CN103889688B - Affect the method and device of the surface characteristic of plastic sheeting or metal forming - Google Patents
Affect the method and device of the surface characteristic of plastic sheeting or metal forming Download PDFInfo
- Publication number
- CN103889688B CN103889688B CN201280047288.7A CN201280047288A CN103889688B CN 103889688 B CN103889688 B CN 103889688B CN 201280047288 A CN201280047288 A CN 201280047288A CN 103889688 B CN103889688 B CN 103889688B
- Authority
- CN
- China
- Prior art keywords
- plasma
- sided corona
- treatment
- shell
- plasma treatment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000004033 plastic Substances 0.000 title claims abstract description 34
- 229920003023 plastic Polymers 0.000 title claims abstract description 34
- 239000002184 metal Substances 0.000 title claims abstract description 21
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 21
- 210000002381 Plasma Anatomy 0.000 claims abstract description 40
- 238000003851 corona treatment Methods 0.000 claims abstract description 24
- 238000009832 plasma treatment Methods 0.000 claims abstract description 20
- 239000002985 plastic film Substances 0.000 claims abstract description 8
- 238000002347 injection Methods 0.000 claims abstract description 3
- 239000007924 injection Substances 0.000 claims abstract description 3
- 239000010409 thin film Substances 0.000 claims description 26
- 108010020147 Protein Corona Proteins 0.000 claims description 22
- 239000010408 film Substances 0.000 claims description 6
- 229920001169 thermoplastic Polymers 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 3
- 239000003792 electrolyte Substances 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- 238000000034 method Methods 0.000 description 27
- 230000000875 corresponding Effects 0.000 description 10
- 230000005611 electricity Effects 0.000 description 9
- 230000002349 favourable Effects 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 230000004913 activation Effects 0.000 description 3
- 230000002457 bidirectional Effects 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000002045 lasting Effects 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 210000001736 Capillaries Anatomy 0.000 description 1
- 208000002173 Dizziness Diseases 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000010891 electric arc Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000006011 modification reaction Methods 0.000 description 1
- 230000002085 persistent Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
Abstract
A kind of method of the surface characteristic for affecting metal forming and plastic sheeting of improvement, the method provides the best result by simplifying device structure and can implement in many ways, and wherein at least side of paper tinsel or film surface carries out local plasma treatment basically identical, simultaneously and sided corona treatment.In addition, the present invention relates to by carrying out plasma treatment and sided corona treatment affects the device of surface characteristic of metal forming and Plastic film surface simultaneously, this device has at least one plasma nozzle (1) being arranged in shell (2), for producing and going out plasma jet (6) by jet expansion vectored injection, relative to the counter electrode (4) of jet expansion and have generation high tension generator of alternating voltage in high pressure range, wherein high tension generator produces potential difference by its outfan, on the one hand this outfan is connected with shell (2) and is on the other hand connected with counter electrode (4).
Description
Technical field
The present invention relates to method and the dress of a kind of surface characteristic affecting plastic sheeting or metal forming
Put.Present invention has particularly advantageous application to the biaxially oriented film being made up of thermoplastic polymer.
Furthermore, it is possible to perform the method by disclosed device.
Background technology
Known and in long-term practice, stretched thermoplastic plastic sheeting, on the one hand, at this
The thickness of kind of thin film particularly plastic sheeting track and width aspect obtain and desired complete size
(Endma β e), on the other hand, stretches on desired direction.Here, make
With stretching device, during its two steps being divided into, also exist in some devices
During one step, longitudinal stretching plastic sheeting, particularly plastic sheeting guide rail, i.e.
Transmission direction or orbital direction stretch and cross directional stretch, laterally draw in particular perpendicular to longitudinal
Stretch.
Furthermore it is known that change plastic sheeting and the surface characteristic of metal forming, such as, improve surface and open
Power and thus improve the adhesion effect of plastic sheeting, or also improve the surface cleaning of metal forming,
Such process is carried out especially at plastic sheeting in the case of activation processing.Special for this
Activation processing, including known flame treatment, plasma treatment or sided corona treatment, and these
The combination processed.
Here, there is following problems all the time, i.e. as far as possible effectively implement and manage knot at which
Surface the most stable in Guo processes.
