CN103880322A - Method for preparing constructional composite mineral admixture - Google Patents

Method for preparing constructional composite mineral admixture Download PDF

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CN103880322A
CN103880322A CN201410045671.XA CN201410045671A CN103880322A CN 103880322 A CN103880322 A CN 103880322A CN 201410045671 A CN201410045671 A CN 201410045671A CN 103880322 A CN103880322 A CN 103880322A
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parts
building
complex mineral
blending material
mineral blending
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CN103880322B (en
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黄小仙
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Jin Guang Dao Environmental Construction Group Co., Ltd.
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黄小仙
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  • Silicates, Zeolites, And Molecular Sieves (AREA)
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Abstract

The invention discloses a method for preparing a constructional composite mineral admixture. The method is characterized by comprising the following raw materials in parts by weight: 45-50 parts of aluminum oxide clinker, 15-20 parts of calcined alunite, 5-10 parts of zinc sulfate, 25-30 parts of dickite, 25-30 parts of attapulgite clay, 20-25 parts of pulverized fuel gas, 1-5 parts of zeolite powder, 2-4 parts of diatomaceous earth, 2-5 parts of bentonite, 1-2 parts of methylcellulose, 0.5-1 part of sodium sulfite, 0.5-1 part of quicklime, 0.3-0.5 part of sodium carbonate, 0.5-1 part of gypsum and 0.2-1 part of sodium silicate. The constructional composite mineral admixture has the function of effectively resisting water, humidity, swelling, cracking, seepage and the like, and does not rust or corrode reinforcing steel bars.

Description

A kind of preparation method of complex mineral blending material for building
Technical field
The preparation method who the present invention relates to a kind of complex mineral blending material for building, belongs to building material manufacture field.
Background technology
In engineering, many building basements, roofing, highway, bridge all do not reach design service life, some engineerings only come into operation and within several years, are just subject to havoc, have to repair, its major cause be current water-proof material and concrete admixture generally containing Cl-,,,,, K+ ion is overweight, join in concrete, react with active silica in concrete, generate the silicate gel of alkali and produce concrete swelling cracking, common alkali-aggregate reaction in engineering that Here it is, accelerate steel bar corrosion simultaneously, caused concrete cracking infiltration.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art, a kind of preparation method of a kind of complex mineral blending material for building with high-effective water-proof, protection against the tide, expansion, cracking resistance, the function such as impervious is provided.
For achieving the above object, the technical solution used in the present invention is as follows:
A kind of preparation method of complex mineral blending material for building, it is characterized in that: described complex mineral blending material raw material for building is (weight): aluminum oxide clinker 45-50 part, calcined alunite 15-20 part, zinc sulfate 5-10 part, dickite 25-30 part, attapulgite clay 25-30 part, flyash 20-25 part, zeolite powder 1-5 part, diatomite 2-4 part, wilkinite 2-5 part, methylcellulose gum 1-2 part, S-WAT 0.5-1 part, unslaked lime 0.5-1 part, sodium carbonate 0.3-0.5 part, gypsum 0.5-1 part, water glass 0.2-1 part
Described preparation method's step is:
Step (1): according to aluminum oxide clinker 45-50 part, calcined alunite 15-20 part, zinc sulfate 5-10 part, dickite 25-30 part, attapulgite clay 25-30 part, flyash 20-25 part, zeolite powder 1-5 part, diatomite 2-4 part, wilkinite 2-5 part, methylcellulose gum 1-2 part, S-WAT 0.5-1 part, unslaked lime 0.5-1 part, sodium carbonate 0.3-0.5 part, gypsum 0.5-1 part, water glass 0.2-1 part proportioning is prepared raw material
Step (2): aluminum oxide clinker 45-50 part, calcined alunite 15-20 part, zinc sulfate 5-10 part, dickite 25-30 part are carried out to grinding in pulverizer, and rotating speed is 120r/min, grinding 6 hours, obtains mixture A granularity size for 0.5-1mm,
Step (3): attapulgite clay 25-30 part, flyash 20-25 part, zeolite powder 1-5 part, diatomite 2-4 part, wilkinite 2-5 part are carried out to grinding in pulverizer, rotating speed is 100r/min, grinding 2 hours, obtains mixture B granularity size for 0.2-0.3mm
Step (4): step (2) is obtained to mixture A and step (3) is obtained to mixture B packing in mechanical mixer, mechanically mixing 1 hour, pour afterwards methylcellulose gum 1-2 part, S-WAT 0.5-1 part into, unslaked lime 0.5-1 part, sodium carbonate 0.3-0.5 part, gypsum 0.5-1 part, water glass 0.2-1 part, mechanically mixing 2 hours, obtains complex mineral blending material for building again.
As preferably, the preparation method of described complex mineral blending material for building, complex mineral blending material raw material for building is: 45 parts of aluminum oxide clinkers, 15 parts of calcined alunites, 5 parts, zinc sulfate, 25 parts of dickites, 25 parts of attapulgite clays, 20 parts, flyash, 1 part of zeolite powder, 2 parts, diatomite, 2 parts of wilkinites, 1 part of methylcellulose gum, 0.5 part of S-WAT, 0.5 part of unslaked lime, 0.3 part, sodium carbonate, 0.5 part, gypsum, 0.2 part of water glass.
As preferably, the preparation method of described complex mineral blending material for building, complex mineral blending material raw material for building is: 50 parts of aluminum oxide clinkers, 20 parts of calcined alunites, 10 parts, zinc sulfate, 30 parts of dickites, 30 parts of attapulgite clays, 25 parts, flyash, 5 parts of zeolite powders, 4 parts, diatomite, 5 parts of wilkinites, 2 parts of methylcellulose gum, 1 part of S-WAT, 1 part of unslaked lime, 0.5 part, sodium carbonate, 1 part, gypsum, 1 part of water glass.
As preferably, the preparation method of described complex mineral blending material for building, complex mineral blending material raw material for building is: 47 parts of aluminum oxide clinkers, 17 parts of calcined alunites, 7 parts, zinc sulfate, 27 parts of dickites, 27 parts of attapulgite clays, 23 parts, flyash, 3 parts of zeolite powders, 3 parts, diatomite, 3 parts of wilkinites, 1.5 parts of methylcellulose gum, 0.8 part of S-WAT, 0.8 part of unslaked lime, 0.4 part, sodium carbonate, 0.8 part, gypsum, 0.6 part of water glass.
As preferably, the preparation method of described complex mineral blending material for building, complex mineral blending material raw material for building is: 46 parts of aluminum oxide clinkers, 16 parts of calcined alunites, 6 parts, zinc sulfate, 26 parts of dickites, 26 parts of attapulgite clays, 24 parts, flyash, 4 parts of zeolite powders, 3 parts, diatomite, 4 parts of wilkinites, 1.5 parts of methylcellulose gum, 0.7 part of S-WAT, 0.7 part of unslaked lime, 0.35 part, sodium carbonate, 0.55 part, gypsum, 0.25 part of water glass.
As preferably, the preparation method of described complex mineral blending material for building, it is 0.7mm that step (2) obtains mixture A granularity size.
As preferably, the preparation method of described complex mineral blending material for building, it is 0.25mm that step (3) obtains mixture B granularity size.
As preferably, the preparation method of described complex mineral blending material for building, attapulgite clay composition is (weight): 56.7%SiO 2, 16.8%MgO, 3.4%FeO, 5.5%Fe 2o 3, 9.1%Al 2o 3, 2.7%CaO, 5.8% loss on ignition.
As preferably, the preparation method of described complex mineral blending material for building, dickite composition is (weight): 61.1%SiO 2, 31.3%Al 2o 3, 1.2%Fe 2o 3, 1.1%CaO, 0.5%MgO, 4.8% loss on ignition.
As preferably, the preparation method of described complex mineral blending material for building, flyash composition is (weight): 53.3%SiO 2, 29.7%Al 2o 3, 5.3%Fe 2o 3, 2.1%CaO, 4.8%MgO, 4.8% loss on ignition.
Compared with prior art, the present invention has following beneficial effect:
The preparation of test sample: adopt cement 282g, the complex mineral blending material 18g for building preparing, sand 750g, water consumption 120ml, and moulding 40 × 40 × 160mm test specimen, 20 ± 2 DEG C of temperature, humidity is maintenance under more than 90% condition.
6 quality % of cement amount in the complex mineral blending material place of cement sill for building making are mixed in cement-based material, make 20 test blocks, the average index that detects the properties of 20 test blocks is: fineness (specific surface area): 420m2/kg, time of coagulation: initial set 125min final set 295min, limited expansion rate: 7d-0.024%; 28d-0.015%, ultimate compression strength: 7d:31.3Mpa; 28d:49.4MPa, permeated height ratio: 34%, water demand ratio: 66%, to steel bar corrosion effect: non-corroding.Complex mineral blending material for building of the present invention has high-effective water-proof, protection against the tide, expansion, cracking resistance, the function such as impervious, to the effect of reinforcing bar non-corroding, is the large technological breakthrough of current architectural waterproof material one.
Embodiment
Embodiment 1
A preparation method for complex mineral blending material for building, is characterized in that:
Described preparation method's step is:
Step (1): according to 45 parts of aluminum oxide clinkers, 15 parts of calcined alunites, 5 parts, zinc sulfate, 25 parts of dickites, 25 parts of attapulgite clays, 20 parts, flyash, 1 part of zeolite powder, 2 parts, diatomite, 2 parts of wilkinites, 1 part of methylcellulose gum, 0.5 part of S-WAT, 0.5 part of unslaked lime, 0.3 part, sodium carbonate, 0.5 part, gypsum, 0.2 part of proportioning of water glass is prepared raw material
Step (2): 25 parts of 45 parts of aluminum oxide clinkers, 15 parts of calcined alunites, 5 parts, zinc sulfate, dickite are carried out to grinding in pulverizer, and rotating speed is 120r/min, grinding 6 hours, obtaining mixture A granularity size is 0.5-1mm,
Step (3): 25 parts of attapulgite clays, 20 parts, flyash, 1 part of zeolite powder, 2 parts, diatomite, wilkinite 2-5 part are carried out to grinding in pulverizer, and rotating speed is 100r/min, grinding 2 hours, obtains mixture B granularity size for 0.2-0.3mm,
Step (4): step (2) is obtained to mixture A and step (3) is obtained to mixture B packing in mechanical mixer, mechanically mixing 1 hour, pour afterwards 1 part of methylcellulose gum, 0.5 part of S-WAT into, 0.5 part of unslaked lime, 0.3 part, sodium carbonate, 0.5 part, gypsum, 0.2 part of water glass, mechanically mixing 2 hours, obtains complex mineral blending material for building again.
 
Embodiment 2
A preparation method for complex mineral blending material for building, is characterized in that:
Described preparation method's step is:
Step (1): according to 50 parts of aluminum oxide clinkers, 20 parts of calcined alunites, 10 parts, zinc sulfate, 30 parts of dickites, 30 parts of attapulgite clays, 25 parts, flyash, 5 parts of zeolite powders, 4 parts, diatomite, 5 parts of wilkinites, 2 parts of methylcellulose gum, 1 part of S-WAT, 1 part of unslaked lime, 0.5 part, sodium carbonate, 1 part, gypsum, water glass 0.2-1 part proportioning is prepared raw material
Step (2): 30 parts of 50 parts of aluminum oxide clinkers, 20 parts of calcined alunites, 10 parts, zinc sulfate, dickite are carried out to grinding in pulverizer, and rotating speed is 120r/min, grinding 6 hours, obtaining mixture A granularity size is 0.5-1mm,
Step (3): 5 parts of 30 parts of attapulgite clays, 25 parts, flyash, 5 parts of zeolite powders, 4 parts, diatomite, wilkinite are carried out to grinding in pulverizer, and rotating speed is 100r/min, grinding 2 hours, obtaining mixture B granularity size is 0.2-0.3mm,
Step (4): step (2) is obtained to mixture A and step (3) is obtained to mixture B packing in mechanical mixer, mechanically mixing 1 hour, pour afterwards 2 parts of methylcellulose gum, 1 part of S-WAT into, 1 part of unslaked lime, 0.5 part, sodium carbonate, 1 part, gypsum, 1 part of water glass, mechanically mixing 2 hours, obtains complex mineral blending material for building again.
 
