CN103911063B - A kind of self-lubrication treatment agent compositions and hot dip aluminum zinc plate and preparation method thereof - Google Patents
A kind of self-lubrication treatment agent compositions and hot dip aluminum zinc plate and preparation method thereof Download PDFInfo
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Abstract
The invention discloses a kind of self-lubrication treatment agent compositions, wherein, said composition contains water, silica sol, sodium silicate, lubricant, inorganic inhibitor, silane coupler and organic resin.Present invention also offers a kind of hot dip aluminum zinc plate, this hot dip aluminum zinc plate includes hot-dip aluminizing zinc plate substrate and attachment coating on substrate surface, and wherein, described coating is formed by self-lubrication treatment agent compositions as above.The preparation method that the invention also discloses a kind of hot dip aluminum zinc plate, the method includes: self-lubrication treatment agent compositions as above is configured to coating fluid, by described coating solution on hot-dip aluminizing zinc plate substrate, then solidifies.The coating that self-lubrication treatment agent compositions provided by the invention is formed after solidifying has good corrosion resistance, thermostability, resistance to water and adsorptivity, and its anti-finger printing and self lubricity are excellent especially.
Description
Technical field
The present invention relates to a kind of self-lubrication treatment agent compositions and hot dip aluminum zinc plate and preparation method thereof.
Background technology
In recent years, improving constantly the needs with market along with technology, hot dip aluminum zinc plate develops rapidly because the characteristics such as its excellent corrosion resistance, decorative appearance obtain.Hot dip aluminum zinc plate application at home essentially consists in building and regulator cubicle manufacturing industry: it based on Thin Specs, is mainly used as precoated substrate in the application of building industry；It based on think gauge, is mainly directly used as cabinet in the manufacturing application of regulator cubicle.At present, the application of hot dip aluminum zinc plate is significantly to household electrical appliances, the extension of automobile sheetsteel field.But hot dip aluminum zinc plate great majority in user's use procedure such as household electrical appliances, auto manufacturing need stamped shaping.Due to the friction between mould and steel plate, easily there is the problem such as dry linting, black change when shaping in coating, not only affect the presentation quality of forming part, corrosion resistance, coating etc., and the abrasion of mould can be aggravated, reduce its service life, and the performance such as the corrosion resistance of existing hot dip aluminum zinc plate, anti-finger printing, thermostability still needs to be improved further.Therefore, need badly exploitation a kind of without chromium, constituent is half organically, has the self-lubrication treatment agent being base material with hot-dip aluminizing zincium steel plate of good corrosion resistance, thermostability, resistance to water, adsorptivity, film property, lubricity.
Summary of the invention
It is an object of the invention to provide a kind of without chromium, constituent is half organically, has the self-lubrication treatment agent compositions of good corrosion resistance, anti-finger printing, thermostability, resistance to water, adsorptivity, film property and self lubricity, and use said composition as hot dip aluminum zinc plate of coating and preparation method thereof.
To achieve these goals, the present invention provides a kind of self-lubrication treatment agent compositions, and wherein, said composition contains water, silica sol, sodium silicate, lubricant, inorganic inhibitor, silane coupler and organic resin.
Present invention also offers a kind of hot dip aluminum zinc plate, this hot dip aluminum zinc plate includes hot-dip aluminizing zinc plate substrate and attachment coating on substrate surface, and wherein, described coating is formed by self-lubrication treatment agent compositions provided by the present invention.
The preparation method that present invention also offers a kind of hot dip aluminum zinc plate, the method includes: self-lubrication treatment agent compositions provided by the present invention is configured to coating fluid, by described coating solution on hot-dip aluminizing zinc plate substrate, then solidifies.
By technique scheme, the invention provides a kind of self-lubrication treatment agent compositions and there is the hot dip aluminum zinc plate of excellent self lubricity and the preparation method of this aluminum zine plate.