Special probability described in DE 10 2,005 052 441 is to use relevant plastics thin
Film, it is proposed that during for bidirectional stretching plastic film, after longitudinal stretching step, and at horizontal stroke
Before stretching step, carry out at plasma on this plastic sheeting width by means of atmospheric pressure
Reason, then carries out cross directional stretch, is then followed by carrying out second time and processes, and this process is electricity
Dizzy process or flame treatment.The document gives the description of directiveness, give also for existing
Further and the more detailed embodiment of technology, and give plasma discharge and corona discharge
Model of action, this equally applicable present invention, based on this carry out with reference to and narration.
Method as described at DE 10 2,005 052 441 provides according to the document has height
Capillary extraordinary effect, it is conducive to the later stage of plastic sheeting to apply, such as, prints,
Show the most suitable activation of film surface.This is in the publication owing at longitudinal stretching
(air pressure) plasma treatment afterwards but before cross directional stretch and after cross directional stretch
The special combination processed further carried out by means of corona discharge or flame treatment.At this article
Method described in offering yet suffers from following point during actual converted:
First, this specific process is only applicable to produce drawing plastic film.The method is not suitable for
Metal forming；Process to plastic sheeting subsequently after manufacture it is not suitable for, such as, directly yet
New surface active or printing before processing step further are probably desired.
Additionally, must be integrated attached in device on two separate positions of drawing plastic film
The equipment added, it is, be used for first processing position longitudinal direction at this device of plasma treatment
After extension section, but before cross directional stretch portion, and for the of corona discharge or flame treatment
Two positions are after cross directional stretch portion.And, the method can only be carried out in this manner,
In which, at longitudinal stretching (first this step) and cross directional stretch (this step is at second)
After Fen Kai, drawing plastic film, i.e. there is the production method of cross directional stretch and longitudinal stretching not
It is in a single step.Finally, if ought to occur equally on the whole width of thin film at this
(this is desired), the sided corona treatment implemented after cross directional stretch or flame treatment
Equipment, is built into more corresponding to the plastic sheeting width substantially increased after transverse stretching step
Large-sized.So large scale can bring structure, about the problem of instrument and challenge, especially
It is uniform over a larger distance and the challenge of homogenizing enforcement so that by the plastic sheeting processed
On bigger width after cross directional stretch, there is consistent surface characteristic.For building laterally
Implement large-sized requirement of the processing equipment that second time processes after stretching, cause equipment aspect
Higher cost.For bigger processing section, add the consumption of processing medium, make operation become
This increase.
Summary of the invention
Here, can realize overcoming the problems referred to above by the present invention.The special purpose of the present invention is,
The method and device of surface properties for affecting plastic sheeting and metal forming is provided, the method or
Device can be used in paper tinsel and the production of thin film with relatively small number of equipment cost and the course of processing is different
Position.Especially, also should it is possible that, by the method and device, have at the same time with
In the case of the structure of the result that sample is good simplifies, reason thermoplastic polymer can be located and constitute
Biaxially oriented film.Especially, in a modification of the method, it is used for performing the method
Device should be easily integrated in the existing dress of the plastic sheeting for stretching biaxial tension
In putting, this is the same for completing the device of longitudinal direction and cross directional stretch in one step.
This purpose is realized by technical scheme in terms of method, in the reality of the present invention
Execute the solution according to the present invention in terms of example provides the device of this purpose.The enforcement of the present invention
Example provides the favourable improvement project of the method and the favourable improvement project of this device.
The ultimate principle of the present invention is, at and plasma the most substantially consistent by local simultaneously
Reason and sided corona treatment, can effectively long lasting effect metal forming surface characteristic (especially
For clean as oil or fat residue) or the surface characteristic of plastic sheeting (activate improvement especially
Attachment characteristic).Inventor determines, by one side plasma treatment on the other hand sided corona treatment
Substantially consistent and process simultaneously, particularly preferred result can be produced.Additionally, the party
Formula provides following probability, i.e. compact and be simply integrated simultaneously and be retrofitted in existing apparatus
In equipment in terms of structure.Especially, plasma treatment and sided corona treatment the most in time,
And simultaneously occur on place in a common processing region.
