CN103833878A - Synthesis technology of chelating terpolymer scale inhibitor based on drying temperature control - Google Patents
Synthesis technology of chelating terpolymer scale inhibitor based on drying temperature control Download PDFInfo
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- CN103833878A CN103833878A CN201210471602.6A CN201210471602A CN103833878A CN 103833878 A CN103833878 A CN 103833878A CN 201210471602 A CN201210471602 A CN 201210471602A CN 103833878 A CN103833878 A CN 103833878A
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Abstract
The invention discloses a synthesis technology of a chelating terpolymer scale inhibitor based on drying temperature control. The technology comprises the following steps: 1, putting chelating group monomers, AM and AA in a reaction container according to a certain ratio; 2, adding a solvent for dissolving; 3, adding a catalyst and an initiator; 4, placing the reaction container in a water bath, and reacting to obtain a reaction product mixture; and 5, adding a proper amount of ethanol into the reaction product mixture, carrying out cooling filtration, distilling the obtained filtered liquid, and drying at 80-100DEG C to obtain a target product. The chelating terpolymer scale inhibitor can be successfully synthesized through the technology, and the synthesized chelating terpolymer scale inhibitor has the advantages of excellent performances, simple synthesis steps and low synthesis cost; and the drying temperature in the synthesis process is controlled to improve the reaction conversion rate and the quality of the product.
Description
Technical field
The present invention relates to a kind of synthesis technique of the chelating type terpolymer scale inhibitor of controlling drying temperature.
Background technology
In oilfield exploitation procedure, fluid (oil, G&W) in hydrocarbon-bearing pool flows out from stratum, to surface gathering system, due to the variation of the condition such as temperature, pressure and the thermodynamic phase of water and chemical incompatibility, cause oil gas water balance state to be destroyed through pit shaft, well head.Often cause water filling stratum, tubing and casing, down-hole, uphole equipment and gathering system to occur fouling.Fouling has larger impact to the normal production of oil well, in the time that dirt deposition is on the equipment such as pit shaft, oil pipe, oil well pump, waterflood system, gathering system, heating system, can cause equipment not run well, heat transfer efficiency reduces, cause throughput to decline, and fouling also can cause the corrosion of equipment and pipeline, cause serious financial loss to oil field.
Existing scale inhibitor mainly contains aminopolycanboxylic acid's salt, organic multicomponent phosphonic acid based and organic polymer three major types.Aminopolycanboxylic acid's salt Chelate stability constants is large, can be used for comparatively high temps, but consumption is large, and cost is high; Organic multicomponent phosphonic acids to barium sulfate, Strontium Sulphate without antiscaling effect; And what mostly use is organic polymer scale inhibitor, uses monomer and maleic anhydride, acrylic acid copolymer to expect raising antiscaling rate more, but owing to fundamentally not changing polymer architecture, do not reach the antiscaling effect of expection.
In crude oil production process, fouling is a kind of ubiquitous phenomenon, and fouling is simultaneously one of the most serious problem running in the control of oil-field water water quality.Fouling has larger impact to the normal production of oil well, and dirt deposition can stop up formation pore, crack on stratum, cause permeability reduction, and crude production rate is declined, and even causes oil well to stop production when serious, and the oil reservoir lower on rate of permeation affects more very; In the time that dirt deposition is on the equipment such as pit shaft, oil pipe, oil well pump, waterflood system, gathering system, heating system, can cause equipment not run well, heat transfer efficiency reduces, cause throughput to decline, and fouling also can cause the corrosion of equipment and pipeline, cause serious financial loss to oil field.
The major cause of fouling is due to pressure or temperature change, evaporation or two kinds of water of 5 of mismatching mix mutually, make the inorganic salt (CaCO3, CaSO4 or BaSO4) that are originally present in the aqueous solution with ionic condition reach hypersaturated state, exceeded their solubleness and crystallize out into dirt.Fouling process is the process of certain density incrustation ion crystallization and gathering under certain physical and chemical condition (as pressure, temperature) and equipment surface situation.It is the basic reason that causes fouling that equilibrium state goes to pot.
Chemical scale inhibition agent is the gentle Technology of separating fouling of inhibition that oil field is commonly used the most.In order to prevent fouling, ground flow, oil well and water-injection plant need be connected or in system, add scale inhibitor off and on.For the various fouling situations in oil field, there are two class solutions: the one, scale removal; The 2nd, antiscale.Scale removal is a kind of remedial measures, and when scale removal, the corrosion that it has produced the underproduction and equipment, has caused larger financial loss, therefore, prevents that dirty generation is only a kind of good measure.In the method for antiscale, with chemical agent antiscale be people generally acknowledge the simplest, effectively, convenient, economic method.Therefore each oil field all adapts to the chemical scale inhibition agent of different condition for block the characteristic study separately.And develop the efficient scale inhibitor common objective that just generally pursue in each oil field especially.
In the synthesis process of chelating type terpolymer scale inhibitor, drying temperature will directly have influence on reaction conversion ratio and quality product, therefore determine a suitable drying temperature, the synthesis technique of chelating type terpolymer scale inhibitor be seemed to particularly important.
Summary of the invention
The object of the invention is to overcome the shortcoming and defect of above-mentioned prior art, a kind of synthesis technique of the chelating type terpolymer scale inhibitor of controlling drying temperature is provided, this synthesis technique can successfully synthesize chelating type terpolymer scale inhibitor, and the excellent property of the chelating type terpolymer scale inhibitor synthesizing, synthesis step is simple, and synthetic cost is low; And by controlling the drying temperature in building-up process, thereby reaction conversion ratio and quality product are improved.
Object of the present invention is achieved through the following technical solutions: a kind of synthesis technique of the chelating type terpolymer scale inhibitor of controlling drying temperature, comprises the following steps:
(a) first, chelating group monomer, AM and AA are put into reaction vessel according to a certain percentage;
(b) then add dissolution with solvents;
(c) add catalyzer and initiator;
(d) will in reaction vessel, be placed in water-bath, reaction obtains mixture of reaction products;
(e) will in mixture of reaction products, add appropriate ethanol, and cold filtration processing, liquid distillation after filtering, then dry at the temperature of 80～100 DEG C, obtain target product.
Described reaction vessel is beaker.
In described step (e), carry out filtration treatment by molecular sieve.
In described step (e), carry out underpressure distillation by rotatory evaporator.
In described step (e), drying temperature is 85 DEG C.
In described step (e), drying temperature is 90 DEG C.
In described step (e), drying temperature is 95 DEG C.
In sum, the invention has the beneficial effects as follows: can successfully synthesize chelating type terpolymer scale inhibitor, and the excellent property of the chelating type terpolymer scale inhibitor synthesizing, synthesis step is simple, and synthetic cost is low; And by controlling the drying temperature in building-up process, thereby reaction conversion ratio and quality product are improved.
Embodiment
Below in conjunction with embodiment, the present invention is described in further detail, but embodiments of the present invention are not limited only to this.
Embodiment:
The synthesis technique of a kind of chelating type terpolymer scale inhibitor of controlling drying temperature the present invention relates to, comprises the following steps:
(a) first, chelating group monomer, AM and AA are put into reaction vessel according to a certain percentage;
(b) then add dissolution with solvents;
(c) add catalyzer and initiator;
(d) will in reaction vessel, be placed in water-bath, reaction obtains mixture of reaction products;
(e) will in mixture of reaction products, add appropriate ethanol, and cold filtration processing, liquid distillation after filtering, then dry at the temperature of 80～100 DEG C, obtain target product.
Described reaction vessel is beaker.
In described step (e), carry out filtration treatment by molecular sieve.
In described step (e), carry out underpressure distillation by rotatory evaporator.
In described step (e), drying temperature is 85 DEG C.
In described step (e), drying temperature is 90 DEG C.
In described step (e), drying temperature is 95 DEG C.
In the synthesis process of chelating type terpolymer scale inhibitor, drying temperature will directly have influence on reaction conversion ratio and quality product, therefore determine a suitable drying temperature, the synthesis technique of chelating type terpolymer scale inhibitor be seemed to particularly important.In order to obtain best drying temperature, the present invention has done the impact experiment of different drying temperatures on reaction conversion ratio and quality product, result is known by experiment: control suitable drying temperature and be very helpful to improving reaction conversion ratio and quality product, suitably increase drying temperature, can improve reaction conversion ratio, but, in the time that drying temperature is reduced to certain value, increase again drying temperature, do not produce any impact for improving reaction conversion ratio, on the contrary, can increase the quality of product, therefore should consider.
To sum up, the drying temperature control in the present invention is 80～100 DEG C, and the best is 90 DEG C.
The above, be only preferred embodiment of the present invention, not the present invention done to any pro forma restriction, every foundation technical spirit of the present invention, and any simple modification, equivalent variations that above embodiment is done, within all falling into protection scope of the present invention.
Claims (7)
1. the synthesis technique of controlling the chelating type terpolymer scale inhibitor of time of drying, is characterized in that, comprises the following steps:
(a) first, chelating group monomer, AM and AA are put into reaction vessel according to a certain percentage;
(b) then add dissolution with solvents;
(c) add catalyzer and initiator;
(d) will in reaction vessel, be placed in water-bath, reaction obtains mixture of reaction products;
(e) will in mixture of reaction products, add appropriate ethanol, and cold filtration processing, liquid distillation after filtering, then dry 20～40 minutes, obtains target product.
2. the synthesis technique of the chelating type terpolymer scale inhibitor of controlling time of drying according to claim 1, is characterized in that, described reaction vessel is beaker.
3. the synthesis technique of the chelating type terpolymer scale inhibitor of controlling time of drying according to claim 1, is characterized in that, in described step (e), carries out filtration treatment by molecular sieve.
4. the synthesis technique of the chelating type terpolymer scale inhibitor of controlling time of drying according to claim 1, is characterized in that, in described step (e), carries out underpressure distillation by rotatory evaporator.
5. the synthesis technique of the chelating type terpolymer scale inhibitor of controlling time of drying according to claim 1, is characterized in that, in described step (e), be 25 minutes time of drying.
6. the synthesis technique of the chelating type terpolymer scale inhibitor of controlling time of drying according to claim 1, is characterized in that, in described step (e), be 30 minutes time of drying.
7. the synthesis technique of the chelating type terpolymer scale inhibitor of controlling time of drying according to claim 1, is characterized in that, in described step (e), be 35 minutes time of drying.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210471602.6A CN103833878A (en) | 2012-11-20 | 2012-11-20 | Synthesis technology of chelating terpolymer scale inhibitor based on drying temperature control |
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| CN201210471602.6A CN103833878A (en) | 2012-11-20 | 2012-11-20 | Synthesis technology of chelating terpolymer scale inhibitor based on drying temperature control |
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| CN103833878A true CN103833878A (en) | 2014-06-04 |
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| CN201210471602.6A Pending CN103833878A (en) | 2012-11-20 | 2012-11-20 | Synthesis technology of chelating terpolymer scale inhibitor based on drying temperature control |
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Application publication date: 20140604 |