Self-lubrication treatment agent compositions provided by the present invention is not owing to containing heavy metal chromium, so having the feature of Environmental Safety, additionally, the constituent of self-lubrication treatment agent compositions provided by the present invention is half organic composition, the coating formed after hardening has good corrosion resistance, thermostability, resistance to water, tack and film property, and its anti-finger printing and self lubricity are excellent especially.
Other features and advantages of the present invention will be described in detail in detailed description of the invention part subsequently.
Detailed description of the invention
Hereinafter the specific embodiment of the present invention is described in detail.It should be appreciated that detailed description of the invention described herein is merely to illustrate and explains the present invention, it is not limited to the present invention.
The invention provides a kind of self-lubrication treatment agent compositions, wherein, said composition contains water, silica sol, sodium silicate, lubricant, inorganic inhibitor, silane coupler and organic resin.
The content of above each material is had no particular limits by the present invention, as long as can realize the purpose of the present invention containing above material in compositions.Preferably, with the water of 100 weight portions for benchmark, the content of described silica sol is 2-30 weight portion, the content of described sodium silicate is 0.5-10 weight portion, the content of described lubricant is 5-30 weight portion, the content of described inorganic inhibitor is 0.1-5 weight portion, and the content of described silane coupler is 2-20 weight portion, and the content of described organic resin is 1-50 weight portion.
More preferably, with the water of 100 weight portions for benchmark, the content of described silica sol is 5-20 weight portion, the content of described sodium silicate is 4-8 weight portion, the content of described lubricant is 10-25 weight portion, the content of described inorganic inhibitor is 1.5-4 weight portion, and the content of described silane coupler is 8-16 weight portion, and the content of described organic resin is 15-45 weight portion.
Self-lubrication treatment agent compositions according to the present invention, wherein, described silica sol can be purchased, it is also possible to prepares according to the preparation method of the silica sol of this area routine.Preferably, the particle diameter of silica sol of the present invention is 1-150nm, more preferably 1-50nm.
Self-lubrication treatment agent compositions according to the present invention, wherein, described lubricant can be at least one in water-base fluorocarbon emulsion, silicone oil emulsion, polythene wax emulsion, polytetrafluoroethylwax wax emulsion and Brazil wax emulsion.In order to improve self-lubricating property further, described lubricant is preferably at least one in water-base fluorocarbon emulsion, polythene wax emulsion and polytetrafluoroethylwax wax emulsion.
Self-lubrication treatment agent compositions according to the present invention, wherein, described organic resin can be at least one in water-borne acrylic resin, aqueous styrene-acrylic resin, resol resins, waterborne polyurethane resin, waterborne organic silicon resin and aqueous epoxy resins.In order to improve coating performance further, described organic resin is preferably at least one in water-borne acrylic resin, aqueous styrene-acrylic resin and aqueous polyurethane.
Self-lubrication treatment agent compositions according to the present invention, wherein, described inorganic inhibitor can be at least one in potassium permanganate, disodium-hydrogen, sodium nitrite, sodium tripolyphosphate, zinc sulfate and sodium molybdate.In order to improve corrosion resisting property further, described inorganic inhibitor is preferably at least one in sodium nitrite, sodium molybdate and potassium permanganate.
Self-lubrication treatment agent compositions according to the present invention, wherein, described silane coupler can be at least one in gamma-aminopropyl-triethoxy-silane (KH550), γ-glycidyl ether oxygen propyl trimethoxy silicane (KH560), γ-methacryloxypropyl trimethoxy silane (KH570), γ-mercaptopropyl trimethoxysilane (KH590), vinyltrimethoxy silane (KH171) and N-(β-aminoethyl)-γ-aminopropyltrimethoxysilane (KH792).In order to obtain the corrosion proof effect of excellence further, described silane coupler is preferably N-(β-aminoethyl)-γ-aminopropyltrimethoxysilane and/or γ-methacryloxypropyl trimethoxy silane.