Here, the process performed according to the present invention can metal forming or plastic sheeting produce or
Complete during subsequently, thus the identical paper tinsel processed through respective surfaces can be provided from factory
Or thin film.It may be thus possible, for example, to provide plastics that surface tension significantly improves, that so process
Thin film, i.e. it such as needs for reliable and lasting printing.
For plastic sheeting, owing to surface tension declines over time, metal forming may be dirty
Dye surface, if directly carried out the place according to the present invention before processing paper tinsel or thin film further
Reason, it is possible to be favourable and desired.This can be disposable process, but or also may be used
To be process repeatedly.
Especially, the method is suitable on persistent movement and pending paper tinsel or thin film track real
Execute.
Especially, the bidirectional stretching plastic film being made up of thermoplastic polymer is according to the present invention
Process in the case of confirm, in contrast to DE's 10 2,005 052 441 it is assumed that result not
Depend on following situation, i.e. different process steps is separated, and after cross directional stretch,
Biaxial stretch-formed different time points implements final process, and this can also by carry out etc. simultaneously from
Son processes and sided corona treatment, particularly carries out before cross directional stretch.The place the most simultaneously carried out
Reason, had the most both activated plasma and had driven up plasma in the side of surface to be treated, again thin
Proceed by corona discharge in film surface range, therefore can carry out before cross directional stretch, make
Must plastic sheeting process in, device structure on its whole width corresponding to cross directional stretch it
Before narrower width and can be built into less.Therefore, as long as arbitrarily before cross directional stretch
At correct position, the compactest device is installed, it is possible to existing for plastic sheeting track
Stretching device merges corresponding method step.Preferably, if in office after longitudinal stretching
Consistent plasma treatment that the is while of in portion's process range and that preferably carry out and sided corona treatment,
This is dispensable, it might even be possible to perform in the method step before this longitudinal stretching, thus
It is also employed in especially in the method for stretched plastic film, wherein, in single common step
Implement longitudinal stretching and cross directional stretch.
In terms of device, the solution of the present invention is, has the present invention's as already mentioned
The device of technical scheme.This device is characterized in that, combination arrange in, this device have to
A few plasma nozzle being arranged in shell, this nozzle is used for producing plasma jet and orientation
Injection plasma jet, and there is the setting for corona ignition, this setting has serves as
The plasma nozzle shell of electrode or the part of this shell, have the corresponding electricity serving as the second electrode
Pole, and there is alternating voltage (1000 volts or the higher alternating current produced in high pressure range
Pressure) high tension generator.On the one hand this high tension generator is connected with shell by output unit, its
At device for the part of ignition power corona as electrode, in the portion of the only shell as electrode
In the case of Fen, it is connected with housing portion, is on the other hand connected with counter electrode.
Here, this high tension generator is provided for producing the typical case's height for corresponding sided corona treatment
Pressure, under the most typical and general frequency, such as this high pressure can 10 to 20KV it
Between, frequency is between 10 to 60kHz.
It is particularly compact according to assembly of the invention, integrated as independent plasma in shell
The plasma nozzle of generator, this shell is arranged as the electrode for ignition power corona simultaneously
Electrode, save space to the full extent, allow at the same time to be moved by this layout
Paper tinsel or thin film or paper tinsel track or effective process of thin film track, and the side sprayed at paper tinsel or thin film
Upwards and by the corona discharge of the igniting between shell and motor or the type that thus occurs.
The plasma nozzle used in a device in accordance with the invention, such as, can be as at DE
196 48 999 descriptions, and AFS development and sale company limited (AFS Entwicklungs-und
Vertriebs GmbH) with trade markThere is provided and sell.
In order to pass through according to assembly of the invention at pending metal forming or pending plastics
Realizing enough surfaces in the overall width of thin film to process, this shell can be configured to the beam stretched out
Shape, this shell under any circumstance by corresponding paper tinsel track or thin film track towards part and
As the electrode of plasma discharge equipment, wherein, along longitudinally disposed multiple next-door neighbour arrange etc.
