CN103834347A - Viscose glue, viscose glue plaster prepared from viscose glue, and making method and application of viscose glue plaster - Google Patents
Viscose glue, viscose glue plaster prepared from viscose glue, and making method and application of viscose glue plaster Download PDFInfo
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- CN103834347A CN103834347A CN201210472605.1A CN201210472605A CN103834347A CN 103834347 A CN103834347 A CN 103834347A CN 201210472605 A CN201210472605 A CN 201210472605A CN 103834347 A CN103834347 A CN 103834347A
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Abstract
The invention relates to a viscose glue and a viscose glue plaster prepared from the viscose glue, wherein the viscose glue is capable of realizing non-trace adhesion and being repeatedly used for multiple times. The main components of the viscose glue include silica gel and a tackifier, the silica gel weight accounts for 40%-60% of the overall weight of the viscose glue, and the tackifier weight accounts for 40%-60% of the overall weight of the viscose glue. The viscose glue has high activity groups, and when in use, the viscose glue can fill gaps on the glued material surface to exclude air inside the gaps so as to enable the viscose glue to attach to the glued material surface. The viscose glue mainly depends on adsorption type adhesive force for attaching, so that the viscose glue is convenient to tear off, and no residual excess viscose glue may be left on an attached material. The viscose glue plaster prepared from the viscose glue, which has a certain pattern, can be widely applied to sticky hooks, hanging pasters, electronic product pasting films and other various home furnishing, advertising and printing products, and has a great applicable range and market prospect.
Description
[technical field]
The present invention relates to a kind of adhesives, particularly one realize seamless bonding, the viscose glue that can be repeatedly used and the adhesive plaster that adopts this viscose glue to prepare.
[background technology]
Traditional object fixed form mainly comprises that nail is solid, gluing, absorption.Solid object is fixing relatively, the general solid mode of nail that adopts, and its shortcoming is: can stay nail trace, and follow closely trace and cannot repair, also can cause damage to fixed body, also increase fixing difficulty simultaneously, if in the situation that rigid condition can be met, generally do not select this fixed form.Be fixed for low weight object, generally adopt fixed form gluing or absorption.
If employing suction type, must use electrostatic material, because electrostatic material is the type material of development in recent years, the not concrete feature of environmental protection of this type material itself, simultaneously because material behavior makes the viscosity of product very poor, causes product easily come off and be out of shape.
If employing adhesive means, just need to adopt the sticking glue of tool, and adopt existing viscose glue that sticker is attached to basal plane (body of wall, panel, glass etc.) upper after, sticker just can not be taken off again, if tear sticker or be replaced by new sticker, sticker will be damaged, lingering section viscose glue on basal plane, causes basal plane very untidy simultaneously.Therefore, adopt the sticker that existing viscose glue is made to use once, but also the residual viscose glue of meeting is in putting up on basal plane, very impracticable.The more important thing is, existing viscose glue all comprises some poisonous volatility additives, and unsuitable life-time service, also can damage human body, uses very dangerous.In addition, for rough basal plane, can only adopt gluing mode, will cause above-described defect, for rough surface, just adopt the mode of absorption, but the defect that can cause product easily to come off and be out of shape, therefore, faces many environments for use, cannot use unified fixed form, limit greatly wideling popularize of viscose glue.
Face stickup articles for use that existing viscose glue and viscose glue make and be pasted with residually, cannot reuse, use technical barrier dangerous and that use range is narrow, people in the urgent need to a kind of can be seamless, can repeat, the viscose glue of safety makes up the defect of prior art.
[summary of the invention]
Be pasted with residually for overcoming existing viscose glue, cannot reuse, use unsafe technical barrier, the invention provides a kind of seamless, can repeat, the viscose glue of safety and the adhesive plaster that adopts this viscose glue to prepare.
The scheme of technical solution problem of the present invention is to provide a kind of viscose glue, the silica gel that the main component of this viscose glue comprises and tackifier, and the weight of this silica gel accounts for the 40%-60% of this viscose glue overall weight, and the weight of these tackifier accounts for the 40%-60% of this viscose glue overall weight.
Preferably, this silica gel is solid-state or liquid crystal state.
Preferably, this silica gel is silicone oil, silicon rubber, one or more of the silicone resin that synthetic resins or organosilicon and resin are mixed into by a certain percentage.
Preferably, these tackifier are silane or the siloxane oligomer containing alkoxyl group, silicon hydrogen base and reactive organic radical, or, rosin, or, terpine resin, terpene phenolic resin, or, copal, shellac, or, one or more of coumarone, indene resin.
The making method that the present invention further provides a kind of adhesive plaster, comprising:
Step S1, provides silica gel and tackifier, and this silica gel and tackifier are for the preparation of a kind of viscose glue, and the weight of this silica gel accounts for the 40%-60% of this viscose glue overall weight, and the weight of these tackifier accounts for the 40%-60% of this viscose glue overall weight;
Step S2, mixing by carrying out after this silica gel and tackifier mixing, make phase mutual diffusion or infiltration between each material;
Step S3, rolls the mixture after mixing on adhesion layer by rolling press, makes viscose glue absorption and pastes.
Preferably, this viscose glue comprises,
Account for the solid state si rubber of this viscose glue overall weight 40%-60%,
Account for the tackifier of this viscose glue overall weight 40%-60%,
Account for the vulcanizing agent of this viscose glue overall weight 1-5%,
Account for the snake glue of this viscose glue overall weight 0.1%-1%;
Or,
Account for the solid state synthetic resin of this viscose glue overall weight 40%-60%,
Account for the tackifier of this viscose glue overall weight 40%-60%,
Account for the vulcanizing agent of this viscose glue overall weight 1-5%,
Account for the snake glue of this viscose glue overall weight 0.1%-1%;
Or,
Account for the solid-state silicone resin of this viscose glue overall weight 40%-60%,
Account for the tackifier of this viscose glue overall weight 40%-60%,
Account for the vulcanizing agent of this viscose glue overall weight 1-5%,
Account for the snake glue of this viscose glue overall weight 0.1%-1%;
Any one.
Preferably, the making method of adhesive plaster further comprises,
Step S4, moulding printed layers, the pattern needing in the preparation of adhesion layer surface, forms printed layers;
Step S5, Making viscose pastes, and attaches a protective layer, at upper attaching one release layer of adhesive-layer in printed layers.
Preferably, this printed layers is to adopt air brushing mode directly form printed layers on adhesion layer surface or adopt the printed layers preparing in advance paste or be adsorbed on adhesion layer surface.
The present invention also provides a kind of adhesive plaster, comprises protective layer, printed layers; adhesion layer; adhesive-layer and release layer, this five-layer structure is followed successively by protective layer, printed layers according to mutual stickup order; adhesion layer; adhesive-layer and release layer, this adhesive-layer is made up of the sticking viscose glue of tool, the silica gel that the main component of this viscose glue comprises and tackifier; the weight of this silica gel accounts for the 40%-60% of this viscose glue overall weight, and the weight of these tackifier accounts for the 40%-60% of this viscose glue overall weight.
Preferably; this adhesive-layer rolls on this adhesion layer; the material of this adhesion layer is any one of PET, PVC, PP, PE; this printed layers material is any one of enamelled paper, PET, PVC, PP, PE, book paper or synthetic paper; this protective layer material is any one of PET, PVC, PP or PE, and this release layer material is any one of enamelled paper, PE, PVC, PET or separate-type paper.
A kind of electronic product decorating film of the present invention, be used for being attached to electronic product, this decorating film comprises a peel ply, one seamless adhesive-layer, one adhesion layer, one printed layers and a protective layer, this peel ply, seamless adhesive-layer, adhesion layer, the shape and size of printed layers and protective layer are all mated with the shape and size of electronic product wall-attached surface, this peel ply, seamless adhesive-layer, adhesion layer, printed layers and protective layer be tight stacked laminating successively, this seamless adhesive-layer is made up of the sticking viscose glue of tool, the silica gel that the main component of this viscose glue comprises and tackifier, the weight of this silica gel accounts for the 40%-60% of this viscose glue overall weight, the weight of these tackifier accounts for the 40%-60% of this viscose glue overall weight.
A kind of household articles decorative paste of the present invention, for family product, this decorative paste comprises a peel ply, one seamless adhesive-layer, one adhesion layer, one printed layers and a protective layer, this peel ply, seamless adhesive-layer, adhesion layer, the shape and size of printed layers and protective layer are all mated with the shape and size of household articles wall-attached surface, this peel ply, seamless adhesive-layer, adhesion layer, printed layers and protective layer be tight stacked laminating successively, this seamless adhesive-layer is made up of the sticking viscose glue of tool, the silica gel that the main component of this viscose glue comprises and tackifier, the weight of this silica gel accounts for the 40%-60% of this viscose glue overall weight, the weight of these tackifier accounts for the 40%-60% of this viscose glue overall weight.
Compared with prior art, viscose glue of the present invention adopts silica gel or resin material and a certain proportion of tackifier to be mixed and made into solid-state colloid, the colloid of this material has higher active group, when use, the gap on adhesion surface can be filled, air in gap is got rid of, colloid is adhered to and attach thing surface.Because mainly relying on the clinging power of adsorption type, viscose glue of the present invention attaches, therefore it can tear very easily, and can residual unnecessary colloid in attaching on thing, in addition this viscose glue bonding plane active group has very large mobility, if there is booty on surface, after only needing to clean, can again use again, not affect the performance of its surface active groups, can realize repeatedly recycling.The present invention also provides the making method of this viscose glue, this making method is directly rolled solid-state silica gel material mixture on adhesion layer, and making processes is very simple, and compares liquid-state silicon gel coating technique, can well maintain the clinging power of silica gel, not be subject to the impact of other extraneous factors.Utilize this viscose glue to be made into the adhesive plaster of subsidiary certain pattern, can widespread use be such as fishing without hook, hang all kinds of households, advertisement, the print products such as subsides, electronic product pad pasting, there are the very large scope of application and market outlook.The more important thing is, utilize the adhesive plaster of viscose glue making of the present invention for smooth wall-attached surface, can control the content of its tackifier, it is mainly attached by adsorptive power.For the more coarse wall-attached surface of surface ratio, can control the content of its tackifier, make it have larger clinging power, lean on clinging power and be tightly attached to coordinating of adsorptive power on attaching thing.Therefore, attach no matter attach the whether smooth bonding articles for use that can use this viscose glue to make of the condition of surface of thing.
[accompanying drawing explanation]
Fig. 1 is the structural representation of adhesive plaster of the present invention as electronic product decorating film.
Fig. 2 is the structural representation of adhesive plaster of the present invention as household articles decorative paste.
[embodiment]
In order to make object of the present invention, technical scheme and advantage are clearer, below in conjunction with accompanying drawing and embodiment, the present invention are further elaborated.Should be appreciated that specific embodiment described herein, only in order to explain the present invention, is not intended to limit the present invention.
The main component of viscose glue of the present invention comprises: the silica gel (accounting for the ratio of this viscose glue overall weight) of 40%-60%, the tackifier (accounting for the ratio of this viscose glue overall weight) of 40%-60%, in this silica gel, active group ratio is 0.1%～10%.This silica gel can be liquid, solid or liquid crystal, and it can be silicone oil, silicon rubber, one or more of the silicone resin that synthetic resins or organosilicon and resin are mixed into by a certain percentage.These tackifier are silane or the siloxane oligomer containing alkoxyl group, silicon hydrogen base and reactive organic radical, or, rosin, modified rosin, or, terpine resin, terpene phenolic resin, or, copal, shellac, or, one or more of coumarone, indene resin.
The present invention further provides a kind of making method that adopts above-mentioned viscose glue Making viscose to paste, concrete steps are:
Step 1, supplies raw materials, the proportioning following (the following stated content is the ratio that accounts for this raw material overall weight) of various raw materials:
Solid state si rubber (40%-60%),
Tackifier (40%-60%),
Vulcanizing agent (1-5%),
Snake glue (0.1%-1%);
Or,
Solid state synthetic resin (40%-60%),
Tackifier (40%-60%),
Vulcanizing agent (1-5%),
Snake glue (0.1%-1%);
Or,
Solid-state silicone resin (40%-60%),
Tackifier (40%-60%),
Vulcanizing agent (1-5%),
Snake glue (0.1%-1%).