Self-lubrication treatment agent compositions according to the present invention, wherein, in order to improve the performance of described self-lubrication treatment agent compositions further, described raw mixture can also contain auxiliary agent.Wherein, it is preferable that in situation, relative to the water of 100 weight portions, the consumption of described auxiliary agent is 0.1-2 weight portion, more preferably 0.3-1 weight portion.
The kind of described auxiliary agent is had no particular limits by the present invention, if the purpose of the present invention of being capable of.It was found by the inventors of the present invention that when described auxiliary agent is at least one in surfactant, levelling agent and defoamer, the as above performance of compositions provided by the invention can be further enhanced.
Wherein, in described auxiliary agent, surfactant, levelling agent and defoamer can be surfactant commonly used in the art, levelling agent and defoamer, such as, described surfactant can be at least one in alkylphenol polyoxyethylene (OP-10), dodecylbenzene sodium sulfonate and sodium lauryl sulphate；Described levelling agent can be polyurethane levelling agent；Described defoamer can be Polyether Modified Polysiloxanes Defoaming Agent.
Wherein, when described auxiliary agent is levelling agent, surfactant and defoamer, in the composition, relative to the water of 100 weight portions, the content of described levelling agent can be 0.05-1 weight portion, described surfactant content can be 0.02-0.5 weight portion, described defoamer content can be 0.03-0.5 weight portion.
Self-lubrication treatment agent compositions according to the present invention, wherein, it is particularly preferred to when, the particle diameter of described silica sol is 1-50nm；Sodium silicate (Na2SiO3)；Described lubricant is water-base fluorocarbon emulsion and/or polythene wax emulsion；Described silane coupler is at least one in gamma-aminopropyl-triethoxy-silane, γ-glycidyl ether oxygen propyl trimethoxy silicane and γ-methacryloxypropyl trimethoxy silane；Described inorganic inhibitor is sodium nitrite and/or sodium molybdate；Described organic resin is water-borne acrylic resin and/or aqueous polyurethane.Under this preferable case, after described self-lubrication treatment agent compositions solidifies at 80-110 DEG C, the coating of gained has prominent corrosion resistance, thermostability, resistance to water, adsorptivity, film property, and its anti-finger printing and self-lubricating property are excellent especially.
Wherein, said composition for obtain after each composition mix homogeneously.Under preferable case, each component in described compositions obtains the compositions of liquid form at this self-lubrication treatment agent compositions 2-60 days mix homogeneously before use.Wherein, the order by merging of each composition is not specially required, it is possible to directly each component in described raw mixture is carried out simultaneously, in batches or substep mixing, if can obtain uniform stable mutually, it is preferable that make mixing more uniform by stirring.
The present inventor has surprisingly found that, the self-lubrication treatment agent compositions that above each material carries out being mixed with according to ratio as above can also effectively be improved rate of film build so that film formation time is greatly shortened, thus effectively providing production efficiency.
The present invention also provides for a kind of self-lubricating agent, and this self-lubricating agent is obtained by after above-mentioned self-lubricating agent compositions mix homogeneously.
Present invention also offers a kind of hot dip aluminum zinc plate, this hot dip aluminum zinc plate includes hot-dip aluminizing zinc plate substrate and attachment coating on substrate surface, and wherein, described coating is formed by self-lubrication treatment agent compositions of the present invention.
Hot dip aluminum zinc plate according to the present invention, wherein, the thickness of described coating can be 0.05-0.3 micron.
Hot dip aluminum zinc plate according to the present invention, wherein, described coating is described self-lubrication treatment agent compositions to be attached on described hot-dip aluminizing zinc plate substrate, and is solidify under 80-110 DEG C and condition of cure that hardening time is 10-60s to obtain in solidification temperature.
The inventors found that, the pH value of self-lubrication treatment agent compositions provided by the invention is between 8-13, it is particularly well-suited to hot dip aluminum zinc plate, when the self-lubrication treatment agent compositions of the present invention is coated on hot dip aluminum zinc plate, the coating of described compositions has good corrosion resistance, thermostability, resistance to water, adsorptivity, film property, especially has good anti-finger printing and self-lubricating property.
