CN1038799A - A kind of method of producing schoenite by solid state reaction - Google Patents
A kind of method of producing schoenite by solid state reaction Download PDFInfo
- Publication number
- CN1038799A CN1038799A CN88101878A CN88101878A CN1038799A CN 1038799 A CN1038799 A CN 1038799A CN 88101878 A CN88101878 A CN 88101878A CN 88101878 A CN88101878 A CN 88101878A CN 1038799 A CN1038799 A CN 1038799A
- Authority
- CN
- China
- Prior art keywords
- schoenite
- solid state
- state reaction
- carnallitite
- saltcake
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D5/00—Sulfates or sulfites of sodium, potassium or alkali metals in general
- C01D5/12—Preparation of double sulfates of magnesium with sodium or potassium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Cosmetics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The invention belongs to the schoenite producing and manufacturing technique.Schoenite is a raw material of producing high-quality chlorideless potassic fertilizer vitriolate of tartar.The present invention after Repone K and saltcake are pressed the mixed in molar ratio of phasor, by solid state reaction, produces schoenite with carnallitite.Reaction equation is: 2Na
2SO
410H
2O+KClMgCL
26H
2O+KCl=K
2SO
4MgSO
46H
2O+4NaCl+20H
2O.The present invention simplifies production technique, and energy consumption is low, and cost is low, the efficient height.
Description
The invention belongs to the schoenite producing and manufacturing technique.
Schoenite is a raw material of producing high-quality chlorideless potassic fertilizer vitriolate of tartar.At present external produce vitriolate of tartar the operational path of industrialization comparative maturity have: one, be with Japan representative be the method for fusing, be about to Repone K and sulfuric acid according to a certain ratio, heating fuses.Data is seen CIM BULL, 1971, v64, No705, p66.Two, all adopt the solution conversion method with the Soviet Union, East Germany and West Germany, Repone K and sal epsom are changed into schoenite in solution, decompose schoenite then and produce vitriolate of tartar.Data is seen Kali und Steinsalz, 1970, Bd, S289.Three, U.S.'s Great Salt lake's mineral and chemical company obtain containing sodium-chlor with the evaporation of crude salt lake water, kainite, the mixture of epsom salt and carnallitite, factory evolve then by (1) flotation sodium-chlor, (2) sylvite is converted into schoenite, (3) add the water decomposition schoenite, crystallisation by cooling is produced vitriolate of tartar.Data is seen PHOSPH POTAS, 1971, and No52, p36 and PHOSPH POTAS, 1972, No56, p39.Domesticly just be the conversion method that carries out at solution in the method for laboratory study.Data is published in " section's journal " on March 4th, 1988 " salt lake, Qinghai institute releases the novel process of extracting vitriolate of tartar from the salt lake, Qinghai ".
Above method complex process, so the energy consumption height is the production cost height.
The objective of the invention is to: produce schoenite by solid state reaction, production technique is simplified, energy consumption is low, reduces cost, and raises the efficiency.
The present invention uses the phasor principle with carnallitite, after Repone K and saltcake (mirabilite hydrate or thenardite) are mixed in proportion, by solid state reaction, produces schoenite.According to the phasor principle, at K, Na, Mg/CL, SO
4-H
2On the Ye Naike phasor of O penton system (seeing accompanying drawing),, carnallitite (Car)+sylvite (Sy)+saltcake (M or T) is mixed, total composition of mixture is dropped on the solidus (Pi) of schoenite by shouldering bar and center-of-gravity rule.Mixture is by solid state reaction, and dehydration is transformed into new thing mutually to carnallitite with saltcake, i.e. schoenite+halite.Reaction equation is:
。At penton is in the phasor, and temperature range and phase region that schoenite exists are very big, and therefore under the natural condition of low temperature (as 0 ℃) and high temperature (as 40 ℃), the above-mentioned solid phase reaction can both very fast realization.
