CN103818904B - A kind of pinecone, rice husk, corn stalk prepare the method for gac - Google Patents
A kind of pinecone, rice husk, corn stalk prepare the method for gac Download PDFInfo
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Abstract
A kind of method utilizing the pinecone, rice husk, corn stalk to prepare gac, comprise choose the pinecone, rice husk, corn stalk be mixed in proportion, mixture after drying is pulverized to obtain raw material, by feed particles and activator mix even mixture, add water retting, material after dipping is put into microwave oven and carries out carbonization-activation, pickling and washing successively, oven dry, drying material is ground, and adopt the sieve of different meshes to carry out screening acquisition three grades of fineness gacs, they are mixed in proportion formation the finished product.Gac prepared by the present invention has good absorption property and work-ing life.
Description
Technical field
The application relates to a kind of preparation method of gac, particularly relates to a kind of method utilizing the pinecone, rice husk, corn stalk to prepare gac.
Background technology
Gac, owing to having flourishing internal pore structure, therefore becomes a kind of extremely important sorbent material, is widely used in many fields such as water treatment, environment protection, agricultural.The raw material preparing gac is a lot, and the plant materials such as existing timber, husk, crop material, also have coal, refinery coke, rubber etc.In energy dilemma and environmental problem day by day serious today, utilize agriculture and forestry organic waste material that is cheap, abundance to prepare gac and receive increasing concern.But existing technique is usually all more single when selecting agriculture and forestry organic waste material raw material, the performance of therefore prepared gac is comparatively uneven, is unfavorable for the Appropriate application of agriculture and forestry organic waste material.
Summary of the invention
The present invention aims to provide a kind of method for preparation of active carbon, and it adopts multiple agriculture and forestry organic waste material to be mixed in proportion formation raw material, particularly, comprises the steps:
(1) choose the pinecone, rice husk, corn stalk be mixed in proportion, dry 18 hours at the temperature of 115 degrees Celsius;
(2) mixture after step 1 being dried is crushed to particle diameter about 1.6-1.8mm, obtains feed particles;
(3) feed particles in step 2 is mixed in proportion to obtain mixture according to potassium hydroxide and salt of wormwood, add the water of 46 degrees Celsius with weight such as mixtures, flood 18 hours;
(4) material after the dipping in step 3 is put into microwave oven, preferably, carbonization-activation 7 minutes under the microwave exposure power of 400-450W.
(5) hydrochloric acid of 1.5 moles often liter is adopted to boil 40 minutes under 85 degrees Celsius material after the activation in step 4, more neutral in rinsing in pure water, then dry 10 hours under 130 degrees Celsius.
(6) drying material in step 5 is ground, and adopt the sieve of different meshes to carry out screening acquisition three grades of fineness gacs, they are mixed in proportion formation the finished product.
Preferably, choose the pinecone, rice husk, corn stalk mix in 1:2:1 or 1:2:2 ratio.
Preferably, the part by weight of step 3 Raw particle and potassium hydroxide and salt of wormwood is 1:2:1 or 1:2:2.
Preferably, in step 6, different meshes is 160 orders, 200 orders and 240 orders, and three grades of fineness activated carbon weight are than being 1:3:2.
Preferably, in step 6, different meshes is 150 orders, 200 orders and 250 orders, and three grades of fineness activated carbon weight are than being 1:3:1.
Because the present invention adopts agriculture and forestry organic waste material as raw material, reduce the manufacturing cost of gac; And be mixed in proportion formation raw material owing to present invention employs multiple different agriculture and forestry organic waste material, take full advantage of the feature that different agriculture and forestry organic waste material possesses the compounds contents such as different xylogen, Mierocrystalline cellulose, hemicellulose, different agriculture and forestry organic waste material is learnt from other's strong points to offset one's weaknesses mutually, enhance the utilising efficiency of agriculture and forestry organic waste material, improve the performance of prepared gac.
Embodiment
Embodiment one
(1) choose the pinecone, rice husk, corn stalk mix according to the ratio of weight ratio 1:2:1, dry 18 hours at the temperature of 115 degrees Celsius.
(2) mixture after step 1 being dried is crushed to particle diameter about 1.8mm, obtains feed particles.
(3) feed particles in step 2 is mixed to obtain mixture according to the ratio of potassium hydroxide and salt of wormwood weight ratio 1:2:1, add the water of 46 degrees Celsius with weight such as mixtures, flood 18 hours.
(4) material after the dipping in step 3 is put into microwave oven, carbonization-activation 7 minutes under the microwave exposure power of 400W.
(5) hydrochloric acid of 1.5 moles often liter is adopted to boil 40 minutes under 85 degrees Celsius material after the activation in step 4, more neutral in rinsing in pure water, then dry 10 hours under 130 degrees Celsius.
(6) drying material in step 6 is ground, and adopting 160 orders, 200 orders and 240 object sieves to carry out screening acquisition three grades of fineness gacs, they are mixed to form the finished product according to the ratio of weight ratio 1:3:2 by (in 160 orders, 200 orders and 240 orders order).Owing to adopting multistage mixed structure herein, the product that obtains has better level and density, therefore has better absorption property and work-ing life.
According to National Standard of the People's Republic of China GB/T12496.8-1999 and GB/T12496.10-1999, the activated carbon-iodine adsorptive value obtained by the present invention is 1332 milligrams every gram, and methylene blue adsorption value is 169 milliliters every gram.
Embodiment two
(1) choose the pinecone, rice husk, corn stalk mix according to the ratio of weight ratio 1:2:2, dry 18 hours at the temperature of 115 degrees Celsius.
(2) mixture after step 1 being dried is crushed to particle diameter about 1.6mm, obtains feed particles.
(3) feed particles in step 2 is mixed to obtain mixture according to the ratio of potassium hydroxide and salt of wormwood weight ratio 1:2:2, add the water of 46 degrees Celsius with weight such as mixtures, flood 18 hours.
(4) material after the dipping in step 3 is put into microwave oven, carbonization-activation 7 minutes under the microwave exposure power of 450W.
(5) hydrochloric acid of 1.5 moles often liter is adopted to boil 40 minutes under 85 degrees Celsius material after the activation in step 4, more neutral in rinsing in pure water, then dry 10 hours under 130 degrees Celsius.
(6) drying material in step 6 is ground, and adopting 150 orders, 200 orders and 250 object sieves to carry out screening acquisition three grades of fineness gacs, they are mixed to form the finished product according to the ratio of weight ratio 1:3:1 by (in 150 orders, 200 orders and 250 orders order).Owing to adopting multistage mixed structure herein, the product that obtains has better level and density, therefore has better absorption property and work-ing life.
According to National Standard of the People's Republic of China GB/T12496.8-1999 and GB/T12496.10-1999, the activated carbon-iodine adsorptive value obtained by the present invention is 1341 milligrams every gram, and methylene blue adsorption value is 173 milliliters every gram.
Those skilled in the art can make replacement or modification according to content disclosed by the invention and the art technology grasped to content of the present invention; but these replacements or modification should not be considered as disengaging the present invention design, and these replacements or modification are all in the interest field of application claims protection.
Claims (1)
1. utilize the pinecone, rice husk, corn stalk to prepare a method for gac, comprise the steps:
(1) choose the pinecone, rice husk, corn stalk mix according to the ratio of weight ratio 1:2:1, dry 18 hours at the temperature of 115 degrees Celsius;
(2) mixture after step 1 being dried is crushed to particle diameter about 1.8mm, obtains feed particles;
(3) feed particles in step 2 is mixed to obtain mixture according to the ratio of potassium hydroxide and salt of wormwood weight ratio 1:2:1, add the water of 46 degrees Celsius with weight such as mixtures, flood 18 hours;
(4) material after the dipping in step 3 is put into microwave oven, carbonization-activation 7 minutes under the microwave exposure power of 400W;
(5) adopt the hydrochloric acid of 1.5 moles often liter to boil 40 minutes under 85 degrees Celsius material after the activation in step 4, then rinsing, to neutral, is then dried 10 hours under 130 degrees Celsius in pure water;
(6) drying material in step 5 is ground, and adopt 160 orders, 200 orders and 240 object sieves to carry out screening acquisition three grades of fineness gacs, in 160 orders, 200 orders and 240 orders order, they are mixed to form the finished product according to the ratio of weight ratio 1:3:2; Obtained activated carbon-iodine adsorptive value is 1332 milligrams every gram.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310496556.XA CN103818904B (en) | 2013-10-21 | 2013-10-21 | A kind of pinecone, rice husk, corn stalk prepare the method for gac |
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| CN201310496556.XA CN103818904B (en) | 2013-10-21 | 2013-10-21 | A kind of pinecone, rice husk, corn stalk prepare the method for gac |
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| CN103818904A CN103818904A (en) | 2014-05-28 |
| CN103818904B true CN103818904B (en) | 2015-09-23 |
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Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109319777A (en) * | 2018-11-21 | 2019-02-12 | 江苏大学 | A kind of pinecone base prepares the method and its application of biological activated carbon |
| CN109721044B (en) * | 2018-12-24 | 2022-02-15 | 哈尔滨工业大学 | Preparation method and application of three-dimensional porous biochar derived from cones |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1970444A (en) * | 2006-12-07 | 2007-05-30 | 湖南大学 | Microwave radiation method for preparing activated carbon with high specific surface area |
| CN101643208A (en) * | 2009-01-16 | 2010-02-10 | 徐克文 | Composite biological activated carbon and rapid preparation method thereof |
| CN102249228A (en) * | 2011-06-14 | 2011-11-23 | 江苏技术师范学院 | Method for preparing activated carbon from pinecone |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1970444A (en) * | 2006-12-07 | 2007-05-30 | 湖南大学 | Microwave radiation method for preparing activated carbon with high specific surface area |
| CN101643208A (en) * | 2009-01-16 | 2010-02-10 | 徐克文 | Composite biological activated carbon and rapid preparation method thereof |
| CN102249228A (en) * | 2011-06-14 | 2011-11-23 | 江苏技术师范学院 | Method for preparing activated carbon from pinecone |
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Effective date of registration: 20170724 Address after: Licheng Town East Street Liyang city 213300 Jiangsu city of Changzhou province No. 182 Patentee after: Liyang Technology Development Center Address before: Li Town of Liyang City, Jiangsu province 213300 Changzhou City Dongmen Street No. 67 Patentee before: LIYANG ZHEDA ACADEMIA RESEARCH SERVICE CENTER CO., LTD. |