The preparation method that present invention also offers a kind of hot dip aluminum zinc plate, the method includes: self-lubrication treatment agent compositions of the present invention is configured to coating fluid, by described coating solution on hot-dip aluminizing zinc plate substrate, then solidifies.
The preparation method of the hot dip aluminum zinc plate according to the present invention, the consumption of described self-lubrication treatment agent makes the thickness of the coating formed on described hot-dip aluminizing zinc plate substrate be 0.05-0.3 micron.
The preparation method of the hot dip aluminum zinc plate according to the present invention, wherein, temperature and time those skilled in the art of described solidification can be adjusted according to practical situation, it is preferable that the temperature of described solidification is 80-110 DEG C, and the time is 10-60s.
Wherein, the method of described coating can adopt the coating process for forming coating on a metal plate that this area is conventional, such as, described self-lubricating agent compositions roller coat can be coated in the surface of described hot-dip aluminizing zinc plate substrate, or described self-lubricating agent compositions is sprayed on the surface of described hot-dip aluminizing zinc plate substrate.
Wherein, the temperature to the coating of described self-lubricating agent compositions, the present invention has no particular limits, and those skilled in the art can not freeze in described self-lubricating agent compositions or select voluntarily in the temperature range vaporized, for instance, it is possible to for 5-40 DEG C.
Wherein, the mode of heating of described solidification, it is possible to for one or more in Hot-blast Heating, sensing heating and infrared radiation heating.Under preferable case, it is possible to use the curing oven on hot-dip aluminizing zinc wire carries out.
Present invention also offers the hot dip aluminum zinc plate that the preparation method according to hot dip aluminum zinc plate as above prepares.
Hereinafter will be described the present invention by embodiment.
Reagent used in following example and comparative example is all commercially available.Without being prescriptive, described reagent is analytical pure.
Embodiment 1-10 and comparative example 1-6
According to the constituent content that table 1 is listed, by each component mix homogeneously under agitation, respectively obtain self-lubricating agent compositions A1-A10 and D1-D6.
Table 1
In self-lubricating agent compositions A1-A10 and D1-D6, each component specifically chosen as follows:
Silica sol mean diameter is 30nm；
Sodium silicate is sodium metasilicate, lubricant is water-base fluorocarbon emulsion (solid content is 46%) and polythene wax emulsion (solid content is 46%) (the two weight ratio is 7:3), inorganic inhibitor is sodium nitrite and sodium molybdate (the two weight ratio is 3:2), the KH560 that silane coupler is selected, organic resin is aqueous polyurethane (solid content is 30%) and aqueous styrene-acrylic resin (solid content is 30%) (the two weight ratio is 4:1), it auxiliary agent is levelling agent, surfactant, defoamer (three's weight ratio is 3:1:1), wherein surfactant is OP-10, levelling agent is polyurethane levelling agent (solid content is 20%)；Defoamer is Polyether Modified Polysiloxanes Defoaming Agent (solid content is 35%).
In self-lubricating agent compositions A7, with A1 the difference is that, lubricant is Brazil wax emulsion (solid content is 30%).
In self-lubricating agent compositions A8, with A1 the difference is that, inorganic inhibitor is sodium tripolyphosphate and potassium permanganate (the two weight ratio is 1:1).
In self-lubricating agent compositions A9, with the A1 KH171 selected the difference is that, silane coupler.
In self-lubricating agent compositions A10, with A1 the difference is that, organic resin is water-borne acrylic resin (solid content is 48%) and resol resins (solid content is 30%) (the two weight ratio is 7:3).
Preparation example 1
Self-lubricating agent compositions A1-A10 and D1-D6 roller coat respectively is coated on hot-dip aluminizing zinc steel band, under the solidification temperatures of 100 DEG C (adopting thermometric reagent paper to measure solidification temperature), solidifies 25s respectively obtain hot dip aluminum zinc plate B1-B10 and the DB1-DB6 containing passivating coating.
