CN103837448A - Method for testing influence of surfactant on apparent viscosity of hydrophobic association polymer - Google Patents
Method for testing influence of surfactant on apparent viscosity of hydrophobic association polymer Download PDFInfo
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- CN103837448A CN103837448A CN201210481861.7A CN201210481861A CN103837448A CN 103837448 A CN103837448 A CN 103837448A CN 201210481861 A CN201210481861 A CN 201210481861A CN 103837448 A CN103837448 A CN 103837448A
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Abstract
The invention discloses a method for testing the influence of a surfactant on the apparent viscosity of a hydrophobic association polymer. The method comprises the following steps: 1, preparing the hydrophobic association polymer; 2, dissolving the hydrophobic association polymer in a solvent to form solutions having a same mass concentration, and respectively adding different amounts of a surfactant; 3, respectively placing the hydrophobic association polymer solutions in different experiment containers; 4, respectively placing the experiment containers in water baths having a same temperature; and 5, measuring through a viscometer to obtain the apparent viscosity of the hydrophobic association polymer under different concentrations of the surfactant, and analyzing data to obtain the influence of the surfactant on the apparent viscosity of the hydrophobic association polymer. The method can be successfully applied to test the influence of the surfactant on the apparent viscosity of the hydrophobic association polymer, and has the advantages of accurate test result, simple test steps, and substantial reduction of the test cost.
Description
Technical field
The present invention relates to the method for testing of a kind of surfactant on the impact of hydrophobic associated polymer apparent viscosity.
Background technology
Hydrophobic associated polymer, refers to the water-soluble polymers with a small amount of hydrophobic grouping on polymer hydrophilicity macromolecular chain.On water-soluble macromolecule chain, introducing a small amount of hydrophobic grouping makes its aqueous solution show unique rheological property.On certain polymer concentration, hydrophobic part associates and forms dynamic three-dimensional net structure, thereby forms very large supermolecule chain aggregation body, increases the hydrodynamic volume of polymkeric substance, improves significantly the viscosity of solution.The electrolytical polarity that can increase solvent that adds of little molecule, strengthens hydrophobic association effect, produces obvious anti-lime chloride.Under high shear forces, the dynamic physical cross-linked network structure that hydrophobic association forms is destroyed, solution viscosity declines, shear action reduction or the physical crosslinking of eliminating between rear macromolecular chain form again, viscosity will be recovered again, the irreversible machinery degraded of the polymkeric substance that general high molecular do not occur under high-rate of shear.Just because of its unique SOLUTION PROPERTIES, it may be applied in a lot of fields, as tertiary oil recovery, pharmacy, sun power conversion, cosmetics, coating, water treatment and drag reducer etc.Its correlative study in recent years receives much attention.
Hydrophobic close ester phenomenon is very general, below critical association concentration, mainly forms in molecule and associates, and consequently makes a ball of string shrink, and hydrodynamic volume reduces; More than CAC, main formation taking Interpolymer Association as main supramolecular structure has good tackifying.By Interpolymer Association, on the macro property of solution, show the feature that tackifying is strong, have certain temperature resistance, anti-lime chloride and anti-shear ability.These special performances of hydrophobic associated polymer make it in many industrial technologies, all show huge application potential, and have great importance for the solution behavior that imitates the amphiphilic class material in life entity, thereby the exploration of hydrophobic associated water-soluble polymer is become to recent two decades carry out one of problem the most interesting in water-soluble polymers research field, and become the focus that industry and academia are studied.
Should trace back to the fifties initial stage to the research of amphiphilic base polymer, Strauss and assistant thereof have synthesized the solution behavior of a series of polysoaps in order to mimic protein for this reason, first Kauzmann has proposed the concept of " hydrophobic interaction ", and describes XC polymer as a series of phenomenons relevant to life science such as the formation of film in the constraint to enzyme of the conformation transition of protein, matrix, biosome with it.In the later stage in the sixties, Strauss group has synthesized again a series of hydrophobic super coil polymkeric substance that have.Contemporaneity, hydrophobically modified urea alkane (HEUR) comes out and is very fast for improving the rheological of water-based latex coating.Until today, researchist, still in effort, attempts that HEUR is made further improvements or find new material and replaces HEUR.
Last century the eighties, the SOLUTION PROPERTIES of hydrophobic associated polymer uniqueness and huge application potential thereof have attracted a large amount of researchists.Landoll is considered to study the real beginning of hydrophobic associated water-soluble polymer about the research of hydroxyethyl cellulose (HEC) hydrophobically modified.The people such as Emmons have delivered the patent with chain alkyl N-substituted acrylamide (CnAM) copolymerization cooperation water-based paint with acrylamide (AM).Before and after 1984, the researchist of Exxon research and engineering corporation starts to inquire into hydrophobic associated polymer the feasibility for oil-gas mining, and this is carried out to lasting and deep research, develop various hydrophobic monomer, and invent the novel polymeric method that solves hydrophilic monomer and the inconsistent problem of hydrophobic monomer in hydrophobic associated polymer polymerization process, it is micellar free radical copolymerization method, be called for short micellar copolymerization, the method is still the best approach in all polymerizations of hydrophobic associated polymer up to now.
Hydrophobic associated water-soluble polymer is by the atom difference that forms main chain, can be divided into carbochain and heteroatoms molecular backbone polymkeric substance, the former is mainly the multipolymer being obtained by the alkene monomer polymer of hydrophilic radical and hydrophobic grouping, what hydrophilic monomer was conventional mainly contains acrylamide and acrylic acid etc., and hydrophobic monomer mainly contains acrylamide derivative, long-chain acrylate etc.; The latter mainly passes through water-soluble high-molecular compound modification through macromolecular reaction, introduces hydrophobic functional group.Macromolecular reaction method advantage is directly to make initiation material with commercial polymer, and the product relative molecular mass obtaining is high, and its shortcoming is that reaction is carried out in full-bodied polymer solution, and reactant is not easy to mix.Hydroxyethyl cellulose (HEC) can be reacted with the hydrophobic compound with reactive group in this way, these hydrophobic compounds can be with the epoxy compound of chain alkyl, halogenated hydrocarbons, carboxylic acid halides, isocyanates etc., also can be at polyglycol (PEG) two termination hydrophobic groupings, but the amount of the general hydrophobic grouping of introducing is all little, because the high dissolubility that can significantly reduce water soluble polymer of content of hydrophobic monomers, and heteroatoms trunk polymer is compared with carbochain polymer, thermal stability is poor.Because when the carbon atom in macromolecular chain is replaced by heteroatomss such as oxygen, sulphur, nitrogen, the bond energy of C-O, C-S, C-N key is lower than C-C key, and polymer thermostable reduces.Therefore be, mainly the multipolymer being obtained by the vinyl monomer polymerization of hydrophilic radical and hydrophobic grouping for the hydrophobic associated water-soluble polymer of tertiary oil production in oil field at present.The conventional hydrophilic monomer of hydrophobic associated polymer that utilizes process for copolymerization to prepare is acrylamide (AM), because acrylamide is suitable for preparing the water-soluble polymers of high molecular, reasonable price.In addition, in order to increase the dissolubility of multipolymer, the anionic monomer that also can add other as acrylic acid (methacrylic acid), vinyl sulfonic acid lime chloride, 2-methyl-2-acrylamido propane sulfonic acid (AMPS) etc. with cationic monomer as β-dimethyl-aminoethylmethacrylate base trimethyl ammonium chloride, 2-acrylimide base-2-trimethoxysilyl propyl methacrylate ammonium chloride (AMPTAC), diallyldimethylammonium chloride etc.
The architectural feature of hydrophobic associated water-soluble polymer is on the strand of polymkeric substance, to introduce a small amount of hydrophobic grouping.The polar group of hydrophilic segment can form hydrogen bond and show very strong affinity with hydrone.What form hydrophobic associated polymer molecule hydrophobic part is non-polar group, between they and hydrone, only has Van der Waals force, this acting force a little less than than the interaction hydrogen bond between hydrone many, thereby can not effectively replace with hydrone with interaction of hydrogen bond.The hydrophobic grouping of this type of solute molecule in dissolved state is present in water environment, and the approach that hydrophobic group is fled from water environment is that hydrophobic associated polymer molecule associates and forms aggregation together with hydrophobic group at the inner association body that forms of solution.Hydrophobic grouping, due to water insoluble, is close together under the driving of hydrone, also can be understood as conversely the effect that hydrophobic grouping is subject to association force and flocks together.
Because hydrophobic associated water-soluble polymer has unique structure, thereby there is good temperature resistance, anti-lime chloride and the special solution property that is different from general polymerization thing such as anti-shearing.In recent years, the exploitation of hydrophobic associated water-soluble polymer new product, structure investigation, performance study become the emphasis of people's research gradually.The character of twin tail hydrophobic associated water-soluble polymer in solution also should have relation with external factor such as the internal factors such as the concentration of polymkeric substance, structure and composition, molecular weight and temperature, shear rate, solution ion strength, surfactants, is necessary it further to inquire into.
Summary of the invention
The object of the invention is to overcome the shortcoming and defect of above-mentioned prior art, the method of testing of a kind of surfactant on the impact of hydrophobic associated polymer apparent viscosity is provided, this method of testing can be successfully applied to the test of surfactant on the impact of hydrophobic associated polymer apparent viscosity, and test result is accurate, testing procedure is simple, greatly reduces testing cost.
Object of the present invention is achieved through the following technical solutions: the method for testing of a kind of surfactant on the impact of hydrophobic associated polymer apparent viscosity, comprises the following steps:
(a) first, prepare hydrophobic associated polymer;
(b) then, hydrophobic associated polymer is become to the solution of equal in quality concentration by dissolution with solvents, add respectively the surfactant of different amounts;
(c) get respectively hydrophobic association polymer solution and be placed in different experiment containers;
(d) experiment container is placed in respectively to the water-bath of uniform temp;
(e) record the apparent viscosity of the hydrophobic associated polymer under different surfaces surfactant concentration by viscosity meter, by analyzing data, thereby draw the impact of surfactant on hydrophobic associated polymer apparent viscosity.
Described experiment container is beaker.
Described viscosity is counted the fast rotational viscosimeter of ZNN-D6 type six.
The mass concentration of described hydrophobic associated polymer is respectively 6.0g/L.
Described bath temperature is respectively 25 DEG C.
Described surfactant is respectively 500mg/L, 1000mg/L, 1500mg/L, 2000mg/L.
In sum, the invention has the beneficial effects as follows: can be successfully applied to the test of surfactant on the impact of hydrophobic associated polymer apparent viscosity, and test result is accurate, testing procedure is simple, greatly reduces testing cost.
Brief description of the drawings
?fig. 1 is that surfactant affects schematic diagram to hydrophobic associated polymer apparent viscosity.
Embodiment
Below in conjunction with embodiment, the present invention is described in further detail, but embodiments of the present invention are not limited only to this.
Embodiment:
The method of testing of a kind of surfactant the present invention relates on the impact of hydrophobic associated polymer apparent viscosity, comprises the following steps:
(a) first, prepare hydrophobic associated polymer;
(b) then, hydrophobic associated polymer is become to the solution of equal in quality concentration by dissolution with solvents, add respectively the surfactant of different amounts;
(c) get respectively hydrophobic association polymer solution and be placed in different experiment containers;
(d) experiment container is placed in respectively to the water-bath of uniform temp;
(e) record the apparent viscosity of the hydrophobic associated polymer under different surfaces surfactant concentration by viscosity meter, by analyzing data, thereby draw the impact of surfactant on hydrophobic associated polymer apparent viscosity.
Described experiment container is beaker.
Described viscosity is counted the fast rotational viscosimeter of ZNN-D6 type six.
The mass concentration of described hydrophobic associated polymer is respectively 6.0g/L.
Described bath temperature is respectively 25 DEG C.
Described surfactant is respectively 500mg/L, 1000mg/L, 1500mg/L, 2000mg/L.
The result being recorded by said method as shown in Figure 1, as shown in Figure 1: surfactant concentration has a significant impact the apparent viscosity of hydrophobic association polymer solution.Along with the rising of surfactant concentration, the apparent viscosity of hydrophobic association polymer solution first increases, after reaching certain value, sharply reduce with the increase of surfactant concentration again, even under certain high surfactant concentration lower than the apparent viscosity of same concentrations partially hydrolyzed polyacrylamide solution.And for partially hydrolyzed polyacrylamide solution, it is less that its apparent viscosity changes with the increase of the concentration of surfactant, be steady state (SS).The Different Effects of surface activity agent to polymer solution apparent viscosity, its reason may be: (1) is in the time that surfactant starts to join in hydrophobic association polymer solution, they are participated in directly in the hydrophobic microcell having existed and associate, the surfactant associating can play the effect that replaces polymkeric substance hydrophilic chain to protect hydrophobic microcell, polymkeric substance hydrophilic chain is stretched from highly curling becoming comparatively, and solution viscosity slowly increases; (2) continue to add surfactant, making has the hydrophobic grouping on enough surfactant and polymer molecular chain to form in solution.Mixed micelle, along with the increase of surfactant, mixed micelle number increases, and in a large amount of molecules, associates and starts to change into Interpolymer Association, makes the compact structure of formation, and intensity is larger, therefore in macroscopic view, shows as viscosity and sharply raises; (3), when surfactant concentration further strengthens, owing to forming mixed micelle in the hydrophobic grouping having on enough surfactant molecules and polymer chain, Interpolymer Association is broken.And along with the concentration of surfactant increases, this mixed micelle that only contains a hydrophobic grouping gets more and more, Interpolymer Association reduces relatively, and it is loose that the structure in solution also becomes, so solution apparent viscosity sharply declines.In addition, due on polyacrylamide strand without hydrophobic grouping, intermolecularly just there is not association, so add surfactant very little on its impact yet.
The above, be only preferred embodiment of the present invention, not the present invention done to any pro forma restriction, every foundation technical spirit of the present invention, and any simple modification, equivalent variations that above embodiment is done, within all falling into protection scope of the present invention.
Claims (6)
1. the method for testing of surfactant on the impact of hydrophobic associated polymer apparent viscosity, is characterized in that, comprises the following steps:
(a) first, prepare hydrophobic associated polymer;
(b) then, hydrophobic associated polymer is become to the solution of equal in quality concentration by dissolution with solvents, add respectively the surfactant of different amounts;
(c) get respectively hydrophobic association polymer solution and be placed in different experiment containers;
(d) experiment container is placed in respectively to the water-bath of uniform temp;
(e) record the apparent viscosity of the hydrophobic associated polymer under different surfaces surfactant concentration by viscosity meter, by analyzing data, thereby draw the impact of surfactant on hydrophobic associated polymer apparent viscosity.
2. the method for testing of surfactant according to claim 1 on the impact of hydrophobic associated polymer apparent viscosity, is characterized in that, described experiment container is beaker.
3. the method for testing of surfactant according to claim 1 on the impact of hydrophobic associated polymer apparent viscosity, is characterized in that, described viscosity is counted the fast rotational viscosimeter of ZNN-D6 type six.
4. the method for testing of surfactant according to claim 1 on the impact of hydrophobic associated polymer apparent viscosity, is characterized in that, the mass concentration of described hydrophobic associated polymer is respectively 6.0g/L.
5. the method for testing of surfactant according to claim 1 on the impact of hydrophobic associated polymer apparent viscosity, is characterized in that, described bath temperature is respectively 25 DEG C.
6. the method for testing of surfactant according to claim 1 on the impact of hydrophobic associated polymer apparent viscosity, is characterized in that, described surfactant is respectively 500mg/L, 1000mg/L, 1500mg/L, 2000mg/L.
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Cited By (4)
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| CN105295153A (en) * | 2015-09-30 | 2016-02-03 | 中国石油大学胜利学院 | Additive and method for improving anti-shearing performance of alcohol-base crude oil drag-reducing agent and method |
| CN106840967A (en) * | 2015-12-04 | 2017-06-13 | 中国石油天然气股份有限公司 | Rheology evaluation method of inferior superheavy oil flow improver |
| CN110542606A (en) * | 2019-09-20 | 2019-12-06 | 中海石油(中国)有限公司 | Method for measuring characteristic viscosity number of hydrophobically associating polymer |
| CN114605981A (en) * | 2022-04-15 | 2022-06-10 | 西南石油大学 | Hydrophobic association polymer quick solvent based on surfactant and dissolving method |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105295153A (en) * | 2015-09-30 | 2016-02-03 | 中国石油大学胜利学院 | Additive and method for improving anti-shearing performance of alcohol-base crude oil drag-reducing agent and method |
| CN107166173A (en) * | 2015-09-30 | 2017-09-15 | 刘玉友 | Pipeline drag reduction conveying additive |
| CN105295153B (en) * | 2015-09-30 | 2017-09-22 | 中国石油大学胜利学院 | A kind of additive and method for being used to improve alcohol radical drag reducer for crude oil anti-shear performance |
| CN107166173B (en) * | 2015-09-30 | 2018-11-20 | 江苏博拓电气设备有限公司 | Additive is used in pipeline drag reduction conveying |
| CN106840967A (en) * | 2015-12-04 | 2017-06-13 | 中国石油天然气股份有限公司 | Rheology evaluation method of inferior superheavy oil flow improver |
| CN110542606A (en) * | 2019-09-20 | 2019-12-06 | 中海石油(中国)有限公司 | Method for measuring characteristic viscosity number of hydrophobically associating polymer |
| CN110542606B (en) * | 2019-09-20 | 2023-03-14 | 中海石油(中国)有限公司 | Method for measuring characteristic viscosity number of hydrophobically associating polymer |
| CN114605981A (en) * | 2022-04-15 | 2022-06-10 | 西南石油大学 | Hydrophobic association polymer quick solvent based on surfactant and dissolving method |
| CN114605981B (en) * | 2022-04-15 | 2022-08-30 | 西南石油大学 | Hydrophobic association polymer quick solvent based on surfactant and dissolving method |
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Application publication date: 20140604 |