Embodiment 3
A preparation method for complex mineral blending material for building, is characterized in that:
Described preparation method's step is:
Step (1): according to 47 parts of aluminum oxide clinkers, 17 parts of calcined alunites, 7 parts, zinc sulfate, 27 parts of dickites, 27 parts of attapulgite clays, 23 parts, flyash, 3 parts of zeolite powders, 3 parts, diatomite, 3 parts of wilkinites, 1.5 parts of methylcellulose gum, 0.6 part of S-WAT, 0.6 part of unslaked lime, 0.4 part, sodium carbonate, 0.7 part, gypsum, 0.7 part of proportioning of water glass is prepared raw material
Step (2): 27 parts of 47 parts of aluminum oxide clinkers, 17 parts of calcined alunites, 7 parts, zinc sulfate, dickite are carried out to grinding in pulverizer, and rotating speed is 120r/min, grinding 6 hours, obtaining mixture A granularity size is 0.5-1mm,
Step (3): 3 parts of 27 parts of attapulgite clays, 23 parts, flyash, 3 parts of zeolite powders, 3 parts, diatomite, wilkinite are carried out to grinding in pulverizer, and rotating speed is 100r/min, grinding 2 hours, obtaining mixture B granularity size is 0.2-0.3mm,
Step (4): step (2) is obtained to mixture A and step (3) is obtained to mixture B packing in mechanical mixer, mechanically mixing 1 hour, pour afterwards 1.5 parts of methylcellulose gum, 0.6 part of S-WAT into, 0.6 part of unslaked lime, 0.4 part, sodium carbonate, 0.7 part, gypsum, 0.7 part of water glass, mechanically mixing 2 hours, obtains complex mineral blending material for building again.
 
Embodiment 4
A preparation method for complex mineral blending material for building, is characterized in that:
Described preparation method's step is:
Step (1): according to 46 parts of aluminum oxide clinkers, 16 parts of calcined alunites, 6 parts, zinc sulfate, 26 parts of dickites, 26 parts of attapulgite clays, 24 parts, flyash, 4 parts of zeolite powders, 4 parts, diatomite, 4 parts of wilkinites, 1.5 parts of methylcellulose gum, 0.9 part of S-WAT, 0.9 part of unslaked lime, 0.35 part, sodium carbonate, 0.9 part, gypsum, 0.9 part of proportioning of water glass is prepared raw material
Step (2): 26 parts of 46 parts of aluminum oxide clinkers, 16 parts of calcined alunites, 6 parts, zinc sulfate, dickite are carried out to grinding in pulverizer, and rotating speed is 120r/min, grinding 6 hours, obtaining mixture A granularity size is 0.5-1mm,
Step (3): 4 parts of 26 parts of attapulgite clays, 24 parts, flyash, 4 parts of zeolite powders, 4 parts, diatomite, wilkinite are carried out to grinding in pulverizer, and rotating speed is 100r/min, grinding 2 hours, obtaining mixture B granularity size is 0.2-0.3mm,
Step (4): step (2) is obtained to mixture A and step (3) is obtained to mixture B packing in mechanical mixer, mechanically mixing 1 hour, pour afterwards 1.5 parts of methylcellulose gum, 0.9 part of S-WAT into, 0.9 part of unslaked lime, 0.35 part, sodium carbonate, 0.9 part, gypsum, 0.9 part of water glass, mechanically mixing 2 hours, obtains complex mineral blending material for building again.
 
Embodiment 5
A preparation method for complex mineral blending material for building, is characterized in that:
Described preparation method's step is:
Step (1): according to 48 parts of aluminum oxide clinkers, 18 parts of calcined alunites, 8 parts, zinc sulfate, 28 parts of dickites, 28 parts of attapulgite clays, 22 parts, flyash, 2 parts of zeolite powders, 2 parts, diatomite, 2 parts of wilkinites, 1.5 parts of methylcellulose gum, 0.8 part of S-WAT, 0.8 part of unslaked lime, 0.4 part, sodium carbonate, 0.8 part, gypsum, 0.8 part of proportioning of water glass is prepared raw material
Step (2): 28 parts of 48 parts of aluminum oxide clinkers, 18 parts of calcined alunites, 8 parts, zinc sulfate, dickite are carried out to grinding in pulverizer, and rotating speed is 120r/min, grinding 6 hours, obtaining mixture A granularity size is 0.5-1mm,
Step (3): 2 parts of 28 parts of attapulgite clays, 22 parts, flyash, 2 parts of zeolite powders, 2 parts, diatomite, wilkinite are carried out to grinding in pulverizer, and rotating speed is 100r/min, grinding 2 hours, obtaining mixture B granularity size is 0.2-0.3mm,
Step (4): step (2) is obtained to mixture A and step (3) is obtained to mixture B packing in mechanical mixer, mechanically mixing 1 hour, pour afterwards 1.5 parts of methylcellulose gum, 0.8 part of S-WAT into, 0.8 part of unslaked lime, 0.4 part, sodium carbonate, 0.8 part, gypsum, 0.8 part of water glass, mechanically mixing 2 hours, obtains complex mineral blending material for building again.

Claims (10)

1. the preparation method of a complex mineral blending material for building, it is characterized in that: described complex mineral blending material raw material for building is (weight): aluminum oxide clinker 45-50 part, calcined alunite 15-20 part, zinc sulfate 5-10 part, dickite 25-30 part, attapulgite clay 25-30 part, flyash 20-25 part, zeolite powder 1-5 part, diatomite 2-4 part, wilkinite 2-5 part, methylcellulose gum 1-2 part, S-WAT 0.5-1 part, unslaked lime 0.5-1 part, sodium carbonate 0.3-0.5 part, gypsum 0.5-1 part, water glass 0.2-1 part
Described preparation method's step is:
Step (1): according to aluminum oxide clinker 45-50 part, calcined alunite 15-20 part, zinc sulfate 5-10 part, dickite 25-30 part, attapulgite clay 25-30 part, flyash 20-25 part, zeolite powder 1-5 part, diatomite 2-4 part, wilkinite 2-5 part, methylcellulose gum 1-2 part, S-WAT 0.5-1 part, unslaked lime 0.5-1 part, sodium carbonate 0.3-0.5 part, gypsum 0.5-1 part, water glass 0.2-1 part proportioning is prepared raw material
Step (2): aluminum oxide clinker 45-50 part, calcined alunite 15-20 part, zinc sulfate 5-10 part, dickite 25-30 part are carried out to grinding in pulverizer, and rotating speed is 120r/min, grinding 6 hours, obtains mixture A granularity size for 0.5-1mm,
Step (3): attapulgite clay 25-30 part, flyash 20-25 part, zeolite powder 1-5 part, diatomite 2-4 part, wilkinite 2-5 part are carried out to grinding in pulverizer, rotating speed is 100r/min, grinding 2 hours, obtains mixture B granularity size for 0.2-0.3mm
Step (4): step (2) is obtained to mixture A and step (3) is obtained to mixture B packing in mechanical mixer, mechanically mixing 1 hour, pour afterwards methylcellulose gum 1-2 part, S-WAT 0.5-1 part into, unslaked lime 0.5-1 part, sodium carbonate 0.3-0.5 part, gypsum 0.5-1 part, water glass 0.2-1 part, mechanically mixing 2 hours, obtains complex mineral blending material for building again.
2. the preparation method of complex mineral blending material for building as claimed in claim 1, complex mineral blending material raw material for building is: 45 parts of aluminum oxide clinkers, 15 parts of calcined alunites, 5 parts, zinc sulfate, 25 parts of dickites, 25 parts of attapulgite clays, 20 parts, flyash, 1 part of zeolite powder, 2 parts, diatomite, 2 parts of wilkinites, 1 part of methylcellulose gum, 0.5 part of S-WAT, 0.5 part of unslaked lime, 0.3 part, sodium carbonate, 0.5 part, gypsum, 0.2 part of water glass.
3. the preparation method of complex mineral blending material for building as claimed in claim 1, complex mineral blending material raw material for building is: 50 parts of aluminum oxide clinkers, 20 parts of calcined alunites, 10 parts, zinc sulfate, 30 parts of dickites, 30 parts of attapulgite clays, 25 parts, flyash, 5 parts of zeolite powders, 4 parts, diatomite, 5 parts of wilkinites, 2 parts of methylcellulose gum, 1 part of S-WAT, 1 part of unslaked lime, 0.5 part, sodium carbonate, 1 part, gypsum, 1 part of water glass.
4. the preparation method of complex mineral blending material for building as claimed in claim 1, complex mineral blending material raw material for building is: 47 parts of aluminum oxide clinkers, 17 parts of calcined alunites, 7 parts, zinc sulfate, 27 parts of dickites, 27 parts of attapulgite clays, 23 parts, flyash, 3 parts of zeolite powders, 3 parts, diatomite, 3 parts of wilkinites, 1.5 parts of methylcellulose gum, 0.8 part of S-WAT, 0.8 part of unslaked lime, 0.4 part, sodium carbonate, 0.8 part, gypsum, 0.6 part of water glass.
5. the preparation method of complex mineral blending material for building as claimed in claim 1, complex mineral blending material raw material for building is: 46 parts of aluminum oxide clinkers, 16 parts of calcined alunites, 6 parts, zinc sulfate, 26 parts of dickites, 26 parts of attapulgite clays, 24 parts, flyash, 4 parts of zeolite powders, 3 parts, diatomite, 4 parts of wilkinites, 1.5 parts of methylcellulose gum, 0.7 part of S-WAT, 0.7 part of unslaked lime, 0.35 part, sodium carbonate, 0.55 part, gypsum, 0.25 part of water glass.
6. the preparation method of complex mineral blending material for building as claimed in claim 1, step (2) obtains mixture A granularity size for 0.7mm.
7. the preparation method of complex mineral blending material for building as claimed in claim 1, step (3) obtains mixture B granularity size for 0.25mm.
8. the preparation method of complex mineral blending material for building as claimed in claim 1, attapulgite clay composition is (weight): 56.7%SiO 2, 16.8%MgO, 3.4%FeO, 5.5%Fe 2o 3, 9.1%Al 2o 3, 2.7%CaO, 5.8% loss on ignition.
9. the preparation method of complex mineral blending material for building as claimed in claim 1, dickite composition is (weight): 61.1%SiO 2, 31.3%Al 2o 3, 1.2%Fe 2o 3, 1.1%CaO, 0.5%MgO, 4.8% loss on ignition.
10. the preparation method of complex mineral blending material for building as claimed in claim 10, flyash composition is (weight): 53.3%SiO 2, 29.7%Al 2o 3, 5.3%Fe 2o 3, 2.1%CaO, 4.8%MgO, 4.8% loss on ignition.
CN201410045671.XA 2014-02-09 2014-02-09 A kind of preparation method of complex mineral blending material for building Expired - Fee Related CN103880322B (en)

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CN104929306A (en) * 2015-05-28 2015-09-23 中航天建设工程有限公司 Self-insulation concrete slab and preparation method thereof
CN105645836A (en) * 2016-01-05 2016-06-08 萧县良宇混凝土有限责任公司 High-flowability anti-cracking concrete additive and preparation method thereof
CN106746874A (en) * 2015-11-20 2017-05-31 甘肃曼特睿尔公路材料研发有限责任公司 A kind of cement additire and preparation method thereof
CN106927714A (en) * 2017-03-29 2017-07-07 合肥天沃能源科技有限公司 A kind of cement additire and preparation method

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CN108002400A (en) * 2017-12-06 2018-05-08 潮州市华中陶瓷实业有限公司 A kind of attapulgite clay product and preparation method thereof

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CN1051032A (en) * 1989-10-17 1991-05-01 中国建筑材料科学研究院 Rapid hardening agent of concrete
KR20020052828A (en) * 2000-12-26 2002-07-04 신현준 Refractory composition
JP2004043207A (en) * 2002-07-09 2004-02-12 Mitsubishi Materials Corp Premix powder for filler for slab track
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Publication number Priority date Publication date Assignee Title
CN104929306A (en) * 2015-05-28 2015-09-23 中航天建设工程有限公司 Self-insulation concrete slab and preparation method thereof
CN104929306B (en) * 2015-05-28 2017-01-04 中航天建设工程有限公司 Self-insulating concrete sheet material and preparation method thereof
CN106746874A (en) * 2015-11-20 2017-05-31 甘肃曼特睿尔公路材料研发有限责任公司 A kind of cement additire and preparation method thereof
CN105645836A (en) * 2016-01-05 2016-06-08 萧县良宇混凝土有限责任公司 High-flowability anti-cracking concrete additive and preparation method thereof
CN106927714A (en) * 2017-03-29 2017-07-07 合肥天沃能源科技有限公司 A kind of cement additire and preparation method

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