Test case 1
The corrosion resistance of the coating of hot dip aluminum zinc plate B1-B10 and DB1-DB6, thermostability, resistance to water, tack and self lubricity is measured by this test case.Result is in Table 2.
Wherein, corrosion resistance carries out corrosion testing according to the method for regulation in GB/T10125-1997 and condition, then according to Corrosion results is evaluated (percentage ratio accounting for the gross area with the corroded area after 72 hours represents) by the regulation of GB12335-90.Wherein, corroded area is the smaller the better.
Anti-finger printing is to smear the change of value of chromatism before and after vaseline according to specimen surface to carry out judging: if the change of front and back aberration is less than 2, be then A level；If front and back aberration vary more than 2, less than 4, be then B level；If front and back aberration vary more than 4, then be C level.
Thermostability is to carry out judging according to sample change of 20min under 300 DEG C of conditions: if the change of front and back aberration is less than 4, and the phenomenon such as rete bubble does not occur, comes off, dry linting, then be A level；If front and back aberration vary more than 4, less than 8, and the phenomenon such as rete bubble does not occur, comes off, dry linting, be then B level；If front and back aberration vary more than 8, and the phenomenon such as rete bubble does not occur, comes off, dry linting, then be C level.
Resistance to water adopts 100 DEG C of deionized water drop to be measured in sample: if the complete anhydrous mark of sample, be then A level；There is slight water mark, be then B level；Obvious water mark, then be C level.
Tack is to carry out judging according to the dry linting degree that comes off of coating after 180 ° of bendings of sample: if the phenomenon such as coming off does not occur in coating, dry linting, be then A level；If dry linting occurring but obscission not occurring, then it it is B level；If obscission occurs, then it it is C level.
Self lubricity judges by measuring the coefficient of friction of coating surface, and wherein coefficient of friction is more little, then self lubricity is more good.
Table 2
| Corrosion resistance/% | Anti-finger printing % | Thermostability | Resistance to water | Tack | Self lubricity | |
| B1 | 1 | A | A | A | A | 0.08 |
| B2 | 1 | B | A | A | A | 0.12 |
| B3 | 4 | A | A | A | B | 0.11 |
| B4 | 10 | B | B | B | B | 0.16 |
| B5 | 5 | A | B | A | A | 0.1 |
| B6 | 3 | A | A | B | B | 0.14 |
| B7 | 1 | A | A | A | A | 0.14 |
| B8 | 4 | A | A | B | A | 0.15 |
| B9 | 6 | A | A | A | A | 0.12 |
| B10 | 3 | A | B | A | A | 0.13 |
| DB1 | 3 | A | A | A | A | 0.41 |
| DB2 | 2 | C | A | B | A | 0.15 |
| DB3 | 25 | A | C | B | B | 0.12 |
| DB4 | 14 | A | C | B | A | 0.11 |
| DB5 | 18 | A | C | C | B | 0.17 |
| DB6 | 17 | A | A | B | B | 0.13 |
By the data of table 2, by the contrast of hot dip aluminum zinc plate B1-B10 and DB1-DB6, it is possible to
9 find out, self-lubricating agent compositions provided by the invention coating of obtaining under solidifying takes into account the performances such as excellent corrosion resistance, thermostability, resistance to water, adsorptivity and self lubricity simultaneously.
Especially, by the contrast of embodiment 1 and embodiment 4-6, it is found that at the water preferably with respect to 100 weight portions, the content of described silica sol is 5-20 weight portion；The content of described sodium silicate is 4-8 weight portion；The content of described lubricant is 10-25 weight portion；The content of described inorganic inhibitor is 1.5-4 weight portion；The content of described silane coupler is 8-16 weight portion；The content of described organic resin is 15-45 weight portion, and when containing auxiliary agent, described coating has prominent corrosion resistance, thermostability, resistance to water, anti-finger printing, self lubricity.