Iron nozzle.The plasma nozzle arranged by such multiple next-door neighbours, it is possible to achieve homogeneous
The plasma radiation or plasma cloud, this plasma radiation or the plasma cloud that elongate can be again at them
On whole width, pending surface is carried out uniform plasma treatment.Similarly, by electricity
Corona by plasma treatment, completes the uniform sided corona treatment to surface simultaneously, if this electricity
On the whole width of corona shell between this shell, this shell is as electrode, and activates
Counter electrode.
This counter electrode is coated with electrolyte and can have the advantage that.That thus avoids between electrode is direct
Electric arc, and ensure compliance with adjustment boundary condition (the high electricity of applying depending on width of air gap accordingly
Pressure and frequency), putting as the igniting between shell or housing portion and the counter electrode of electrode
Electricity is corona discharge.
Particularly advantageously, counter electrode can be roller electrode.Especially, process paper tinsel track or
During thin film track, this roller electrode can function simultaneously as the reliable guiding processing track, if this rail
Road moves on roller electrode or transmits.If track is positioned on roller electrode and directly contacts, permissible
Avoid the sided corona treatment at the back side so that the only paper tinsel of opposite article on plasma nozzle or the surface of thin film is entered
Row plasma treatment and sided corona treatment.By on purpose providing air gap, can be at such dress
In putting except carry out in the face of the metal forming front of plasma nozzle or plastic sheeting front etc. from
Son processes and sided corona treatment, it is also possible to carry out sided corona treatment overleaf, and this is for paper tinsel or thin film
Ensuing that be advantageously applied and desired.
Especially, depend on the connection of plasma nozzle and depend on processing the type of material, making
Shell or corresponding housing portion for electrode can be corresponding on earth potential (Erdpotential)
Electrode connects with corresponding high voltage potential, or provides Opposite direction connection, right in this Opposite direction connection
Answering electrode ground connection, this shell or the housing portion as electrode are in high voltage potential.
Can it appear that, compact, particularly because at present according to assembly of the invention structure
Plasma nozzle the least in structure can be produced, outside being therefore desirably integrated under technical conditions
In space crowded in shell, this shell is as the parts according to assembly of the invention, as corona
The electrode of electric discharge device.Thus, according to assembly of the invention can pending paper tinsel, thin film or
Extend on pending paper tinsel track or the whole width of thin film track.
Because at cross directional stretch pre-test width, so the biaxial stretching before cross directional stretch
In the process of plastic sheeting, this width and warp in the method according to DE 10 2,005 052 441
Cross flame treatment or sided corona treatment stretch in the horizontal after the width of relevant device that provides compare
Less.
Accompanying drawing explanation
Description to embodiment is given below other advantage and feature in conjunction with accompanying drawing.Accompanying drawing
In:
Fig. 1 be shown in schematically first may connect in respective handling method
According to during the enforcement of the present invention according to apparatus of the present invention；And
Fig. 2 is the signal the most relatively according to apparatus of the present invention in Opposite direction connection
Figure.
Detailed description of the invention
Figure illustrates schematically according to assembly of the invention, it is shown that it processes metal forming rail
Road or plastic sheeting track are how to build, connect and work.
Apparatus of the present invention are by the plasma nozzle as plasma source and by electrode and correspondence electricity
Combination between the layout for corona discharge that pole is constituted collectively forms.Plasma nozzle 1 is not
Being perpendicular to mark layer is closely arranged in the shell 2 including this plasma nozzle 1 with describing in detail
In.Shell 2 in the drawings part electrode as corona discharge device is illustrated below, and pass through
Attachment means 3 is connected with the high tension generator not described in detail herein.In this embodiment, roller
Electrode 4 is as the counter electrode of corona discharge device, and this roller electrode 4 is coated with dielectric
Metal roller.Similarly, this carrying roller is not connected with high tension generator with describing in detail herein,
It is connected with the second delivery outlet of this high tension generator.
In operation, the track 5 of metal forming or plastic sheeting runs on roller electrode 4, and with
Dorsad roller electrode 4, towards plasma nozzle 1 or the mode of shell 2, local and time upper one
Cause carries out plasma treatment and sided corona treatment.To this, the plasma of generation in plasma nozzle 1
As plasma jet 6 towards the track of paper tinsel in processing or the track 5 of thin film surface by etc. from
Sub-nozzle 1 sprays.Simultaneously between shell 2 and roller electrode 4, by high pressure range
High-frequency alternating current pressure device activates corona discharge, here, this corona discharge numeral 7 illustrates.