Above-mentioned solid state si rubber, solid state synthetic resin and solid-state silicone resin can be also liquid state or liquid crystal state, optimal selection of the present invention is solid feed.
Step 2, mixing.Under normal temperature by above-mentioned materials mix after put into mill carry out mixing so that phase mutual diffusion or infiltration between each material.Melting temperature is selected to carry out under normal temperature condition, and mixing time is 0.5-2 hour, and best effect is mixing 1 hour.
Step 3, calendering.Solid mixt after mixing is rolled on adhesion layer by rolling press, make certain thickness viscose glue absorption and paste.This adhesion layer can be PET (polyethylene terephthalate, polyethylene terephthalate), PVC (Polyvinylchlorid, polyvinyl chloride), PP (Polypropylene, polypropylene), PE (Polyethylene, polyethylene) etc. there is the material of identical characteristics, in this example preferably PET as adhesion layer.The rolling temperature of this step remains in the scope of (120 ℃-170 ℃).
Step 4, rinses.It is adhesive-layer adsorption plane that layer of surface is pasted in the absorption of viscose glue after calendering, another surface be adhesion layer without adsorptive power smooth surface, water rinses two sides, maintenance two sides dustless, bright and clean.
All there is good viscosity in order to realize viscose glue of the present invention in difference attaching occasion, the invention provides following specific embodiment:
Embodiment mono-, attaching thing is smooth wall-attached surface.
Supply raw materials, the proportioning following (the following stated content is the ratio that accounts for this raw material overall weight) of various raw materials:
Solid state si rubber (40%-50%),
Tackifier (50%-60%),
Vulcanizing agent (1-5%),
Snake glue (0.1%-1%);
Or,
Solid state synthetic resin (40%-50%),
Tackifier (50%-60%),
Vulcanizing agent (1-5%),
Snake glue (0.1%-1%);
Or,
Solid-state silicone resin (40%-50%),
Tackifier (50%-60%),
Vulcanizing agent (1-5%),
Snake glue (0.1%-1%).
Under normal temperature by above-mentioned materials mix after put into mill carry out mixing so that phase mutual diffusion or infiltration between each material.Melting temperature is selected to carry out under normal temperature condition, and mixing time is 0.5-2 hour, and best effect is mixing 1 hour.
Solid mixt after mixing is rolled on adhesion layer by rolling press, make certain thickness viscose glue absorption and paste.The rolling temperature of this step remains in the scope of (120 ℃-170 ℃).
It is adhesive-layer adsorption plane that layer of surface is pasted in the absorption of viscose glue after calendering, another surface be adhesion layer without adsorptive power smooth surface, water rinses two sides, maintenance two sides dustless, bright and clean.
Embodiment bis-, attaching thing is coarse wall-attached surface.
Supply raw materials, the proportioning following (the following stated content is the ratio that accounts for this raw material overall weight) of various raw materials:
Solid state si rubber (50%-60%),
Tackifier (40%-50%),
Vulcanizing agent (1-5%),
Snake glue (0.1%-1%);
Or,
Solid state synthetic resin (50%-60%),
Tackifier (40%-50%),
Vulcanizing agent (1-5%),
Snake glue (0.1%-1%);
Or,
Solid-state silicone resin (50%-60%),
Tackifier (40%-50%),
Vulcanizing agent (1-5%),
Snake glue (0.1%-1%).
Under normal temperature by above-mentioned materials mix after put into mill carry out mixing so that phase mutual diffusion or infiltration between each material.Melting temperature is selected to carry out under normal temperature condition, and mixing time is 0.5-2 hour, and best effect is mixing 1 hour.
Solid mixt after mixing is rolled on adhesion layer by rolling press, make certain thickness viscose glue absorption and paste.The rolling temperature of this step remains in the scope of (120 ℃-170 ℃).
It is adhesive-layer adsorption plane that layer of surface is pasted in the absorption of viscose glue after calendering, another surface be adhesion layer without adsorptive power smooth surface, water rinses two sides, maintenance two sides dustless, bright and clean.
Promote the use of for the viscose glue absorption of above-mentioned making is pasted to put in family life, also need the viscose glue absorption that adopts above-mentioned making method to make to paste and do following processing, make adhesive plaster.
Step 5: moulding printed layers.In order to make product can provide one to have the pattern of aesthetic to user in the process using, or realize certain indication, mark effect, the pattern that the preparation of the adhesion layer of making in above-mentioned steps surface needs, forms printed layers.This printed layers can adopt the usual ways such as air brushing directly to form printed layers on adhesion layer surface.Also can adopt the printed layers preparing in advance paste or be adsorbed on adhesion layer surface, the printed layers material of this direct attaching form can be enamelled paper, PET (polyethylene terephthalate, polyethylene terephthalate), PVC (Polyvinylchlorid, polyvinyl chloride), PP (Polypropylene, polypropylene), PE (Polyethylene, polyethylene), book paper or synthetic paper.
Step 6: Making viscose pastes.At adhesive-layer, adhesion layer, after three layers of printed layers are combined, adhesion layer is between adhesive-layer and printed layers, and a side surface of printed layers is exposed to outside, and a side surface of adhesive-layer is exposed to outside.Attach a protective layer at the exposed surface of printed layers, do not scratched in use and wear and tear for protecting printed layers, this protective layer can be made up of analogous materials such as PET, PVC, PP, PE, and the present invention selects PET as preferred material.Meanwhile; a side surface at adhesive-layer attaches a release layer; release layer is for the protection of this alignment layers; tear in use this release layer; adhesive-layer is pressed on docile thing surface; get rid of adhesive-layer and by the air between wall-attached surface, utilize the stickiness of barometric point and/or viscose glue to be attached on docile thing and do not come off.This release layer can be the analogous materials such as enamelled paper, PE, PVC, PET, separate-type paper, and the present invention selects PET as preferred material.
Step 7: cut.The adhesive plaster of the above-mentioned five-layer structure of making (being followed successively by protective layer, printed layers, adhesion layer, adhesive-layer, release layer) size is as required cut manually or automatically.Make the adhesive plaster that different size needs, relatively conventional has: fishing without hook adhesive plaster, and to coupling adhesive plaster, mobile phone protection adhesive plaster, notebook computer adhesive plaster, variable color coloured picture adhesive plaster, some conventional household articles are with adhesive plaster etc.
Refer to Fig. 1; utilize adhesive plaster of the present invention to be made into the decorating film of electronic product; this electronic product decorating film 100 comprises seamless adhesive-layer 102, one adhesion layers 103 of a peel ply 101; one printed layers 104 and a protective layer 105; peel ply 101, seamless adhesive-layer 102, adhesion layer 103; printed layers 104 is identical with protective layer 105 shapes, and the laminating that is layering successively.
This seamless adhesive-layer 102 is above-mentioned adhesive-layer, and it is that the solid-state viscose glue with certain viscosity forms, and this seamless adhesive-layer 102 is sheet structure, and thickness can be adjusted within the scope of 0.02mm-10mm.
Printed layers 104 materials can be PET, PVC, PP, PE, book paper or synthetic paper, and printing material can carry out noctilucence simultaneously, toning, and base material color and luster is chosen, the processing such as wire printing material.This layer can print various patterns.Printed layers 104 fits tightly on adhesion layer 103, and this layer thickness can be adjusted within the scope of 0.01mm-5mm.
Peel ply 101 materials can be enamelled paper, PE, PVC, PET, separate-type paper etc.This layer is sheet structure, and thickness is within the scope of 0.01mm-5mm.Peel ply 101 fits in seamless adhesive-layer 102, is used for protecting seamless adhesive-layer 102, makes its not sticky dust and dirt, and in use, peel ply 101 will be stripped from.
The shape of above-mentioned peel ply 101, seamless adhesive-layer 102, adhesion layer 103, printed layers 104 and protective layer 105 and protective layer size all match with the shape and size of electronic product 110 wall-attached surfaces.
In sum, in the time using this decorating film 100, as long as we tear its peel ply 101 can directly this decorating film 100 to be sticked on electronic product 110 off.Because these decorating film 100 shape and size are mated with the geomery of electronic product 110, therefore decorating film 100 is just by the surface coverage of electronic product 110.
This electronic product decorating film 100 uses on mobile phone, notebook computer or panel computer conventionally; its surface is protected; prevent from being scratched damage electronic product 110; by print various beautiful patterns in printed layers 104, electronic product 110 is beautified simultaneously, meet human consumer's visual enjoyment.
Refer to Fig. 2, utilize adhesive plaster of the present invention to be made into the decorative paste 300 of household articles, this decorative paste 300 comprises seamless adhesive-layer 302, one adhesion layer 303, one printed layers 304 and the protective layers 305 of a peel ply 301.Peel ply 301, adhesive-layer 302, thin film layer 303, printed layers 304 is identical with protective layer 305 shapes, and fixed layer is stacked successively adds laminating.
This seamless adhesive-layer 302 is above-mentioned adhesive-layer, and it is that the solid-state viscose glue with certain viscosity forms, and this seamless adhesive-layer 302 is sheet structure, and thickness can be adjusted within the scope of 0.02mm-10mm.
Adhesion layer 303 is made for one deck PET material, and adhesion layer 303 is sheet structure, and thickness can be adjusted within the scope of 0.01mm-5mm.Solid-state viscose glue described in seamless adhesive-layer 302 is attached directly on adhesion layer 303 by prolonging compression technology.
Printed layers 304 materials can be PET, PVC, PP, PE, book paper or synthetic paper, on selected printed layers 304 materials, we can adopt any printing board type such as letterpress, lithography, intaglio printing and porous printing to produce required pattern, printing material can carry out noctilucence simultaneously, toning, base material color and luster is chosen, the processing such as wire printing material.After the upper pattern of this layer printing, printed layers 304 fits tightly on adhesion layer 303, and its thickness can be adjusted within the scope of 0.01mm-5mm.
Protective layer 305 materials are PET.This layer is transparent sheet-like structure, and thickness is within the scope of 0.02mm-10mm.Protective layer 305 fits tightly in printed layers 304.This layer is for the protection of printed layers 304.
Peel ply 301 materials can be enamelled paper, PE, PVC, PET, separate-type paper etc.This layer is sheet structure, and thickness is within the scope of 0.02mm-10mm.Peel ply 301 fits in seamless adhesive-layer 302, is used for protecting seamless adhesive-layer 302, makes its not sticky dust and dirt, and in use, peel ply 301 will be stripped from.
Shape and the protective layer size of above-mentioned peel ply 301, seamless adhesive-layer 302, adhesion layer 303, printed layers 304 and protective layer 305 all match with the shape and size of household articles wall-attached surface.
In sum, in the time putting up this decorative paste 300, it can directly sticking on this decorative paste 300 that door is upper, as long as we tear its peel ply 301 off, on wall, on the surface that on glass or other are smooth and more coarse.
Compared with prior art, viscose glue of the present invention adopts silica gel or resin material and a certain proportion of tackifier to be mixed and made into solid-state colloid, the colloid of this material has higher active group, when use, the gap on adhesion surface can be filled, air in gap is got rid of, colloid is adhered to and attach thing surface.Because mainly relying on the clinging power of adsorption type, viscose glue of the present invention attaches, therefore it can tear very easily, and can residual unnecessary colloid in attaching on thing, in addition this viscose glue bonding plane active group has very large mobility, if there is booty on surface, after only needing to clean, can again use again, not affect the performance of its surface active groups, can realize repeatedly recycling.The present invention also provides the making method of this viscose glue, this making method is directly rolled solid-state silica gel material mixture on adhesion layer, and making processes is very simple, and compares liquid-state silicon gel coating technique, can well maintain the clinging power of silica gel, not be subject to the impact of other extraneous factors.Utilize this viscose glue to be made into the adhesive plaster of subsidiary certain pattern, can widespread use be such as fishing without hook, hang all kinds of households, advertisement, the print products such as subsides, electronic product pad pasting, there are the very large scope of application and market outlook.The more important thing is, utilize the adhesive plaster of viscose glue making of the present invention for smooth wall-attached surface, can control the content of its tackifier, it is mainly attached by adsorptive power.For the more coarse wall-attached surface of surface ratio, can control the content of its tackifier, make it have larger clinging power, lean on clinging power and be tightly attached to coordinating of adsorptive power on attaching thing.Therefore, attach no matter attach the whether smooth bonding articles for use that can use this viscose glue to make of the condition of surface of thing.
The foregoing is only preferred embodiment of the present invention, not in order to limit the present invention, all any modifications of doing within principle of the present invention, are equal to and replace and within improvement etc. all should comprise protection scope of the present invention.
Claims (12)
1. a viscose glue, is characterized in that: the silica gel that the main component of this viscose glue comprises and tackifier, and the weight of this silica gel accounts for the 40%-60% of this viscose glue overall weight, and the weight of these tackifier accounts for the 40%-60% of this viscose glue overall weight.
2. viscose glue as claimed in claim 1, is characterized in that: this silica gel is solid-state or liquid crystal state.
3. viscose glue as claimed in claim 1, is characterized in that: this silica gel is silicone oil, silicon rubber, one or more of the silicone resin that synthetic resins or organosilicon and resin are mixed into by a certain percentage.
4. viscose glue as claimed in claim 1, it is characterized in that: these tackifier are silane or the siloxane oligomer containing alkoxyl group, silicon hydrogen base and reactive organic radical, or, rosin, or, terpine resin, terpene phenolic resin, or, copal, shellac, or, one or more of coumarone, indene resin.
5. a making method for adhesive plaster, comprising:
Step S1, provides silica gel and tackifier, and this silica gel and tackifier are for the preparation of a kind of viscose glue, and the weight of this silica gel accounts for the 40%-60% of this viscose glue overall weight, and the weight of these tackifier accounts for the 40%-60% of this viscose glue overall weight;
Step S2, mixing by carrying out after this silica gel and tackifier mixing, make phase mutual diffusion or infiltration between each material;
Step S3, rolls the mixture after mixing on adhesion layer by rolling press, makes viscose glue absorption and pastes.
6. the making method of adhesive plaster as claimed in claim 5, is characterized in that: this viscose glue comprises,
Account for the solid state si rubber of this viscose glue overall weight 40%-60%,
Account for the tackifier of this viscose glue overall weight 40%-60%,
Account for the vulcanizing agent of this viscose glue overall weight 1-5%,
Account for the snake glue of this viscose glue overall weight 0.1%-1%;
Or,
Account for the solid state synthetic resin of this viscose glue overall weight 40%-60%,
Account for the tackifier of this viscose glue overall weight 40%-60%,
Account for the vulcanizing agent of this viscose glue overall weight 1-5%,
Account for the snake glue of this viscose glue overall weight 0.1%-1%;
Or,
Account for the solid-state silicone resin of this viscose glue overall weight 40%-60%,
Account for the tackifier of this viscose glue overall weight 40%-60%,
Account for the vulcanizing agent of this viscose glue overall weight 1-5%,
Account for the snake glue of this viscose glue overall weight 0.1%-1%;
Any one.
7. the making method of adhesive plaster as claimed in claim 5, is characterized in that: further comprises,
Step S4, moulding printed layers, the pattern needing in the preparation of adhesion layer surface, forms printed layers;
Step S5, Making viscose pastes, and attaches a protective layer, at upper attaching one release layer of adhesive-layer in printed layers.
8. the making method of adhesive plaster as claimed in claim 7, is characterized in that: this printed layers is to adopt air brushing mode directly form printed layers on adhesion layer surface or adopt the printed layers preparing in advance paste or be adsorbed on adhesion layer surface.
9. an adhesive plaster, is characterized in that: comprise protective layer, printed layers; adhesion layer; adhesive-layer and release layer, this five-layer structure is followed successively by protective layer, printed layers according to mutual stickup order; adhesion layer; adhesive-layer and release layer, this adhesive-layer is made up of the sticking viscose glue of tool, the silica gel that the main component of this viscose glue comprises and tackifier; the weight of this silica gel accounts for the 40%-60% of this viscose glue overall weight, and the weight of these tackifier accounts for the 40%-60% of this viscose glue overall weight.
10. adhesive plaster as claimed in claim 9; it is characterized in that: this adhesive-layer rolls on this adhesion layer; the material of this adhesion layer is any one of PET, PVC, PP, PE; this printed layers material is any one of enamelled paper, PET, PVC, PP, PE, book paper or synthetic paper; this protective layer material is any one of PET, PVC, PP or PE, and this release layer material is any one of enamelled paper, PE, PVC, PET or separate-type paper.
11. 1 kinds of electronic product decorating films, be used for being attached to electronic product, it is characterized in that: this decorating film comprises a peel ply, one seamless adhesive-layer, one adhesion layer, one printed layers and a protective layer, this peel ply, seamless adhesive-layer, adhesion layer, the shape and size of printed layers and protective layer are all mated with the shape and size of electronic product wall-attached surface, this peel ply, seamless adhesive-layer, adhesion layer, printed layers and protective layer be tight stacked laminating successively, this seamless adhesive-layer is made up of the sticking viscose glue of tool, the silica gel that the main component of this viscose glue comprises and tackifier, the weight of this silica gel accounts for the 40%-60% of this viscose glue overall weight, the weight of these tackifier accounts for the 40%-60% of this viscose glue overall weight.
12. 1 kinds of household articles decorative pastes, for family product, it is characterized in that: this decorative paste comprises a peel ply, one seamless adhesive-layer, one adhesion layer, one printed layers and a protective layer, this peel ply, seamless adhesive-layer, adhesion layer, the shape and size of printed layers and protective layer are all mated with the shape and size of household articles wall-attached surface, this peel ply, seamless adhesive-layer, adhesion layer, printed layers and protective layer be tight stacked laminating successively, this seamless adhesive-layer is made up of the sticking viscose glue of tool, the silica gel that the main component of this viscose glue comprises and tackifier, the weight of this silica gel accounts for the 40%-60% of this viscose glue overall weight, the weight of these tackifier accounts for the 40%-60% of this viscose glue overall weight.
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| CN201210472605.1A CN103834347B (en) | 2012-11-20 | 2012-11-20 | Viscose glue, adopt adhesive plaster, the manufacture method of adhesive plaster and application prepared by viscose glue |
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| CN201210472605.1A CN103834347B (en) | 2012-11-20 | 2012-11-20 | Viscose glue, adopt adhesive plaster, the manufacture method of adhesive plaster and application prepared by viscose glue |
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| CN103834347B CN103834347B (en) | 2016-06-08 |
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| CN104616591A (en) * | 2015-01-10 | 2015-05-13 | 东莞市想联实业投资有限公司 | Anti-counterfeit label and manufacturing method thereof |
| CN104992620A (en) * | 2015-07-28 | 2015-10-21 | 大族激光科技产业集团股份有限公司 | Self-adhesive label |
| CN105479868A (en) * | 2015-12-26 | 2016-04-13 | 曾程琴 | Machining method of traceless self-adhesive glue |
| CN107189747A (en) * | 2017-07-14 | 2017-09-22 | 芜湖市三山区绿色食品产业协会 | Adhesive for paper food package film and preparation method thereof |
| CN107353860A (en) * | 2017-07-14 | 2017-11-17 | 芜湖市三山区绿色食品产业协会 | For paper food package film and preparation method thereof |
| CN107699149A (en) * | 2017-10-18 | 2018-02-16 | 冯新 | A kind of traffic mark sticker |
| CN113201306A (en) * | 2021-05-11 | 2021-08-03 | 江苏申阳交通装备有限公司 | Silicone rubber traceless repairing organic silicon adhesive and preparation method thereof |
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| CN104616591A (en) * | 2015-01-10 | 2015-05-13 | 东莞市想联实业投资有限公司 | Anti-counterfeit label and manufacturing method thereof |
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| CN105479868A (en) * | 2015-12-26 | 2016-04-13 | 曾程琴 | Machining method of traceless self-adhesive glue |
| CN107189747A (en) * | 2017-07-14 | 2017-09-22 | 芜湖市三山区绿色食品产业协会 | Adhesive for paper food package film and preparation method thereof |
| CN107353860A (en) * | 2017-07-14 | 2017-11-17 | 芜湖市三山区绿色食品产业协会 | For paper food package film and preparation method thereof |
| CN107699149A (en) * | 2017-10-18 | 2018-02-16 | 冯新 | A kind of traffic mark sticker |
| CN113201306A (en) * | 2021-05-11 | 2021-08-03 | 江苏申阳交通装备有限公司 | Silicone rubber traceless repairing organic silicon adhesive and preparation method thereof |
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