Especially, contrast by embodiment 1 and embodiment 7-10, it appeared that, the kind of each component is controlled when currently preferred kind, after described self-lubrication treatment agent compositions solidifies at 80-110 DEG C, the coating of gained has prominent tack, corrosion resistance, thermostability, resistance to water and adsorptivity, and its anti-finger printing and self-lubricating property are excellent especially.
The preferred embodiment of the present invention described in detail above; but, the present invention is not limited to the detail in above-mentioned embodiment, in the technology concept of the present invention; technical scheme can being carried out multiple simple variant, these simple variant belong to protection scope of the present invention.
It is further to note that each the concrete technical characteristic described in above-mentioned detailed description of the invention, in reconcilable situation, it is possible to be combined by any suitable mode.In order to avoid unnecessary repetition, various possible compound modes are no longer illustrated by the present invention separately.
Additionally, can also carry out combination in any between the various different embodiment of the present invention, as long as it is without prejudice to the thought of the present invention, it should be considered as content disclosed in this invention equally.
Claims (16)
1. a self-lubrication treatment agent compositions, it is characterized in that, said composition is made up of water, silica sol, sodium silicate, lubricant, inorganic inhibitor, silane coupler and organic resin, wherein, described lubricant is at least one in water-base fluorocarbon emulsion, silicone oil emulsion, polythene wax emulsion, polytetrafluoroethylwax wax emulsion and Brazil wax emulsion；Described inorganic inhibitor is at least one in potassium permanganate, disodium-hydrogen, sodium nitrite, sodium tripolyphosphate, zinc sulfate and sodium molybdate；Described silane coupler is at least one in gamma-aminopropyl-triethoxy-silane, γ-glycidyl ether oxygen propyl trimethoxy silicane, γ-methacryloxypropyl trimethoxy silane, γ-mercaptopropyl trimethoxysilane, vinyltrimethoxy silane and N-(β-aminoethyl)-γ-aminopropyltrimethoxysilane；Described organic resin is at least one in water-borne acrylic resin, aqueous styrene-acrylic resin, resol resins, aqueous polyurethane and waterborne organic silicon resin；With the water of 100 weight portions for benchmark, the content of described silica sol is 2-30 weight portion, the content of described sodium silicate is 0.5-10 weight portion, the content of described lubricant is 5-30 weight portion, the content of described inorganic inhibitor is 0.1-5 weight portion, the content of described silane coupler is 2-20 weight portion, and the content of described organic resin is 1-50 weight portion.
2. agent composition according to claim 1, wherein, with the water of 100 weight portions for benchmark, the content of described silica sol is 5-20 weight portion, the content of described sodium silicate is 4-8 weight portion, and the content of described lubricant is 10-25 weight portion, and the content of described inorganic inhibitor is 1.5-4 weight portion, the content of described silane coupler is 8-16 weight portion, and the content of described organic resin is 15-45 weight portion.
3. agent composition according to claim 1 and 2, wherein, the particle diameter of described silica sol is 1-150nm.
4. agent composition according to claim 3, wherein, the particle diameter of described silica sol is 1-50nm.
5. agent composition according to claim 1 and 2, wherein, described lubricant is at least one in water-base fluorocarbon emulsion, polythene wax emulsion and polytetrafluoroethylwax wax emulsion.
6. agent composition according to claim 1 and 2, wherein, described organic resin is at least one in water-borne acrylic resin, aqueous styrene-acrylic resin and aqueous polyurethane.
7. agent composition according to claim 1 and 2, wherein, described inorganic inhibitor is at least one in sodium nitrite, sodium molybdate and potassium permanganate.
8. agent composition according to claim 1 and 2, wherein, described silane coupler is N-(β-aminoethyl)-γ-aminopropyltrimethoxysilane and/or γ-methacryloxypropyl trimethoxy silane.