This corona discharge 7 also affects the track 5 of paper tinsel or the surface of the track 5 of thin film.
Because Fig. 1 and Fig. 2 is identical in respective view, they differ only in, and make
Shell (housing portion) 2 and the connection of roller electrode 4 for electrode.Shell 2 in Fig. 1 connects
During earth potential, roller electrode 4 is set to high voltage, is precisely and connects on the contrary in Fig. 2.Former
Then going up, two kinds of connected modes may be used to corona discharge.Certainly, institute is utilized at metal track
State in the case of device carries out surface process, can select to connect according to Fig. 2, to avoid roller electricity
The voltage extremely gone up is directed in whole system on other assembly (being not shown here).
This problem is there is not in the case of electrically isolated plastic sheeting carries out surface process.At this
For the plasma nozzle 1 used and working method thereof, the connection side that optional electricity aspect is favourable
Formula.
The plasma nozzle 1 not being described and illustrated in detail at this is preferably directed at DE 196 48
This type described in 999 and model of action.
According to the present invention, during producing plastic sheeting track by the device shown in figure, mould
Processing of material thin film track occurs before the cross directional stretch of the thin film track 5 processed, especially
It is can to carry out after longitudinal stretching, but can also be before.
The electrical connection of plasma nozzle 1 is integrated in shell 2, does not describes in detail here.Deng from
Sub-nozzle is corresponding to the requirement to element, i.e. plasma nozzle is connected to high Hair Fixer by shell
On raw device, and as the not contradiction of the electrode for corona discharge 7.
Description of reference numerals
1 plasma nozzle
2 shells
3 attachment means
4 roller electrodes
5 metal forming tracks and plastic sheeting track
6 plasma jets
7 corona discharges
Claims (13)
1. the method for the surface characteristic affecting metal forming and plastic sheeting, it is characterised in that
At least side, surface of paper tinsel or thin film locally, unanimously, is simultaneously carried out plasma treatment
And sided corona treatment.
2. the method for claim 1, it is characterised in that
Locally, unanimously the plasma treatment, simultaneously carried out and sided corona treatment occur at paper tinsel or thin
In the manufacture of film, or the most after the fabrication.
3. such as method in any one of the preceding claims wherein, it is characterised in that
Locally, unanimously, plasma treatment and the sided corona treatment simultaneously carried out occurs directly in paper tinsel
Or before being processed further of thin film.
4. the method for claim 1, it is characterised in that
Described method performs constantly, to this end, paper tinsel or thin film as track relative to performing institute
The vertical of device stating method moves up, for local, unanimously, simultaneously plasma treatment and
Sided corona treatment.
5. the method for claim 1, it is characterised in that
For the biaxially oriented film being made up of thermoplastic polymer, drawing of this thermoplastic polymer
Stretch is longitudinally to carry out longitudinal stretching and laterally carrying out cross directional stretch, before cross directional stretch
Step in, at least side of Plastic film surface is simultaneously carried out at plasma treatment and corona
Reason.
6. method as claimed in claim 5, it is characterised in that
On the whole width transversely extended of plastic sheeting not carrying out cross directional stretch simultaneously
Ground carries out plasma treatment and sided corona treatment.
7. the method as described in claim 5 or 6, it is characterised in that
Carry out plasma treatment and sided corona treatment after longitudinal stretching simultaneously.
8. one kind affects metal forming by carrying out plasma treatment and sided corona treatment simultaneously and moulds
The device of surface characteristic of material thin film (5), its have at least one arrange in the enclosure etc.
Iron nozzle (1), is used for producing and by jet expansion vectored injection plasma jet (6), phase
To the counter electrode (4) of jet expansion setting and for producing the alternating current in high pressure range
The high tension generator of pressure, wherein, this high tension generator produces potential difference by its outfan, should
On the one hand outfan is connected with shell (2), and is on the other hand connected with counter electrode (4),
Described high pressure is 1000V or higher.