The present invention can realize like this, raw material is mixed in proportion stirring after, as doing coal briquette, make bead or little cake, and make its seasoning, after waiting to do bath, reaction is promptly finished.The mixture of the schoenite that obtains and sodium-chlor is carried out flotation just can obtain schoenite.(flotation has sophisticated processing method)
Characteristics of the present invention are: the reaction of producing schoenite is not to carry out in solution, therefore compared with prior art has following advantage:
1, do not need to deposit the salt pond or the container of bittern, thereby, facility investment can be saved greatly.
2, saved technological processs such as crystallization, solid-liquid separation, production technique is simple.
3, there is not tailing (solution method is analysed the mother liquor behind the schoenite) to handle problems in the production process.
4, in the reaction process, except that utilizing sun power, do not need other energy.
5, speed of response is fast, and is with short production cycle, the efficient height.
Accompanying drawing is: K, Na, Mg/CL, SO
4-H
2The Ye Naike phasor of O penton system
Solid phase becomes branch
The M saltcake
The T thenardite
The Car carnallitite
The Sy sylvite
The embodiment I: testing sequence and effect are carried out in test at room temperature (15-18 ℃):
1. take by weighing 200 gram carnallitites, 53.2 gram Repone K, 136 gram thenardites (powdery) and 154.3 gram mirabilite hydrates.
2. with above mixing of materials, grind, be pressed into the pellet of coal briquette size.
3. after 3-4 hour, pellet is wetting, but flowing liquid not.
4. dry naturally, product is through being accredited as the thin crystalline substance of schoenite+salt two days later, original phase (carnallitite, saltcake, sylvite) completely dissolve, and product weighs 457 grams.
[notes]: the weight ratio of schoenite and salt is 1.722: 1 in the product.
The embodiment II: test is carried out under 0-5 ℃ of condition: 1. take by weighing carnallitite 200 grams, Repone K 53.2 grams, ten moisture saltcake, 463 grams.
2. above mixing of materials is ground, become the cake shape less than 10 minutes materials, identify solid phase after 45 minutes, having seen has a large amount of salt (NaCl) and schoenite fine crystals to form.
3. material is dried naturally at indoor stand cake, dry two days later, product is the tiny salt of the bigger schoenite+crystal of crystal, saltcake, carnallitite and sylvite completely dissolve, and product weighs 460 grams.
The embodiment III: test at room temperature (16-18 ℃) is carried out:
1. take by weighing carnallitite 200 grams, Repone K 53.2 grams, thenardite (powder) 204.2 grams
2. above mixing of materials is ground and spray 150 ml waters, material can be bondd, and make pellet.
3. pellet is in indoor seasoning, and product is schoenite+salt two days later, and product weighs 459 grams.
Claims (3)
1, a kind ofly produces the method for schoenite, after it is characterized in that carnallitite, Repone K and saltcake (mirabilite hydrate or thenardite) be mixed in proportion,, produce schoenite by solid state reaction by solid state reaction.
2, such as claim 1 the request solid state reaction produce the method for schoenite, it is characterized in that at K Na, Mg/CL, SO
4-H
2On the Ye Naike phasor of O penton system (seeing accompanying drawing),, carnallitite (Car)+sylvite (Sy)+saltcake (M or T) is mixed, total composition of mixture is dropped on the solidus (Pi) of schoenite by shouldering bar and center-of-gravity rule.
