transplanting rice tiller number.
In sum, Herbicidal combinations of the present invention is outstanding to paddy field barnyard grass, annual broadleaf weed and sedge weed drug effect under appropriate dose, is the herbicide composition of preventing and kill off paddy field barnyard grass, annual broadleaf weed and sedge weed.
Claims (3)
1. a Herbicidal combinations that contains benzobicylon and halosulfuronmethyl, is characterized in that: active ingredient is benzobicylon, halosulfuronmethyl, and the ratio of weight and number of benzobicylon and halosulfuronmethyl is 15:1~1:60.
2. a kind of Herbicidal combinations that contains benzobicylon and halosulfuronmethyl according to claim 1, is characterized in that: its formulation is a kind of in suspending agent, oil-suspending agent, water dispersible granules, wetting powder, effervescent tablet, granulae effervescentes or granule.
3. a kind of Herbicidal combinations that contains benzobicylon and halosulfuronmethyl according to claim 1, is applicable to prevent and kill off paddy field barnyard grass, annual broadleaf weed and sedge weed.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410119307.3A CN103918688A (en) | 2014-03-27 | 2014-03-27 | Weeding composition containing benzobicylon and halosulfuron-methyl |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410119307.3A CN103918688A (en) | 2014-03-27 | 2014-03-27 | Weeding composition containing benzobicylon and halosulfuron-methyl |
Publications (1)
Publication Number | Publication Date |
---|---|
CN103918688A true CN103918688A (en) | 2014-07-16 |
Family
ID=51137275
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201410119307.3A Pending CN103918688A (en) | 2014-03-27 | 2014-03-27 | Weeding composition containing benzobicylon and halosulfuron-methyl |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN103918688A (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104255749A (en) * | 2014-09-10 | 2015-01-07 | 广东中迅农科股份有限公司 | Herbicide composition containing pyraclonil and benzobicylon |
CN106359427A (en) * | 2016-08-20 | 2017-02-01 | 广东中迅农科股份有限公司 | Weeding composition containing benzobicylon and propyrisulfuron |
CN106818830A (en) * | 2017-01-23 | 2017-06-13 | 河北博嘉农业有限公司 | A kind of ternary weeding composition containing pyraclonil, benzobicylon and sulfonylurea herbicide |
CN107156161A (en) * | 2017-06-08 | 2017-09-15 | 南京红太阳股份有限公司 | A kind of Herbicidal combinations and its application containing the bicyclic ketone of benzo and halosulfuronmethyl |
CN112674104A (en) * | 2015-12-23 | 2021-04-20 | 江苏龙灯化学有限公司 | Methods of controlling ALS-tolerant plant growth |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH1179910A (en) * | 1997-09-04 | 1999-03-23 | Sds Biotech Kk | Herbicidal composition for paddy field |
-
2014
- 2014-03-27 CN CN201410119307.3A patent/CN103918688A/en active Pending
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH1179910A (en) * | 1997-09-04 | 1999-03-23 | Sds Biotech Kk | Herbicidal composition for paddy field |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104255749A (en) * | 2014-09-10 | 2015-01-07 | 广东中迅农科股份有限公司 | Herbicide composition containing pyraclonil and benzobicylon |
CN112674104A (en) * | 2015-12-23 | 2021-04-20 | 江苏龙灯化学有限公司 | Methods of controlling ALS-tolerant plant growth |
CN106359427A (en) * | 2016-08-20 | 2017-02-01 | 广东中迅农科股份有限公司 | Weeding composition containing benzobicylon and propyrisulfuron |
CN106818830A (en) * | 2017-01-23 | 2017-06-13 | 河北博嘉农业有限公司 | A kind of ternary weeding composition containing pyraclonil, benzobicylon and sulfonylurea herbicide |
CN107156161A (en) * | 2017-06-08 | 2017-09-15 | 南京红太阳股份有限公司 | A kind of Herbicidal combinations and its application containing the bicyclic ketone of benzo and halosulfuronmethyl |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN108432769A (en) | A kind of composition pesticide of humulone containing quinoline and benzene flumetsulam | |
CN103918688A (en) | Weeding composition containing benzobicylon and halosulfuron-methyl | |
CN103392723B (en) | The Herbicidal combinations that contains pyrazosulfuron and KIH 6127 | |
CN103392713B (en) | The Herbicidal combinations that contains penoxsuam and KIH 6127 | |
CN103392722A (en) | Weeding composition containing bensulfuron methyl and pyriminobac-methyl | |
CN103392721B (en) | Containing AC322140 and the Herbicidal combinations of KIH 6127 | |
CN104472512A (en) | Herbicide in paddy field | |
CN104886099A (en) | Weeding composition for rice field | |
CN103518759A (en) | Weeding composition containing bensulfuron methyl and pyriftalid | |
CN102907447A (en) | Farm-oriented sterilization composition | |
CN105494407A (en) | Herbicide composition containing metamifop and cafenstrole | |
CN104823984A (en) | Weeding composition containing fluoropyribenzoxim and triafamone | |
CN104872143A (en) | Weeding composition containing fluorine pyribenzoxim and carfentrazone-ethyl | |
CN104012562A (en) | Weed control composition containing atrazine | |
CN103688967A (en) | Weeding composition containing halosulfuron-methyl and pyriftalid | |
CN105211074A (en) | Composition pesticide containing ring sulphur ketone and benzene azoles humulone and bromoxynil octanoate | |
CN104839188A (en) | Weeding composition containing propyrisulfuron, cyhalofop-butyl and penoxsulam | |
CN105746524A (en) | Pesticide composition containing bicyclopyrone, halosulfuron-methyl and bromoxynil octanoate | |
CN103098810B (en) | Penoxsulam-amidosulfuron weeding composition | |
CN103098812B (en) | Penoxsulam and triflusulfuron-methyl weeding composition | |
CN103960268A (en) | Herbicidecomposition containing oxadiargyl and orthosulfamuron | |
CN103109837B (en) | Penoxsulam and cyclosulfamuron herbicidal composition | |
CN103461351A (en) | Weeding composition containing bentazone and pyriminobac-methyl | |
CN105191949A (en) | Pesticide composition containing tembotrione, topramezone and atrazine | |
CN103858877B (en) | Biological bactericide neochamaejasmine B water dispersible granules and preparation method thereof |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
EXSB | Decision made by sipo to initiate substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
RJ01 | Rejection of invention patent application after publication | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20140716 |