CN103866640B - Noryl wet strength agent and preparation method thereof - Google Patents
Noryl wet strength agent and preparation method thereof Download PDFInfo
- Publication number
- CN103866640B CN103866640B CN201410072977.4A CN201410072977A CN103866640B CN 103866640 B CN103866640 B CN 103866640B CN 201410072977 A CN201410072977 A CN 201410072977A CN 103866640 B CN103866640 B CN 103866640B
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- China
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- parts
- wet strength
- strength agent
- noryl
- isocyanates
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- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 30
- 239000004727 Noryl Substances 0.000 title claims abstract description 14
- 229920001207 Noryl Polymers 0.000 title claims abstract description 14
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 24
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000012948 isocyanate Substances 0.000 claims abstract description 21
- 150000002513 isocyanates Chemical class 0.000 claims abstract description 18
- 239000003960 organic solvent Substances 0.000 claims abstract description 17
- 229920000768 polyamine Polymers 0.000 claims abstract description 17
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 14
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 claims abstract description 13
- 229920006380 polyphenylene oxide Polymers 0.000 claims abstract description 13
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 claims abstract description 12
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 claims abstract description 12
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 12
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 12
- 235000011114 ammonium hydroxide Nutrition 0.000 claims abstract description 12
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 claims abstract description 12
- 229960000735 docosanol Drugs 0.000 claims abstract description 12
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 claims abstract description 12
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims abstract description 12
- CMOAHYOGLLEOGO-UHFFFAOYSA-N oxozirconium;dihydrochloride Chemical compound Cl.Cl.[Zr]=O CMOAHYOGLLEOGO-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 12
- 229940093609 tricaprylin Drugs 0.000 claims abstract description 12
- VLPFTAMPNXLGLX-UHFFFAOYSA-N trioctanoin Chemical compound CCCCCCCC(=O)OCC(OC(=O)CCCCCCC)COC(=O)CCCCCCC VLPFTAMPNXLGLX-UHFFFAOYSA-N 0.000 claims abstract description 12
- 238000007865 diluting Methods 0.000 claims abstract description 6
- 239000002994 raw material Substances 0.000 claims abstract description 6
- 238000003756 stirring Methods 0.000 claims abstract description 6
- 238000010792 warming Methods 0.000 claims abstract description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 9
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 6
- 238000009413 insulation Methods 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 claims description 4
- 229960001124 trientine Drugs 0.000 claims description 4
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical group NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 claims description 3
- 239000005058 Isophorone diisocyanate Substances 0.000 claims description 3
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 3
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 claims description 3
- 235000019437 butane-1,3-diol Nutrition 0.000 claims 2
- 230000000694 effects Effects 0.000 abstract description 6
- AXPZIVKEZRHGAS-UHFFFAOYSA-N 3-benzyl-5-[(2-nitrophenoxy)methyl]oxolan-2-one Chemical compound [O-][N+](=O)C1=CC=CC=C1OCC1OC(=O)C(CC=2C=CC=CC=2)C1 AXPZIVKEZRHGAS-UHFFFAOYSA-N 0.000 abstract description 5
- 229920001955 polyphenylene ether Polymers 0.000 description 3
- 235000013399 edible fruits Nutrition 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000003389 potentiating effect Effects 0.000 description 2
- 238000011056 performance test Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920013636 polyphenyl ether polymer Polymers 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
Abstract
The invention discloses a kind of Noryl wet strength agent and preparation method thereof, wet strength agent comprises following raw material: polyphenylene oxide, dimethyl diallyl ammonium chloride, polyethylene glycol, hexadecanol, triethanolamine, 1,3-BDO, ferric trichloride, docosanol, tricaprylin, disodium ethylene diamine tetraacetate, hydrochloric acid, zirconium oxychloride, ammoniacal liquor, isocyanates, polyamine, organic solvent.Its preparation method is by polyphenylene oxide, dimethyl diallyl ammonium chloride, polyethylene glycol, hexadecanol, triethanolamine, 1,3-butanediol, ferric trichloride, docosanol, tricaprylin, disodium ethylene diamine tetraacetate mix, be warming up to 80 ~ 100 DEG C of stirring reaction 1 ~ 2h, add hydrochloric acid, be cooled to 35 ~ 40 DEG C, add zirconium oxychloride, ammoniacal liquor, isocyanates, polyamine reaction 10 ~ 20h, add organic solvent diluting.The present invention is than the wet strength better effects if of prior art wet strength agent.
Description
Technical field
The present invention relates to papermaking treatments field, particularly relate to a kind of Noryl wet strength agent and preparation method thereof.
Background technology
Wet strength agent is mainly used in paper industry, different its consumptions of paper kind differs widely, and the wet strength agent of prior art is PAE, PPE (polyphenylene oxide) wet strength agent mostly, certain wetly pretends use although have paper, but DeGrain, also have the good wet strength agent of some effects, but production cost is high, is not suitable for suitability for industrialized production, therefore, polyphenylene ether wet strength agent of the present invention carries out modification, makes it while low cost, has better wet potent fruit.
Summary of the invention
The object of the invention is: provide a kind of Noryl wet strength agent and preparation method thereof, wet strong better effects if, cost is low.
The present invention is technical solution problem by the following technical solutions:
A kind of Noryl wet strength agent, comprise the raw material of following parts by weight: polyphenylene oxide 40 ~ 60 parts, dimethyl diallyl ammonium chloride 20 ~ 40 parts, polyethylene glycol 45 ~ 50 parts, hexadecanol 66 ~ 70 parts, triethanolamine 70 ~ 80 parts, 1,3-BDO 50 ~ 60 parts, ferric trichloride 45 ~ 55 parts, docosanol 50 ~ 60 parts, tricaprylin 30 ~ 50 parts, disodium ethylene diamine tetraacetate 25 ~ 30 parts, hydrochloric acid 10 ~ 20 parts, zirconium oxychloride 20 ~ 30 parts, ammoniacal liquor 10 ~ 20 parts, isocyanates 50 ~ 70 parts, polyamine 70 ~ 75 parts, organic solvent 90 ~ 100 parts.
As preferably, isocyanates is one or more in toluene di-isocyanate(TDI), '-diphenylmethane diisocyanate, isophorone diisocyanate.
As preferably, polyamine is diethylenetriamine or triethylene tetramine.
As preferably, organic solvent is the one in acetone, butanone or 1-METHYLPYRROLIDONE.
The preparation method of above-mentioned wet strength agent, comprise the following steps: by polyphenylene oxide, dimethyl diallyl ammonium chloride, polyethylene glycol, hexadecanol, triethanolamine, 1,3-butanediol, ferric trichloride, docosanol, tricaprylin, disodium ethylene diamine tetraacetate mix, be warming up to 80 ~ 100 DEG C, stirring reaction 1 ~ 2h, mixing speed is 100 ~ 120r/min, add hydrochloric acid, be cooled to 35 ~ 40 DEG C, add zirconium oxychloride, ammoniacal liquor, isocyanates, polyamine, insulation reaction 10 ~ 20h, adds organic solvent diluting.
Technique effect
The present invention is by introducing dimethyl diallyl ammonium chloride, and polyphenylene ether carries out modification, adding of isocyanates, and making the molecular weight of polymer strengthen stability increases, and follow-up reaction is more easily carried out, makes product have higher wet potent fruit.
Dry tensile strength of the present invention is 8.19 ~ 8.63kN/m, dry breaking length is 7.23 ~ 8.01km, apparently higher than the wet strength agent dry strength of prior art, and wet tensile (strength) is 4.25 ~ 4.92kN/m, wet breaking length is 1.99 ~ 2.16km, and the wet strength better effects if of the present invention than prior art wet strength agent is described.
Detailed description of the invention
Embodiment 1
A kind of Noryl wet strength agent, comprise the raw material of following parts by weight: polyphenylene oxide 40 parts, dimethyl diallyl ammonium chloride 20 parts, polyethylene glycol 45 parts, hexadecanol 66 parts, triethanolamine 70 parts, 1,3-BDO 50 parts, ferric trichloride 45 parts, docosanol 50 parts, tricaprylin 30 parts, disodium ethylene diamine tetraacetate 25 parts, hydrochloric acid 10 parts, zirconium oxychloride 20 parts, ammoniacal liquor 10 parts, isocyanates 50 parts, polyamine 70 parts, organic solvent 90 parts.
Wherein, isocyanates is toluene di-isocyanate(TDI), and polyamine is diethylenetriamine, and organic solvent is acetone.
The preparation method of above-mentioned wet strength agent, comprise the following steps: by polyphenylene oxide, dimethyl diallyl ammonium chloride, polyethylene glycol, hexadecanol, triethanolamine, 1,3-butanediol, ferric trichloride, docosanol, tricaprylin, disodium ethylene diamine tetraacetate mix, and are warming up to 80 DEG C, stirring reaction 1h, mixing speed is 100r/min, add hydrochloric acid, be cooled to 35 DEG C, add zirconium oxychloride, ammoniacal liquor, isocyanates, polyamine, insulation reaction 10h, adds organic solvent diluting.
Embodiment 2
A kind of Noryl wet strength agent, comprise the raw material of following parts by weight: polyphenylene oxide 60 parts, dimethyl diallyl ammonium chloride 40 parts, polyethylene glycol 50 parts, hexadecanol 70 parts, triethanolamine 80 parts, 1,3-BDO 60 parts, ferric trichloride 55 parts, docosanol 60 parts, tricaprylin 50 parts, disodium ethylene diamine tetraacetate 30 parts, hydrochloric acid 20 parts, zirconium oxychloride 30 parts, ammoniacal liquor 20 parts, isocyanates 70 parts, polyamine 75 parts, organic solvent 100 parts.
Wherein, isocyanate is '-diphenylmethane diisocyanate and isophorone diisocyanate than 1:1, and polyamine is triethylene tetramine, and organic solvent is 1-METHYLPYRROLIDONE.
The preparation method of above-mentioned wet strength agent, comprise the following steps: by polyphenylene oxide, dimethyl diallyl ammonium chloride, polyethylene glycol, hexadecanol, triethanolamine, 1,3-butanediol, ferric trichloride, docosanol, tricaprylin, disodium ethylene diamine tetraacetate mix, and are warming up to 100 DEG C, stirring reaction 2h, mixing speed is 120r/min, add hydrochloric acid, be cooled to 40 DEG C, add zirconium oxychloride, ammoniacal liquor, isocyanates, polyamine, insulation reaction 20h, adds organic solvent diluting.
Embodiment 3
A kind of Noryl wet strength agent, comprise the raw material of following parts by weight: polyphenylene oxide 50 parts, dimethyl diallyl ammonium chloride 30 parts, polyethylene glycol 48 parts, hexadecanol 68 parts, triethanolamine 75 parts, 1,3-BDO 55 parts, ferric trichloride 50 parts, docosanol 55 parts, tricaprylin 40 parts, disodium ethylene diamine tetraacetate 28 parts, hydrochloric acid 15 parts, zirconium oxychloride 25 parts, ammoniacal liquor 15 parts, isocyanates 60 parts, polyamine 73 parts, organic solvent 95 parts.
Wherein, isocyanates is '-diphenylmethane diisocyanate, and polyamine is triethylene tetramine organic solvent is butanone.
The preparation method of above-mentioned wet strength agent, comprise the following steps: by polyphenylene oxide, dimethyl diallyl ammonium chloride, polyethylene glycol, hexadecanol, triethanolamine, 1,3-butanediol, ferric trichloride, docosanol, tricaprylin, disodium ethylene diamine tetraacetate mix, and are warming up to 90 DEG C, stirring reaction 1.5h, mixing speed is 110r/min, add hydrochloric acid, be cooled to 38 DEG C, add zirconium oxychloride, ammoniacal liquor, isocyanates, polyamine, insulation reaction 15h, adds organic solvent diluting.
The performance indications of coated paper:
Contrast: adopt sample prepared by CN1966855A method.
Carry out performance test according to for the wet strength agent of GB12005.1-89 to blank, contrast and embodiment 1 ~ 3, the results are shown in following table.
Dry tensile strength of the present invention is 8.19 ~ 8.63kN/m, dry breaking length is 7.23 ~ 8.01km, apparently higher than the wet strength agent dry strength of prior art, and wet tensile (strength) is 4.25 ~ 4.92kN/m, wet breaking length is 1.99 ~ 2.16km, and the wet strength better effects if of the present invention than prior art wet strength agent is described.
Claims (5)
1. a Noryl wet strength agent, it is characterized in that, comprise the raw material of following parts by weight: polyphenylene oxide 40 ~ 60 parts, dimethyl diallyl ammonium chloride 20 ~ 40 parts, polyethylene glycol 45 ~ 50 parts, hexadecanol 66 ~ 70 parts, triethanolamine 70 ~ 80 parts, 1, 3-butanediol 50 ~ 60 parts, ferric trichloride 45 ~ 55 parts, docosanol 50 ~ 60 parts, tricaprylin 30 ~ 50 parts, disodium ethylene diamine tetraacetate 25 ~ 30 parts, hydrochloric acid 10 ~ 20 parts, zirconium oxychloride 20 ~ 30 parts, ammoniacal liquor 10 ~ 20 parts, isocyanates 50 ~ 70 parts, polyamine 70 ~ 75 parts, organic solvent 90 ~ 100 parts.
2. Noryl wet strength agent according to claim 1, is characterized in that, isocyanates is one or more in toluene di-isocyanate(TDI), '-diphenylmethane diisocyanate, isophorone diisocyanate.
3. Noryl wet strength agent according to claim 1, is characterized in that, polyamine is diethylenetriamine or triethylene tetramine.
4. Noryl wet strength agent according to claim 1, is characterized in that, organic solvent is the one in acetone, butanone or 1-METHYLPYRROLIDONE.
5. the preparation method of Noryl wet strength agent according to claim 1, it is characterized in that, comprise the following steps: by polyphenylene oxide, dimethyl diallyl ammonium chloride, polyethylene glycol, hexadecanol, triethanolamine, 1, 3-butanediol, ferric trichloride, docosanol, tricaprylin, disodium ethylene diamine tetraacetate mixes, be warming up to 80 ~ 100 DEG C, stirring reaction 1 ~ 2h, mixing speed is 100 ~ 120r/min, add hydrochloric acid, be cooled to 35 ~ 40 DEG C, add zirconium oxychloride, ammoniacal liquor, isocyanates, polyamine, insulation reaction 10 ~ 20h, add organic solvent diluting.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410072977.4A CN103866640B (en) | 2014-02-28 | 2014-02-28 | Noryl wet strength agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410072977.4A CN103866640B (en) | 2014-02-28 | 2014-02-28 | Noryl wet strength agent and preparation method thereof |
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| Publication Number | Publication Date |
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| CN103866640A CN103866640A (en) | 2014-06-18 |
| CN103866640B true CN103866640B (en) | 2016-04-20 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201410072977.4A Expired - Fee Related CN103866640B (en) | 2014-02-28 | 2014-02-28 | Noryl wet strength agent and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106087563A (en) * | 2016-06-20 | 2016-11-09 | 广州聚注专利研发有限公司 | The preparation method of a kind of wet strength agent and wet strength agent |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0600074B1 (en) * | 1992-06-18 | 1997-09-17 | National Starch and Chemical Investment Holding Corporation | Composition of a cationic micro-emulsion and its preparation method |
| JP4054614B2 (en) * | 2002-06-24 | 2008-02-27 | 泉株式会社 | Inkjet recording medium and method for producing the same |
| CN101331222A (en) * | 2005-12-15 | 2008-12-24 | 金伯利-克拉克环球有限公司 | Premoistened tissue products |
| CN102190850A (en) * | 2010-03-11 | 2011-09-21 | 段全义 | Production method for papermaking wet strength agent |
| CN102191720A (en) * | 2010-03-15 | 2011-09-21 | 殷邗清 | Method for producing paper wet-strength agent with polyamide polyamine epichlorohydrin resin |
-
2014
- 2014-02-28 CN CN201410072977.4A patent/CN103866640B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0600074B1 (en) * | 1992-06-18 | 1997-09-17 | National Starch and Chemical Investment Holding Corporation | Composition of a cationic micro-emulsion and its preparation method |
| JP4054614B2 (en) * | 2002-06-24 | 2008-02-27 | 泉株式会社 | Inkjet recording medium and method for producing the same |
| CN101331222A (en) * | 2005-12-15 | 2008-12-24 | 金伯利-克拉克环球有限公司 | Premoistened tissue products |
| CN102190850A (en) * | 2010-03-11 | 2011-09-21 | 段全义 | Production method for papermaking wet strength agent |
| CN102191720A (en) * | 2010-03-15 | 2011-09-21 | 殷邗清 | Method for producing paper wet-strength agent with polyamide polyamine epichlorohydrin resin |
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| CN103866640A (en) | 2014-06-18 |
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Inventor after: Talent seeking Army Inventor before: Deng Qiang |
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Effective date of registration: 20160318 Address after: 750000, the Ningxia Hui Autonomous Region, Yinchuan, Xingqing District, Xinhua East Street, Lishui homes, No. 42 business building, room 7 Applicant after: NINGXIA HONGYU MACHINERY SCIENCE & TECHNOLOGY CO.,LTD. Address before: Baoan high tech Zone Xushuguan Town Road Suzhou City, Jiangsu province 215001 No. 196 Applicant before: SUZHOU HENGKANG NEW MATERIAL Co.,Ltd. |
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