CN103915623B - The preparation method of nano porous metal sulfide rechargeable magnesium cell anode material - Google Patents
The preparation method of nano porous metal sulfide rechargeable magnesium cell anode material Download PDFInfo
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- CN103915623B CN103915623B CN201410103424.0A CN201410103424A CN103915623B CN 103915623 B CN103915623 B CN 103915623B CN 201410103424 A CN201410103424 A CN 201410103424A CN 103915623 B CN103915623 B CN 103915623B
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/581—Chalcogenides or intercalation compounds thereof
- H01M4/5815—Sulfides
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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Abstract
The invention discloses the preparation method of a kind of nano porous metal sulfide rechargeable magnesium cell anode material, slaine and sulfur source compound being dissolved respectively in a solvent, then mix homogeneously, mixed solution is transferred in reactor, again reactor is transferred in baking oven, it is warmed up to 140～200 DEG C, after insulation 15～24h, furnace cooling, product deionized water and absolute ethanol washing are repeatedly, last drying processes, and obtains above-mentioned positive electrode, positive electrode chemical formula MyCoS1+xRepresenting, described M is the one of transition metal, and the span of described x, y is 0 ＜ x≤1,0≤y≤1.Positive electrode crystal property is good, regular appearance, it is possible to realize the reversible intercalation/deintercalation behavior of magnesium ion.The invention provides that a kind of electrochemical performance, preparation technology be simple, abundant raw material source, the preparation method of cheap rechargeable magnesium cell anode material, have broad application prospects.
Description
Technical field
The present invention relates to a kind of cell positive material, particularly relate to a kind of nano porous metal sulfide positive electrode
Preparation method, belong to rechargeable magnesium cell field.
Background technology
Recent decades, along with people's exploitation energetically to non-renewable resources, coal, oil equal energy source is the most withered
While exhausting, environmental pollution has also become problem demanding prompt solution.The demand of the energy is still constantly being increased by people,
The challenge of environmental problem is still in aggravation, therefore in the urgent need to research and development high-performance, the Green Chemistry power supply of low cost,
Electronic equipment and electric motor car project for high speed development.At present, business is widely used fills electrical source of power
Including lead-acid battery, Ni-MH battery and lithium secondary battery.Lithium battery is due to its high-energy-density and long circulating
In the life-span, become the most most popular electrochmical power source.But, owing to lithium metal fusing point is low, have the strongest change
Learn activity, will have serious potential safety hazard for large-sized power battery, and limit it and develop further.Metal
The features such as magnesium has cheap, and safety is high, environmentally friendly, as cell negative electrode material, theoretical ratio
Capacity is up to 2205mAh/g, and relative to standard hydrogen electrode, electrode potential is about-2.37V, is expected to become new
The chargeable electrochmical power source of large-sized power of type, for the exploitation of electric automobile.
Owing to magnesium ion polarity is strong, solvation phenomenon is serious, generates the passivating film of densification the most in the electrolytic solution,
At present, it is adaptable to the positive electrode of Mg secondary cell is less.The research of rechargeable magnesium cell anode is concentrated mainly on
It is capable of the material of magnesium ion embedding/deintercalation, such as transition metal oxide V2O5、MoO3, three dimensional structure
Sulfide Cheverel phase compound, polyanionic compound Mg0.5Ti2(PO4)3、Mg1.03Mn0.97SiO4
Deng.Wherein, Aurbach.D et al. is with Mg (AlCl2BuEt)2/ THF is as electrolyte, with Mo6S8As
The rechargeable magnesium cell that positive electrode is made, is the optimal rechargeable magnesium cell anode material of current combination property.
Transient metal sulfide is many excellent physical and chemical performances owing to its special structure has, by extensively
Use as energy storage material.Big theoretical specific capacity and preferable electric conductivity can be had as electrode material
Energy.Many metal sulfides all have two-dimentional interlayer structure, and its more weak Van der Waals force between layers makes
It has bigger interlamellar spacing, and the insertion/abjection reversible for magnesium ion provides certainly possible.
Nano material is due to its special " nano effect ": small-size effect, interface and skin effect, quantum
Dimensional effect, and have the magnetics more excellent than blocks of large material, optics, electricity, catalytic performance.
Due to the superior function of nano material, people's size to granule during preparing material, pattern has
The highest requirement, obtains the performance of excellence higher than block materials with expectation.In Mg secondary cell system
In, nano material has more preferable electrochemistry to show compared to block materials, little particle size can make magnesium from
Son diffusion length in positive electrode framework shortens, and the highest specific surface area makes between itself and electrolyte
Contact the most abundant.These performances all will be effectively improved the embedding kinetics of material.
Therefore, those skilled in the art be devoted to develop the more excellent rechargeable magnesium cell anode material of a kind of performance and
Preparation method.
Summary of the invention
Because the drawbacks described above of prior art, the technical problem to be solved is to provide a kind of electrochemistry
Excellent performance, preparation technology be simple, abundant raw material source, cheap rechargeable magnesium cell anode material
Preparation method.
The preparation method of a kind of rechargeable magnesium cell anode material, comprises the following steps:
A. by dissolving metal salts in a solvent, metal salt solution is obtained；Sulfur source compound is dissolved in a solvent,
Obtain sulfur source compound solution；
B. metal salt solution and sulfur source compound solution are mixed and stirred for more than 30min, obtain mixing molten
Liquid, transfers to mixed solution to have in teflon-lined stainless steel cauldron；
C. stainless steel cauldron is transferred in baking oven, be warmed up to 140～200 DEG C, after insulation 15～24h,
With described baking oven natural cooling, obtain product；
The most first with deionized water, product is repeatedly washed, more repeatedly washs with dehydrated alcohol, after through dry
Dry process, obtains positive electrode；
The positive electrode that above-mentioned steps obtains is nano porous metal sulfide, uses chemical formula MyCoS1+xRepresent,
M is the one of transition metal, and the span of x, y is 0 ＜ x≤1,0≤y≤1.
Further, in step a, slaine is the villaumite of metal, acetate, nitrate or sulfate, gold
Belong to the combination for cobalt or cobalt with other metals, other metals among titanium, ferrum, nickel, zinc, copper one
Plant or multiple.
Further, in step a, sulfur source compound is selected from ammonium sulfide (NH4S), thioacetamide (C2H5NS),
Thiourea (CH4N2S), cysteine (C3H7NO2S) one or more among.
Further, in step a, solvent one among water, water and ethylene glycol mixture.
Further, water and ethylene glycol mixture are by water and ethylene glycol water by volume: ethylene glycol=1:1's～1:4
Ratio mixes.
Further, in step a, in metal salt solution, the substance withdrawl syndrome of metallic element is
0.05～0.5mol/L.
Further, in step b, according to gold during the amount of the material of element sulphur is slaine in sulfur source compound
The ratio of 1～3 times of the amount of the material of genus element, mixes metal salt solution and sulfur source compound solution.
Further, in step b, slaine accounts in reactor with the volume of the mixed solution of sulfur source compound
The 80% of volume.
Further, in step d, described dried refers to 60 DEG C of vacuum drying 10h.
The invention has the beneficial effects as follows: use solvent structure nano porous metal sulfide material, institute
Obtaining material and have good crystallinity, granule is tiny, does not produce serious agglomeration phenomenon, well-regulated pattern.
At 0.25M Mg (AlCl2BuEt)2In/THF electrolyte system, this material shows good electrochemistry
Can: having obvious charging/discharging voltage platform, stable discharging specific capacity is 125mAh/g, circulates through 60 times,
Specific capacity is still more than the 80% of initial capacity, has preferable reversibility.
Below with reference to accompanying drawing, the technique effect of design, concrete structure and the generation of the present invention is described further,
To be fully understood from the purpose of the present invention, feature and effect.
Accompanying drawing explanation
Fig. 1 is the XRD figure of the pure phase of CoS that embodiment 1 prepares；
Fig. 2 is the SEM shape appearance figure of the pure phase of CoS that embodiment 1 prepares；
Fig. 3 is that CoS compound the stablizing under the electric current density of 50mA/g that embodiment 1 prepares is filled
Discharge curve；
Fig. 4 be the circulation under the electric current density of 50mA/g of the CoS compound for preparing of embodiment 1-
Specific discharge capacity curve；
Fig. 5 is the Ni that embodiment 2 prepares0.5CoS2Compound circulation under 0.5mV/s scanning speed
Volt-ampere curve；
Fig. 6 is the Fe that embodiment 3 prepares0.1The room temperature cycles of CoS compound-specific capacity curve, internal
Curve is the charging and discharging curve under different cycle-indexes.
Detailed description of the invention
Below by way of specific embodiment, technical scheme is described in further detail.Hereinafter implement
Example is to further illustrate the present invention, but does not limits the scope of the invention.
In following example preparation the positive electrode compound powder obtained apply in rechargeable magnesium cell with
Method of testing is as follows:
The nanometer powder prepared with the present embodiment is as positive electrode active materials, with activated carbon, binding agent (poly-partially
Difluoroethylene PVDF) uniformly mix according to mass ratio 8:1:1 after, add organic solvent N-methyl pyrilidone
(NMP) as dispersant, stir to viscous pasty state, according to experiment demand pole piece weight, by coating automatically
Machine selects suitable thickness, is coated on copper foil of affluxion body, with 60 DEG C of dry 5h in vacuum drying oven.
Then, apply certain pressure by electronic twin rollers, be pressed into thickness uniform, the pole piece of powder difficult drop-off,
The disk being cut into diameter 16mm by microtome i.e. prepares positive plate.Pure magnesium ingot is cut by line, cutting
Become thick 1mm, the disk of diameter 15mm, soak the oxide layer removing surface with dilute hydrochloric acid after, beat with sand paper
It is milled to the magnesium sheet of double-sided light, i.e. prepares battery cathode.With positive plate as working electrode, simple metal magnesium is right
Electrode, Celgard2400 is barrier film, 0.25M Mg (AlCl2BuEt)2/ THF is electrolyte, at argon hands
Casing is assembled into button cell.
Electrochemical property test uses Land battery performance testing system and CHI-660A electrochemical workstation to enter
Row characterizes, and charge-discharge test uses the constant current test under different electric current density, and discharge and recharge blanking voltage scope is
0.1～2V, cyclic voltammetry sweep limits is 0.1～2V, and scanning speed is respectively 0.1mV/s according to condition,
0.5mV/s。
Embodiment 1: the preparation of compound CoS
1, weighing 60mL deionized water and 15mL ethylene glycol with graduated cylinder, mix homogeneously is as reaction dissolvent.
2, with cobaltous chloride (CoCl2·6H2O), cysteine (C3H7NO2S) it is raw material, according to atom
Mol ratio is that Co:S=1:3 weighs, and is dissolved in mixed solvent, by magnetic stirring apparatus strong stirring uniformly after, will
Mixed solution moves on to have in teflon-lined stainless steel cauldron, solution pinkiness.
3, the reactor of sealing is transferred in baking oven, be slowly warmed up to 200 DEG C, cold with stove after insulation 20h
But.
4, reacted solution (comprising black precipitate) is the most washed with ethanol by deionized water
Filter to remove Organic substance and the inorganic ions being coated on its surface.Product is put into vacuum drying oven with 60 DEG C
Temperature is dried 10h, prepares electrode slice and carries out electro-chemical test.
The present embodiment has prepared the pure phase of CoS (such as Fig. 1), and the CoS of synthesis is by independent CoS nanometer
Thin slice is self-assembly of hierarchy.The thickness of each CoS nanometer sheet is about 40nm, is typical
Nanostructured (such as Fig. 2).
Nano Co S that the present embodiment prepares carries out charge and discharge in aforementioned Mg secondary cell electrolyte system
Electricity, has obvious charging/discharging voltage platform, and stable discharging specific capacity is 125mAh/g, circulates through 60 times,
Specific capacity is still more than the 80% of initial capacity, has preferable reversibility (such as Fig. 3, Fig. 4).
Embodiment 2: compound N i0.5CoS2Preparation:
1, with nickel sulfate (Ni (SO4)2·6H2O), cobaltous chloride (CoCl2·6H2And thiourea (CH O)4N2S)
For raw material, weigh raw material respectively according to the atomic molar ratio than Ni:Co:S=1:2:12, soluble in water, logical
Cross magnetic stirring apparatus strong stirring uniformly after, mixed solution is moved on to has teflon-lined rustless steel
In reactor.
2, aforesaid reaction vessel is transferred in baking oven, be warmed up to 180 DEG C, furnace cooling after insulation 15h.
3, reacted solution (comprising black precipitate) is the most washed with ethanol by deionized water
Filter to remove Organic substance and the inorganic ions being coated on its surface.Product is put into vacuum drying oven with 60 DEG C
Temperature is dried 10h, prepares electrode slice and carries out electro-chemical test.
The present embodiment has obtained Ni0.5CoS2Phase, in electrochemical property test, the cyclic voltammetric of this battery is bent
Line has obvious oxidoreduction peak, and the most corresponding electric potential difference between oxidoreduction peak is less than 0.5V, explanation
There is preferable cyclic reversibility (such as Fig. 5).
Embodiment 3: compound Fe0.1The preparation of CoS:
1, with ferrous sulfate (Fe (SO4)2·6H2O), cobaltous sulfate (CoSO4·7H2And thioacetamide O)
(C2H5NS) it is raw material, weighs raw material respectively according to the atomic molar ratio than Fe:Co:S=1:8:18, molten
In ethylene glycol, by magnetic stirring apparatus strong stirring uniformly after, mixed solution is moved on to have polytetrafluoroethyl-ne
In the stainless steel cauldron of alkene liner.
2, aforesaid reaction vessel is transferred in baking oven, be warmed up to 160 DEG C, furnace cooling after insulation 20h.
3, reacted solution (comprising black precipitate) is the most washed with ethanol by deionized water
Filter to remove Organic substance and the inorganic ions being coated on its surface.Product is put into vacuum drying oven with 60 DEG C
Temperature is dried 10h, prepares electrode slice and carries out electro-chemical test.
The present embodiment has obtained Fe0.1CoS phase, is being circulated charge and discharge process, and specific discharge capacity can reach
To 160mAh/g, front 15 charge and discharge process do not occur the decay (such as Fig. 6) of capacity.
The preferred embodiment of the present invention described in detail above.Should be appreciated that the ordinary skill of this area
Personnel just can make many modifications and variations according to the design of the present invention without creative work.Therefore, all
Technical staff passes through logical analysis the most on the basis of existing technology, pushes away in the art
Reason or the limited available technical scheme of experiment, all should be at the protection model being defined in the patent claims
In enclosing.
Claims (8)
1. the preparation method of a rechargeable magnesium cell anode material, it is characterised in that comprise the following steps:
A. by dissolving metal salts in a solvent, obtaining metal salt solution, described slaine is the villaumite of ferrum, acetic acid
Salt, nitrate or sulfate；Sulfur source compound is dissolved in a solvent, obtains sulfur source compound solution；
B. described metal salt solution and described sulfur source compound solution are mixed and stirred for, obtain slaine and sulfur source
The mixed solution of compound, transfers to have politef by the mixed solution of described slaine Yu sulfur source compound
In the stainless steel cauldron of liner；
C. transferring in baking oven by described stainless steel cauldron, described baking oven is warmed up to 140～200 DEG C, insulation 15～
After 24h, described stainless steel cauldron, with described baking oven natural cooling, obtains product；
The most first with deionized water, above-mentioned product is repeatedly washed, more repeatedly washs with dehydrated alcohol, after warp
Dried, obtains described positive electrode；
The described positive electrode that above-mentioned steps obtains is nano porous metal sulfide Fe0.1CoS。
The preparation method of a kind of rechargeable magnesium cell anode material the most according to claim 1, it is characterised in that:
The one among ammonium sulfide, thioacetamide, thiourea or cysteine of sulfur source compound described in step a or
Multiple.
The preparation method of a kind of rechargeable magnesium cell anode material the most according to claim 1, it is characterised in that:
In step a, described solvent one among water, water and ethylene glycol mixture.
The preparation method of a kind of rechargeable magnesium cell anode material the most according to claim 3, it is characterised in that:
Described water with ethylene glycol mixture by water and ethylene glycol water by volume: the ratio of ethylene glycol=1:1～1:4 mix and
Become.
The preparation method of a kind of rechargeable magnesium cell anode material the most according to claim 1, it is characterised in that
In step a, in described metal salt solution, the substance withdrawl syndrome of metallic element is 0.05～0.5mol/L.
The preparation method of a kind of rechargeable magnesium cell anode material the most according to claim 1, it is characterised in that
In step b, it is the material of metallic element in slaine according to the amount of the material of element sulphur in described sulfur source compound
The ratio of 1～3 times of amount, mixes described metal salt solution and described sulfur source compound solution.
The preparation method of a kind of rechargeable magnesium cell anode material the most according to claim 1, it is characterised in that
In step b, described slaine accounts for the 80% of reactor internal volume with the volume of the mixed solution of sulfur source compound.
The preparation method of a kind of rechargeable magnesium cell anode material the most according to claim 1, it is characterised in that:
In step d, described dried refers to 60 DEG C of vacuum drying 10h.
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| CN104227013B (en) * | 2014-09-13 | 2016-05-11 | 福建医科大学 | N-acetyl-L-cysteine-gold nano cluster fluorescent material and preparation method thereof |
| CN105355919A (en) * | 2015-11-12 | 2016-02-24 | 西南大学 | Preparation method of copper, cobalt and sulfur micropowder |
| CN106904653B (en) * | 2017-01-22 | 2019-06-07 | 重庆大学 | It the preparation method of vanadium dioxide nano material and is applied in magnesium chargeable battery |
| CN110078121A (en) * | 2019-05-21 | 2019-08-02 | 上海交通大学 | A kind of preparation method and application of Magnesium ion battery vanadic anhydride positive electrode |
| CN111599980A (en) * | 2020-06-18 | 2020-08-28 | 电子科技大学 | NixFe1-xS2Solid solution cathode material and preparation method thereof |
| CN113725416A (en) * | 2021-09-01 | 2021-11-30 | 广东省国研科技研究中心有限公司 | CuCo2S4/Cu7.4S4Nano composite material and preparation method and application thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102024996A (en) * | 2010-11-26 | 2011-04-20 | 南开大学 | High-performance rechargeable magnesium battery and manufacturing method thereof |
| CN102969501A (en) * | 2012-11-19 | 2013-03-13 | 上海交通大学 | Application method of binary metal sulfides in chargeable magnesium battery |
| CN103137965A (en) * | 2011-11-25 | 2013-06-05 | 中国科学院物理研究所 | Multi-metal sulfide composite negative electrode material, preparation method and uses thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102024996A (en) * | 2010-11-26 | 2011-04-20 | 南开大学 | High-performance rechargeable magnesium battery and manufacturing method thereof |
| CN103137965A (en) * | 2011-11-25 | 2013-06-05 | 中国科学院物理研究所 | Multi-metal sulfide composite negative electrode material, preparation method and uses thereof |
| CN102969501A (en) * | 2012-11-19 | 2013-03-13 | 上海交通大学 | Application method of binary metal sulfides in chargeable magnesium battery |
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