CN103837915A - Retro-reflective film - Google Patents

Retro-reflective film Download PDF

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Publication number
CN103837915A
CN103837915A CN201410102851.7A CN201410102851A CN103837915A CN 103837915 A CN103837915 A CN 103837915A CN 201410102851 A CN201410102851 A CN 201410102851A CN 103837915 A CN103837915 A CN 103837915A
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China
Prior art keywords
microstructure
reflection
counter
upper bottom
reflex
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Pending
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CN201410102851.7A
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Chinese (zh)
Inventor
朱伟
陆国华
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Zhangjiagang Kangdexin Optronics Material Co Ltd
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Zhangjiagang Kangdexin Optronics Material Co Ltd
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Priority to CN201410102851.7A priority Critical patent/CN103837915A/en
Publication of CN103837915A publication Critical patent/CN103837915A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a retro-reflective film which comprises a base material layer and a retro-reflective microstructure layer. The base material layer is made of transparent materials. The retro-reflective microstructure layer comprises a first microstructure and a second microstructure. The first microstructure comprises an upper bottom face and a lower bottom face. The second microstructure is in the shape of a triangular pyramid and comprises three side faces which intersect at the same point. The upper bottom face of the first microstructure surrounds the second microstructure and the upper bottom face of the first microstructure is a rough face. The retro-reflective film can guarantee the requirements for the intensity of retro-reflective light parallel to the incident direction, can also conduct retro-reflection on spare light energy parallel to the incident direction in a scattering mode, therefore, it is guaranteed that the light energy is scattered, meanwhile, the scattering angle is enlarged, and the observation angle of the retro-reflective film is enlarged.

Description

A kind of Counter-reflection membrane
Technical field
The present invention relates to optical technical field, particularly relate to a kind of Counter-reflection membrane.
Background technology
Counter-reflection membrane has been widely used in the aspects such as various traffic alarms and personal security, as mark, navigation marker or billboard etc. are controlled in the warning against danger mark on warning notice, road on vehicle, friendship.
Be Counter-reflection membrane structure of the prior art as depicted in figs. 1 and 2, current Counter-reflection membrane comprises at least one deck substrate layer and one deck reflex reflection microstructured layers, be used for the microstructure design of reflex reflection at the opposite side of incident ray, first incident ray passes through base material, enter afterwards reflex reflection microstructured layers, after corresponding optical total-reflection is carried out in reflex reflection microstructured layers inside with the direction outgoing contrary with incident light.
Counter-reflection membrane structure of the prior art is that the total reflection characteristic of simple dependence cube corner part that incident ray is met to total reflection condition is carried out reflex reflection, all the other light that do not meet total reflection condition carry out reflex reflection through small part light after catadioptric repeatedly with the form of scattering in the inside of cube corner combination, cause the reflex reflection light viewing angle of this cube corner combination little, and after departing from certain angle, reflection ray intensity is little, is unfavorable for being found and paying attention to.
As shown in Figure 3, this Counter-reflection membrane is mainly by substrate layer 1, reflex reflection microstructured layers 2 and light diffusion layer 3 form, incident ray is divided into 2 parts in reflex reflection microstructure inside, meet the light 4 process microstructure total reflections of total reflection condition afterwards with the direction outgoing contrary with incident direction, after the catadioptric of the light 5 that does not meet total reflection condition through microstructures, enter light diffusion layer 3, after diffusion layer is through catadioptric repeatedly, carry certain angle secretly with the direction contrary with incident direction and form scattering in shining air.
Counter-reflection membrane shown in Fig. 3 is the combination of glass microballoon type Counter-reflection membrane and prism-type Counter-reflection membrane, with respect to traditional prism-type Counter-reflection membrane, this structure is to carry out catadioptric by wide-angle incident or because not meeting the light that total reflection condition loses by glass microballoon diffusion layer, the effect that promotes diffusion is very limited, and this complex structure, difficulty of processing is larger.
As shown in Figure 4, this retroreflective structure need to be by whole microstructure unit to some direction integral inclination certain angles according to design, and then combination, are combined to form the Counter-reflection membrane with disunity microstructure by the microstructure of different angles.Such structure decrease the light of total reflection part, increased scattered light.
Retroreflective structure shown in Fig. 4 is to be combined into by the microstructure unit of different angle, and owing to having skimble-scamble microstructure, difficulty of processing is larger.
Therefore,, for above-mentioned technical matters, be necessary to provide a kind of new Counter-reflection membrane.
Summary of the invention
In view of this, the object of the present invention is to provide a kind of Counter-reflection membrane, its scattering angle that can expand light can ensure again the energy of reflex reflection light simultaneously.
To achieve these goals, the technical scheme that the embodiment of the present invention provides is as follows:
A kind of Counter-reflection membrane, comprise substrate layer and reflex reflection microstructured layers, substrate layer is transparent material, described reflex reflection microstructured layers comprises some reflex reflection microstructures, and described reflex reflection microstructure comprises the first microstructure and the second microstructure, and the first microstructure comprises upper bottom surface, bottom surface, the second microstructure is triangular pyramidal, comprise 3 sides that intersect at same point, the upper bottom surface of the first microstructure is around the second microstructure, and the upper bottom surface of described the first microstructure is uneven surface.
As a further improvement on the present invention, the angle between the adjacent side of described the second microstructure is 90 °.
As a further improvement on the present invention, described upper bottom surface is diffuse surface, and on described upper bottom surface, scribbles diffuse reflection coating.
As a further improvement on the present invention, in described diffuse reflection coating, comprise white plastic particle and/or transparent grain.
As a further improvement on the present invention, described upper bottom surface is transmission plane, and is attached with diffuse reflector on described reflex reflection microstructured layers.
As a further improvement on the present invention, the projected area ratio of the upper bottom surface between the first microstructure of described each reflex reflection microstructure and bottom surface is identical or different.
As a further improvement on the present invention, upper bottom surface and the bottom surface shape of the first microstructure of described each reflex reflection microstructure have angle, and upper bottom surface tilts to any direction.
As a further improvement on the present invention, described angle is more than or equal to 0 degree and is less than or equal to 30 degree.
As a further improvement on the present invention, the complex that described substrate layer material is one or more transparent materials of transparent material in PET, PMMA, PC, glass.
The present invention has following beneficial effect:
Counter-reflection membrane of the present invention both can ensure to be parallel to the requirement of incident direction reflex reflection light intensity, can will be parallel to the unnecessary luminous energy of incident direction with the form reflex reflection of scattering again, the angle that has expanded scattering in ensureing scattered energy, has expanded Counter-reflection membrane viewing angle.
Brief description of the drawings
In order to be illustrated more clearly in the embodiment of the present invention or technical scheme of the prior art, to the accompanying drawing of required use in embodiment or description of the Prior Art be briefly described below, apparently, the accompanying drawing the following describes is only some embodiment that record in the present invention, for those of ordinary skill in the art, do not paying under the prerequisite of creative work, can also obtain according to these accompanying drawings other accompanying drawing.
Fig. 1 is the plan structure schematic diagram of Counter-reflection membrane in prior art;
Fig. 2 is the side-looking structural representation of Counter-reflection membrane in prior art;
Fig. 3 is the optical schematic diagram of another Counter-reflection membrane in prior art;
Fig. 4 is the plan structure schematic diagram of another Counter-reflection membrane in prior art;
Fig. 5 is the structural representation of reflex reflection microstructure in Counter-reflection membrane of the present invention;
Fig. 6 is the optical schematic diagram of a kind of Counter-reflection membrane of the present invention (embodiment 1);
Fig. 7 is the optical schematic diagram of a kind of Counter-reflection membrane of the present invention (embodiment 2);
Fig. 8 be traditional structure Counter-reflection membrane light move towards schematic diagram;
Fig. 9 be in embodiment 1 Counter-reflection membrane light move towards schematic diagram;
Figure 10 is the Counter-reflection membrane light angle of traditional structure and the curve map of light intensity;
Figure 11 is the curve map of Counter-reflection membrane light angle and light intensity in embodiment 1;
Figure 12 be in embodiment 2 Counter-reflection membrane light move towards schematic diagram;
Figure 13 is the curve map of Counter-reflection membrane light angle and light intensity in embodiment 2.
Embodiment
Describe the present invention below with reference to embodiment shown in the drawings.But these embodiments do not limit the present invention, the conversion in structure, method or function that those of ordinary skill in the art makes according to these embodiments is all included in protection scope of the present invention.
For the scattering angle that can better expand light ensures again reflex reflection light simultaneously, the present invention proposes a kind of Counter-reflection membrane, this Counter-reflection membrane is by least one deck substrate layer and one deck reflex reflection microstructured layers form, reflex reflection microstructured layers comprises some reflex reflection microstructures, can increase if desired one deck diffuse reflector.
As shown in Figure 5, in the present invention, reflex reflection microstructure comprises the first microstructure 201 and is seated the second microstructure 202 in the first microstructure, the first microstructure 201 comprises upper bottom surface 21, bottom surface 22, the second microstructure 202 is triangular pyramidal, comprise 3 sides that intersect at same point, the upper bottom surface 21 of the first microstructure 201 is around the second microstructure 202.Three sides of the second microstructure 202 are mutually approximately 90 ° of angles.Upper bottom surface 21 is uneven surface (Matte face), Matte face can better spread light, it can be used as diffuse surface or transmission plane, during as diffuse surface, can be coated with diffuse reflection coating at this face, diffuse reflection coating can comprise PMMA, and PC or other white plastic particles also can mix the transparent grains such as glass microballoon, when as transmission plane, need be at reflex reflection microstructure laminating one deck diffuse reflector for diffuse reflection.
Reflex reflection microstructure is attached on substrate layer, and substrate layer material is the complex of one or more transparent materials of PET, PMMA, PC, glass or other transparent materials.First light be incident to substrate layer, after substrate layer, enter reflex reflection microstructured layers, in reflex reflection microstructured layers, total reflection zonal ray can carry out total reflection, at Matte face diffuse reflection region or regional transmission, light can carry out diffuse reflection or transmission, and the light after transmission carries out diffuse reflection at diffuse reflector.
Shown in Fig. 6, the first Counter-reflection membrane of the present invention comprises substrate layer 10 and reflex reflection microstructured layers 20, reflex reflection microstructured layers comprises upper bottom surface 21,22 and 3 sides 23 of bottom surface, bottom surface is equilateral triangle, and three sides are mutually approximately 90 degree, and wherein upper bottom surface (Matte face) scribbles diffuse reflection coating (not shown), diffuse reflection coating can comprise PMMA, and PC or other white plastic particles also can mix the transparent grains such as glass microballoon.
Light is incident to Counter-reflection membrane, is divided into 3 parts in microstructure internal light:
1. meet the light 6 of total reflection condition by the form reflex reflection with total reflection;
2. directly directive for another part light 7 of diffuse reflection Matte face through the diffusion of Matte faces and diffuse reflection the form reflex reflection with scattering;
3. other do not meet total reflection condition does not have the light 8 of directive diffuse reflection Matte face between microstructure, to carry out catadioptric rear section loss repeatedly yet, and part also forms reflex reflection.
Can be by regulating the area of upper bottom surface (Matte face) and bottom surface recently to control the energy of scattered beam, with realistic application requirements in the time of actual design.
Shown in Fig. 7, the second Counter-reflection membrane of the present invention comprises substrate layer 10 and reflex reflection microstructured layers 20, and reflex reflection microstructured layers comprises upper bottom surface 21,22 and 3 sides 23 of bottom surface, and bottom surface is equilateral triangle, three sides are mutually approximately 90 degree.Wherein, on reflex reflection microstructured layers 20, be also attached with diffuse reflector 30.
Light is incident to Counter-reflection membrane, is divided into 3 parts in microstructure internal light:
1. meet the light 6 of total reflection condition by the form reflex reflection with total reflection;
2. directly another part light 7 of directive plane will be incident to reflectance coating through Matte face, and the reflex reflection that diffuses to form of Matte face is passed through in the diffuse reflection of passing through reflectance coating afterwards again;
3. other do not meet total reflection condition does not have the light 8 of directive Matte face to form reflex reflection after carrying out catadioptric repeatedly between microstructure and reflectance coating yet yet.
Can be by regulating the area of upper bottom surface (Matte face) and bottom surface recently to control the energy of scattered beam, with realistic application requirements in the time of actual design.
Below in conjunction with specific embodiment, the invention will be further described.
Embodiment 1:
As shown in Figure 5,6, a kind of Counter-reflection membrane, comprise one deck substrate layer, one deck reflex reflection microstructured layers, reflex reflection microstructure upper bottom surface 21 (Matte face) is about 0.5142 with the Area Ratio of bottom surface, substrate layer refractive index is 1.6, the refractive index of reflex reflection microstructured layers is that 1.56, Matte face scribbles diffuse reflection coating, and incident ray is had to irreflexive effect.A branch of approximately parallel light beam is incident to this Counter-reflection membrane from afar, by base material laggard enter microstructure area, carry out catadioptric in microstructure inside.
Fig. 8 is that the Counter-reflection membrane light of traditional structure moves towards schematic diagram, can see that by Fig. 8 its light concentrates in certain angular range, and light beam is concentrated, and dispersion angle is little.
Fig. 9 is that the light of the Counter-reflection membrane after the present embodiment improves moves towards schematic diagram.Can see that by Fig. 9 light concentrates on reflex reflection in certain angle through part light after Counter-reflection membrane, another part light is certain large angle scattering, and light is compared Fig. 8 and relatively disperseed.
Figure 10 is the curve map of traditional structure light angle and light intensity, is shown that the general overall scattering angle of Counter-reflection membrane of traditional structure is about 80 ° of left and right by Figure 10, and reflection potential is too concentrated, and observer slightly angle deviating just can not well find reverberation.
Figure 11 is the light angle that obtains of microstructure that adopts of the present embodiment and the curve map of light intensity, the distribution again that the Counter-reflection membrane of the present embodiment carries out light ray energy as seen from Figure 11, has suitably reduced front reflex reflection light intensity and has expanded the catoptrical viewing angle of object simultaneously.The overall scattering angle of the present embodiment approaches 180 ° as seen from Figure 11, decreases though central light strength is compared Figure 10, and the observer that the viewing angle expanding can allow in larger viewing angle also can find the existence of reverberation.
Embodiment 2:
As shown in Fig. 5,7, a kind of Counter-reflection membrane, comprises one deck substrate layer, one deck reflex reflection microstructured layers, is also attached with diffuse reflector, for light is carried out to diffuse reflection on reflex reflection microstructured layers.
A branch of approximately parallel light beam is incident to this Counter-reflection membrane from afar, by base material laggard enter microstructure area, between microstructure inside and diffuse reflector, carry out catadioptric.Can see that by Figure 12 light concentrates on reflex reflection in certain angle through part light after Counter-reflection membrane, another part light is owing to inciding on diffuse reflector, add Matte in the face of the diffusion of light, be certain large angle scattering and overall light energy loss little.
Figure 13 is the light angle that obtains of microstructure that adopts of the present embodiment and the curve map of light intensity, the distribution again that the Counter-reflection membrane of the present embodiment carries out light ray energy as seen from Figure 13, has suitably reduced front reflex reflection light intensity and has expanded the catoptrical viewing angle of object simultaneously.Find out that by Figure 13 the overall scattering angle of the present embodiment approaches 180 °, Figure 10 relatively, though central light strength decreases, the observer that the viewing angle expanding can allow in larger viewing angle also can find the existence of reverberation.Figure 11 relatively, in ensureing diffusion angle, central light strength increases relatively, improves reflection strength.
Further, in other embodiments, the projected area of the upper and lower bottom surface in same Counter-reflection membrane between the first microstructure of reflex reflection microstructure can have different Area Ratios, with according to the energy of actual requirement control scattered beam.
Further, in other embodiments, upper bottom surface and the bottom surface shape of the first microstructure of reflex reflection microstructure have angle, and upper bottom surface can tilt to any direction, combine, angle can be more than or equal to 0 degree and be less than or equal to 30 degree again, with according to actual requirement control radiation direction.
As can be seen from the above embodiments, compared with prior art, Counter-reflection membrane of the present invention both can ensure to be parallel to the requirement of incident direction reflex reflection light intensity, can will be parallel to the unnecessary luminous energy of incident direction with the form reflex reflection of scattering again, the angle that has expanded scattering in ensureing scattered energy, has expanded Counter-reflection membrane viewing angle.
Counter-reflection membrane of the present invention is also by increasing diffuse reflection Matte face or diffuse reflector, to be parallel to the unnecessary luminous energy of incident direction with the form reflex reflection of scattering, in ensureing to be parallel to incident light direction reflex reflection light intensity, expand again scattering angle, improve scattared energy, expanded the viewing angle of Counter-reflection membrane and still can make object be found and draw attention.
To those skilled in the art, obviously the invention is not restricted to the details of above-mentioned example embodiment, and in the situation that not deviating from spirit of the present invention or essential characteristic, can realize the present invention with other concrete form.Therefore, no matter from which point, all should regard embodiment as exemplary, and be nonrestrictive, scope of the present invention is limited by claims instead of above-mentioned explanation, is therefore intended to all changes that drop in the implication and the scope that are equal to important document of claim to include in the present invention.Any Reference numeral in claim should be considered as limiting related claim.
In addition, be to be understood that, although this instructions is described according to embodiment, but be not that each embodiment only comprises an independently technical scheme, this narrating mode of instructions is only for clarity sake, those skilled in the art should make instructions as a whole, and the technical scheme in each embodiment also can, through appropriately combined, form other embodiments that it will be appreciated by those skilled in the art that.

Claims (9)

1. a Counter-reflection membrane, comprise substrate layer and reflex reflection microstructured layers, substrate layer is transparent material, and described reflex reflection microstructured layers comprises some reflex reflection microstructures, it is characterized in that, described reflex reflection microstructure comprises the first microstructure and the second microstructure, the first microstructure comprises upper bottom surface, bottom surface, and the second microstructure is triangular pyramidal, comprises 3 sides that intersect at same point, the upper bottom surface of the first microstructure is around the second microstructure, and the upper bottom surface of described the first microstructure is uneven surface.
2. Counter-reflection membrane according to claim 1, is characterized in that, the angle between the adjacent side of described the second microstructure is 90 °.
3. Counter-reflection membrane according to claim 1, is characterized in that, described upper bottom surface is diffuse surface, and on described upper bottom surface, scribbles diffuse reflection coating.
4. Counter-reflection membrane according to claim 3, is characterized in that, in described diffuse reflection coating, comprises white plastic particle and/or transparent grain.
5. Counter-reflection membrane according to claim 1, is characterized in that, described upper bottom surface is transmission plane, and is attached with diffuse reflector on described reflex reflection microstructured layers.
6. Counter-reflection membrane according to claim 1, is characterized in that, the upper bottom surface between the first microstructure of described each reflex reflection microstructure and the projected area ratio of bottom surface are identical or different.
7. Counter-reflection membrane according to claim 1, is characterized in that, upper bottom surface and the bottom surface shape of the first microstructure of described each reflex reflection microstructure have angle, and upper bottom surface tilts to any direction.
8. Counter-reflection membrane according to claim 7, is characterized in that, described angle is more than or equal to 0 degree and is less than or equal to 30 degree.
9. Counter-reflection membrane according to claim 1, is characterized in that, described substrate layer material is the complex of one or more transparent materials of transparent material in PET, PMMA, PC, glass.
CN201410102851.7A 2014-03-19 2014-03-19 Retro-reflective film Pending CN103837915A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104181698A (en) * 2014-09-03 2014-12-03 张家港康得新光电材料有限公司 Alignment target, 3D pillar mirror film comprising alignment target, optical film and display device
CN105278015A (en) * 2015-11-12 2016-01-27 中国科学院重庆绿色智能技术研究院 Double-side micro pyramid array retroreflection structure
CN105333398A (en) * 2015-12-01 2016-02-17 济南昊泽环保科技有限公司 Diffuse reflection structure for lamp groove inner wall
CN108983331A (en) * 2018-07-24 2018-12-11 京东方科技集团股份有限公司 A kind of semi-transparent half converse diaphragm and aerial display device
WO2021022566A1 (en) * 2019-08-08 2021-02-11 深圳市汇顶科技股份有限公司 Security chip, preparation method for security chip, and electronic device

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CN1169780A (en) * 1994-09-28 1998-01-07 瑞弗莱克塞特公司 Cube-corner retroreflective article of prism
CN1161627C (en) * 1999-01-11 2004-08-11 3M创新有限公司 Cube corner cavity based refroreflectors and methods for making same
WO2014035111A1 (en) * 2012-08-31 2014-03-06 미래나노텍(주) Wide-angle retroreflective sheet

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1169780A (en) * 1994-09-28 1998-01-07 瑞弗莱克塞特公司 Cube-corner retroreflective article of prism
CN1161627C (en) * 1999-01-11 2004-08-11 3M创新有限公司 Cube corner cavity based refroreflectors and methods for making same
WO2014035111A1 (en) * 2012-08-31 2014-03-06 미래나노텍(주) Wide-angle retroreflective sheet

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104181698A (en) * 2014-09-03 2014-12-03 张家港康得新光电材料有限公司 Alignment target, 3D pillar mirror film comprising alignment target, optical film and display device
CN105842860A (en) * 2014-09-03 2016-08-10 张家港康得新光电材料有限公司 3D (three dimensional) lenticular film with alignment targets, optical film and display device
CN104181698B (en) * 2014-09-03 2017-06-13 张家港康得新光电材料有限公司 Contraposition target and the 3D post mirrors film with it, optical film and display device
CN105278015A (en) * 2015-11-12 2016-01-27 中国科学院重庆绿色智能技术研究院 Double-side micro pyramid array retroreflection structure
CN105278015B (en) * 2015-11-12 2017-11-07 中国科学院重庆绿色智能技术研究院 A kind of retroreflective structure of two-sided micro- pyramid array
CN105333398A (en) * 2015-12-01 2016-02-17 济南昊泽环保科技有限公司 Diffuse reflection structure for lamp groove inner wall
CN108983331A (en) * 2018-07-24 2018-12-11 京东方科技集团股份有限公司 A kind of semi-transparent half converse diaphragm and aerial display device
CN108983331B (en) * 2018-07-24 2020-12-01 京东方科技集团股份有限公司 Semi-transparent semi-reverse diaphragm and aerial display device
US11231595B2 (en) 2018-07-24 2022-01-25 Boe Technology Group Co., Ltd Semi-transparent semi-retroreflective film and air display device
WO2021022566A1 (en) * 2019-08-08 2021-02-11 深圳市汇顶科技股份有限公司 Security chip, preparation method for security chip, and electronic device
US11462490B2 (en) 2019-08-08 2022-10-04 Shenzhen GOODIX Technology Co., Ltd. Security chip, security chip production method and electronic device

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