9. device as claimed in claim 8, it is characterised in that
Shell (2) is formed as elongated beam-like, has the plasma being disposed adjacent in a longitudinal direction thereof
Nozzle (1).
10. device as claimed in claim 8 or 9, it is characterised in that
Counter electrode (4) is coated with electrolyte.
11. devices as claimed in claim 8 or 9, it is characterised in that
Counter electrode (4) is roller electrode.
12. devices as claimed in claim 8 or 9, it is characterised in that
High tension generator is connected with shell by ground connection outfan.
13. devices as claimed in claim 8 or 9, it is characterised in that
High tension generator is connected with counter electrode by ground connection outfan.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP11183383.6A EP2574446B1 (en) | 2011-09-30 | 2011-09-30 | Method and Device for Manipulating Surface Characteristics of Plastic Films or Metal Foils |
| EP11183383.6 | 2011-09-30 | ||
| PCT/EP2012/068236 WO2013045304A1 (en) | 2011-09-30 | 2012-09-17 | Method and device for influencing surface properties of plastic films or metal foils |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103889688A CN103889688A (en) | 2014-06-25 |
| CN103889688B true CN103889688B (en) | 2016-11-30 |
Family
ID=
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6429595B1 (en) * | 2001-02-14 | 2002-08-06 | Enercon Industries Corporation | Multi-mode treater with internal air cooling system |
| DE102005052441A1 (en) * | 2005-11-03 | 2007-05-16 | Treofan Germany Gmbh & Co Kg | Biaxially oriented polyolefin film with improved surface properties |
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6429595B1 (en) * | 2001-02-14 | 2002-08-06 | Enercon Industries Corporation | Multi-mode treater with internal air cooling system |
| DE102005052441A1 (en) * | 2005-11-03 | 2007-05-16 | Treofan Germany Gmbh & Co Kg | Biaxially oriented polyolefin film with improved surface properties |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102204414B (en) | Device for generating a plasma discharge for patterning the surface of a substrate | |
| JP3750817B2 (en) | Static eliminator | |
| CN102834545B (en) | Method and device for layer deposition | |
| CN108367487A (en) | Method for the silicone elastomer product for producing print quality raising | |
| US20110285792A1 (en) | Liquid Droplet Spraying Apparatus and Method | |
| JP2013519991A (en) | Apparatus and method for generating plasma discharge for patterning a surface of a substrate | |
| JP2011096675A (en) | Ion generation method and apparatus | |
| ATE547250T1 (en) | PRINTING BY DEFLECTING AN INK JET THROUGH A VARIABLE FIELD | |
| WO2009069759A1 (en) | Ultrafine composite fiber, ultrafine fiber, method for manufacturing same, and fiber structure | |
| CN106626803B (en) | A kind of flexible electronic EFI printing apparatus for possessing electric field adaptive characteristic and its method | |
| CN101432080A (en) | Printing apparatus | |
| KR101552433B1 (en) | Electrohydrodynamic patterning apparatus using electromagnetic field control and patterning apparatus using the same | |
| CN112895426A (en) | Micro-nano 3D printing method for single-plate electrode electric field driven jet deposition | |
| CN107321986A (en) | Electric field driven jet deposition 3D printing device for printing high-viscosity conductive material | |
| CN103889688B (en) | Affect the method and device of the surface characteristic of plastic sheeting or metal forming | |
| CN102922891A (en) | Electro-hydraulic jet printing device of metal micro-nanometer structure | |
| KR101425021B1 (en) | Improved Spray-Type Pattern Forming Apparatus and Method | |
| JP2007220460A (en) | Injection type ionizer | |
| CN101480639B (en) | Device for neutralizing static electricity | |
| CN105792498A (en) | Multi-nozzle cascade type plasma jet-triggered high-voltage switch | |
| KR101819654B1 (en) | Solution process apparatus and manufacturing method of multilayered structure device using the same | |
| KR20170064201A (en) | Apparatus of forming patterns by electrospinning method | |
| KR20170058685A (en) | Electro hydro dynamic inkjet apparatus | |
| KR101696885B1 (en) | Multi-nozzle head having an injection electrode | |
| CN103889688A (en) | Method and device for influencing surface properties of plastic films or metal foils |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant |