CN103866961A - Composite material polyurethane rigid foam decorative marble pillar - Google Patents

Composite material polyurethane rigid foam decorative marble pillar Download PDF

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Publication number
CN103866961A
CN103866961A CN201210539230.6A CN201210539230A CN103866961A CN 103866961 A CN103866961 A CN 103866961A CN 201210539230 A CN201210539230 A CN 201210539230A CN 103866961 A CN103866961 A CN 103866961A
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China
Prior art keywords
base
post part
composite material
cylinder shell
strengthen
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Pending
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CN201210539230.6A
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Chinese (zh)
Inventor
徐小虎
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
XIAMEN FINEHOPE POLYURETHANE PRODUCE CO Ltd
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XIAMEN FINEHOPE POLYURETHANE PRODUCE CO Ltd
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Priority to CN201210539230.6A priority Critical patent/CN103866961A/en
Priority to US13/969,428 priority patent/US20140170349A1/en
Publication of CN103866961A publication Critical patent/CN103866961A/en
Pending legal-status Critical Current

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    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00Coverings or linings, e.g. for walls or ceilings
    • E04F13/07Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
    • E04F13/072Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of specially adapted, structured or shaped covering or lining elements
    • E04F13/073Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of specially adapted, structured or shaped covering or lining elements for particular building parts, e.g. corners or columns
    • E04F13/0736Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of specially adapted, structured or shaped covering or lining elements for particular building parts, e.g. corners or columns for columns
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00Coverings or linings, e.g. for walls or ceilings
    • E04F13/07Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
    • E04F13/072Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of specially adapted, structured or shaped covering or lining elements
    • E04F13/073Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of specially adapted, structured or shaped covering or lining elements for particular building parts, e.g. corners or columns
    • E04F13/0733Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of specially adapted, structured or shaped covering or lining elements for particular building parts, e.g. corners or columns for corners
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00Coverings or linings, e.g. for walls or ceilings
    • E04F13/07Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
    • E04F13/08Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
    • E04F13/18Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements of organic plastics with or without reinforcements or filling materials or with an outer layer of organic plastics with or without reinforcements or filling materials; plastic tiles
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/13Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352Polymer or resin containing [i.e., natural or synthetic]
    • Y10T428/1376Foam or porous material containing

Abstract

A composite material polyurethane rigid foam decorative marble pillar comprises a pillar outer casing which is provided with interior space and an inner layer; the interior space is defined by the pillar casing in a sealing mode; the pillar outer casing comprises a pillar base portion, a pillar body portion which is arranged on the pillar base portion, a pillar head portion which is arranged on the pillar body portion; the inner layer is made of PU (Poly Urethane); the inner layer is tightly adhered to an inner surface of the pillar outer casing to form into the composite materials with the pillar outer casing to be used for reinforcing the supporting intensity and the impact resistant force of the pillar outer casing.

Description

The composite material polyurethane decoration FRP Columns that hard bubbles
Technical field
The present invention relates to a kind of FRP Columns, hard foamed decoration FRP Columns of especially a kind of composite material polyurethane being bonded by composite material and PU material decorated.
Background technology
FRP Columns is the classical order in Rome, always has 5 kinds of pillars: Doric formula, Ai Aonikeshi, Corinthian, Roman style (tower department dry type, combined type).Because FRP Columns has graceful noble makings, be widely used for now building building large-scale, that be gaily decorated.
In prior art, FRP Columns generally adopts the manufactures such as rigid poly urethanes foaming, gypsum, wooden, rock material to form.Traditional polyurethane FRP Columns surface strength is poor, shock resistance is poor; Traditional gypsum FRP Columns, when construction, easily damaged fracture, brings inconvenience to our housing decoration; Traditional wooden FRP Columns moisture-sensitive, easily damaged by worms, inflammable and surface strength is poor, felling on a large scale, destroys large natural environment; Traditional stone FRP Columns, weight is large, construction is more difficult, cost is higher.Between conventional composite materials and PU material, cohesive is poor.
Summary of the invention
The object of the present invention is to provide a kind of composite material polyurethane decoration FRP Columns that hard bubbles, it adopts environmental protection, and pollution-free raw material are produced.
Another object of the present invention is to provide a kind of composite material polyurethane decoration FRP Columns that hard bubbles, its anti-moth, protection against the tide, do not chap, indeformable, do not come off, durability is strong.
Another object of the present invention is to provide a kind of composite material polyurethane decoration FRP Columns that hard bubbles, and its anti-impact force is strong, intensity is high, anti-aging, weatherability is strong.
Another object of the present invention is to provide a kind of composite material polyurethane decoration FRP Columns that hard bubbles, and the gap that it does not have matched moulds, adopts integrated processing technology, has good intensity.
Another object of the present invention is to provide a kind of composite material polyurethane decoration FRP Columns that hard bubbles, and it reduces the consumption of PU by the design of structure, reduces costs.
Another object of the present invention is to provide a kind of composite material polyurethane decoration FRP Columns that hard bubbles, and its quality is light, constructs simple and convenient, and easy damaged not in work progress, reduces the time that construction spends.
Another object of the present invention is to provide a kind of composite material polyurethane decoration FRP Columns that hard bubbles, and between itself and PU material, cohesive increases.
Another object of the present invention is to provide a kind of composite material polyurethane decoration FRP Columns that hard bubbles, and it is avoided making influencing each other between material heterogeneity in reaction forming process.Another object of the present invention is to provide a kind of composite material polyurethane decoration FRP Columns that hard bubbles, and the release problems that its circular arc and chamfering cause is solved.
Another object of the present invention is to provide a kind of composite material polyurethane decoration FRP Columns that hard bubbles, and it has good appearance effect, and smooth surface is easy to clean, rear road processes and colouring.
For reaching above object, the invention provides a kind of composite material polyurethane decoration FRP Columns that hard bubbles, comprising:
One cylinder shell, has an inner space, is formed around definition by this cylinder shell seal, and wherein, this cylinder shell comprises: a base for post part; One shaft part, is arranged in this base for post part; And a column cap part, be arranged in this shaft part; And
One internal layer, material is PU, fits tightly in this cylinder inner surface of outer cover, with this cylinder shell composition composite material, in order to strengthen support strength, the anti-impact force of this cylinder shell.
These objects of the present invention, feature, and the specific embodiment that advantage will be below, accompanying drawing, and detailed exposure in claim.
Accompanying drawing explanation
Fig. 1 hard bubbles and decorates not sectional view when bonding inner layers of cylinder shell column cap part of FRP Columns according to a kind of composite material polyurethane of a preferred embodiment of the present invention.
Fig. 2 hard bubbles and decorates not sectional view when bonding inner layers of cylinder shell base for post part of FRP Columns according to this composite material polyurethane of another preferred embodiment of the present invention.
Fig. 3 hard bubbles and decorates the sectional view after the cylinder shell column cap part bonding inner layers of FRP Columns according to this composite material polyurethane of above-mentioned preferred embodiment of the present invention.
Fig. 4 hard bubbles and decorates the sectional view after the cylinder shell base for post part bonding inner layers of FRP Columns according to this composite material polyurethane of above-mentioned preferred embodiment of the present invention.
Fig. 5 hard bubbles and decorates the cylinder shell base for post part top view of FRP Columns according to this composite material polyurethane of above-mentioned preferred embodiment of the present invention.
Fig. 6 hard bubbles and decorates T font reinforcing rib bone structure and the reinforcing rib partial enlarged drawing of FRP Columns according to this composite material polyurethane of above-mentioned preferred embodiment of the present invention.
Fig. 7 hard bubbles and decorates the cylinder shell base for post part three-dimensional view of FRP Columns according to this composite material polyurethane of above-mentioned preferred embodiment of the present invention.
Fig. 8 be according to this composite material polyurethane of above-mentioned preferred embodiment of the present invention hard bubble decorate FRP Columns front attempt.
The specific embodiment
Refer to Fig. 1-8, the present invention is a kind of composite material polyurethane decoration FRP Columns that hard bubbles, and comprising:
One cylinder shell 1, has an inner space 11, is formed around definition by this cylinder shell seal, and wherein, this cylinder shell comprises: a base for post part 12; One shaft part 13, is arranged in this base for post part; And a column cap part 14, be arranged in this shaft part; And
One internal layer 2, material is PU, fits tightly in this cylinder shell 1 inner surface, with this cylinder shell composition composite material, in order to strengthen support strength, the anti-impact force of this cylinder shell 1.
Further, between this cylinder shell 1 and this internal layer 2, comprise a PU glue 3, be applied on this cylinder shell 1 inner surface and these internal layer 2 external surfaces, in order to hard bubble to decorate under the prerequisite of FRP Columns hardness and density and strengthen the combination between this cylinder shell 1 and this internal layer 2 not affecting this composite material polyurethane, comprise: an A component and a B component, wherein, this A component comprises: polyethers (hydroxyl value: 800-850): 35-45, meet skill polyethers (hydroxyl value: 400-450): 55-65, cross linking agent 2-4, organotin catalysts: 0.3-0.7, surfactant: 0-2; And this B component comprises: isocyanates: 95-105.
Further, this base for post part 12 and this column cap part 14 respectively comprise: a T font reinforcing rib bone structure 121, in order to strengthen the support strength of this base for post part 12 and this column cap part 14, further comprise: one first baffle plate 1211, its both sides are arranged on this base for post part 12 and these column cap part 14 inner surfaces, an and second baffle 1212, setting vertical with this first baffle plate 1211, one side is arranged on these the first baffle plate 1211 center lines, and opposite side is arranged on this base for post part 12 and these column cap part 14 inner surfaces; And many reinforcing ribs 122, evenly be arranged at this base for post part 12 and these column cap part 14 inner surfaces with the direction parallel with this shaft, in order to strengthen the support strength of this base for post part 12 and this column cap part 14, and make this base for post part 12 and this column cap part 14 and this internal layer 2 intersect combination, increase contact area, improve blending and the associativity of this base for post part 12 and this column cap part 14 and this internal layer 2.
Further, the raw material of this cylinder shell 1 comprises: a crosslinking agent.
Preferably, this A component comprises: polyethers (hydroxyl value: 800-850): 40, connect skill polyethers (hydroxyl value: 400-450): and 60, cross linking agent: 3, organotin catalysts: 0.5, surfactant: 1; And this B component comprises: isocyanates: 95-105.
Preferably, these base for post part 12 inner surfaces are crude, in order to strengthen frictional force, strengthen combining closely of this base for post part 12 and this internal layer 2.
Preferably, these column cap part 14 inner surfaces are crude, in order to strengthen frictional force, strengthen combining closely of this column cap part 14 and this internal layer 2.
Preferably, the thickness of this cylinder shell 1 is in 1-3mm.
Preferably, the material of this cylinder shell 1 is plastics, glass fiber reinforced plastic, carbon fibre, wooden, gypsum and stone etc.
Preferably, the content of this crosslinking agent is 5%-10%.
The present invention also provides a kind of composite material polyurethane of manufacturing to hard bubble and decorate the method for FRP Columns, comprising:
A base for post part 12, a shaft part 13 and column cap part 14 inner surfaces in a cylinder shell 1 fit tightly an internal layer 2, and material is PU, with this cylinder shell composition composite material, in order to strengthen support strength, the anti-impact force of this cylinder shell 1.
Further, this base for post part 12 in this cylinder shell 1, this shaft part 13 and this column cap part 14 inner surfaces fit tightly this internal layer 2 and comprise: between this cylinder shell 1 inner surface and this internal layer 2 external surfaces, smear a PU glue, in order to hard bubble to decorate under the prerequisite of FRP Columns hardness and density and strengthen the combination between this cylinder shell 1 and this internal layer 2 not affecting this composite material polyurethane, its formula is an A component and a B component, wherein, this A component comprises: polyethers (hydroxyl value: 800-850): 40, connect skill polyethers (hydroxyl value: 400-450): 60, crosslinking agent: 3, there is quick-witted tin catalyst: 0.5, surfactant: 1, and this B component comprises: isocyanates: 95-105.
Further, this base for post part 12 in this cylinder shell 1, this shaft part 13 and this column cap part 14 inner surfaces fit tightly this internal layer 2 and comprise: in this base for post part 12 and this column cap part 14, a T font reinforcing rib bone structure 121 is respectively set, in order to strengthen the support strength of this base for post part 12 and this column cap part 14, one the first baffle plate 1211 both sides are arranged on these base for post part 12 inner surfaces, one second baffle 1212 setting vertical with this first baffle plate 1211, these second baffle 1,212 one sides are arranged on these the first baffle plate 1211 center lines, these second baffle 1212 opposite sides are arranged on these base for post part 12 inner surfaces, and in this base for post part 12 and this column cap part 14, many reinforcing ribs 122 are respectively set, it is evenly arranged at this base for post part 12 and these column cap part 14 inner surfaces with the direction parallel with this shaft, in order to strengthen the support strength of this base for post part 12 and this column cap part 14, and make this base for post part 12 and this column cap part 14 and this internal layer 2 intersect combination, increase contact area, improve blending and the associativity of this base for post part 12 and this column cap part 14 and this internal layer 2.
Further, this base for post part 12 in this cylinder shell 1, this shaft part 13 and this column cap part 14 inner surfaces fit tightly this internal layer 2 and comprise: in this cylinder shell 1 raw material, add a crosslinking agent.
Preferably, this base for post part 12 and these column cap part 14 inner surfaces are all crude, in order to strengthen frictional force, strengthen combining closely of this base for post part 12 and this column cap part 14 and this internal layer 2.
Preferably, the thickness of this cylinder shell 1 is in 1-3mm.
Preferably, the material of this cylinder shell 1 is plastics, glass fiber reinforced plastic, carbon fibre, wooden, gypsum and stone etc.
Preferably, the content of this crosslinking agent is 5%-10%.
Preferably, smear this PU glue 3 latter standing approximately 15 minutes at this cylinder shell 1 inner surface, after this PU glue 3 is dry, pour into internal layer 2, form firm solid integration product.
Hardness, intensity, impact strength, the incompressible intensity of the various decoration FRP Columns of table 1 material
Figure BSA00000822999700051
Figure BSA00000822999700061
From table 1, a kind of composite material polyurethane of the present invention hard bubble decorate FRP Columns aspect hardness, intensity, impact strength and incompressible intensity than wooden, gypsum, that stone conventional polyurethanes is decorated FRP Columns is strong.
The performance comparison of adhesive when table 2 cylinder sheathing material is plastics
Performance Common adhesive PU viscose binder
Curing rate Speed is slow Speed is fast
Shelf stability Unstable More stable
Ageing resistance Aging fast Aging slow
To the sticky stickiness of various matrix Be difficult for bonding Bonding firm
Mechanical performance Poor Better
Temperature tolerance Non-refractory High temperature resistant
From table 2, when a kind of composite material polyurethane of the present invention hard bubbles and decorates FRP Columns cylinder sheathing material and be plastics, using PU glue bonds at various aspect of performances more can be effective than using other common adhesive.
Table 3 has or not T font to strengthen the support strength contrast of muscles and bones design
Support strength
Strengthen muscles and bones design without T font Poor
There is T font to strengthen muscles and bones design Improve 50%
From table 3, a kind of composite material polyurethane of the present invention hard bubbles and decorates FRP Columns to have T font to strengthen muscles and bones design stronger than strengthen muscles and bones design support strength without T font.
Table 4 has or not the intensity contrast of reinforcing rib
Intensity
Without reinforcing rib Poor
There is reinforcing rib Improve 60%
From table 4, a kind of composite material polyurethane of the present invention hard bubbles and decorates FRP Columns and have reinforcing rib than stronger without reinforcing rib intensity.
Table 5 has the sticky stickiness contrast of cross-linking agent-free
Sticky stickiness
Cross-linking agent-free Generally
Add crosslinking agent Improve 50%
From table 5, a kind of composite material polyurethane of the present invention hard bubbles and decorates FRP Columns and connect skill agent than stronger without connecing the sticky stickiness of skill agent.
By above-described embodiment, object of the present invention is by fully effective having reached.The personage who is familiar with this skill should be understood that the content the present invention includes but be not limited to accompanying drawing and describe in the specific embodiment above.Any modification that does not depart from function and structure principle of the present invention all will be included in the scope of claims.

Claims (14)

1. the composite material polyurethane decoration FRP Columns that hard bubbles, comprising:
One cylinder shell, has an inner space, is formed around definition by this cylinder shell seal, and wherein, this cylinder shell comprises: a base for post part; One shaft part, is arranged in this base for post part; And a column cap part, be arranged in this shaft part; And
One internal layer, material is PU, fits tightly in this cylinder inner surface of outer cover, with this cylinder shell composition composite material, in order to strengthen support strength, the anti-impact force of this cylinder shell.
2. the composite material polyurethane according to claim 1 decoration FRP Columns that hard bubbles, wherein, between this cylinder shell and this internal layer, comprise a PU glue, be applied on this cylinder inner surface of outer cover and this inner layer outer surface, in order to hard bubble to decorate under the prerequisite of FRP Columns hardness and density and strengthen the combination between this cylinder shell and this internal layer not affecting this composite material polyurethane, comprise: an A component and a B component, wherein, this A component comprises: polyethers (hydroxyl value: 800-850): 35-45, meet skill polyethers (hydroxyl value: 400-450): 55-65, cross linking agent 2-4, there is quick-witted tin catalyst: 0.3-0.7, surfactant: 0-2 and isocyanates: 95-105, and this B component comprises: isocyanates: 95-105.
3. the composite material polyurethane according to claim 1 decoration FRP Columns that hard bubbles, wherein, this base for post part and this column cap part respectively comprise: a T font reinforcing rib bone structure, in order to strengthen the support strength of this base for post part, further comprise: one first baffle plate, its both sides are arranged on this base for post part inner surface, an and second baffle, the first baffle plate is vertical arranges with this, and one side is arranged on this first baffle plate center line, and opposite side is arranged on this base for post part inner surface; And many reinforcing ribs, evenly be arranged at this base for post part inner surface with the direction parallel with this shaft, in order to strengthen the support strength of this base for post part, and make this base for post part and the combination of this internal layer intersection, increase contact area, improve blending and the associativity of this base for post part and this internal layer.
4. the composite material polyurethane according to claim 3 decoration FRP Columns that hard bubbles, wherein, this base for post part and this column cap part inner surface are all crude, in order to strengthen frictional force, strengthen this base for post part and this column cap part respectively with the combining closely of this internal layer.
5. the composite material polyurethane according to claim 1 decoration FRP Columns that hard bubbles, wherein, the thickness of this cylinder shell is in 1-3mm.
6. the composite material polyurethane according to claim 1 decoration FRP Columns that hard bubbles, wherein, the raw material of this cylinder shell comprises: a crosslinking agent.
7. the composite material polyurethane according to claim 6 decoration FRP Columns that hard bubbles, wherein, the content of this crosslinking agent is 5%-10%.
8. manufacture composite material polyurethane and hard bubble and decorate the method for FRP Columns, comprising:
A) provide a cylinder shell;
B) the base for post part in this cylinder shell, a shaft part and a column cap part inner surface fit tightly an internal layer, and material is PU, with this cylinder shell composition composite material, in order to strengthen support strength, the anti-impact force of this cylinder shell.
9. method according to claim 8, wherein, step b) comprising: between this cylinder inner surface of outer cover and this inner layer outer surface, smear a PU glue, in order to hard bubble to decorate under the prerequisite of FRP Columns hardness and density and strengthen the combination between this cylinder shell and this internal layer not affecting this composite material polyurethane, its formula is an A component and a B component, wherein, this A component comprises: polyethers (hydroxyl value: 800-850): 35-45, meet skill polyethers (hydroxyl value: 400-450): 55-65, cross linking agent 2-4, there is quick-witted tin catalyst: 0.3-0.7, surfactant: 0-2, and this B component comprises: isocyanates: 95-105.
10. method according to claim 8, wherein, step a) comprising: in this base for post part and this column cap part, one T font reinforcing rib bone structure is respectively set, in order to strengthen the support strength of this base for post part, one the first baffle plate both sides are arranged on this base for post part inner surface, the first baffle plate is vertical arranges with this for one second baffle, and this second baffle one side is arranged on this first baffle plate center line, and this second baffle opposite side is arranged on this base for post part inner surface; And in this base for post part, many reinforcing ribs are set, it is evenly arranged at this base for post part inner surface with the direction parallel with this shaft, in order to strengthen the support strength of this base for post part, and make this base for post part and this internal layer intersect combination, increase contact area, improve blending and the associativity of this base for post part and this internal layer.
11. methods according to claim 10, wherein, this base for post part and this column cap part inner surface are all crude, in order to strengthen frictional force, strengthen this base for post part and this column cap part respectively with the combining closely of this internal layer.
12. methods according to claim 8, wherein, the thickness of this cylinder shell is in 1-3mm.
13. methods according to claim 8, wherein, step a) comprising: in this cylinder shell material, add one and connect skill agent.
14. methods according to claim 13, wherein, this content that connects skill agent is 5%-10%.
CN201210539230.6A 2012-12-13 2012-12-13 Composite material polyurethane rigid foam decorative marble pillar Pending CN103866961A (en)

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US13/969,428 US20140170349A1 (en) 2012-12-13 2013-08-16 Composite Material Polyurethane Rigid Foam Decoration Roman Column

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* Cited by examiner, † Cited by third party
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CN104827674A (en) * 2015-04-13 2015-08-12 泰兴市权兴装饰材料有限公司 Production process of marble pillar
CN107724621A (en) * 2017-11-07 2018-02-23 成都建工装饰装修有限公司 A kind of installation method of column cap stone material
CN107724621B (en) * 2017-11-07 2018-07-31 成都建工装饰装修有限公司 A kind of installation method of column cap stone material

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