9. agent composition according to claim 1, wherein, this agent composition is possibly together with auxiliary agent.
10. agent composition according to claim 9, wherein, described auxiliary agent is at least one in surfactant, levelling agent and defoamer；Relative to the water of 100 weight portions, the consumption of described auxiliary agent is 0.1-2 weight portion.
11. agent composition according to claim 10, wherein, relative to the water of 100 weight portions, the consumption of described auxiliary agent is 0.3-1 weight portion.
12. a hot dip aluminum zinc plate, this hot dip aluminum zinc plate includes hot-dip aluminizing zinc plate substrate and attachment coating on substrate surface, it is characterised in that described coating self-lubrication treatment agent compositions described in any one in claim 1-11 is formed.
13. hot dip aluminum zinc plate according to claim 12, wherein, the thickness of described coating is 0.05-0.3 micron.
14. a preparation method for hot dip aluminum zinc plate, the method includes: the self-lubrication treatment agent compositions described in any one in claim 1-11 is configured to coating fluid, by described coating solution on hot-dip aluminizing zinc plate substrate, then solidifies.
15. preparation method according to claim 14, wherein, the condition of described solidification includes: temperature is 80-110 DEG C, and the time is 10-60s.
16. the preparation method according to claims 14 or 15, wherein, the consumption of described coating fluid makes the thickness of the coating formed on described hot-dip aluminizing zinc plate substrate be 0.05-0.3 micron.
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| EP2980166B1 (en) * | 2014-08-01 | 2017-06-07 | Ewald Dörken Ag | Anticorrosive coating composition |
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| CN112301342B (en) * | 2020-07-02 | 2021-12-21 | 上海兴赛尔表面材料有限公司 | Chromium-free passivation composition for aluminum-plated zinc plate and manufacturing and using method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011046993A (en) * | 2009-08-26 | 2011-03-10 | Sumitomo Metal Ind Ltd | Coated and heat-treated steel and method for manufacturing the same |
| CN102115885A (en) * | 2009-12-30 | 2011-07-06 | 上海工程技术大学 | Oil-free self-lubricating plating technique of aluminum alloy parts |
| CN102747346A (en) * | 2012-07-28 | 2012-10-24 | 西安科技大学 | Preparation method of self-lubricating coating of traveller for textile |
| CN103290401A (en) * | 2013-05-10 | 2013-09-11 | 安徽工业大学 | Chromium-free self-lubricating passivation solution and preparation method thereof |
| CN103289569A (en) * | 2013-05-09 | 2013-09-11 | 安徽工业大学 | Self-lubricating passivation solution and hot galvanizing self-lubricating coating steel sheet coated thereby |
| JP2013194258A (en) * | 2012-03-16 | 2013-09-30 | Jfe Steel Corp | Surface-treated steel sheet |
-
2014
- 2014-04-10 CN CN201410142968.8A patent/CN103911063B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011046993A (en) * | 2009-08-26 | 2011-03-10 | Sumitomo Metal Ind Ltd | Coated and heat-treated steel and method for manufacturing the same |
| CN102115885A (en) * | 2009-12-30 | 2011-07-06 | 上海工程技术大学 | Oil-free self-lubricating plating technique of aluminum alloy parts |
| JP2013194258A (en) * | 2012-03-16 | 2013-09-30 | Jfe Steel Corp | Surface-treated steel sheet |
| CN102747346A (en) * | 2012-07-28 | 2012-10-24 | 西安科技大学 | Preparation method of self-lubricating coating of traveller for textile |
| CN103289569A (en) * | 2013-05-09 | 2013-09-11 | 安徽工业大学 | Self-lubricating passivation solution and hot galvanizing self-lubricating coating steel sheet coated thereby |
| CN103290401A (en) * | 2013-05-10 | 2013-09-11 | 安徽工业大学 | Chromium-free self-lubricating passivation solution and preparation method thereof |
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