3, such as claim 1 the request solid state reaction produce the method for schoenite, after it is characterized in that powder raw material is mixed in proportion, make bead or little cake, and make it do bath naturally.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN88101878A CN1010674B (en) | 1988-04-12 | 1988-04-12 | Method of preparation of soft potassium-magnesium alum by solid phase reaction |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN88101878A CN1010674B (en) | 1988-04-12 | 1988-04-12 | Method of preparation of soft potassium-magnesium alum by solid phase reaction |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1038799A true CN1038799A (en) | 1990-01-17 |
| CN1010674B CN1010674B (en) | 1990-12-05 |
Family
ID=4831922
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN88101878A Expired CN1010674B (en) | 1988-04-12 | 1988-04-12 | Method of preparation of soft potassium-magnesium alum by solid phase reaction |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1010674B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1065213C (en) * | 1998-05-21 | 2001-05-02 | 中国科学院青海盐湖研究所 | Process for preparing soft leonite |
| CN104261940A (en) * | 2014-09-24 | 2015-01-07 | 中国科学院青海盐湖研究所 | Method for preparing potassic-magnesian fertilizer |
| CN109354042A (en) * | 2018-11-22 | 2019-02-19 | 青海蓝湖善成生物技术有限公司 | The preparation method and picromerite feed of picromerite |
-
1988
- 1988-04-12 CN CN88101878A patent/CN1010674B/en not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1065213C (en) * | 1998-05-21 | 2001-05-02 | 中国科学院青海盐湖研究所 | Process for preparing soft leonite |
| CN104261940A (en) * | 2014-09-24 | 2015-01-07 | 中国科学院青海盐湖研究所 | Method for preparing potassic-magnesian fertilizer |
| CN109354042A (en) * | 2018-11-22 | 2019-02-19 | 青海蓝湖善成生物技术有限公司 | The preparation method and picromerite feed of picromerite |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1010674B (en) | 1990-12-05 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US8431005B1 (en) | Production of lithium and potassium compounds | |
| CN103420401B (en) | Method for preparing large-particle picromerite | |
| MXPA00010125A (en) | Method of procucing potassium sulfate. | |
| CN1025727C (en) | Potassium chloride preparing by chloride type patassium brine | |
| CN101143731A (en) | Vacuum crystallization technique for producing potassium nitrate from potassium chloride by sodium nitrate | |
| US4582697A (en) | Production of aluminum trihydroxide having median diameter of 2 to 100 microns | |
| CN1038799A (en) | A kind of method of producing schoenite by solid state reaction | |
| CN108367934A (en) | The method that control forms the compound of sulfate in high environment temperature prepares potassium sulfate from mine containing potassium | |
| CN1252775A (en) | Method for producing calcium borate | |
| CN1083398C (en) | Method for producing calcium borate | |
| CN1171794C (en) | Preparation method of potassium sulfate with sulfate-type salt lake bittern containing potassium salt | |
| CA3204124A1 (en) | Method for the production of lithium hydroxide (lioh) directly from lithium chloride (lici), without the need for an intermediate production of lithium carbonate or similar | |
| CN1673083A (en) | Technological process of preparing potassium nitrate and magnesium chloride | |
| Sedivy | Purification of salt for chemical and human consumption | |
| CN102432042B (en) | Method for directly producing potassium nitrate end product from complex nitrate bittern | |
| CN103553087B (en) | Method of preparing lithium sulfate ores from mixed brine by utilizing natural energy | |
| CN107867712A (en) | A kind of active nano-ZnO | |
| CN115066395A (en) | Process and method for refining lithium carbonate starting from an impure lithium chloride solution | |
| CN1398784A (en) | Potassium sulfate producing process | |
| CN117385469B (en) | Method for preparing alpha-hemihydrate gypsum seed crystal by using natural gypsum | |
| RU2795224C1 (en) | Process and method for lithium carbonate purification based on a lithium chloride solution with impurities | |
| Silvia et al. | The effect of variation concentration sodium hydroxide (Naoh) on the structure of calcium carbonate (caco3) based on natural sand | |
| CN110790238B (en) | Treatment method for recycling comprehensive utilization of antimony wool crystal salt | |
| CN1015435B (en) | Extracting potassium sulphate and its by-products magnesium sulfate, etc. from gypsum and halogen chroismite | |
| Bayca | A New Method for Colemanite Waste Processing |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C13 | Decision | ||
| GR02 | Examined patent application | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |